Study of Cavitation Corrosion Behaviors and Mechanism of Carbon Steel in Neutral Sodium Chloride Aqueous Solution

CORROSION ◽  
2005 ◽  
Vol 61 (11) ◽  
pp. 1061-1069 ◽  
Author(s):  
J. Liu ◽  
Y. Lin ◽  
X. Yong ◽  
X. Li
Keyword(s):  
Aqueous Solution ◽  
Sodium Chloride ◽  
Carbon Steel ◽  
Corrosion Behaviors ◽  
Neutral Sodium

scholarly journals Inhibitive effect of N,N'-Dimethylaminoethanol on carbon steel corrosion in neutral sodium chloride solution, at different temperatures

2018 ◽  
Vol 149 ◽  
pp. 01050
Author(s):  
Mohammed Hassoune ◽  
Abdelillah Bezzar ◽  
Latéfa Sail ◽  
Fouad Ghomari
Keyword(s):  
Sodium Chloride ◽  
Carbon Steel ◽  
Potentiodynamic Polarization ◽  
Chloride Solution ◽  
Sodium Chloride Solution ◽  
Steel Corrosion ◽  
Passive State ◽  
Protective Film ◽  
Different Temperatures ◽  
Neutral Sodium

The inhibition of carbon steel corrosion in neutral sodium chloride solution by N,N'- Dimethylaminoethanol (DMEA), at different temperatures, was investigated using weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. The results obtained confirm that DMEA is a good organic corrosion inhibitor for carbon steel in 0.5M of NaCl (concentration encountered in the Mediterranean seawater), over the whole range of temperatures studied. The inhibition efficiency (IE%) increases with increasing DMEA concentration; it reaches highest value for a concentration around 0.125 mol.L-1. Potentiodynamic polarization data show that, the compound studied in this research predominantly act as anodic-type inhibitor. The EIS study reveals that the addition of DMEA decreases the corrosion rate of carbon steel in neutral sodium chloride solution, due to the fact that the inhibitor molecules are strongly adsorbed on the active sites following Langmuir isotherm, thus leading to the formation of a stable protective film on the steel surface which is able to keep the metal/solution interface in a passive state. Furthermore, the values of the activation parameters, i.e. ΔHa and Ea obtained in this study indicate that the adsorption process of DMEA is endothermic and could be mainly attributed to chemisorption, respectively.

DETERMINATION OF TRACE AMOUNTS OF SILVER IN GALENA ORES

1960 ◽  
Vol 38 (9) ◽  
pp. 1488-1494 ◽  
Author(s):  
E. J. Bounsall ◽  
W. A. E. McBryde
Keyword(s):  
Aqueous Solution ◽  
Nitric Acid ◽  
Sodium Chloride ◽  
Hydrochloric Acid ◽  
Chloride Solution ◽  
Sodium Chloride Solution ◽  
Silver Content ◽  
Aqueous Sodium Chloride Solution ◽  
Aqueous Sodium

An analytical method is described for the determination of microgram amounts of silver in galena ores, based on the "reversion" of silver dithizonate. Silver is separated from relatively large amounts of lead by extraction as dithizonate into chloroform from an aqueous 1:99 nitric acid solution. Separation from mercury, which is also extracted under these conditions and would, if present, interfere in the analysis, is achieved by reverting the dithizonate solution with a 5% aqueous sodium chloride solution which is also 0.015 molar in hydrochloric acid. Following dilution of this aqueous solution and adjustment of pH, silver is again extracted into chloroform as the dithizonate, and determined absorptiometrically. Analyses of a number of galena ore samples showed a precision of within 3% for a silver content ranging from 0.03 to 0.4%.Some other methods for isolating silver from these samples, which were tried but found unsatisfactory, are discussed.

