Corrosion Resistance and Galvanic Coupling of UNS N08031 Base Metal, Heat-Affected Zone, and Weld Metal in Phosphoric Acid at Different Temperatures

CORROSION ◽  
2011 ◽  
Vol 67 (3) ◽  
pp. 035001-1-035001-10 ◽  
Author(s):  
E. Blasco-Tamarit ◽  
D.M. García-García ◽  
M. Ibáñez Ferrándiz ◽  
J. García Antón ◽  
A. Guenbour
Keyword(s):  
Corrosion Resistance ◽  
Phosphoric Acid ◽  
Weld Metal ◽  
Base Metal ◽  
Heat Affected Zone ◽  
Galvanic Coupling ◽  
Different Temperatures

scholarly journals Testing of intergranular and pitting corrosion in sensitized welded joints of austenitic stainless steel

10.30544/274 ◽  
2017 ◽  
Vol 23 (2) ◽  
pp. 109-117 ◽  
Author(s):  
Bore V. Jegdic ◽  
Biljana Bobić ◽  
Milica Bošnjakov ◽  
Behar Alić
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Austenitic Stainless Steel ◽  
Weld Metal ◽  
Base Metal ◽  
Pitting Corrosion ◽  
Heat Affected Zone ◽  
Intergranular Corrosion ◽  
Chromium Concentration ◽  
Pitting Corrosion Resistance

Pitting corrosion resistance and intergranular corrosion of the austenitic stainless steel X5Cr Ni18-10 were tested on the base metal, heat affected zone and weld metal. Testing of pitting corrosion was performed by the potentiodynamic polarization method, while testing of intergranular corrosion was performed by the method of electrochemical potentiokinetic reactivation with double loop. The base metal was completely resistant to intergranular corrosion, while the heat affected zone showed a slight susceptibility to intergranular corrosion. Indicators of pitting corrosion resistance for the weld metal and the base metal were very similar, but their values are significantly higher than the values for the heat affected zone. This was caused by reduction of the chromium concentration in the grain boundary areas in the heat affected zone, even though the carbon content in the examined stainless steel is low (0.04 wt. % C).

Investigating the Effect of Friction Stir Welding on Microstructure and Corrosion Behaviour of Al-Zn-Mg Alloy

2019 ◽  
Vol 969 ◽  
pp. 517-523
Author(s):  
Chaitanya Sharma ◽  
Vikas Upadhyay
Keyword(s):  
Corrosion Resistance ◽  
Friction Stir Welding ◽  
Base Metal ◽  
Heat Affected Zone ◽  
Corrosion Behaviour ◽  
Metal Dissolution ◽  
Nugget Zone ◽  
Precipitate Morphology ◽  
Friction Stir ◽  
Secondary Precipitates

In this work, Friction Stir Welding (FSW) of alloy 7039 was carried out in T4 temper and resulting microstructure and corrosion behaviour of developed weld were studied. FSW transformed the starting microstructure of base metal and formed stirred zone (SZ) and heat affected zone (HAZ) with varying microstructure and precipitate morphology. The observed zones in welded joints exhibited decreased protection to corrosion resistance than base metal. Dissolution of secondary precipitates in SZ and occurrence of precipitate free zones (PFZs) in HAZ enhanced susceptibility to corrosion of HAZ and weld nugget zone (WNZ) than base metal.

Application of FIB/SEM/EBSD for Evaluation of Residual Strains and Their Relationship to Weld Metal Hydrogen Assisted Cold Cracking

2012 ◽  
Author(s):  
W. L. Costin ◽  
I. H. Brown ◽  
L. Green ◽  
R. Ghomashchi
Keyword(s):  
Residual Stresses ◽  
Weld Metal ◽  
Base Metal ◽  
Heat Affected Zone ◽  
Ion Beam ◽  
Base Material ◽  
Welding Process ◽  
Cold Cracking ◽  
Predictive Methods ◽  
Residual Strains

