Optimization of Cu(II) removal/recovery by bulk liquid membranes containing benzoylacetone as mobile carrier

2017 ◽  
Vol 88 ◽  
pp. 139-144
Author(s):  
Gerardo León ◽  
Asunción María Hidalgo ◽  
María Gómez ◽  
Beatriz Miguel ◽  
Elisa Gómez
Keyword(s):  
Bulk Liquid ◽  
Liquid Membranes ◽  
Mobile Carrier

Carrier‐Mediated Transport of Amino Acids Through Bulk Liquid Membranes

2004 ◽  
Vol 39 (16) ◽  
pp. 3821-3838 ◽  
Author(s):  
R. Bucci ◽  
S. Canepari ◽  
E. Cardarelli ◽  
A. M. Girelli ◽  
A. Pietrodangelo ◽  
...  
Keyword(s):  
Amino Acids ◽  
Bulk Liquid ◽  
Liquid Membranes ◽  
Carrier Mediated Transport

scholarly journals Transport and Separation of the Silver Ion with n–decanol Liquid Membranes Based on 10–undecylenic Acid, 10–undecen–1–ol and Magnetic Nanoparticles

Membranes ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 936
Author(s):  
Gheorghe Nechifor ◽  
Florentina Mihaela Păncescu ◽  
Paul Constantin Albu ◽  
Alexandra Raluca Grosu ◽  
Ovidiu Oprea ◽  
...  
Keyword(s):  
Magnetic Nanoparticles ◽  
Membrane Separation ◽  
Silver Ions ◽  
Silver Ion ◽  
Bulk Liquid ◽  
Liquid Membranes ◽  
Gravimetric Analysis ◽  
Undecylenic Acid ◽  
Scanning Calorimetry ◽  
Source Phase

This paper presents a transport and recovery of silver ions through bulk liquid membranes based on n–decanol using as carriers 10–undecylenic acid and 10–undecylenyl alcohol. The transport of silver ions across membranes has been studied in the presence of two types of magnetic oxide nanoparticles obtained by the electrochemical method with iron electrodes in the electrolyte with and without silver ions, which act as promoters of turbulence in the membrane. Separation of silver ions by bulk liquid membranes using 10–undecylenic acid and 10–undecylenyl alcohol as carriers were performed by comparison with lead ions. The configuration of the separation module has been specially designed for the chosen separation process. Convective-generating magnetic nanoparticles were characterized in terms of the morphological and structural points of view: scanning electron microscopy (SEM), high-resolution SEM (HR–SEM), energy dispersive spectroscopy analysis (EDAX), Fourier Transform InfraRed (FTIR) spectroscopy, thermal gravimetric analysis (TGA), differential scanning calorimetry and magnetization. The process performance (flux and selectivity) was tested were tested for silver ion transport and separation through n–decanol liquid membranes with selected carriers. Under the conditions of the optimized experimental results (pH = 7 of the source phase, pH = 1 of the receiving phase, flow rate of 30 mL/min for the source phase and 9 mL/min for the receiving phase, 150 rot/min agitation of magnetic nanoparticles) separation efficiencies of silver ions of over 90% were obtained for the transport of undecenoic acid and about 80% for undecylenyl alcohol.

scholarly journals KINETIKA TRANSPOR Co(II) MELALUI TEKNIK MEMBRAN CAIR FASA RUAH SECARA KONSEKUTIF

2015 ◽  
Vol 3 (1) ◽  
pp. 67
Author(s):  
Riana Dewi ◽  
Admin Alif ◽  
Hermansyah Aziz
Keyword(s):  
Optimum Condition ◽  
Ion Transport ◽  
Intermediate Phase ◽  
Bulk Liquid ◽  
Liquid Membranes ◽  
Kinetic Evaluation ◽  
Irreversible Reaction ◽  
First Order ◽  
Source Phase

 ABSTRACT Determination of kinetic analysis of Co(II) ion transport through bulk liquid membranes by consecutive method have been study. The optimum condition was obtained at pH 4 for the intermediate phase and receiving phase at pH near zero, while the source phase at pH 7, oxine concentration in chloroform at source phase is 2.10 M, methyl red concentration in chloroform at receiving phase is 3.10 M. It was found that Co(II) ion receiving phase at optimum condition as 4.40%. Evaluation of Co(II) ion kinetic transport shows k1 as 0.0116 minutes-1 and k4 0.0113 minutes-1. Kinetic transport process of Co(I1) ion through bulk liquid membranes by consecutive method followed first order consecutive irreversible reaction rate low. Consecutive method can used as an alternative method in determination the optimum condition of metals ion transport and kinetic evaluation of mentioned transport metals ion. Keywords : bulk liquid membranes, consecutive, cobalt

ChemInform Abstract: ENANTIOMER DIFFERENTIATION IN TRANSPORT THROUGH BULK LIQUID MEMBRANES

1975 ◽  
Vol 6 (4) ◽  
pp. no-no
Author(s):  
MARTIN NEWCOMB ◽  
ROGER C. HELGESON ◽  
DONALD J. CRAM
Keyword(s):  
Bulk Liquid ◽  
Liquid Membranes

Kinetic studies of copper permeation through supported liquid membranes containing hydroxyoxime as a mobile carrier.

MEMBRANE ◽  
1988 ◽  
Vol 13 (4) ◽  
pp. 229-232
Author(s):  
Haruhiko OHYA ◽  
Kouji SONOBE ◽  
Junichi TAGA ◽  
Takanori HASHIMOTO ◽  
Masafumi ENDO ◽  
...  
Keyword(s):  
Kinetic Studies ◽  
Liquid Membranes ◽  
Supported Liquid Membranes ◽  
Mobile Carrier

Electrodeposition of Cobalt and Lead in the Hybrid Liquid Membrane - Electrodialysis-Electrolysis Process

2016 ◽  
Vol 721 ◽  
pp. 399-403 ◽  
Author(s):  
Tatiana Sadyrbaeva
Keyword(s):  
Liquid Membrane ◽  
Nitric Acid Concentration ◽  
Feed Solution ◽  
Bulk Liquid ◽  
Liquid Membranes ◽  
Dilute Solutions ◽  
Cathodic Electrodeposition ◽  
Fine Grained ◽  
Fine Grained Structure ◽  
Effective Transfer

A novel method for Co (II) and Pb (II) recovery from acidic solutions is presented. The extraction of Co (II) and Pb (II) ions using the bulk liquid membranes during a galvanostatic electrodialysis process accompanied by cathodic electrodeposition of the metals was studied. Solutions of di (2-ethylhexyl) phosphoric acid (D2EHPA) with admixtures of tri-n-octylamine (TOA) in 1,2-dichloroethane were used as the liquid membranes. Effects of current density, Co (II) and Pb (II) concentrations in the feed solution, sulfuric or nitric acid concentration in the feed solution, D2EHPA and TOA concentration in the liquid membrane, of the type and concentration of acid in the cathodic solution were studied, and optimal conditions were determined. It is demonstrated that a practically complete (98-99%) removal of Co (II) and Pb (II) from the feed solutions containing 0.01 mol∙L-1 CoSO4 or 0.01 mol∙L-1 Pb (NO3)2 is achieved during 1.0 − 4.0 h of electrodialysis. A possibility of effective transfer of Pb (II) into dilute solutions of perchloric and nitric acids was demonstrated. The liquid membranes ensure the recovery of Co (II) ions into dilute solutions of perchloric, sulphuric, hydrochloric and nitric acids. Adherent, compact cobalt and lead electrodeposits with a fine-grained structure were obtained in the studied systems.

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