Adhesion of marzipan pastes based on dry demineralized whey

10.5219/1351 ◽  
2020 ◽  
Vol 14 ◽  
pp. 1149-1160
Author(s):  
Igor Stadnyk ◽  
Volodymyr Piddubnyi ◽  
Mykhail Kravchenko ◽  
Larysa Rybchuk ◽  
Olena Kolomiiets ◽  
...  
Keyword(s):  
Moisture Absorption ◽  
Surface Effect ◽  
Work Of Adhesion ◽  
Technological Properties ◽  
Adhesive Properties ◽  
Adhesion Properties ◽  
Adhesion Behavior ◽  
Applied Shear Stress ◽  
Confectionery Products ◽  
Positive Effect

The results of researches of rheological and adhesion characteristics of marzipan pastes with dry demineralized whey (DDW) and glycerin are given. The positive effect of dry demineralized whey and glycerin on the characteristics of model compositions of marzipan pastes has been established. The component compatibility of DDW and almonds has been confirmed. It has been experimentally established that DDW and glycerin lead to changes in the structural state of marzipan pastes, changing the quantitative values ​​of rheological characteristics. It is confirmed that with increasing DDW concentration, the indicators of deformation and plasticity increase. The indicators of elasticity and resilience of marzipan paste decrease, which in general leads to an increase in molding ability. The surface effect on the properties of marzipan pastes with dry demineralized whey and glycerin was carried out. The technological expediency of using glycerin in the composition of marzipan pastes with DDW to increase their plasticity and pliability while maintaining high molding properties is substantiated. The rational content of glycerin is established, which allows regulating the adhesion properties within the set limits for paste-like finishing semi-finished products from marzipan masses. The rational content of DDW and glycerin in the composition of marzipan pastes while ensuring high functional and technological properties in the application of confectionery flour on the surface is substantiated. Mathematical modeling of adhesion behavior of marzipan pastes is carried out. The adhesive properties of the pastes are mathematically substantiated and their ability to have flexibility under the action of the applied shear stress is confirmed within the established limits. Its currents are considered and substantiated. A study of moisture absorption by flour confectionery when covered with marzipan paste is provided. The wetting angle is considered and the work of adhesion is determined. Based on researches the directions of use of the developed marzipan pastes in confectionery production as finishing semi-finished products for a covering and as a layer for flour confectionery products and modeling of figured products are offered. 

Simultaneous Analysis of Elastic and Nonspecific Adhesive Properties of Thin Sample and Biological Cell Considering Bottom Substrate Effect

2017 ◽  
Vol 139 (9) ◽  
Author(s):  
Vishwanath Managuli ◽  
Sitikantha Roy
Keyword(s):  
Atomic Force Microscopy ◽  
Correction Term ◽  
Work Of Adhesion ◽  
Common Source ◽  
Substrate Effect ◽  
Adhesive Properties ◽  
Adhesion Properties ◽  
Force Microscopy ◽  
Bottom Substrate ◽  
Atomic Force

A new asymptotically correct contact model has been developed for conical tip based atomic force microscopy (AFM) nanoindentation. This new model provides both elastic and nonspecific adhesion properties of cells and soft gels by taking sample thickness at the point of indentation and its depth of indentation into consideration. The bottom substrate effect (BSE) is the most common source of error in the study of “AFM force maps” of the cellular sample. The present model incorporates an asymptotically correct correction term as a function of depth of indentation to eliminate the substrate effect in the analysis. Later, the model is extended to analyze the unloading portion of the indentation curve to extract the stiffness and adhesive properties simultaneously. A comparative study of the estimated material properties using other established contact models shows that the provided corrections effectively curb the errors coming from infinite thickness assumption. Nonspecific adhesive nature of a cell is represented in terms of adhesion parameter (γa) based on the “work of adhesion,” this is an alternative to the peak value of tip–sample attractive (negative) force commonly used as representative adhesion measurement. The simple analytical expression of the model can help in estimating more realistic and accurate biomechanical properties of cells from atomic force microscopy based indentation technique.

scholarly journals THE DETERMINATION OF THE POSSIBILITY OF OBTAINING OF AN ADHESIVE ADDITIVE TO ROAD BITUMEN PRODUCED FROM LIQUID PRODUCTS OF COAL COKING USING CARBAZOLE

2020 ◽  
Vol 6 ◽  
pp. 27-36
Author(s):  
Yu.V. Prysiazhnyi ◽  
S.V. Pyshyev ◽  
Guri Isaiah ◽  
T.I Chervinskyy ◽  
B.O. Korchak
Keyword(s):  
Functional Groups ◽  
Polymeric Materials ◽  
Softening Temperature ◽  
Raw Material ◽  
Mass Content ◽  
Modified Bitumen ◽  
Adhesive Properties ◽  
Adhesion Properties ◽  
Positive Effect ◽  
Qualitative Characteristics

