scholarly journals Synchrotron FTIR imaging of OH in quartz mylonites

2017 ◽  
Author(s):  
Andreas K. Kronenberg ◽  
Hasnor F. B. Hasnan ◽  
Caleb W. Holyoke III ◽  
Richard D. Law ◽  
Zhenxian Liu ◽  
...  
Keyword(s):  
Fluid Inclusions ◽  
Light Sources ◽  
Main Central Thrust ◽  
Absorption Bands ◽  
Hydrous Mineral ◽  
Ir Radiation ◽  
Mineral Inclusions ◽  
Measurement Resolution ◽  
Quartz Grains ◽  
Water Contents

Abstract. Methods of measuring OH absorption bands of fluid inclusions and hydrogen defects in deformed quartz rocks at high spatial resolution are described, using synchrotron infrared IR radiation coupled with a Fourier transform infrared FTIR microscope, and applied to imaging OH in mylonites of the Moine Thrust (from the Stack of Glencoul, NW Scotland Caledonides) and the Main Central Thrust (from the Himalayan front, Sutlej Valley, NW India). Previous measurements of water in deformed quartzites using conventional FTIR instruments, through apertures of 50–100 μm for specimens ~ 100 μm in thickness have shown that water contents of larger grains vary from one grain to another. However, the non-equilibrium variations in water content between neighboring grains and within quartz grains cannot be interrogated further without greater measurement resolution, nor can water contents be measured in finely recrystallized grains without including absorption bands due to fluid inclusions, films, and secondary minerals at grain boundaries. Synchrotron IR radiation is brighter and more collimated than offered by conventional FTIR globar light sources, and we have been able to distinguish and measure OH bands due to fluid inclusions, hydrogen point defects, and secondary hydrous mineral inclusions through an aperture of 10 μm for specimens > 40 μm thick. Doubly polished IR plates can be prepared with thicknesses down to 4–8 μm, but measurement of small OH bands is currently limited by strong interference fringes for samples

scholarly journals Synchrotron FTIR imaging of OH in quartz mylonites

Solid Earth ◽  
2017 ◽  
Vol 8 (5) ◽  
pp. 1025-1045 ◽  
Author(s):  
Andreas K. Kronenberg ◽  
Hasnor F. B. Hasnan ◽  
Caleb W. Holyoke III ◽  
Richard D. Law ◽  
Zhenxian Liu ◽  
...  
Keyword(s):  
Water Content ◽  
Point Defects ◽  
Fluid Inclusions ◽  
Hanging Wall ◽  
Molecular Water ◽  
Main Central Thrust ◽  
Absorption Bands ◽  
Uniform Equilibrium ◽  
Quartz Grains ◽  
Water Contents

Abstract. Previous measurements of water in deformed quartzites using conventional Fourier transform infrared spectroscopy (FTIR) instruments have shown that water contents of larger grains vary from one grain to another. However, the non-equilibrium variations in water content between neighboring grains and within quartz grains cannot be interrogated further without greater measurement resolution, nor can water contents be measured in finely recrystallized grains without including absorption bands due to fluid inclusions, films, and secondary minerals at grain boundaries.Synchrotron infrared (IR) radiation coupled to a FTIR spectrometer has allowed us to distinguish and measure OH bands due to fluid inclusions, hydrogen point defects, and secondary hydrous mineral inclusions through an aperture of 10 µm for specimens > 40 µm thick. Doubly polished infrared (IR) plates can be prepared with thicknesses down to 4–8 µm, but measurement of small OH bands is currently limited by strong interference fringes for samples < 25 µm thick, precluding measurements of water within individual, finely recrystallized grains. By translating specimens under the 10 µm IR beam by steps of 10 to 50 µm, using a software-controlled x − y stage, spectra have been collected over specimen areas of nearly 4.5 mm2. This technique allowed us to separate and quantify broad OH bands due to fluid inclusions in quartz and OH bands due to micas and map their distributions in quartzites from the Moine Thrust (Scotland) and Main Central Thrust (Himalayas).Mylonitic quartzites deformed under greenschist facies conditions in the footwall to the Moine Thrust (MT) exhibit a large and variable 3400 cm−1 OH absorption band due to molecular water, and maps of water content corresponding to fluid inclusions show that inclusion densities correlate with deformation and recrystallization microstructures. Quartz grains of mylonitic orthogneisses and paragneisses deformed under amphibolite conditions in the hanging wall to the Main Central Thrust (MCT) exhibit smaller broad OH bands, and spectra are dominated by sharp bands at 3595 to 3379 cm−1 due to hydrogen point defects that appear to have uniform, equilibrium concentrations in the driest samples. The broad OH band at 3400 cm−1 in these rocks is much less common. The variable water concentrations of MT quartzites and lack of detectable water in highly sheared MCT mylonites challenge our understanding of quartz rheology. However, where water absorption bands can be detected and compared with deformation microstructures, OH concentration maps provide information on the histories of deformation and recovery, evidence for the introduction and loss of fluid inclusions, and water weakening processes.

