Relating General and Phase Specific Corrosion in a Super Duplex Stainless Steel with Phase Specific Microstructure Evolution

CORROSION ◽  
10.5006/3091 ◽  
2019 ◽  
Vol 75 (11) ◽  
pp. 1315-1326 ◽  
Author(s):  
Riya Mondal ◽  
Sunil Kumar Bonagani ◽  
A. Lodh ◽  
Tenneti Sharma ◽  
P.V. Sivaprasad ◽  
...  
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Duplex Stainless Steel ◽  
Corrosion Behavior ◽  
True Strain ◽  
Shear Bands ◽  
Austenite Phase ◽  
General Corrosion ◽  
Super Duplex Stainless Steel ◽  
Band Formation

Controlled near plane strain deformation was imposed on a super duplex stainless steel. Subsequent characterization involved extensive microtexture measurements, and measurements of general corrosion and corrosion behavior (and nature of the passive film) of the individual phases. The general corrosion was controlled by the corrosion performance of the austenite phase, and corresponding microtextural developments. Corrosion resistance in the austenite phase, as well as the general corrosion, improved until a true strain of 0.26 and then dropped. Enhanced corrosion resistance coincided with slip band formation and generation of low-angle boundaries. Beyond a strain of 0.26, shear bands and associated lattice curvatures plus high-angle boundaries led to a clear degradation in the corrosion behavior.

Precipitation condition and effect of volume fraction on corrosion properties of secondary phase on casted super-duplex stainless steel UNS S32750

2019 ◽  
Vol 66 (1) ◽  
pp. 61-66 ◽  
Author(s):  
Byung-Hyun Shin ◽  
Dohyung Kim ◽  
Sanghyup Park ◽  
Myungwon Hwang ◽  
Junghyun Park ◽  
...  
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Grain Boundary ◽  
Duplex Stainless Steel ◽  
Corrosion Behavior ◽  
Volume Fraction ◽  
Secondary Phase ◽  
Super Duplex Stainless Steel ◽  
Precipitation Condition ◽  
Content Type

Purpose The secondary phase decreased the corrosion resistance because of the segregation of Cr and Mo. Therefore, this paper aims to study the precipitation condition and the effect of secondary phase with volume fraction on corrosion behavior. Design/methodology/approach Secondary phase precipitated approximately from 375°C to 975°C because of saturated Cr and Mo at grain boundary by growth of austenite. Therefore, heat treatment from 800°C to 1,300°C was applied to start the precipitation of the secondary phase. Findings The secondary phase is precipitated at 1,020°C because of segregation by heterogeneous austenite. The growth of austenite at 1,000°C needs the time to saturate the Cr and Mo at grain boundary. When the volume fraction of austenite is 56 per cent (14 min at 1,000°C), the secondary phase is precipitated with grain boundary of austenite. The secondary phase increased the current density (corrosion rate) and decreased the passivation. That is checked to the critical pitting temperature (CPT) curves. The 1 per cent volume fraction of secondary phase decreased CPT to 60°C from 71°C. Research limitations/implications The precipitation of secondary phase not wants anyone. Casted super-duplex stainless steel (SDSS) of big size precipitates the secondary phase. This study worked the precipitation condition and the suppression conditions of secondary phase. Social implications Manufacturers need precipitation condition to make high-performance SDSS. Originality/value The corrosion resistance of SDSS is hard the optimization because SDSS is dual-phase stainless steel. The precipitation of the secondary phase must be controlled to optimize of the corrosion resistance of SDSS. Anyone not studied the precipitation condition of secondary phase and the effect of secondary phase with volume fraction on corrosion behavior of SDSS.