Coumarone-indene resins (CIR) have been obtained from a narrow coumarone-indene fraction by ionic cooligomerization. To improve the adhesion properties of CIR, nitrogen-containing functional groups have been additionally introduced into them at the stage of synthesis. The positive effect of carbazole on the degree of polymerization of styrene, coumarone and indene was noted. The products obtained (coumarone-indenecarbazole resins – CICR) have been used as modifiers for the road oil bitumen. The analysis of physical and technological indicators of the original and modified bitumen has been carried out in accordance with the standardized methods. The influence has been investigated of the temperature of separation of the unreacted part of the raw material from the CICR on its qualitative characteristics. It has been experimentally proved that the unreacted raw material is completely separated from the resin at a distillation temperature of about 150 °C. The experimental data obtained indicates that CIR, in comparison with CICR, due to its own high softening temperature, increases the same indicator of modified bitumen, however, this effect is achieved when the resin content in the bitumen is too high, namely ≥ 3.0-5.0 % by mass. At the same time, the addition of CIR to bitumen worsens it ductility and penetration. Adhesion is significantly improved, but again with the mass content of CIR in the mixture at the level of 3.0-5.0 % and more. The use of CICR as a modifier showed that this resin has practically no effect on the softening temperature and has a less negative effect on bitumen ductility and penetration, than CIR. At the same time, a positive effect has been observed in relation to the adhesion to glass - this indicator significantly increases even at a mass content of resin in bitumen at the level of 0.5-1.0 %. Thus, coumarone-indene-carbazole resins should be used as an adhesive additive that has a positive effect only on the adhesion of bitumen to a solid surface. In order to improve CIR adhesive properties, nitrogen-containing functional groups were additionally introduced into them at the synthesis stage. The resulting products (coumarone-indene-carbazole resins - CICR) were used as modifiers for road petroleum bitumen. The influence of the temperature of separation of raw materials unreacted part from CICR on its qualitative characteristics was investigated. It was established that the key effect of adding CICR to bitumen is the improvement of adhesive properties of the obtained bituminous-polymeric materials.

scholarly journals 3D-printing on textiles – an investigation on adhesion properties of the produced composite materials

2021 ◽  
Vol 28 (6) ◽  
Author(s):  
Maryna Gorlachova ◽  
Boris Mahltig
Keyword(s):  
3D Printing ◽  
Adhesive Properties ◽  
Adhesion Properties ◽  
Practical Applications ◽  
3D Print ◽  
3D Objects ◽  
Textile Fabrics ◽  
Polylactide Acid ◽  
Polyamide 6.6 ◽  
Textile Sector

AbstractThe actual paper is related to adhesive properties of 3D objects printed on cotton textile fabrics. For practical applications of 3D prints in the textile sector, the adhesion of the printed object on the textile substrate is an important issue. In the current study, two different types of polymers are printed on cotton – polylactide acid (PLA) and polyamide 6.6 (Nylon). Altogether six cotton fabrics differing in structure, weight and thickness are evaluated. Also, the effect of washing and enzymatic desizing is investigated. For printing parameters, best results are gained for elevated process temperatures, intermediate printing speed and low Z-distance between printing head and substrate. Also, a textile treatment by washing and desizing can improve the adhesion of an afterwards applied 3D print. The presented results are quite useful for future developments of 3D printing applications on textile substrates, e.g. to implement new decorative features or protective functions.

scholarly journals Effects of Pre- and Post-Carburizing Surface Modification on the Tribological and Adhesion Properties of Heat-Resistant KHR 45A Steel for Cracking Tubes

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3658
Author(s):  
Auezhan Amanov ◽  
Joo-Hyun Choi ◽  
Young-Sik Pyun
Keyword(s):  
Surface Modification ◽  
Surface Treatment ◽  
Steel Substrate ◽  
Heat Exposure ◽  
Scratch Resistance ◽  
Adhesion Properties ◽  
Heat Resistant ◽  
Adhesion Behavior ◽  
Steel Substrates ◽  
Carburizing Process