A Comparison of FT-IR/PA and FT-IR/PBD Spectra of Powders

1986 ◽  
Vol 40 (5) ◽  
pp. 636-641 ◽  
Author(s):  
P. G. Varlashkin ◽  
M. J. D. Low ◽  
G. A. Parodi ◽  
C. Morterra
Keyword(s):  
Probe Beam ◽  
Beam Deflection ◽  
Signal To Noise ◽  
Absorption Bands ◽  
Ir Radiation ◽  
Laser Probe ◽  
Ft Ir ◽  
Better Than

FT-IR photoacoustic (PA) and also photothermal beam deflection (PBD) spectra were recorded with the same particulate samples (graphite, charcoal, aspirin, and silica) under the same conditions in order to compare the quality of the spectra obtainable with the two techniques. A PA cell fitted with windows for the PBD laser probe beam was used, and PA and PBD spectra of each sample were recorded at 8 cm−1 resolution at each of the four different interferometer scan velocities. Although the overall aspects of FT-IR/PA and FT-IR/PBD spectra are the same, the signal-to-noise ratios of PA spectra are appreciably better than those of PBD spectra because PBD detection is more prone to disturbance by vibration than is PA detection. Absorption bands appear at the same wavenumbers in PA and PBD spectra. However, the relative intensities of bands of PBD spectra depend on the absorptive properties of the powdered solids; with weak absorbers, some bands may not be detected at all. PAS can be used with all powders. PBDS is of little or no use for the examination of weakly absorbing powders unless they scatter IR radiation extensively.

The Witwatersrand pyrites and metamorphism

1983 ◽  
Vol 47 (345) ◽  
pp. 473-479 ◽  
Author(s):  
D. K. Hallbauer ◽  
K. von Gehlen
Keyword(s):  
Trace Element ◽  
Fluid Inclusions ◽  
Depositional Environment ◽  
Volcanic Rocks ◽  
Source Rocks ◽  
Fine Grained ◽  
Mineral Inclusions ◽  
Ore Minerals ◽  
Hand Specimen

AbstractEvidence obtained from morphological and extensive trace element studies, and from the examination of mineral and fluid inclusions in Witwatersrand pyrites, shows three major types of pyrite: (i) detrital pyrite (rounded pyrite crystals transported into the depositional environment); (ii) synsedimentary pyrite (round and rounded aggregates of fine-grained pyrite formed within the depositional environmen); and (iii) authigenic pyrite (newly crystallized and/or recrystallized pyrite formed after deposition). The detrital grains contain mineral inclusions such as biotite, feldspar, apatite, zircon, sphene, and various ore minerals, and fluid inclusions with daughter minerals. Most of the inclusions are incompatible with an origin by sulphidization. Recrystallized authigenic pyrite occurs in large quantities but only in horizons or localities which have been subjected to higher temperatures during the intrusion or extrusion of younger volcanic rocks. Important additional findings are the often substantial amounts of pyrite and small amounts of particles of gold found in Archaean granites (Hallbauer, 1982) as possible source rocks for the Witwatersrand detritus. Large differences in Ag and Hg content between homogeneous single gold grains within a hand specimen indicate a lack of metamorphic homogenization. The influence of metamorphism on the Witwatersrand pyrites can therefore be described as only slight and generally negligible.