ZERON 100

Alloy Digest ◽  
1993 ◽  
Vol 42 (11) ◽  
Keyword(s):  
Fracture Toughness ◽  
Stainless Steel ◽  
Corrosion Resistance ◽  
High Temperature ◽  
Duplex Stainless Steel ◽  
Heat Treating ◽  
Super Duplex Stainless Steel ◽  
Corrosion Performance ◽  
Temperature Performance ◽  
Offshore Oil

Abstract ZERON 100 is a super duplex stainless steel which is manufactured to give a guaranteed corrosion performance by using an equation to control the chemistry in those elements which will determine the corrosion resistance of the material. Major usages in seawater applications, particularly offshore oil gathering systems. This datasheet provides information on composition, hardness, and tensile properties as well as fracture toughness. It also includes information on low and high temperature performance as well as heat treating, machining, and joining. Filing Code: SS-555. Producer or source: Weir Material Services Ltd.

Corrosion Resistance of Dissimilar GTA Welds of Pipeline Steel and Super Duplex Stainless Steels in Synthetic Brine

CORROSION ◽  
10.5006/3746 ◽  
2021 ◽  
Author(s):  
Víctor Vargas ◽  
Apolinar Albiter-Hernandez ◽  
Marco Dominguez Aguilar ◽  
Gerardo Altamirano-Guerrero ◽  
Cuahtemoc Maldonado
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Duplex Stainless Steel ◽  
Pipeline Steel ◽  
Localized Corrosion ◽  
Nickel Wire ◽  
Super Duplex Stainless Steel ◽  
Gas Tungsten Arc ◽  
Dissimilar Welds ◽  
Super Duplex Stainless Steels

The effect of weld passes and single V grove designs, on the corrosion resistance of dissimilar welds of a low alloy steel and a super-duplex stainless steel, was studied in synthetic brine. Welds were manufactured in argon by gas tungsten arc (GTA) technique and joined by a high nickel wire of super-duplex stainless steel. Samples of weld regions were characterized by composition scans, electrochemical measurements, micro-hardness and scanning electron microscopy. In X52/ER2594, a transition region (TR) of grain boundaries type II and a band of martensite were formed. The base metal of X52 underwent the highest corrosion rate and localized corrosion occurred in the heat affected zone. Interface ER2594/25Cr7Ni and 25Cr7Ni showed the presence of pitting near intermetallics.

Influence of Sigma Phase Precipitation on Pitting Corrosion of 2507 Super-Duplex Stainless Steel

2010 ◽  
Vol 658 ◽  
pp. 380-383 ◽  
Author(s):  
Ying Han ◽  
De Ning Zou ◽  
Wei Zhang ◽  
Jun Hui Yu ◽  
Yuan Yuan Qiao
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Ambient Temperature ◽  
Duplex Stainless Steel ◽  
Pitting Corrosion ◽  
Super Duplex Stainless Steel ◽  
Phase Precipitation ◽  
Pitting Potential ◽  
Σ Phase ◽  
Pitting Corrosion Resistance

Specimens of 2507 super-duplex stainless steel aging at 850°C for 5 min, 15 min and 60 min were investigated to evaluate the pitting corrosion resistance in 3.5% NaCl solution at 30°C and 50°C. The results are correlated with the microstructures obtained with different aging time. The precipitation of σ phase remarkably decreases the pitting corrosion resistance of the steel and the specimen aged for 60 min presents the lowest pitting potential at both 30°C and 50°C. With increasing the ambient temperature from 30°C to 50°C, the pitting potential exhibits a reduction tendency, while this tendency is less obviously in enhancing the ambient temperature than in extending the isothermal aging duration from 5 to 60 min. SEM analysis shows that the surrounding regions of σ phase are the preferable sites for the formation of corrosion pits which grew up subsequently. This may be attributed to the lower content of corrosion resistance elements in these regions formatted with σ phase precipitation.