Hydrogen assisted cold cracking (HACC) is a welding defect which may occur in the heat affected zone (HAZ) of the base metal or in the weld metal (WM). Initially the appearance of HACC was associated more closely with the HAZ of the base metal. However, recent developments in advanced steel processing have considerably improved the base material quality, thereby causing a shift of HACC to the WM itself. This represents a very serious problem for industry, because most of the predictive methods are intended for prevention of HACC in the HAZ of the base metal, not in the weld metal [1]. HACC in welded components is affected by three main interrelated factors, i.e. a microstructure, hydrogen concentration and stress level [2–4]. In general, residual stresses resulting from the welding process are unavoidable and their presence significantly influences the susceptibility of weld microstructures to cracking, particularly if hydrogen is introduced during welding [5]. Therefore various weldability tests have been developed over the years which are specifically designed to promote HACC by generating critical stress levels in the weld metal region due to special restraint conditions [4, 6–8]. These tests were used to develop predictive methods based on empirical criteria in order to estimate the cracking susceptibility of both the heat-affected zone and weld metal [4]. However, although the relationship between residual stress, hydrogen and HACC has received considerable attention, the interaction of residual stresses and microstructure in particular at microscopic scales is still not well understood [5, 9–21]. Therefore the current paper focuses on the development and assessment of techniques using Focused Ion Beam (FIB), Scanning Electron Microscopy (SEM) and Electron Backscatter Diffraction for the determination of local residual strains at (sub) micron scales in E8010 weld metal, used for the root pass of X70 pipeline girth welds, and their relationship to the WM microstructure. The measurement of these strains could be used to evaluate the pre-existing stress magnitudes at certain microstructural features [22].

scholarly journals Effect of Microstructure on Hydrogen Diffusion in Weld and API X52 Pipeline Steel Base Metals under Cathodic Protection

2017 ◽  
Vol 2017 ◽  
pp. 1-14 ◽  
Author(s):  
R. C. Souza ◽  
L. R. Pereira ◽  
L. M. Starling ◽  
J. N. Pereira ◽  
T. A. Simões ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Weld Metal ◽  
Base Metal ◽  
Cathodic Protection ◽  
Hydrogen Diffusion ◽  
Hydrogen Permeation ◽  
Pipeline Steel ◽  
Sodium Thiosulfate ◽  
Hydrogen Flow ◽  
Electrochemical Tests

The aim of this research was to evaluate the influence of microstructure on hydrogen permeation of weld and API X52 base metal under cathodic protection. The microstructures analyzed were of the API X52, as received, quenched, and annealed, and the welded zone. The test was performed in base metal (BM), quenched base metal (QBM), annealed base metal (ABM), and weld metal (WM). Hydrogen permeation flows were evaluated using electrochemical tests in a Devanathan cell. The potentiodynamic polarization curves were carried out to evaluate the corrosion resistance of each microstructure. All tests were carried out in synthetic soil solutions NS4 and NS4 + sodium thiosulfate at 25°C. The sodium thiosulfate was used to simulate sulfate reduction bacteria (SRB). Through polarization, assays established that the microstructure does not influence the corrosion resistance. The permeation tests showed that weld metal had lower hydrogen flow than base metal as received, quenched, and annealed.

Mechanical Properties and Microstructures of Narrow Gap Orbital Welded P91 Steel

2016 ◽  
Vol 258 ◽  
pp. 635-638 ◽  
Author(s):  
Michal Junek ◽  
Marie Svobodová ◽  
Jiří Janovec ◽  
Jakub Horváth
Keyword(s):  
Mechanical Properties ◽  
Weld Metal ◽  
Base Metal ◽  
Heat Affected Zone ◽  
Room Temperature ◽  
Tensile Specimen ◽  
Narrow Gap ◽  
P91 Steel ◽  
Microstructure Evaluation ◽  
The Individual

This article deals with the results of mechanical testing and structural analysis of sections of narrow gap orbital welded P91 steel on tube OD 355.6 x 40 mm. The evaluation of mechanical properties was based on tensile test at room temperature on mini-tensile specimens and on measurement of modulus of elasticity. Weld was cut longitudinally into 9 narrow slices by using waterjet. From these slices 108 flat mini-tensile specimens (dimensions of gauge is 2 x 2 mm) were prepared. In experimental part microstructure evaluation and documentation of fracture surface of each mini-tensile specimen were carried out. The aim of these experiments was to assess the mechanical properties of the individual sections of the weld (base metal, heat affected zone and weld metal). These data can be used for new approaches of FEM modelling of welds considering heat affected zone like a combination of different materials with different mechanical properties, which connect the thermally unaffected base metal and weld metal.