A new occurrence of lazulite from the Main Central Thrust in Kumaun Himalaya, India: fluid inclusion, EPMA and Raman spectroscopy focusing on lazulite in a highly tectonized zone

2019 ◽  
Vol 481 (1) ◽  
pp. 211-230 ◽  
Author(s):  
Dinesh S. Chauhan ◽  
Rajesh Sharma ◽  
D. R. Rao
Keyword(s):  
Raman Spectroscopy ◽  
Fluid Inclusion ◽  
Fluid Inclusions ◽  
Structural Formula ◽  
Stability Field ◽  
Adjacent Area ◽  
Structural Level ◽  
Main Central Thrust ◽  
Kumaun Himalaya ◽  
D Values

AbstractThe present study reports and investigates ‘lazulite’ occurring in the vicinity of a highly tectonized zone of the Main Central Thrust (MCT) in the Himalaya. The azure blue lazulite, hosted in quartz veins, occurs in fractured Berinag quartzite, which forms the footwall of the MCT near Sobla village in NE Kumaun Himalaya, India. Lazulite was investigated using SEM-EDX, micro Raman spectroscopy, fluid inclusion microthermometry and electron probe microanalysis (EPMA). Lazulite contains inclusions of rutile and hematite and has Mg/(Mg+Fe) ratios of 0.86 to 0.90. The phosphorus in lazulite shows a negative trend with Mg+Al contents. This lazulite is an intermediate solid solution near the lazulite end-member with a cationic composition in the structural formula: Mg0.81–0.89Fe0.10–0.13 Al1.88–1.98P2.00–2.07. Its composition in the lazulite–scorzalite stability field points to a higher temperature of its formation. Fluids trapped as inclusions in lazulite and the associated quartz are generally C–O–H fluid. The fluid inclusion isochors for lazulite, together with the temperature calculated for metamorphism of the equivalent structural level in the adjacent area suggest 500–600°C and 7.25 to 9.25 kbar, which match the peak metamorphic temperature–pressure derived elsewhere for the Higher Himalayan Crystallines. Moderately enriched δD‰ values and H2O–CO2–low NaCl fluid suggest that water from a deep reservoir, more likely a metamorphic fluid, participated in lazulite formation. Classic sigmoidal fluid inclusions in lazulite reveal their development during MCT shearing, whereas the overpressured fluid inclusions suggest a post-lazulite uplift. The MCT lazulite is interpreted to have formed during Himalayan shearing and concurrent metamorphism. The present study also implies that this refractory mineral can sustain fluid inclusions within it against intense deformation conditions, such as in the MCT.

scholarly journals Cavity Ring-Down Spectroscopy for Molecular Trace Gas Detection Using A Pulsed DFB QCL Emitting at 6.8 µm

Photonics ◽  
2020 ◽  
Vol 7 (3) ◽  
pp. 74
Author(s):  
Komlan S. Gadedjisso-Tossou ◽  
Lyubomir I. Stoychev ◽  
Messanh A. Mohou ◽  
Humberto Cabrera ◽  
Joseph Niemela ◽  
...  
Keyword(s):  
Optical Path Length ◽  
High Energy ◽  
High Resolution Spectroscopy ◽  
Trace Gas ◽  
Absorption Bands ◽  
Ir Radiation ◽  
Cavity Ring Down Spectroscopy ◽  
Spectral Performance ◽  
Partial Interference ◽  
Cavity Ring Down

A trace gas sensor based on pulsed cavity ring-down spectroscopy (CRDS) was developed for measurement of the ν4 fundamental vibrational band of ammonia (NH3) centered at 1468.898 cm−1. A pulsed distributed feedback quantum cascade laser (DFB-QCL) operating at 6.8 µm (1470.58 cm−1) quite well covered the absorption band of the ammonia and strong fundamental vibrational absorption bands of different molecular gases in this unexplored region. The cavity was partially evacuated down to 0.4 Atm by a turbo-molecular pump to reduce the partial interference between the NH3 spectra and water near the absorption peak of ammonia. A sensitivity of nine parts per billion was reached for a measurement time of 120 s as well as an optical path length of 226 m. The device demonstrated high spectral performance and versatility due to its wide tuning range, narrow linewidth, and comparatively high-energy mid-IR radiation in the relatively unexplored 6.8 µm region, which is very important for high-resolution spectroscopy of a variety of gases.

scholarly journals Low water contents in diamond mineral inclusions: Proto-genetic origin in a dry cratonic lithosphere

