Localized Corrosion of UNS A95052 Aluminum Alloy for Application in Multi-Effect Desalinator Plants

CORROSION ◽  
10.5006/2815 ◽  
2018 ◽  
Vol 74 (9) ◽  
pp. 1023-1032
Author(s):  
Dannisa R. Chalfoun ◽  
Mariano A. Kappes ◽  
Mauricio Chocrón ◽  
Raul B. Rebak
Keyword(s):  
Aluminum Alloy ◽  
Crevice Corrosion ◽  
Low Cost ◽  
Localized Corrosion ◽  
Complete Evaluation ◽  
Electrochemical Tests ◽  
Metal Plates ◽  
Different Temperatures ◽  
Partially Occluded ◽  
Desalination Plants

Aluminum alloy UNS A95052 (AA5052) is very attractive for desalination applications because of its good corrosion resistance in seawater at temperatures up to 125°C, low cost, good thermal conductivity, and non-toxicity of its corrosion products. The pitting corrosion potential, Epit, and the pit repassivation potential, Er,pit, of AA5052 were measured in deaerated 65,000 ppm sodium chloride (NaCl) solutions at 30°C, 60°C, and 85°C. Epit decreased with temperature, in accord with literature results. Er,pit was a function of anodic charge passed during pit growth stage. A complete evaluation of suitability of this alloy from a corrosion perspective requires also studies of crevice corrosion at different temperatures, considering that multi-plate designs of desalinators have metal plates in contact with rubber gaskets and seals. Cyclic potentiodynamic polarization was used to estimate crevice repassivation potentials, Er,crev, at 30°C, 60°C, and 85°C, in specimens with an attached rubber O-ring as a crevice former. This crevice former simulated the partially occluded geometry expected in desalination plants. Stable crevice corrosion potentials, Ecrev, were similar to Epit, and, when polarized to a similar anodic charge density, Er,crev were similar to Er,pit. Based on this result, from a corrosion perspective, the presence of crevices in the desalination plant is not expected to present an additional risk during operation of the plant. Electrochemical tests were also performed in saturated AlCl3 solutions to explain the results using Galvele’s localized acidification model.

A Critical Appraisal of Some Popular Laboratory Electrochemical Tests for Predicting the Localized Corrosion Resistance of Stainless Alloys in Sea Water

CORROSION ◽  
1972 ◽  
Vol 28 (8) ◽  
pp. 283-291 ◽  
Author(s):  
B. E. WILDE
Keyword(s):  
Crevice Corrosion ◽  
Anodic Polarization ◽  
Sea Water ◽  
Chloride Ion ◽  
Localized Corrosion ◽  
Cyclic Polarization ◽  
Pitting Potential ◽  
Electrochemical Tests ◽  
The Difference ◽  
Pit Initiation

Abstract Evidence is presented to demonstrate that although the critical pitting potential is qualitatively related to the resistance of a material to passivity breakdown by pit initiation, it is of questionable value in predicting the corrosion performance off a structure containing crevices. Experiments conducted on a 30Cr-3Mo-Fe alloy indicated total immunity to passivity breakdown by pit initiation during anodic polarization in 1M NaCl and under freely corroding conditions in acidified 10% FeCl3. However, on specimens containing an artificial crevice, passivity breakdown by crevice corrosion initiation was observed in the same two media. The long term implications of these data were confirmed by 16 month immersion tests in sea water, where severe crevice attack was noted equal in extent to that observed on A9SS Types 304 and 316 stainless steels whose pit initiation properties were considerably inferior to those of the 30Cr-3Mo-Fe alloy. The results of cyclic potentiodynamic anodic polarization experiments conducted on A8S1 Type 430 stainless steel are presented to demonstrate that the so called protection potential, Ep, is not a unique material parameter. It is shown that Ep varies in a semi logarithmic manner with the amount of localized attack induced by polarization; that is, with the chemistry changes in the growing pit caused by hydrolysis of corrosion products and chloride ion buildup in the pit cavities. On this basis, it is concluded that Ep data (however determined) cannot be used alone as a criteria for protection against the propagation of pre-existing pits or crevices in an engineering structure. Based on cyclic polarization procedures, a method of assessing the susceptibility and resistance of an alloy to crevice corrosion is suggested. It is shown that, for alloys which initiate pits during anodic polarization, the magnitude of the “difference potential” (Ec-Ep) is related to the crevice corrosion weight loss. For alloys that have no critical pitting potential, the presence of hysteresis during cyclic polarization with an artificial crevice indicates susceptibility to crevice corrosion.