Evaluation of Welding Metal Zones in the Case Welded with 0.5 Mo Filler Metal to Forged Steel for Piston Crown Material

2014 ◽  
Vol 887-888 ◽  
pp. 1294-1300
Author(s):  
Kyung Man Moon ◽  
Jong Pil Won ◽  
Dong Hyun Park ◽  
Sung Yul Lee ◽  
Yun Hae Kim ◽  
...  
Keyword(s):  
Weld Metal ◽  
Combustion Chamber ◽  
Base Metal ◽  
Current Density ◽  
Heavy Oil ◽  
Heat Affected Zone ◽  
Corrosion Current Density ◽  
Filler Metal ◽  
Corrosion Current ◽  
Piston Crown

Since the oil price has been significantly jumped for recent some years, the diesel engine of the merchant ship has been mainly used the heavy oil of low quality. Thus, it has been often exposed to severely corrosive environment more and more because temperature of the exhaust gas of a combustion chamber is getting higher and higher with increasing of using the heavy oil of low quality. As a result, wear and corrosion of the most parts surrounded with combustion chamber is more serious compared to the other parts of the engine. Therefore, an optimum repair welding for these parts is very important to prolong their lifetime in a economical point of view. In this study, 0.5Mo filler metal was welded with SMAW method in the forged steel which would be generally used with piston crown material. And the corrosion properties of weld metal zone, heat affected zone and base metal zone were investigated using electrochemical methods such as measurement of corrosion potential, anodic polarization curves, cyclic voltammogram and impedance etc. in 35% H2SO4 solution. The heat affected and base metal zones exhibited the highest and lowest values of hardness respectively. And, the corrosion current density of the heat affected zone indicated the lowest value, having the highest value of hardness. It appeared that the corrosive products with red color was wholly covered on the surface of the base metal zone, while its products was not observed in the heat affected zone. The microstructure of the pearlite with black color was more or less observed in the base metal zone with patterns such as crystal and needle, in particular, the crystal pattern of ferrite microstructure with white color was considerably included in the base metal and heat affected zone, and the ferrite microstructure was significantly observed in the weld metal zone. In particular, the polarization characteristics such as impedance, polarization curve associated with corrosion resistance property were well in good agreement with each other. Keywords: Forged steel, Microstructure, 0.5Mo filler metal, SMAW, Weld metal zone, Electrochemical method, Corrosion current density, Hardness.

scholarly journals PENGARUH MEDIA PENDINGINAN TERHADAP KEKERASAN DAN STRUKTUR MIKRO HASIL PENGELASAN OXY ACETYLENE PADA MATERIAL BAJA ST-37

2017 ◽  
Vol 5 (2) ◽  
Author(s):  
Made Angga Priadi ◽  
I Nyoman Pasek Nugraha ◽  
Gede Widayana
Keyword(s):  
Weld Metal ◽  
Base Metal ◽  
Heat Affected Zone ◽  
Quantitative Research ◽  
Welding Process ◽  
Air Cooling ◽  
Water Cooling ◽  
Independent Variable ◽  
The Mean ◽  
Cooling Media

