Properties of Highly Filled, Highly Plasticized, Semicrystalline Polymer Networks

1991 ◽  
Vol 64 (2) ◽  
pp. 181-201 ◽  
Author(s):  
Richard D. Vargo ◽  
Frank N. Kelley
Keyword(s):  
Tensile Strength ◽  
Mechanical Response ◽  
Polymer Networks ◽  
Three Dimensional ◽  
Important Variable ◽  
Failure Behavior ◽  
Energy Data ◽  
Viscoelastic Effects ◽  
Tearing Energy ◽  
Increasing Temperature

Abstract 1. Component reactivity of ingredients such as fillers and plasticizers is significant and is measurable by a technique developed during this work. 2. The undesirable syneresis problem common to these highly plasticized materials can be controlled through adjusting equivalence ratios. Syneresis can be controlled primarily by decreasing the crystallinity of the material. 3. Changing percent crystallinity with temperature is a very important variable controlling the physical properties, i.e., ultimate properties, tearing energy, and dynamic-mechanical response. 4. The tearing energy data did not display simple amorphous behavior, and, as such, could not be shifted using a reduced variables technique such as WLF shifting. All variables were needed to represent the data. Three dimensional plotting developed previously by von Merrwall et al. was utilized to represent the data. The resulting tear-energy data exhibit the normal viscoelastic effects of rate and temperature as well as the superposition of the effects of crystallinity on the tearing energy. A decrease in tearing energy with increasing temperature is primarily due to increasing crystallinity in the samples. Plasticizer decreased the tearing energy, while filler increased the tearing energy. Filler lessened the effects of temperature and plasticizer on tearing energy. 5. Ultimate property measurements using ring samples for these model propellants revealed that these materials did not behave in a simple thermo-rheological manner, since crystallinity effects are predominant in the tensile mode. Because of crystallinity and strain-induced crystallinity, the data could not be represented by a failure envelope as proposed by Smith. The presence of plasticizer has the effect of decreasing the tensile strength, while filler tends to increase the tensile strength for the plasticized systems. 6. A model is presented to explain the high strain-to-failure behavior of these systems. Further details of this work can be found in Reference 22.

Strength Analysis of Syntactic Foams Using a Three-Dimensional Continuum Damage Finite Element Model

2015 ◽  
Vol 82 (2) ◽  
Author(s):  
Yejie Shan ◽  
Guodong Nian ◽  
Qiang Xu ◽  
Weiming Tao ◽  
Shaoxing Qu
Keyword(s):  
Finite Element ◽  
Tensile Strength ◽  
Volume Fraction ◽  
Three Dimensional ◽  
Syntactic Foam ◽  
Interfacial Strength ◽  
Strength Analysis ◽  
Failure Behavior ◽  
Fe Model ◽  
Syntactic Foams

The failure behavior of the syntactic foams is investigated based on a three-dimensional (3D) micromechanical finite element (FE) model, by varying the volume fraction, the wall thickness of the hollow particles, and the interfacial strength. The maximum principal stress criterion is adopted to determine the state (damaged or undamaged) for both interface and matrix. Material property degradation is used to describe the mechanical behavior of those damaged elements. The current model can reasonably predict the tensile strength of the syntactic foams with high volume fractions (40%–60%). The failure mechanism of the syntactic foam under uniaxial tension is captured by analyzing the stress–strain curves and the contours of damaging evolution process. Results from the quantitative simulations demonstrate that the tensile strength of the syntactic foam can be improved effectively by enhancing the interfacial strength.

scholarly journals A Spherical Indentation Study on the Mechanical Response of Selected Rocks in the Range from Very Hard to Soft with Particular Interest to Drilling Application

2020 ◽  
Vol 53 (12) ◽  
pp. 5809-5821
Author(s):  
M. Saadati ◽  
K. Weddfelt ◽  
P.-L. Larsson
Keyword(s):  
Tensile Strength ◽  
Compressive Strength ◽  
Mechanical Response ◽  
Three Dimensional ◽  
Spherical Shape ◽  
Spherical Indentation ◽  
Rock Classification ◽  
Compaction Behavior ◽  
Drill Bits ◽  
Close Condition