2016 ◽  
Vol 433 ◽  
pp. 125-132 ◽  
Author(s):  
Lawrence A. Taylor ◽  
Alla M. Logvinova ◽  
Geoffrey H. Howarth ◽  
Yang Liu ◽  
Anne H. Peslier ◽  
...  
Keyword(s):  
Genetic Origin ◽  
Mineral Inclusions ◽  
Water Contents

scholarly journals Strength of dry and wet quartz in the low–temperature plasticity regime: insights from nanoindentation

2021 ◽  
Author(s):  
Luca Menegon ◽  
Alberto Ceccato ◽  
Lars N. Hansen
Keyword(s):  
Low Temperature ◽  
Water Content ◽  
Crystallographic Orientation ◽  
Secondary Ion Mass Spectrometry ◽  
High Stress ◽  
Peierls Stress ◽  
Strain History ◽  
Synthetic Quartz ◽  
Quartz Grains ◽  
Water Contents

&lt;p&gt;The strength of experimentally deformed natural and synthetic quartz is strongly affected by the intracrystalline water content. Water&amp;#8211;related defects weaken quartz by either decreasing the resistance to dislocation motion (Peierls stress) or by enhancing the nucleation of dislocations, during what is commonly referred to as hydrolytic weakening. However, hydrolytic weakening has been observed predominantly in synthetic quartz grains, with water contents higher than 20&amp;#8211;30 wt ppm H&lt;sub&gt;2&lt;/sub&gt;O and at high-homologous temperatures, for which the activation of dislocation climb and recovery processes is enhanced.&lt;/p&gt;&lt;p&gt;In the low-temperature plasticity (LTP) regime, at low-homologous temperatures and high stress conditions, quartz plasticity is mainly controlled by dislocation glide. At these conditions, the possible effect of intracrystalline water on quartz strength is still a matter of debate.&lt;/p&gt;&lt;p&gt;In order to analyse the effects of intracrystalline water content on the plastic yield and hardness of quartz in the LTP regime, natural samples from recrystallized quartz domains of a granulite-facies migmatitic gneiss, presenting different water contents and microstructures, have been investigated through a series of spherical and Berkovich nanoindentation tests at room conditions. Nanoindentation tests have been integrated with measurements of intracrystalline water contents of the indented grains with secondary ion-mass spectrometry (SIMS), and with electron backscatter diffraction (EBSD) measurements of the crystallographic orientation of the indented grains.&lt;/p&gt;&lt;p&gt;Water content of indented quartz grains ranges between 2 and 104 wt ppm H&lt;sub&gt;2&lt;/sub&gt;O. Samples and related nanoindentation tests were thus classified as either &amp;#8220;dry&amp;#8221; (DQ, for water contents &lt; 20 wt ppm H&lt;sub&gt;2&lt;/sub&gt;O) or &amp;#8220;wet&amp;#8221; (WQ, for water content &gt; 20 wt ppm H&lt;sub&gt;2&lt;/sub&gt;O). Spherical nanoindentation tests revealed comparable yield stresses (ranging between 3.5 and 8.8 GPa, depending on the crystal orientation) for DQ and WQ grains. In addition, significant strain hardening was observed in both DQ and WQ grains. Berkovich nanoindentation tests also resulted in comparable hardness (ranging from 8.0 to 13.5 GPa) in both DQ and WQ grains. The hardness also increases with indentation depth, which is consistent with the &amp;#8220;size-effect&amp;#8221; on mineral strength during LTP.&lt;/p&gt;&lt;p&gt;These results suggest that, for the investigated range of water contents, the yield strength and flow stress of quartz in the LTP regime is not affected by the intracrystalline water content of the indented grain. Both the dry and wet quartz experienced significant crystal plastic deformation prior to the nanoindentation tests, as evidenced by the occurrence of undulatory extinction, misorientation bands, subgrains, and recrystallized grains. This pre-indentation strain history may have had a major role in generating the dislocation density, which then controlled the yield stresses during low-temperature plasticity in our experiments. Hence, inherited strain history, crystallographic orientation, and grain size may play a more important role than water in controlling the strength of the continental crust at the brittle&amp;#8211;ductile transition, where LTP is dominant and quartz is the most abundant phase.&lt;/p&gt;

scholarly journals A Comparison between FTIR Spectra from HUKE and SH-SY5Y Cell Lines Grown on Different Substrates