Surface Characterization of Incoloy 825 Ni-Based Alloy/2507 Super Duplex Stainless Steel Dissimilar Friction Stir Welds

CORROSION ◽  
10.5006/2755 ◽  
2018 ◽  
Vol 74 (11) ◽  
pp. 1259-1271 ◽  
Author(s):  
Jalal Kangazian ◽  
Morteza Shamanian ◽  
Ali Ashrafi
Keyword(s):  
Stainless Steel ◽  
Duplex Stainless Steel ◽  
Surface Characterization ◽  
Electrochemical Impedance ◽  
Friction Stir Weld ◽  
General Corrosion ◽  
Super Duplex Stainless Steel ◽  
Friction Stir ◽  
Surface Corrosion ◽  
Incoloy 825

Surface features of a dissimilar friction stir weld between Incoloy 825 Ni-based alloy and SAF 2507 super duplex stainless steel were investigated using scanning electron microscopy, microhardness test, cyclic potentiodynamic polarization, and electrochemical impedance spectroscopy. The surface of the weldment showed lower general corrosion resistance in comparison to the base metals. Areas under the weld shoulder exhibited weak pitting resistance because of the deformed structure and/or chromium nitride precipitates. Incoloy 825 located under the shoulder also displayed the highest susceptibility to pit growth because of the austenite matrix containing titanium nitride phases. Overall, the obtained results demonstrated that the friction stir welding method could significantly deteriorate the surface corrosion behavior of the processed regions.

Investigation of mechanical and corrosion behavior of laser hybrid weld joint of 2205 duplex stainless steel

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Chuanbo Zheng ◽  
Cheng Zhang ◽  
Xiao Yong Wang ◽  
Jie Gu
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Duplex Stainless Steel ◽  
Base Metal ◽  
Corrosion Behavior ◽  
Welded Joints ◽  
Two Phase ◽  
Content Type ◽  
2205 Duplex Stainless Steel ◽  
Laser Hybrid

Purpose Duplex stainless steel is composed of equal amounts of austenite and ferrite, which has excellent corrosion resistance and strength. However, after the metal was welded, the ratio of austenite and ferrite in the joint is unbalanced, and secondary phase precipitates are produced, which is also an important cause of pitting corrosion in the joint. Design/methodology/approach This paper aims to study the mechanical and corrosion behavior of welded joints, by adjusting the welding parameters of laser hybrid welding, dual heat sources are used to weld 2205 duplex stainless steel. The two-phase content of different parts of the welded joint is measured to study the influence of the ratio of the two-phase on the mechanical and corrosion properties of the joint. Findings The ratio of austenite and ferrite in different welded joints has an obvious difference, and from top to bottom, the austenite content decreased gradually, and the ferrite content increased gradually. The harmful phases are precipitated in the middle and lower part of the joint. The strength of welded joints is slightly lower than that of base metal. At the same time, the fracture analysis shows that some ferrite phases are affected by the precipitate in the grain and produce quasi-cleavage fracture. The corrosion results show that the corrosion resistance of the welded joints is lower than that of the base metal, and the concentration of chloride ions affects the corrosion resistance. Originality/value In this paper, the authors use the influence of different welding processes on the two-phase ratio of the joint to further study the influence of the microstructure on the corrosion resistance and mechanical properties of the weld.

scholarly journals Pitting Corrosion Resistance on Annealing Treated Super Duplex Stainless Steel S32750

Crystals ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 294
Author(s):  
Shuang Liu ◽  
Chaohua Yue ◽  
Xi Chen ◽  
Qiuhua Zhu ◽  
Yiyou Tu
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Duplex Stainless Steel ◽  
Pitting Corrosion ◽  
Annealing Temperature ◽  
Super Duplex Stainless Steel ◽  
Boundary Area ◽  
Pitting Potential ◽  
Pitting Corrosion Resistance ◽  
Equivalent Number

The pitting corrosion resistance of S32750 super duplex stainless steel, annealing treated at temperatures of 950–1200 °C for 20–60 min, was investigated using potentiodynamic polarization tests. The results show that the volume fractions of ferrite in the S32750 duplex stainless steel increased from 48.9% to 68.4% as annealing temperatures increased from 950 to 1200 °C. The pitting potential of the sample increased first and then decreased from an annealing temperature of 950 to 1050 °C, and the highest pitting potential was observed after annealing at 1050 °C for 35 min. The pitting corrosion resistance of S32750 stainless steel is due to the combination of pitting resistance equivalent number (PREN) value, phase fraction and grain boundary area fraction, and the imbalance of corrosion potential.