AbstractThe focus of this work is toward an investigation of the mechanical response of a variety of rocks to indentation loading as a close condition to drilling application. A rock classification method is introduced based on the mechanical response of the rock when loaded by a spherical indenter. Spherical shape is selected for the indenter as a common geometry, which to some extent represents most of the new or worn inserts in drill bits. Both of the force–penetration and fragmentation responses are studied and the results are categorized accordingly. Indentation loading of a quasi-brittle medium like rock contains a complex three-dimensional stress state, in which the compressive strength, tensile strength, compaction behavior and the brittleness of the rock all together are reflected in its mechanical response. Therefore, depending on the type of the rock and its properties, this response is also very diverse for different rocks. Eight types of rocks are investigated and the results from the force–penetration and fragmentation responses are summarized into three different classes.

Construction of plastic contact deformation maps on ceramics: a case study on aluminum nitride

1996 ◽  
Vol 54 ◽  
pp. 636-637
Author(s):  
D. L. Callahan
Keyword(s):  
Plastic Deformation ◽  
Aluminum Nitride ◽  
Mechanical Response ◽  
Three Dimensional ◽  
Bright Field Image ◽  
Perfectly Plastic ◽  
Contrast Analysis ◽  
Deformation Patterns

Modern polishing, precision machining and microindentation techniques allow the processing and mechanical characterization of ceramics at nanometric scales and within entirely plastic deformation regimes. The mechanical response of most ceramics to such highly constrained contact is not predictable from macroscopic properties and the microstructural deformation patterns have proven difficult to characterize by the application of any individual technique. In this study, TEM techniques of contrast analysis and CBED are combined with stereographic analysis to construct a three-dimensional microstructure deformation map of the surface of a perfectly plastic microindentation on macroscopically brittle aluminum nitride.The bright field image in Figure 1 shows a lg Vickers microindentation contained within a single AlN grain far from any boundaries. High densities of dislocations are evident, particularly near facet edges but are not individually resolvable. The prominent bend contours also indicate the severity of plastic deformation. Figure 2 is a selected area diffraction pattern covering the entire indentation area.

Tensile properties of finger-jointed lumber under high-temperature and oxygen-free conditions

Holzforschung ◽  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Kong Yue ◽  
Feng Wang ◽  
Weidong Lu ◽  
Zhongqiu Tang ◽  
Zhangjing Chen ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Tensile Properties ◽  
High Temperatures ◽  
Variable Temperature ◽  
Physical Property ◽  
Solid Wood ◽  
Nitrogen Atmosphere ◽  
Thermal Physical Property ◽  
Electron Microscopy Analysis ◽  
Increasing Temperature

Abstract A model for engineered wood was developed that considers the parallel-to-grain tensile strength of finger-jointed lumber at high temperatures relevant to fire conditions. The finger-jointed lumber was composed of Douglas fir, larch, and poplar wood with phenol-resorcinol-formaldehyde (PRF) as an adhesive. The tensile properties of the finger-jointed lumber were evaluated at high temperatures under oxygen-free conditions, i.e. in a nitrogen atmosphere. A combination of chemical and thermal-physical property analysis of the PRF adhesive and microscopic observations on the glueline was used to discuss the reduction of tensile strength of the parallel-to-grain finger-jointed lumber at variable temperature. The results show that the tensile strength of the finger-jointed lumber decreased linearly with increasing temperature. The parallel-to-grain tensile strength of the PRF finger-jointed samples at 20 and 280 °C were 84 and 5% of the tensile strength of the solid wood at 20 °C, respectively. The thermal-physical properties and scanning electron microscopy analysis revealed that the pyrolysis intensity of the PRF adhesive was lower than that of the wood at 220 °C or higher.