2020 ◽  
Vol 10 (24) ◽  
pp. 8825
Author(s):  
Giuseppe Perna ◽  
Vito Capozzi ◽  
Maria Lasalvia
Keyword(s):  
Principal Component ◽  
Medical Diagnostics ◽  
Cellular Level ◽  
Ftir Spectra ◽  
Pathological State ◽  
Absorption Bands ◽  
Ir Radiation ◽  
Glass Slides ◽  
Fingerprint Region ◽  
Cellular Components

In recent years, Fourier Transform Infrared (FTIR) micro-spectroscopy has shown promising potential in medical diagnostics at the cellular level. In fact, FTIR spectra can provide information related to DNA, protein, and lipid content and how such a content changes when a pathological state arises. Most of these information is included in the so-called fingerprint region (1000–1800 cm−1), consisting of several spectral peaks related to vibrational modes occurring inside cellular components. Unfortunately, the slides commonly used in cytology (as the glass microscopy slides and coverslips) are opaque to IR radiation in the fingerprint region, whereas they are transparent for wavenumber values larger than 2000 cm−1, where few and broad spectral absorption bands, mainly due to lipids and proteins, are present. Nonetheless, here we show that FTIR spectra performed in the high wavenumber range 2750–3000 cm−1 can be used to discriminate two different types of cells, one from a normal cell line (Human Keratinocyte, HUKE) and the other from a cancer one (SH-SY5Y). The spectra are discriminated by means of their Principal Component Analysis, according to the PC1 component, and by means of ratiometric analysis, according to the ratio of the intensity of the peak at 2956 cm−1 and that of the peak at 2924 cm−1. The PC1 score values of the HUKE are statistically different from the PC1 score values of SH-SY5Y, whereas the intensity ratio results larger for SH-SY5Y than for HUKE cells. Such results occur for different substrates over which the cells have been grown, including the thick glass slides used for cytological analysis. This result is a further step toward the application of FTIR microspectroscopy in the cytological routine diagnosis.

scholarly journals Nonlinear Optics in Silicon Wire Waveguides: Towards Integrated Long Wavelength Light Sources

2012 ◽  
Vol 1437 ◽  
Author(s):  
Bart Kuyken ◽  
Xiaoping Liu ◽  
Richard M. Osgood ◽  
Roel Baets ◽  
Gunther Roelkens ◽  
...  
Keyword(s):  
Nonlinear Optics ◽  
Silicon Nanowire ◽  
Wavelength Region ◽  
High Sensitivity ◽  
Silicon On Insulator ◽  
Light Sources ◽  
Absorption Bands ◽  
Central Wavelength ◽  
Mid Infrared ◽  
Long Wavelength

ABSTRACTMost of the research on silicon-on-insulator integrated circuits has been focused on applications for telecommunication. By using the large refractive index of silicon, compact complex photonic functions have been integrated on a silicon chip. However, the transparency of silicon up to 8.5 μm enables the use of the platform for the mid infrared wavelength region, albeit limited by the absorption in silicon oxide from 4 μm on. This could lead to a whole new set of integrated photonics circuits for sensing, given the distinct absorption bands of many molecules in this wavelength region. These long wavelength integrated photonic circuits would preferably need broadband or widely tunable sources to probe these absorption bands.We propose the use of nonlinear optics in silicon wire waveguides to generate light in this wavelength range. Nonlinear interactions in just a few cm of silicon wire waveguides can be very efficient as a result of both the high nonlinear index of silicon and the high optical confinement obtained in these waveguides. We demonstrate the generation of a supercontinuum spanning from 1.53 μm up to 2.55 μm in a 2 cm dispersion engineered silicon nanowire waveguide by pumping the waveguide with strong picoseconds pulses at 2.12 μm [1]. Furthermore we demonstrate broadband nonlinear optical amplification in the mid infrared up to 50 dB [2] in these silicon waveguides. By using this broadband parametric gain a silicon-based synchronously pumped optical parametric oscillator (OPO) is constructed [3]. This OPO is tunable over 70 nm around a central wavelength of 2080 nm.Finally, we also demonstrate the use of higher order dispersion terms to get phase matching between optical signals at very different optical frequencies in silicon wire waveguides. In this way we demonstrate conversion of signals at 2.44 μm to the telecommunication band with efficiencies up to +19.5 dB [4]. One particularly attractive application of such wide conversion is the possibility of converting weak signals in the mid-IR to the telecom window after which they can be detected by a high-sensitivity telecom-band optical receiver.

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