The Effect of Network Formation on the Rheological Properties of SBR Modified Asphalt Binders

1997 ◽  
Vol 70 (2) ◽  
pp. 256-263 ◽  
Author(s):  
Yong-Joon Lee ◽  
Lawrence M. France ◽  
Martin C. Hawley
Keyword(s):  
Rheological Properties ◽  
Laser Scanning ◽  
Network Formation ◽  
Complex Modulus ◽  
Mechanical Analysis ◽  
Global Network ◽  
Asphalt Binders ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Local Networks

Abstract Styrene-butadiene rubber (SBR) was used to modify asphalt binders. The rheological and thermo-mechanical properties of the binders were investigated using rotational viscometry, dynamic shear rheometry, and thermal mechanical analysis. The optimum SBR content and mixing procedure were determined based on the rheological properties of the asphalt/SBR blends. The addition of 3–5% (w/w) SBR resulted in enhanced high temperature performance of the binders. The SBR progresses from a dispersed polymer to local networks to a global network with increasing SBR content. This phenomenon is exhibited in rheological properties such as complex modulus and melt viscosity. It is also verified visually by using a Laser Scanning Confocal Microscope. Because of this network formation, the binders showed a large increase in the complex modulus which indicates resistance to rutting.

Investigation on Preparation and Performance of Micro-Powder Rubber Modified Asphalt

2009 ◽  
Vol 620-622 ◽  
pp. 351-354
Author(s):  
Cong Hui Liu ◽  
Shao Peng Wu ◽  
Hong Wang ◽  
Yuan Zhang
Keyword(s):  
Storage Stability ◽  
Complex Modulus ◽  
Asphalt Binders ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Modified Asphalt ◽  
The Difference ◽  
And Performance ◽  
High And Low Temperatures ◽  
Soft Point

One micro-powder rubber (styrene butadiene rubber-SBR) at three concentration levels are used for manufacturing polymer modified asphalt with a mixing technique. The effects of concentration of modifiers and mixing temperature on the mechanical properties of the compounds are investigated. Based on a limited study, test results indicate that micro-powder rubbers have positive effect on the performance of asphalt in low temperature. Soft point, penetration and ductility show that the ideal percentage of rubber additive (7 wt. %) and preparing temperature (210°C) are brought forward. The fluorescence microscopy test indicates that rubbers are homogeneous dispersed in asphalt and have a little dissolving at the surface of the ultra-fine rubbers. The difference between soft point values in the high temperature storage stability test is only 0.2~0.5°C, which proves that modified asphalts have good storage stability. Complex modulus master curves are drawn to analyze and compare the rheological properties of various modified asphalts. Results indicate that modified asphalt binders have more excellent properties at both high and low temperatures, compared with original asphalt.

scholarly journals Influence of Treated Distillate Aromatic Extract (TDAE) Content and Addition Time on Rubber-Filler Interactions in Silica Filled SBR/BR Blends

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 698
Author(s):  
Selin Sökmen ◽  
Katja Oßwald ◽  
Katrin Reincke ◽  
Sybill Ilisch
Keyword(s):  
Mechanical Properties ◽  
Oil Content ◽  
Tensile Modulus ◽  
Mechanical Analysis ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Binary Blends ◽  
Rubber Layer ◽  
Processing Aids ◽  
Rubber Filler

High compatibility and good rubber–filler interactions are required in order to obtain high quality products. Rubber–filler and filler–filler interactions can be influenced by various material factors, such as the presence of processing aids. Although different processing aids, especially the plasticizers, and their effects on compatibility have been investigated in the literature, their influence on rubber–filler interactions in highly active filler reinforced mixtures is not explicit and has not been investigated in depth. For this purpose, the influence of treated distillate aromatic extract (TDAE) oil content and its addition time on interactions between silica and rubber chains were investigated in this study. Rubber–filler and filler–filler interactions of uncured and cured silica-filled SBR/BR blends were characterized by using rubber layer L concept and dynamic mechanical analysis, whereas mechanical properties were studied by tensile test and Shore A hardness. Five parts per hundred rubber (phr) TDAE addition at 0, 1.5, and 3 min of mixing were characterized to investigate the influence of TDAE addition time on rubber–filler interactions. It was observed that addition time of TDAE can influence the development of bounded rubber structure and the interfacial interactions, especially at short time of mixing, less than 5 min. Oil addition with silica at 1.5 min of mixing resulted in fast rubber layer development and a small reduction in storage shear modulus of uncured blends. The influence of oil content on rubber–filler and filler–filler interactions were investigated for the binary blends without oil, with 5 and 20 phr TDAE content. The addition of 5 phr oil resulted in a slight increase in rubber layer and 0.05 MPa reduction in Payne effect of uncured blends. The storage tensile modulus of vulcanizates at small strains decreased from 13.97 to 8.28 MPa after oil addition. Twenty parts per hundred rubber (phr) oil addition to binary blends caused rubber layer L to decrease from 0.45 to 0.42. The storage tensile modulus of the vulcanizates and its reduction with higher amplitudes were incontrovertibly high among the vulcanizates with lower oil content, which were 13.57 and 4.49 MPa, respectively. When any consequential change in mechanical properties of styrene–butadiene rubber (SBR)/butadiene rubber (BR) blends could not be observed at different TDAE addition time, increasing amount of oil in blends enhanced elongation at break, and decreased Shore A hardness and tensile strength.