Effect of Filler Dispersion on Tensile Strength and Tearing Energy of Natural Rubber (NR) Latex Films

2015 ◽  
Vol 1134 ◽  
pp. 56-60 ◽  
Author(s):  
Siti Aisyah Jarkasi ◽  
Dzaraini Kamarun ◽  
Azemi Samsuri ◽  
Amir Hashim Md Yatim
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Latex Film ◽  
High Tensile Strength ◽  
Latex Films ◽  
Optimum Amount ◽  
Dispersing Agent ◽  
Two Factors ◽  
Filler Dispersion ◽  
Tearing Energy

Fillers play important roles in enhancing mechanical properties of NR latex films. The effect of filler dispersion and amount of dispersing agent to the tensile strength and tearing energy of NR latex films were investigated in this study. The studies were carried out by (i) varying the amount of dispersing agent (Anchoid) added which is an anionic surfactant; and (ii) varying the speed of stirring during mixing of latex with compounding ingredients. It was observed that tensile strength and tearing energy were affected by both factors listed. In the case of NR latex film filled with 10 pphr of carbon black (Super Abrasion Furnace, SAF), the optimum stirring speed was 400 rpm and the optimum amount of surfactant was in the range of 5 to 10 % by weight. High tensile strength ranging from 29 - 31 MPa and high tearing energies ranging from 90.6 - 111.0 kJ/m2were achieved from optimization of these two factors; rendering their importance.

scholarly journals Three-dimensional thermomechanical converting of CTMP substrates: effect of bio-based strengthening agents and new mineral filling concept

Cellulose ◽  
2021 ◽  
Vol 28 (15) ◽  
pp. 9751-9768
Author(s):  
Teija Laukala ◽  
Sami-Seppo Ovaska ◽  
Ninja Kerttula ◽  
Kaj Backfolk
Keyword(s):  
Tensile Strength ◽  
Elastic Modulus ◽  
Three Dimensional ◽  
Microfibrillated Cellulose ◽  
New Mineral ◽  
Thermomechanical Pulp ◽  
Cationic Starch ◽  
Precipitated Calcium Carbonate ◽  
Filling Method ◽  
Positive Effect

AbstractThe effects of bio-based strengthening agents and mineral filling procedure on the 3D elongation of chemi-thermomechanical pulp (CTMP) handsheets with and without mineral (PCC) filling have been investigated. The 3D elongation was measured using a press-forming machine equipped with a special converting tool. The strength of the handsheets was altered using either cationic starch or microfibrillated cellulose. Precipitated calcium carbonate (PCC) was added to the furnish either as a slurry or by precipitation of nano-sized PCC onto and into the CTMP fibre. The 3D elongation of unfilled sheets was increased by the dry-strengthening agents, but no evidence on the theorised positive effect of mineral fill on 3D elongation was seen in either filling method. The performance of the strengthening agent depended on whether the PCC was as slurry or as a precipitated PCC-CTMP. The starch was more effective with PCC-CTMP than when the PCC was added directly as a slurry to the furnish, whereas the opposite was observed with microfibrillated cellulose. The 3D elongation correlated positively with the tensile strength, bursting strength, tensile stiffness, elastic modulus and bending stiffness, even when the sheet composition was varied, but neither the strengthening agent nor the method of PCC addition affected the 3D elongation beyond what was expectable based on the tensile strength of the sheets. Finally, mechanisms affecting the properties that correlated with the 3D elongation are discussed.

Stress-strain curve of paper revisited

2012 ◽  
Vol 27 (2) ◽  
pp. 318-328 ◽  
Author(s):  
Svetlana Borodulina ◽  
Artem Kulachenko ◽  
Mikael Nygårds ◽  
Sylvain Galland
Keyword(s):  
Three Dimensional ◽  
Strain Curve ◽  
Failure Behavior ◽  
Three Dimensional Model ◽  
Stress Strain Curve ◽  
Stress Strain ◽  
Fiber Network ◽  
Bonding Parameters ◽  
Particle Level ◽  
The Impact

Abstract We have investigated a relation between micromechanical processes and the stress-strain curve of a dry fiber network during tensile loading. By using a detailed particle-level simulation tool we investigate, among other things, the impact of “non-traditional” bonding parameters, such as compliance of bonding regions, work of separation and the actual number of effective bonds. This is probably the first three-dimensional model which is capable of simulating the fracture process of paper accounting for nonlinearities at the fiber level and bond failures. The failure behavior of the network considered in the study could be changed significantly by relatively small changes in bond strength, as compared to the scatter in bonding data found in the literature. We have identified that compliance of the bonding regions has a significant impact on network strength. By comparing networks with weak and strong bonds, we concluded that large local strains are the precursors of bond failures and not the other way around.

