Corrosion Product Formation in Simulated Energy Systems

CORROSION ◽  
1982 ◽  
Vol 38 (4) ◽  
pp. 191-201 ◽  
Author(s):  
P. Fabis ◽  
C. Brown ◽  
T. Rockett ◽  
R. Heidersbach

Abstract Two commercial iron-chromium alloys (AISI 446 and AISI 502) were exposed to elevated temperature hydrogen sulfide and chloride environments. Scale formation was studied using infrared (IR) and Raman spectroscopy as the principle analysis methods. The scales formed are discussed in terms of temperature of formation, duration of exposure, and alloy composition. Comparisons are made to scales formed on pure iron and chromium in the same environments.

CORROSION ◽  
1981 ◽  
Vol 37 (12) ◽  
pp. 700-711 ◽  
Author(s):  
P. Fabis ◽  
R. Heidersbach ◽  
C. Brown ◽  
T. Rockett

Abstract Oxide scales formed on metals at elevated temperatures may be different, both chemically and structurally, from the scales on the metal once it has cooled to room temperature. This paper discusses Raman spectroscopy instrumentation for the in-situ identification of scales formed on metal surfaces exposed to gaseous environments. The results of an experimental program to characterize scales formed on two commercial iron-chromium alloys, AISI 446 and 502, in air and oxygen environments are also presented.


Author(s):  
Jay Anderson ◽  
Mustafa Kansiz ◽  
Michael Lo ◽  
Curtis Marcott

Abstract Failure analysis of organics at the microscopic scale is an increasingly important requirement, with traditional analytical tools such as FTIR and Raman microscopy, having significant limitations in either spatial resolution or data quality. We introduce here a new method of obtaining Infrared microspectroscopic information, at the submicron level in reflection (far-field) mode, called Optical-Photothermal Infrared (O-PTIR) spectroscopy, that can also generate simultaneous Raman spectra, from the same spot, at the same time and with the same spatial resolution. This novel combination of these two correlative techniques can be considered to be complimentary and confirmatory, in which the IR confirms the Raman result and vice-versa, to yield more accurate and therefore more confident organic unknowns analysis.


2005 ◽  
Vol 39 (2) ◽  
pp. 249-256 ◽  
Author(s):  
Hartwig Schulz ◽  
Gülcan Özkan ◽  
Malgorzata Baranska ◽  
Hans Krüger ◽  
Musa Özcan

2002 ◽  
Vol 43 (12) ◽  
pp. 3065-3071 ◽  
Author(s):  
Yoshiaki Ikarashi ◽  
Toshie Tsuchiya ◽  
Kazuhiro Toyoda ◽  
Equo Kobayashi ◽  
Hisashi Doi ◽  
...  

1976 ◽  
Vol 33 (1) ◽  
pp. 354-367 ◽  
Author(s):  
B. Dubois ◽  
S. A. Rizkallah ◽  
G. Brun ◽  
G. Flamant ◽  
G. Bouquet

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