scholarly journals Hybrid Silica-Based Fillers in Nanocomposites: Influence of Isotropic/Isotropic and Isotropic/Anisotropic Fillers on Mechanical Properties of Styrene-Butadiene (SBR)-Based Rubber

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2413
Author(s):  
Mariapaola Staropoli ◽  
Vincent Rogé ◽  
Enzo Moretto ◽  
Joffrey Didierjean ◽  
Marc Michel ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Silica Nanoparticles ◽  
Synergetic Effect ◽  
Mechanical Analysis ◽  
Rubber Matrix ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Precipitated Silica ◽  
Scanning Transmission ◽  
Styrene Butadiene

The improvement of mechanical properties of polymer-based nanocomposites is usually obtained through a strong polymer–silica interaction. Most often, precipitated silica nanoparticles are used as filler. In this work, we study the synergetic effect occurring between dual silica-based fillers in a styrene-butadiene rubber (SBR)/polybutadiene (PBD) rubber matrix. Precipitated Highly Dispersed Silica (HDS) nanoparticles (10 nm) have been associated with spherical Stöber silica nanoparticles (250 nm) and anisotropic nano-Sepiolite. By imaging filler at nano scale through Scanning Transmission Electron Microscopy, we have shown that anisotropic fillers align only in presence of a critical amount of HDS. The dynamic mechanical analysis of rubber compounds confirms that this alignment leads to a stiffer nanocomposite when compared to Sepiolite alone. On the contrary, spherical 250 nm nanoparticles inhibit percolation network and reduce the nanocomposite stiffness.

The effect of styrene-butadiene rubber modification on the properties of asphalt binders: Aging and restoring

2022 ◽  
Vol 316 ◽  
pp. 126034
Author(s):  
Tiankai Che ◽  
Baofeng Pan ◽  
Yudong Li ◽  
Dongdong Ge ◽  
Dongzhao Jin ◽  
...  
Keyword(s):  
Asphalt Binders ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Styrene Butadiene ◽  
Rubber Modification

scholarly journals Dynamo-mechanical analysis of rubbers with mineral fillers in comparison with fillers widely used in the tire industry

2021 ◽  
pp. 05-13
Author(s):  
Oleg K. Garishin ◽  
◽  
Anton Y. Beliaev ◽  
Keyword(s):  
Experimental Testing ◽  
Loss Modulus ◽  
Mechanical Analysis ◽  
Operating Conditions ◽  
Styrene Butadiene Rubber ◽  
Structural Level ◽  
Butadiene Rubber ◽  
Tire Industry ◽  
Mineral Fillers ◽  
Styrene Butadiene

The work is devoted to the study of nanocomposites based on synthetic (styrene-butadiene) rubber with different fillers not previously used. The issue of using composites with alternative fillers is being investigated. The results of experimental testing and analysis of thermo-visco-elastic behav-ior of styrene-butadiene rubbers filled by various mineral particles of micro and nanosize, as well as pyrolysis products of organic food waste, are presented. The filled elastomers discussed in this work are mainly used in the tire industry to improve the performance of tires. All samples were tested on a dynamo-mechanical analyzer (DMA). Temperature and frequency dependences of the dynamic modulus and loss modulus are plotted for each of the composites. The frequency charac-teristics corresponded to the real range of rotation speeds of the car wheel, and the temperature var-ied from –50 to +50ºC. A comparative analysis of the results obtained was carried out. The struc-tural mechanisms of the filler are not investigated. It is assumed that the principles of operation of the investigated fillers at the structural level are similar to those described in many works for clas-sical fillers. Based on the test results a conclusion about the preferable operating conditions for the considered materials was made.

scholarly journals Evaluating the Rheological Properties of High-Modulus Asphalt Binders Modified with Rubber Polymer Composite Modifier

