Membrane fouling mitigation during enhanced coagulation membrane filtration via zero valent iron (ZVI) addition to treat micro-polluted surface water

2017 ◽  
Vol 96 ◽  
pp. 3-11
Author(s):  
Xinfei Guo ◽  
Dongliang Liu ◽  
Cong Ma ◽  
Jie Wang ◽  
Hongwei Zhang
2015 ◽  
Vol 16 (1) ◽  
pp. 104-114 ◽  
Author(s):  
Jie Wang ◽  
Lulu Liu ◽  
Jun Yang ◽  
Sasa Yang ◽  
Hongwei Zhang ◽  
...  

The magnetic enhanced coagulation membrane filtration (MECMF) process was introduced into micro-polluted surface water treatment. The process was conducted by adding magnetic powder (MP) for enhancing coagulation. By contrasting the water quality parameters including dissolved organic carbon (DOC), UV254 and turbidity of permeates of MECMF and coagulation/flocculation membrane filtration (CFMF), results showed that the removal efficiency in the MECMF process was higher than those in the CFMF process. According to normalized flux and resistance analysis, membrane flux declined relatively slow and irreversible fouling resistance was lesser in the MECMF process. By analyzing the three-dimensional fluorescence of permeates and raw water, it was clearly shown that the permeate quality of the MECMF process was superior to that of the CFMF process apparently, which highlighted the removal of protein-like substances was more effectively in MECMF. Furthermore, the addition of MP could provide Lorentz and magnetic dipole forces between colloidal matters during coagulation, leading to the increase of collision frequency and efficiency and the formation of large size flocs with high fractal dimension. Large and high fractal dimension flocs could form a porous cake layer, which could increase water permeability. On the basic of the above findings, it was suggested that magnetic-enhanced coagulation that promoted flocs to develop could regulate cake layer structure and mitigate membrane fouling to some extent.


2018 ◽  
Vol 19 (3) ◽  
pp. 855-863 ◽  
Author(s):  
T. Miyoshi ◽  
Y. Takahashi ◽  
T. Suzuki ◽  
R. Nitisoravut ◽  
C. Polprasert

Abstract This study investigated the performance of a hybrid membrane filtration system to produce industrial water from highly-colored surface water. The system consists of a membrane filtration process with appropriate pretreatments, including coagulation, pre-chlorination, and anion exchange (IE) process. The results of the pilot-scale experiments revealed that the hybrid system can produce treated water with color of around 5 Pt-Co, dissolved manganese concentration of no more than 0.05 mg/L, and a silt density index (SDI) of no more than 5 when sufficient coagulant and sodium hypochlorite were dosed. Although the IE process effectively reduced the color of the water, a moderate increase in the color of the IE effluent was observed when there was a significant increase in the color of the raw water. This resulted in a severe membrane fouling, which was likely to be attributed to the excess production of inorganic sludge associated with the increased coagulant dosage required to achieve sufficient reduction of color. Such severe membrane fouling can be controlled by optimising the backwashing and relaxation frequencies during the membrane filtration. These results indicate that the hybrid system proposed is a suitable technology for treating highly-colored surface water.


2017 ◽  
Vol 76 (2) ◽  
pp. 490-500 ◽  
Author(s):  
Yufei Wang ◽  
Hui Jia ◽  
Hongwei Zhang ◽  
Jie Wang ◽  
Wenjin Liu

A recycling magnetic flocculation membrane filtration (RMFMF) process integrating circulating coagulation, magnetic enhanced flocculation and membrane filtration was investigated for the treatment of surface water micro-polluted by tetracycline, a typical pharmaceutical and personal care product. A bench-scale experiment was conducted and several water quality parameters including turbidity, ultraviolet absorbance at 254 nm (UV254), total organic carbon and tetracycline concentration were evaluated, taking coagulation membrane filtration and magnetic flocculation membrane filtration processes as reference treatments. The experimental results showed that at the optimum doses of 20 mg·L−1 ferric chloride (FeCl3), 4 mg·L−1 magnetite (Fe3O4) and 6 mg·L−1 reclaimed magnetic flocs in RMFMF processes, removal efficiencies of above evaluated parameters ranged from 55.8% to 92.9%, which performed best. Simultaneously, the largest average particle size of 484.71 μm and the highest fractal dimension of 1.37 of flocs were achieved, which did not only present the best coagulation effect helpful in enhancing the performance of removing multiple contaminants, but also lead to the generation of loose and porous cake layers favouring reduced permeate flux decline and membrane fouling.