Phosphate Inhibition Effect on Chloride-Induced Crevice Corrosion of Alloy 22

2012 ◽  
Vol 1475 ◽  
Author(s):  
Marcela Miyagusuku ◽  
Ricardo M. Carranza ◽  
Raul B. Rebak
Keyword(s):  
Crevice Corrosion ◽  
Concentration Ratio ◽  
Localized Corrosion ◽  
Potential Range ◽  
Nacl Solution ◽  
Electrochemical Tests ◽  
Inhibition Effect ◽  
Phosphate Ions ◽  
Alloy 22 ◽  
Phosphate Inhibition

ABSTRACTAlloy 22 has been extensively studied regarding its crevice corrosion (CC) resistance both in pure chloride solutions and in solutions containing different oxyanions that may act as inhibitors of crevice corrosion. The scope of this work was to study the general and localized corrosion behavior of Alloy 22 when phosphate ions were added to a 1 M NaCl solution at 90°C. Results from the electrochemical tests indicate that the size of the passive potential range and the localized corrosion repassivation potential value increased in the presence of phosphate ions. Results from creviced specimens showed a strong inhibition effect of phosphate ions on the chloride induced crevice corrosion of Alloy 22. The critical molar concentration ratio (RCRIT = [phosphate]/[Cl]) to inhibit crevice corrosion was 0.3.

scholarly journals Effect of Benzotriazole on the Localized Corrosion of Copper Covered with Carbonaceous Residue

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2722
Author(s):  
Yun-Ho Lee ◽  
Min-Sung Hong ◽  
Sang-Jin Ko ◽  
Jung-Gu Kim
Keyword(s):  
Oxygen Concentration ◽  
Photoelectron Spectroscopy ◽  
Crevice Corrosion ◽  
Galvanic Corrosion ◽  
Tap Water ◽  
Energy Dispersive Spectrometer ◽  
Copper Surface ◽  
Localized Corrosion ◽  
Electrochemical Tests ◽  
Corrosion Mechanisms

Carbonaceous residues on copper pipes during the manufacturing process are known to be one of the main causes of pitting corrosion on copper pipes. This study examined the corrosion-inhibiting effect of benzotriazole (BTA) on C12200 copper pipes with carbonaceous film in synthetic tap water. In the absence of BTA, localized corrosion mechanisms due to galvanic corrosion, crevice corrosion, and oxygen-concentration cell were proposed in the boundary part of the carbonaceous film on the copper through X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) with energy dispersive spectrometer (EDS) analyses. Electrochemical tests showed that BTA inhibits corrosion by forming Cu−BTA complexes on all over the copper surface where carbonaceous film is present. BTA mitigates galvanic corrosion and crevice corrosion at the boundary of the carbonaceous film and suppresses the formation of oxygen-concentration cells through the formation of a Cu−BTA complex.

scholarly journals Superior Degradation Performance of Nanoporous Copper Catalysts on Methyl Orange

Metals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 913
Author(s):  
Jinyi Wang ◽  
Sen Yang
Keyword(s):  
Activation Energy ◽  
Methyl Orange ◽  
High Efficiency ◽  
Low Cost ◽  
Degradation Process ◽  
Copper Catalysts ◽  
Reaction Rate Constant ◽  
Nanoporous Structure ◽  
Intra Particle Diffusion ◽  
Different Temperatures

The development of low-cost and high-efficiency catalysts for wastewater treatment is of great significance. Herein, nanoporous Cu/Cu2O catalysts were synthesized from MnCu, MnCuNi, and MnCuAl with similar ligament size through one-step dealloying. Meanwhile, the comparisons of three catalysts in performing methyl orange degradation were investigated. One of the catalysts possessed a degradation efficiency as high as 7.67 mg·g−1·min−1. With good linear fitting by the pseudo-first-order model, the reaction rate constant was evaluated. In order to better understand the degradation process, the adsorption behavior was considered, and it was divided into three stages based on the intra-particle diffusion model. Three different temperatures were applied to explore the activation energy of the degradation. As a photocatalytic agent, the nanoporous structure of Cu/Cu2O possessed a large surface area and it also had low activation energy, which were beneficial to the excellent degradation performance.

scholarly journals The electrochemical behavior of an aluminum alloy anode for rechargeable Al-ion batteries using an AlCl3–urea liquid electrolyte

RSC Advances ◽  
2017 ◽  
Vol 7 (51) ◽  
pp. 32288-32293 ◽  
Author(s):  
Chen Wang ◽  
Junfeng Li ◽  
Handong Jiao ◽  
Jiguo Tu ◽  
Shuqiang Jiao
Keyword(s):  
Aluminum Alloy ◽  
Electrochemical Behavior ◽  
Low Cost ◽  
Pyrolytic Graphite ◽  
Liquid Electrolyte ◽  
Al Alloy ◽  
Alloy Anode ◽  
Aluminum Alloy Anode

A novel Al-ion battery based on an Al alloy anode, pyrolytic graphite paper cathode, and low-cost AlCl3–urea liquid analogue electrolyte was successfully established. The present Al alloy/PG battery can afford a capacity as high as 105 mA h g−1.