Materials ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 7727
Author(s):  
Xiaorui Zhang ◽  
Chao Han ◽  
Jun Yang ◽  
Xinquan Xu ◽  
Fan Zhang
Keyword(s):  
Low Temperature ◽  
Rheological Properties ◽  
Polymer Composite ◽  
Complex Modulus ◽  
Asphalt Binder ◽  
Climatic Conditions ◽  
Morphological Properties ◽  
Asphalt Binders ◽  
High Modulus ◽  
Petroleum Asphalt

With the increasing traffic loading and changing climatic conditions, there is a need to use novel superior performing pavement materials such as high-modulus asphalt binders and asphalt mixtures to mitigate field distress such as rutting, cracking, etc. This laboratory study was thus conducted to explore and substantiate the usage of Rubber Polymer Composite Modifier (RPCM) for high-modulus asphalt binder modification. The base asphalt binder used in the study comprised A-70# Petroleum asphalt binder with RPCM dosages of 0.25%, 0.30%, 0.35%, 0.40% and 0.45%, separately. The laboratory tests conducted for characterizing the asphalt binder rheological and morphological properties included the dynamic mechanical analysis (DM), temperature-frequency sweep in the dynamic shear rheometer (DSR) device, bending beam rheometer (BBR), and florescence microscopic (FM) imaging. The corresponding test results exhibited satisfactory compatibility and potential for using RPCM as a high-modulus asphalt binder modifier to enhance the base asphalt binder’s rheological properties, both with respect to high- and low-temperature performance improvements. For the A-70# Petroleum asphalt binder that was evaluated, the optimum RPCM dosage was found to be 0.30–0.35%. In comparison to styrene–butadiene–styrene (SBS), asphalt binder modification with RPCM exhibited superior high-temperature rutting resistance properties (as measured in terms of the complex modulus and phase angle) and vice versa for the low-temperature cracking properties. Overall, the study beneficially contributes to the literature through provision of a reference datum toward the exploratory usage of RPCM for high-modulus asphalt binder modification and performance enhancements.

scholarly journals Mechanistic-empirical evaluation of specific polymer-modified asphalt binders effect on the rheological performance

2020 ◽  
Vol 103 (4) ◽  
pp. 003685042095987
Author(s):  
Ghazi G Al-Khateeb ◽  
Waleed Zeiada ◽  
Mohammed Ismail ◽  
Ahmad Shabib ◽  
Adel Tayara
Keyword(s):  
Rheological Properties ◽  
Laboratory Tests ◽  
Complex Modulus ◽  
Heavy Traffic ◽  
Asphalt Binder ◽  
Empirical Evaluation ◽  
Asphalt Binders ◽  
Modified Asphalt ◽  
Pavement Structures ◽  
Polymer Modified Asphalt

Major distresses such as rutting, fatigue, and thermal cracking are facing asphalt pavement structures due to continuous heavy traffic loading and climate change. The modification of asphalt binders (one of the main components of the asphalt paving mix) has the potential to mitigate distresses through using different additives. Polymer modified asphalt (PMA) binders showed a noticeable resistance to pavement distresses as reported in previous studies. The present study aims to evaluate the effect of polymer modification on the rheological properties of asphalt binders through laboratory tests. The polymers included styrene-butadiene-styrene (SBS) and epolene emulsifiable (EE2) types. The 60/70 binder was used as a control for comparison. The Mechanistic-Empirical Pavement Design Guide (MEPDG) was also utilized to simulate the effect of PMA binders on the rheological properties under different climatic conditions and structural capacities. Additionally, the MEPDG was further utilized to compare the effect of asphalt binders on rheological properties using four different binder input levels. Findings of the study showed that laboratory tests experienced varying outcomes regarding the most efficient asphalt binder by means of distresses resistance. However, the MEPDG evaluation showed that the overall ranking of asphalt binders positively impacting the rheological properties was as following: (1) 4.5% EE2 PMA, (2) 4% EE2 PMA, (3) 60/70 binder, (4) 5% SBS PMA, and (5) 4% SBS PMA binders. Furthermore, statistical analysis illustrated that the effect of using different binder input levels on the performance of pavement varied relatively to the evaluated distresses. The analysis showed that using different binder input levels would affect, to a certain extent, the asphalt binder influence on rheological properties only when evaluating rutting and fatigue distresses. Therefore, it is recommended that precise asphalt binder inputs, that is, shear complex modulus (G*) and phase angle (δ) are used when designing pavement structures in regions with hot and mild climate conditions.

