Effect of Oriented Platy Filler on the Fracture Mechanism of Elastomers
Abstract Through an investigation of tension fatigue failure modes, oriented platy fillers have been found to provide elastomers with a unique failure mechanism which allows the elastomer to resist destructive crack growth. Samples of chlorosulfonated polyethylene containing talc as a reinforcing agent failed in an interlaminar shear mode, parallel to the applied stress. This fracture pattern resulted from diversion of the classical Griffith-type crack which would normally proceed perpendicularly to the stress. The theoretical criterion for diversion requires the adhesive fracture energy, Gad, in the plane of the diverted crack to be about one-tenth of the cohesive fracture energy, Gco, in the plane of the Griffith crack. Measured values of the fracture energies determined by 180° peel (Gad) tests and trouser tear (Gco) tests showed that the talc-filled elastomer satisfied the criterion. However, the criterion was met, not by the introduction of planes of weakness in the lateral direction (thereby reducing Gad), but by a more than five-fold increase in the cohesive fracture energy over that measured for a control containing carbon black as reinforcing agent. Examination of the fractured surfaces by scanning electron microscopy showed that the increase in Gco was due to the many energy absorbing fracture paths down which the tear was diverted as it advanced through the elastomer. Besides exhibiting high tear energies, the elastomer was found to be highly insensitive to stress risers such as razor cuts. The combination of tear resistance and insensitivity to flaws leads to a prediction that elastomers containing oriented platy fillers will exhibit increased strength and durability. This first practical system affording crack diversion has special application to hoses and topologically similar shapes such as boots and sleeves.