Corrosion behaviors of iron, chromium, nickel, low-carbon steel and four types of stainless steels in liquid antimony-tin alloy

CORROSION ◽  
10.5006/3820 ◽  
2021 ◽  
Author(s):  
Wei Liu ◽  
Huayi Yin ◽  
Kaifa Du ◽  
Bing Yang ◽  
Dihua Wang
Keyword(s):  
Carbon Steel ◽  
Corrosion Rate ◽  
Stainless Steels ◽  
Liquid Metals ◽  
Low Carbon Steel ◽  
Solid Substrate ◽  
Low Carbon ◽  
Corrosion Resistant ◽  
Corrosion Behaviors ◽  
Iron Chromium

Corrosion-resistant metals and alloys towards liquid metals determine the service performances and lifetime of the devices employing liquid metals. This paper studies the static corrosion behaviors of iron, chromium, nickel, low carbon steel, and four types of stainless steels (SS410, SS430, SS304, SS316L) in liquid Sb-Sn at 500 oC, aiming to screen corrosion-resistant SS for Li||Sb-Sn liquid metal batteries (LMBs). The corrosion rates of Fe and Ni are 0.94 μm h-1 and 6.03 μm h-1 after 160 h’s measurement, respectively. Cr shows a low corrosion rate of < 0.05μm h-1, which is due to the formation of a relatively stable Cr-Sb layer that may be able to prevent the interdiffusion between the solid substrate and liquid Sb-Sn. Ni has a high corrosion rate because the formed Ni-Sb and Ni-Sn compounds are soluble in the liquid Sb-Sn. The corrosion products of both pure metals and SS can be predicted by thermodynamic and phase diagram analysis. Among the four types of SS, SS430 shows the best corrosion resistance towards liquid Sb-Sb with a corrosion rate of 0.19 μm h-1. Therefore, a liquid Sb-Sn resistant material should have a high Cr content and a low Ni content, and this principle is applicable to design metallic materials not only for LMBs but also for other devices employing liquid Sb- and Sn-containing liquid metals.

scholarly journals MOLECULAR MECHANISM OF RELAXATION ABSORPTION OF ULTRASONIC WAVES IN AN AQUEOUS SOLUTION OF CALCIUM ACETATE

InterConf ◽  
2021 ◽  
pp. 970-978
Author(s):  
Z. Nizomov ◽  
M. Asozoda ◽  
A. Olimi ◽  
A. Karimzoda
Keyword(s):  
Experimental Data ◽  
Aqueous Solution ◽  
Sodium Chloride ◽  
Sodium Acetate ◽  
Ultrasonic Waves ◽  
Calcium Acetate ◽  
Acetate Anion ◽  
Frequency Range ◽  
Calcium Cations ◽  
Calcium Cation

The absorption of ultrasonic waves in the frequency range from 6 to 146 MHz in aqueous solutions of sodium acetate, sodium chloride and calcium has been studied. It was found that only in solutions of calcium cations and acetate anion present simultaneously, relaxation absorption of ultrasonic waves is observed. The experimental data obtained indicate that the observed relaxation absorption of ultrasound in the studied frequency range by an aqueous solution of calcium acetate is associated with the interaction of the acetate anion with the calcium cation in the solution.

Corrosion Behavior of Al-Si-Cr-Cu Bearing Low Carbon Steel in A Cyclic Dry/Wet Laboratory Test

2009 ◽  
Vol 79-82 ◽  
pp. 1017-1020 ◽  
Author(s):  
Hui Shu Zhang ◽  
Dong Ping Zhan ◽  
Song Lian Bai ◽  
Zhou Hua Jiang
Keyword(s):  
Carbon Steel ◽  
Electrochemical Impedance ◽  
Low Carbon Steel ◽  
Optical Microscope ◽  
Low Carbon ◽  
Rust Layer ◽  
Electrochemical Behaviors ◽  
Corrosion Rates ◽  
The Matrix ◽  
Corrosion Behaviors

The corrosion behaviors of Al-Si-Cr-Cu bearing low carbon steel and a reference steel Q235 were tested in a cyclic dry/wet environment containing 0.01mol/L NaHSO3 in laboratory. Rust layers were observed by optical microscope (OM), scanning electron microscopy (SEM) and XRD. The electrochemical behaviors of the steels were studied on the polarization curves and electrochemical impedance spectroscopy (EIS). The results indicate that after 120h corrosion test, the annual corrosion rates of the designed steels reduce 42 % than Q235 at least. The corrosion products are generally iron oxyhydroxides and oxides such as FeOOH, γ-FeOOH, α-FeOOH, γ-Fe2O3, Fe3O4. The α-FeOOH possesses good stabilization mainly exits and can improve the corrosion resistance. There are the enrichments of Cu, Cr, Si and Al in the rust layer close to the matrix, which make the rust layer be more compact and protected. The corrosion currents of the two designed steels are lower than that of Q235, the corrosion potentials are higher than that of Q235 after Tafel fitting. The rust layer impedances of the designed steels are higher than that of Q235.

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