FURTHER EVIDENCE OF FILLER–FILLER MECHANICAL ENGAGEMENT IN RUBBER COMPOUNDS FILLED WITH SILICA TREATED BY LONG-CHAIN SILANE

2017 ◽  
Vol 90 (3) ◽  
pp. 508-520 ◽  
Author(s):  
Amirhossein Mahtabani ◽  
Mohammad Alimardani ◽  
Mehdi Razzaghi-Kashani
Keyword(s):  
Surface Energy ◽  
Elevated Temperatures ◽  
Network Formation ◽  
Liquid Paraffin ◽  
Rolling Resistance ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Silica Network ◽  
Rubber Compounds ◽  
Long Chain

ABSTRACT The present study discusses that filler–filler mechanical engagement resulting from the grafted long-chain silanes on the silica surface is indeed a reinforcing mechanism in rubber composites, as already speculated by nonlinear viscoelastic properties in our previous study. The existence and severity of such a phenomenon are assessed purely by isolating the energetic contribution of reinforcement from interfering with filler mechanical engagement in the silica network formation and breakdown processes. In a novel approach, the driving force of fillers to flocculate energetically at elevated temperatures was defined using surface energy theories, and it was adjusted to be similar in two composites having silica treated by short- and long-chain silanes. Filler–filler mechanical engagement was monitored by tracking network formation (filler flocculation) in a matrix of styrene–butadiene rubber and also by conducting various dynamic viscoelastic experiments on liquid paraffin suspensions having short- and long-chain silica of similar surface energy. Results consistently confirmed the existence of mechanical engagement between silica particles having the long-chain silane in both rubber compounds and paraffin suspensions. The results may find applications in the rolling resistance of tires, for example, where stabilization of the filler network by displacing the peak energy dissipation of the network breakdown from applied service strains to larger values would be of technical importance.

ACOUSTIC ABSORPTION, RHEOLOGICAL AND MECHANICAL CHARACTERISTICS OF WASTE EGG BOXES FIBERS FILLED SBR

2015 ◽  
Vol 77 (1) ◽  
Author(s):  
Bashir Algaily ◽  
Sombat Puttajukr ◽  
Thoranit Navarat
Keyword(s):  
Rheological Properties ◽  
Nonlinear Behavior ◽  
Strain Curve ◽  
Noise Pollution ◽  
Primary Component ◽  
Styrene Butadiene Rubber ◽  
Experimental Investigations ◽  
Acoustic Absorption ◽  
Butadiene Rubber ◽  
Design And Optimization

There are a few interesting to develop a procedure for design material with high acoustic absorption with broad acoustic frequencies range  and assess the potential of using waste living materials as the primary component in the production of sound absorbing materials for use in walls and ceilings. This research provides experimental investigations for design and optimization of composite sound absorbers with styrene butadiene rubber (SBR) and waste egg boxes (EB) fibers. The SBR/EB composites have been investigated for their acoustic absorption at different frequencies, their mechanical and rheological properties. Results indicated that an increasing EB composition enhanced the acoustic absorption coefficient. The density of SBR/EB composites were directly related to the presence of the EB fibers. The principal experimental evidences of nonlinear behavior of viscoelastic materials were discussed by investigating the stress-strain curve. In view of the rheological properties, the SBR/EB composites showed shear thinning behavior at various different conditions, that the apparent viscosity reduced with increasing shear rates and it was greater temperature sensitivity. Eventually, the data obtained clearly indicated that the heterogeneity and the viscosity of the materials play very important factors to provide suitable absorbers, these new materials were beneficial for using as a sound absorber and could be used as an alternative replacement for conventional product because for instance, they are cheaper, nonabrasive and may serve to reduce the noise pollution.

Preferential Media for Abrasive Flow Machining

2009 ◽  
Vol 131 (1) ◽  
Author(s):  
Kamal K. Kar ◽  
N. L. Ravikumar ◽  
Piyushkumar B. Tailor ◽  
J. Ramkumar ◽  
D. Sathiyamoorthy
Keyword(s):  
Rheological Properties ◽  
Testing Machine ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Abrasive Flow Machining ◽  
Wide Range ◽  
Good Improvement ◽  
Temperature Shear ◽  
Styrene Butadiene ◽  
Surface Improvement

The abrasive flow machining (AFM) is used to deburr, radius, polish and remove recast layer of components in a wide range of applications. Material is removed from the workpiece by a flowing semisolid mass across the surface to be finished. In this study a medium for AFM has been developed from the various viscoelastic carriers and has been contrasted through experimental investigation. The viscoelastic media are selected on the basis of existing media through the studies of thermogravimetric analysis and are characterized by mechanical, as well as rheological, properties with the help of a universal testing machine and a rheometer. The performance of the medium is evaluated through the finishing criteria on a two-way AFM setup. The investigation reveals that the styrene butadiene rubber (SBR) medium gives a good improvement in surface finish. The surface improvement through SBR media is 88%. It is also found that the strain, temperature, shear rate, time of applied constant stress, cyclic loading, etc. have an impact on the mechanical and rheological properties of the newly developed medium, which are ultimately governed by the performance of the medium in the target applications.

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