Effects of N Content on Microstructure and Properties of SAF2906 Casting Super Duplex Stainless Steel after Cryogenic Treatment

2010 ◽  
Vol 139-141 ◽  
pp. 670-676
Author(s):  
Hong Liang Xiang ◽  
Dong Liu ◽  
Wei Lin Huang ◽  
Fu Shan He
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Duplex Stainless Steel ◽  
Cryogenic Treatment ◽  
Optical Microscope ◽  
Super Duplex Stainless Steel ◽  
X Ray Diffraction ◽  
Alloying Element ◽  
N Content ◽  
Relationship Of

SAF2906 is a new kind of super duplex stainless steel, and more corrosion-resistant and strong than SAF2507, suitable to be used in the low temperature and corrosion conditions. In order to prevent the occurrence of microstructure changes resulting in the property deterioration, in the general, the castings made for SAF2906 should be cryogenically treated before they are used in the ultra low conditions. N is an alloying element, usually added to stainless steels to increase the material properties. So, In this paper, the effects of N content on microstructure, mechanical and corrosion resistance properties of SAF2906 casting super duplex stainless steel (SDSS) after cryogenic treatment were studied by means of Optical Microscope(OM), X-ray Diffraction(XRD) and electrochemical workstation. The results indicate that N can increase the amount of γ phase according to a linear relationship of Φ(γ)=99.4×w(N)+6.16. When N content is low or medial, γ phase can precipitate from ferrite. When N content is high, γ phase does not precipitate from ferrite and is converted directly from ferrite and austenite grain boundaries. The higher N content, the greater tensile strength and elongation, the better corrosion resistance. Compared with solution state, cryogenic treatment can improve corrosion resistance.

Influence of Argon-Nitrogen Gas to Balance the Microstructure in the Welding of Super Duplex Stainless Steel

2016 ◽  
Vol 836 ◽  
pp. 165-172
Author(s):  
Suheni
Keyword(s):  
Stainless Steel ◽  
Weld Metal ◽  
Duplex Stainless Steel ◽  
Heat Input ◽  
Oil And Gas ◽  
Austenite Phase ◽  
Super Duplex Stainless Steel ◽  
Shielding Gas ◽  
Input Variables ◽  
Protective Gas

Super duplex stainless steel is steel that has a corrosion resistance and good mechanical strength so that used in industry especially in oil and gas and petrochemical industry. In use in the field is often used for the connection process by welding methods. To produce good welds, it should be noted that the welding procedures and parameters used , especially the heat input. In this study is used the heat input variables shielding gas composition to determine how much influence on the balance of ferrite - austenite phase structure in the weld stainless steels SAF 2507 super duplex with tungsten inert gas welding method (TIG). Heat input varied by applying different welding speed 1,3,4 and 5 mm /sec while the shielding gas is used 100 % argon, 98 % argon + 2 % nitrogen and 95 % argon + 5 % nitrogen. The result showed that at different welding speeds generated depth and width of the weld metal which is different. Likewise the use of protective gas will produce a different ratio wide and deep of weld metal which is different. By using protective gas 95 % argon + 5 % nitrogen squeak - ausenit phase, resulting in weld metal that is relatively balanced than others. On a slow welding in addition to produce a large heat input also produces weld metal hardness at high and affect the growth of the austenite phase. The higher the heat input ( 2,280 kJ / mm ) , the lower the austenite phase in the weld metal.

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