Molecular dynamics study on the mechanical response and failure behaviour of graphene: performance enhancement via 5–7–7–5 defects

RSC Advances ◽  
2016 ◽  
Vol 6 (31) ◽  
pp. 26361-26373 ◽  
Author(s):  
G. Rajasekaran ◽  
Avinash Parashar
Keyword(s):  
Molecular Dynamics ◽  
Tensile Strength ◽  
Structural Properties ◽  
Elastic Moduli ◽  
Mechanical Response ◽  
Performance Enhancement ◽  
Structural Defects ◽  
Thick Sheet ◽  
Failure Behaviour ◽  
Production Techniques

A one atom-thick sheet of carbon exhibits outstanding elastic moduli and tensile strength in its pristine form but structural defects which are inevitable in graphene due to its production techniques can alter its structural properties.

scholarly journals Mechanical Response of Al-1.09Mg2Si Alloy under Varying Mould and Thermal Ageing Conditions

2012 ◽  
Vol 2012 ◽  
pp. 1-7
Author(s):  
O. I. Sekunowo ◽  
G. I. Lawal ◽  
S. O. Adeosun
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Ultimate Tensile Strength ◽  
Ambient Temperature ◽  
Mechanical Response ◽  
Ageing Time ◽  
Thermal Ageing ◽  
Alloy Ingot ◽  
Solution Treated ◽  
Crucible Furnace

Samples of the 6063 (Al-1.09Mg2Si) alloy ingot were melted in a crucible furnace and cast in metal and sand moulds, respectively. Standard tensile, hardness, and microstructural test specimens were prepared from cast samples, solution treated at 520∘C, soaked for 6 hrs, and immediately quenched at ambient temperature in a trough containing water to assume a supersaturated structure. The quenched specimens were then thermally aged at 175∘C for 3–7 hrs. Results show that at different ageing time, varied fractions of precipitates and intermetallics evolved in the specimens’ matrices which affect the resulting mechanical properties. The metal mould specimens aged for four hours (MTA-4) exhibited superior ultimate tensile strength of 247.8 MPa; microhardness, 68.5 HV; elongation, 28.2% . It is concluded that the extent of improvement in mechanical properties depends on the fractions, coherence, and distribution of precipitates along with the type of intermetallics developed in the alloy during ageing process.

Tensile Properties of Low Nickel Austenitic Stainless Steel at Elevated Temperatures

2012 ◽  
Vol 159 ◽  
pp. 346-350
Author(s):  
Shu Min Liu ◽  
Jian Bin Zhang
Keyword(s):  
Tensile Strength ◽  
Stainless Steel ◽  
Elevated Temperatures ◽  
Peak Stress ◽  
Temperature Curve ◽  
Delta Ferrite ◽  
Cross Sectional ◽  
Different Temperatures ◽  
Increasing Temperature ◽  
Reduction Percentage

The elevated temperature short-time tensile test with the sample of casting low nickel stainless steel was conducted on SHIMADZU AG-10 at ten temperatures 300, 500, 600, 700, 800, 950, 1000, 1050, 1100, and 1250°C, respectively. The stress-strain curves with the thermal deformation at the different temperatures, the peak stress intensity-temperature curve, and the reduction percentage of cross sectional area-temperature curve were obtained. Metallographic test samples were prepared and the morphology of deforming zone was observed by optical microscopy. The experimental results show that the tensile strength of the test samples decreases with increasing temperature. From 300 to 800°C, the work harding occurred and the tensile strength increases with increasing strain. The work softening occurred and the tensile strength decreases with increasing strain at temperatures of 800 to 1250°C. The minimum value of reduction percentage was measured at 800 °C. The austenite and delta-ferrite are the main phase in the tested samples. When the tensile temperatures are increased to 1200°C, the delta-ferrite became thinner and broke down to be spheroidized.

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