Media pendingin merupakan suatu substansi yang berfungsi dalam menentukan kecepatan pendinginan yang dilakukan terhadap material yang telah diuji dalam perlakuan panas. Penelitian ini bertujuan untuk mengetahui tingkat kekerasan dan pengamatan struktur mikro material baja ST-37 yang dipengaruhi media pendinginan air, udara dan oli serta penelitian ini dapat memberikan bahan referensi bagi lingkup pendidikan teknik mesin dan sebagai acuan di dunia industri dalam menggunakan media pendingin pada proses pengelasan. Adapun jenis metode yang digunakan dalam penelitian ini adalah metode penelitian eksperimen. Terdapat dua jenis variable yang digunakan dalam penelitian ini yaitu variabel bebas yang berupa media pendingin air, media pendingin udara dan media pendingin oli dan variabel terikatnya berupa sifat kekerasan. Dari hasil penelitian yang telah dilakukan dimana kekerasan daerah logam induk dengan media pendingin air memperoleh nilai rata-rata sebesar 63,10 Kg/mm2, pendingin udara memperoleh nilai rata-rata sebesar 65,61 Kg/mm2, dan media pendingin oli memperoleh nilai rata-rata sebesar 62,68 Kg/mm2. Kekerasan pada daerah HAZ dengan media pendingin air memperoleh nila rata-rata sebesar 68,49 Kg/mm2, media pendingin udara memperoleh nilai rata-rata sebesar 71,05 Kg/mm2 dan media pendingin oli memperoleh nilai rata-rata sebesar 70,34 Kg/mm2. Kekerasan pada daerah logam las dengan media pendingin air memperoleh nilai rata-rata sebesar 60,99 Kg/mm2, media pendingin udara memperoleh nilai rata-rata sebesar 61,79 Kg/mm2 dan media pendingin oli memperoleh nilai rata-rata sebesar 60,79 Kg/mm2. Berdasarkan dari hasil yang telah didapatkan baik pada logam induk, daerah HAZ dan logam Las dimana tingkat kekerasan yang lebih baik diperoleh dari proses pendinginan udara dibandingkan dengan media pendingin air dan media pendingin oli dari proses pengelasan oxy acytelene.Kata Kunci : Baja ST-37, Kekerasan Material, media pendinginan. The cooling media is a substance which has a function to determine the speed refrigeneration which carried out of the material that has been tasted by heat treatment. The objective of the research is to know the level of hardness and the observation of steel ST-37 material which is affected by cooling media such as water, air, and oil. Also this research may give a reference for Engineering Department of Education and industry in using cooling media for welding process. There is a method that use in this research, that is called quantitative research. There are two variables that use in this research. Independent variable and dependent variable. An independent variable are water, air, and oil cooling media. On the other hand, a dependent variable is nature of hardness. In this research the researcher got a results where the mean of hardness of the base metal area with the water cooling media is 63.10 Kg/mm2, in air conditioning is 61Kg/mm2, and the oil cooling is 62.68 Kg/mm2. The mean of a hardness in Heat Affected Zone (HAZ) by water cooling media 68,49 Kg/mm2, air cooling media is 71,05 Kg/mm2 and an air cooling is 70,34 Kg/mm2. The mean of Hardness in the weld metal area with water cooling media is 60,99 Kg/mm2, air-cooling media is 61,79 Kg/mm2 and oil-cooling media is 60,79Kg/mm2. Based on the result which has been gotten from base metal, Heat Affected Zone (HAZ), and weld metal where the best hardness level is obtained from air-cooling process rather than water cooling media and oil cooling media from oxy acytelene welding process.keyword : Cooling media, steel ST-37, hardness properties.

Characteristics of Inconel 625 Filler Metal Affecting to Weld and Deposited Metal Zones in the Case of Welded to Forged Steel for Piston Crown Material

2014 ◽  
Vol 1004-1005 ◽  
pp. 1114-1119
Author(s):  
Sung Yul Lee ◽  
Kyung Man Moon ◽  
Jong Pil Won ◽  
Jae Hyun Jeong ◽  
Tae Sil Baek
Keyword(s):  
Corrosion Resistance ◽  
Weld Metal ◽  
Base Metal ◽  
Anodic Polarization ◽  
Corrosion Potential ◽  
Filler Metal ◽  
Polarization Curves ◽  
Inconel 625 ◽  
Piston Crown ◽  
Deposited Metal

Recently, wear and corrosion of the engine parts surrounded with combustion chamber is more serious compared to the other parts of the engine due to using of heavy oil of low quality. Therefore, an optimum repair welding for these parts is very important to prolong their lifetime in a economical point of view. In this study, Inconel 625 filler metal was welded with GTAW method in the forged steel which would be generally used with piston crown material. In this case, the mechanical and corrosion properties between weld metal zone (WM) welded to the groove which were artificially made in the base metal and deposited metal zone (DM) only welded by Inconel 625 filler metal on the surface of the base metal were investigated using electrochemical methods, such as measurement of corrosion potential, anodic polarization curves, cyclic voltammogram and impedance etc. in 35% H2SO4 solution. The deposited metal zone exhibited a better corrosion resistance compared to the weld metal zone, furthermore, its corrosion potential was a nobler value rather than that of the weld metal zone. However, the hardness indicated more or less higher value in the weld metal zone. The corrosive products after measurement of anodic polarization curves was hardly observed both in the weld and deposited zones, while, the morphologies of the corroded surfaces exhibited general and pitting corrosion in the weld and deposited metal zones respectively. The fine pearlite microstructure was a little observed in the weld metal zone, moreover, the microstructure of ferrite with elliptical pattern was significantly increased in the deposited metal zone. As a result, it is considered that the amount of Cr, Mo and Ni having a high corrosion resistance diffuse and migrate from the weld metal zone to the base metal zone, thus, the deposited metal zone indicated a better corrosion resistance than the weld metal zone because the amount of Cr, Mo and Ni were much involved in deposited metal zone compared to the weld metal zone.

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