In this study, the effects of ultrasonic nanocrystal surface modification (UNSM) technology on the tribological properties and scratch-induced adhesion behavior of a heat-resistant KHR 45A steel cracking tube, which is used for the pyrolysis process, were investigated. The main objective of this study is to investigate the effects of pre- and post-carburizing UNSM treatment on the tribological and adhesion performances of carburized domestic KHR 45A (A) steel and to compare the results with the existing carburized Kubota-made KHR 45A steel (B). A carburizing process was carried out on the polished and UNSM-treated KHR 45A steel substrates, which were cut out from the cracking tube, at 300 °C heat exposure for 300 h. The thickness of the carburizing layer was about 10 μm. UNSM technology was applied as pre- and post-carburizing surface treatment; both reduced the friction coefficient and wear rate compared to that of the carburized KHR 45A steel substrate. It was also found that the application of UNSM technology increased the critical load, which implies the improvement of adhesion behavior between the carburizing layer and the KHR steel substrate. The application of UNSM technology as pre- and post-carburizing surface treatment could help replace carburized Kubota-made KHR 45A steel (B) thanks to the improved tribological performance, enhanced scratch resistance, load bearing capacity, and adhesion of domestic KHR 45A (A) steel.

scholarly journals Experimental and Numerical Peeling Investigation on Aged Multi-Layer Anti-Shatter Safety Films (ASFs) for Structural Glass Retrofit

Symmetry ◽  
2022 ◽  
Vol 14 (1) ◽  
pp. 162
Author(s):  
Silvana Mattei ◽  
Luca Cozzarini ◽  
Chiara Bedon
Keyword(s):  
Young Modulus ◽  
Adhesive Layer ◽  
Experimental Program ◽  
Fe Model ◽  
Structural Glass ◽  
Adhesive Properties ◽  
Test Protocol ◽  
Adhesion Properties ◽  
The Impact ◽  
Pet Films

Anti-shatter safety films (ASFs) are often used for structural glass applications. The goal is to improve the response of monolithic elements and prevent fragments from shattering. Thus, the main reason behind their use is the possibility to upgrade safety levels against the brittle failure of glass and minimize the number of possible injuries. However, the impact response of glass elements bonded with Polyethylene terephthalate (PET)-films and pressure sensitive adhesives (PSAs) still represents a research topic of open discussion. Major challenges derive from material characterization and asymmetrical variability under design loads and ageing. In particular, the measurement of interface mechanical characteristics for the adhesive layer in contact with glass is a primary parameter for the ASF choice optimization. For this reason, the present paper presents an experimental campaign aimed at calibrating some basic mechanical parameters that provide the characterization of constitutive models, such as tensile properties (yielding stress and Young modulus) for PET-film and adhesive properties for PSA (energy fracture and peel force). In doing so, both tensile tests for PET-films and peeling specimens are taken into account for a commercially available ASF, given that the peeling test protocol is one of most common methods for the definition of adhesion properties. Moreover, an extensive calibration of the Finite Element (FE) model is performed in order to conduct a parametric numerical analysis of ASF bonded glass solutions. Furthermore, a Kinloch approach typically used to determine the fracture energy of a given tape by considering a variable peel angle, is also adopted to compare the outcomes of calibration analyses and FE investigations on the tested specimens. Finally, a study of the effect of multiple aspects is also presented. The results of the experimental program and the following considerations confirm the rate dependence and ageing dependence in peel tests.

scholarly journals Production of modified adhesive composites based on EVA and modified PE

2020 ◽  
pp. 45-47
Author(s):  
M. D. Sizova ◽  
A. N. Zelenetsky ◽  
V. Ya. Ivolgin
Keyword(s):  
Maleic Anhydride ◽  
Polymer Matrix ◽  
Morphological Changes ◽  
Adhesive Properties ◽  
Adhesion Properties ◽  
High Adhesion

An adhesive based on EVA and LDPE is developed which can be used up to 60°C. It was modified by polyisocyanate fragments of a grafted and reticulate nature for structural and morphological changes of the polymer matrix and improvement of physical, mechanical and adhesive properties. For additional compatibilization of the components, LDPE modified with maleic anhydride (MA) was used. High adhesion properties of the obtained composites were confirmed.

scholarly journals Justification of sorption composite usage on the basis of nanodisperse silica for sepsis prevention in complex treatment of purulent-inflammatory processes

2019 ◽  
Vol 41 part 3 (2) ◽  
pp. 45-50
Author(s):  
O. A. Viltsaniuk ◽  
P. V. Belyaev ◽  
T. P. Osolodchenko ◽  
O. O. Viltsaniuk
Keyword(s):  
Antimicrobial Activity ◽  
Antimicrobial Properties ◽  
Statistical Processing ◽  
Toxic Substances ◽  
Adhesive Properties ◽  
Adhesion Properties ◽  
E Coli ◽  
Adhesion Ability ◽  
Treatment And Prevention ◽  
Inflammatory Processes