Simulation on Flexible Thixo-Extrusion of Variable Cross-Section Part Based on DEFORM-3D Software

2014 ◽  
Vol 217-218 ◽  
pp. 201-207
Author(s):  
Chun Fang Wang ◽  
Kai Kun Wang ◽  
Zhe Luo
Keyword(s):  
Aluminum Alloy ◽  
Control Method ◽  
Complex Geometry ◽  
Variable Cross Section ◽  
Extrusion Process ◽  
Simulation Software ◽  
Variable Cross ◽  
Stress Strain ◽  
Different Temperatures ◽  
Deform 3D

Flexible thixo-extrusion, as an innovative near-net-shape forming method, has huge advantages in processing the components with complex geometry. However, it should keep in mind that conventional liquid casting still represents the dominant mean of aluminum alloys production. One of the obstacles the thixo-extrusion has to overcome is lack of proof that can live up to the claim that thixo-extruded components have better mechanical properties. The main aim of this paper is to simulate the flexible thixo-extrusion process of aluminum alloy A356 and investigate the control method of materials flow front. An isothermal compression test of aluminum alloy A356 is first conducted to obtain the true stress-strain curves at different temperatures and strain rates. A constitutive equation describing the relationship of stress, strain, strain rate and temperature is fitted by Origin and then imported to the DEFORM-3D simulation software. The results show that the quality of final component is enormously influenced by the radius of the arcs and the flexible thixo-extruded components has less defects compared with the conventional extruded ones.

Direct Writing on Paper Substrate to Prepare Silver Electrode Structures for Flexible Sensors

2021 ◽  
Vol 21 (12) ◽  
pp. 6048-6053
Author(s):  
Qi Wang ◽  
Mingwei Li ◽  
Yao Xie ◽  
Yun Ou ◽  
Weiping Zhou
Keyword(s):  
Low Cost ◽  
Rapid Development ◽  
Silver Electrode ◽  
Silver Nanostructures ◽  
Direct Writing ◽  
Paper Substrate ◽  
Electronic Products ◽  
Glass Substrates ◽  
Different Temperatures ◽  
Writing Technology

With the rapid development of the electronics industry, electronic products based on silicon and glass substrates electronic products will gradually be unable to meet the rising demand. Flexibility, environmental protection, and low costs are important for the development of electronic products. In this study, an efficient and low-cost method for preparing silver electrode structures by direct writing on paper has been demonstrated. Based on this method, a flexible paper-based sensor was prepared. The liquid printing ink used mainly comprises a precursor liquid without pre-prepared nanomaterials. The precursor liquid is transparent with good fluidity. Simple direct writing technology was used to write on the paper substrate using the precursor ink. When the direct-writing paper substrate was subsequently heated, silver nanostructures precipitated from the precursor liquid ink onto the paper substrate. The effect of different temperatures on the formation of the silver nanostructures and the influence of different direct writing processes on the structures were studied. Finally, a paper-based flexible sensor was prepared for finger-bending signal detection. The method is simple to operate and low in cost and can be used for the preparation of environment-friendly paper-based devices.

Crevice Corrosion of Grade-2 Titanium in Saline Solutions at Different Temperatures and Oxygen Concentrations

2017 ◽  
Vol 164 (13) ◽  
pp. C788-C795 ◽  
Author(s):  
Thalia E. Standish ◽  
Mehdi Yari ◽  
David W. Shoesmith ◽  
James J. Noël
Keyword(s):  
Crevice Corrosion ◽  
Different Temperatures ◽  
Saline Solutions ◽  
Oxygen Concentrations

scholarly journals Effect of Mn Content and Solution Annealing Temperature on the Corrosion Resistance of Stainless Steel Alloys

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Ihsan-ul-Haq Toor
Keyword(s):  
Corrosion Resistance ◽  
Annealing Temperature ◽  
Electrochemical Impedance ◽  
Austenitic Stainless Steels ◽  
Electrochemical Tests ◽  
Linear Polarization Resistance ◽  
Ni Content ◽  
Different Temperatures ◽  
Acidic Chloride ◽  
Mn Content

The corrosion behavior of two specially designed austenitic stainless steels (SSs) having different Nickel (Ni) and Manganese (Mn) contents was investigated. Prior to electrochemical tests, SS alloys were solution-annealed at two different temperatures, that is, at 1030°C for 2 h and 1050°C for 0.5 h. Potentiodynamic polarization (PD) tests were carried out in chloride and acidic chloride, whereas linear polarization resistance (LPR) and electrochemical impedance spectroscopy (EIS) was performed in 0.5 M NaCl solution at room temperature. SEM/EDS investigations were carried out to study the microstructure and types of inclusions present in these alloys. Experimental results suggested that the alloy with highest Ni content and annealed at 1050°C/0.5 hr has the highest corrosion resistance.

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