Introduction. The problem of purulent-inflammatory processes treatment and the prevention of sepsis remains one of the most pressing problems of surgery.Purpose of the study. Is to estimate the effectiveness of sorption composition with antimicrobial properties on the basis of nanodisperse silica on the adhesive properties of microorganisms and to substantiate the expediency of its use for the purulent and inflammatory processes treatment and prevention of sepsis.Materials and methods.To determine the antimicrobial activity and the influence of the antiseptics of decasan, myramistin, ethonium, chlorhexidine and the sorption on the microorganisms adhesion properties composition was used the method of diffusion in agar of the museum strains of microorganisms S. Aureus ATCC 25923, E. Coli ATCC 25922, R. Vulgaris 4636, R. Aureginosa ATCC 27853, S. AIbicans 855/653, SI. Perfringens 28, Peptostreptococcus anaerobicus 22, Bacteroides fragilis 13/83, and clinical strains of S. Aureus, R. Aeuroginosa, E. Coli. Adhesive properties of microorganisms were studied according to the Brillis method et al. (1986) with the subsequent statistical processing of the data.Results. Studies have shown that antiseptics have high antimicrobial activity and reduce the adhesion ability of microorganisms. But the use of only antiseptics or only antibiotics for the purification of purulent foci can lead to toxins absorption and tissue decay products from purulent foci. That processes could be the trigger mechanism for sepsis development. The sorption composition is able to reduce the adhesive activity of bacteria, allows to absorb toxic substances from pathological foci, what preventing their resorption and thereby prevent the development of sepsis.Conclusions. The composition made from sorbents and antiseptics is not inferior to antimicrobial activity to antiseptics, which can reduce the virulence of bacteria, by reducing their adhesive activity, and absorb toxins of microorganisms and tissue decomposition products on their surface, thus prevent their absorption, which will prevent the purulent-inflammatory process progression and sepsis development.Keywords: sorption composition, nanodisperse silica, antiseptics, adhesive properties of microorganisms, prevention of sepsis.

Adhesion Properties between Swollen Hydrogels in Air

2005 ◽  
Vol 897 ◽  
Author(s):  
Daisuke Sakasegawa ◽  
Takaya Sato ◽  
Motoaki Goto ◽  
Atsushi Suzuki
Keyword(s):  
Room Temperature ◽  
Normal Force ◽  
Adhesion Force ◽  
Point Contact ◽  
Sodium Acrylate ◽  
Evaluation Technique ◽  
Adhesive Properties ◽  
Adhesion Properties ◽  
Aluminum Ions ◽  
Separation Velocity

AbstractAdhesion between swollen hydrogels was studied using a simple tack-evaluation technique by a point contact in air at room temperature. The hydrogel used here was poly(sodium acrylate) (PSA) gel physically cross-linked by aluminum ions. The adhesion force and the separation energy showed a power-law increase with separation velocity, normal force, and waiting period　prior to separate. Effects of the degrees of protonation in PSA as well as of dehydration on the adhesive properties are also presented. The results are discussed in terms of the surface molecular interaction and the bulk elastic and viscous properties.

The Effectiveness of Using RAA-TA Additives for the Preparation of Warm Asphalt Concrete

2017 ◽  
Vol 865 ◽  
pp. 259-262 ◽  
Author(s):  
Valentina V. Yadykina ◽  
Anatoly M. Gridchin ◽  
Anna Trautvain ◽  
Vladimir Kholopov
Keyword(s):  
Asphalt Concrete ◽  
Water Saturation ◽  
Asphalt Mixture ◽  
Road Construction ◽  
State Standards ◽  
Adhesive Properties ◽  
Preparation Temperature ◽  
Asphalt Mix ◽  
Positive Effect ◽  
Physical And Mechanical Characteristics

The possibility to reduce the temperature during manufacturing and the temperature of compaction of asphalt mix by introducing the specially designed RAA-TA (Road Adhesive Additive for the warm asphalt concrete) additive to the bitumen has been demonstrated. Reducing the preparation temperature for asphalt mixture to 130 ° C, and the compaction temperature of the hot mix to 100 ° C, by using the additives, the characteristics of warm asphalt concrete meet the requirements of State Standards for hot asphalt concrete. The results indicate that the administration of additives improves strength at 20 and 50 ° C and reduces this index at 0 ° C, and with increasing the concentration of the researched additive its positive effect increases. The greatest effect of the additive is observed on such parameters as water saturation and water resistance of asphalt concrete, which is obviously connected with the improved encapsulation of mineral materials by bitumen due to the reduction of its viscosity and improvement of adhesive properties due to the additive composition. This will reduce the fuel consumption, the emissions of harmful substances into the atmosphere during the bituminous mixture production and asphalt coating making, as well as increase the distance of its transportation to the work site. At the same time the physical and mechanical characteristics of asphalt concrete with the addition of RAA-TA do not deteriorate. As a result of reducing the temperature of laying and compacting of asphalt mix the season of road construction can be extended and the pressure on the environment can be significantly reduced.

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