2016 ◽  
Vol 88 ◽  
pp. 285-292 ◽  
Author(s):  
Xinfei Fan ◽  
Huimin Zhao ◽  
Xie Quan ◽  
Yanming Liu ◽  
Shuo Chen

2020 ◽  
Vol 26 (1) ◽  
Author(s):  
Hyeongok Lee ◽  
Kilsoo Hyun

The objectives of this study are to assess the potential of an activated and granular sludge (AS and GS) sequencing batch reactor (SBR)/granular activated carbon (GAC) coupled with a membrane for achieving reclamation and reuse of real mixed wastewater and to evaluate the feasibility of the configured systems for achieving membrane fouling mitigation. A better performance of membrane filtration (MF) having lower membrane fouling was observed at both higher agitation velocity and lower permeate flux. Despite a twice shorter hydraulic retention time (HRT) than that of the AS-SBR/MF configured system, the performances of the GS-SBR/MF system without and with a GAC bed as a pretreatment for the MF process achieved higher efficiencies than those of the AS-SBR system for organics and nutrient removal and higher flux in the MF. The addition of a GAC filter after SBR processes was more effective in mitigating membrane fouling due to effective foulant removal. These results indicate that the GS-SBR as an alternative process for the AS-SBR or the addition of a GAC bed after the SBR process is needed to obtain the reusable water with good quality and to improve the fouling rate and filtration time of the MF process.


2013 ◽  
Vol 864-867 ◽  
pp. 1226-1232
Author(s):  
Xue Hui Zhao ◽  
Hong Wei Zhang ◽  
Jie Wang

The effect of aggregated floc circulation on membrane fouling in contact circulated coagulation-membrane filtration hybrid process for treatment of surface water was investigated in this study. In order to understand the floc characteristics, the floc formation, breakage and re-growth were monitored by Mastersizer 2000 under the coagulation dosage of 5, 10, 15 and 20mg/l. A contact circulated coagulation tests were carried out and the effluent was filtered by a dead-end micro-filtration with the hollow fibre membrane. The coagulation effluent quality and the relative permeability J/J0 of membrane was determined at the circulated floc dosage of 22, 44 and 66mg/l. The experiment results indicated that the addition of circulated floc obviously improved the flux decline and the degree of improvement was closely related to the dosage of circulated floc. Compared to traditional coagulation, the contact circulated coagulation was an economic and efficient method to retard the membrane fouling.


2020 ◽  
Vol 610 ◽  
pp. 118234
Author(s):  
Lei Xu ◽  
Chaocheng Wei ◽  
Muhammad Saboor Siddique ◽  
Wenzheng Yu

2004 ◽  
Vol 4 (5-6) ◽  
pp. 215-222 ◽  
Author(s):  
A.R. Costa ◽  
M.N. de Pinho

Membrane fouling by natural organic matter (NOM), namely by humic substances (HS), is a major problem in water treatment for drinking water production using membrane processes. Membrane fouling is dependent on membrane morphology like pore size and on water characteristics namely NOM nature. This work addresses the evaluation of the efficiency of ultrafiltration (UF) and Coagulation/Flocculation/UF performance in terms of permeation fluxes and HS removal, of the water from Tagus River (Valada). The operation of coagulation with chitosan was evaluated as a pretreatment for minimization of membrane fouling. UF experiments were carried out in flat cells of 13.2×10−4 m2 of membrane surface area and at transmembrane pressures from 1 to 4 bar. Five cellulose acetate membranes were laboratory made to cover a wide range of molecular weight cut-off (MWCO): 2,300, 11,000, 28,000, 60,000 and 75,000 Da. Severe fouling is observed for the membranes with the highest cut-off. In the permeation experiments of raw water, coagulation prior to membrane filtration led to a significant improvement of the permeation performance of the membranes with the highest MWCO due to the particles and colloidal matter removal.


2003 ◽  
Vol 3 (5-6) ◽  
pp. 15-22
Author(s):  
P. Kouadio ◽  
M. Tétrault

Three colored surface water nanofiltration pilot-scale projects were conducted in the province of Quebec (eastern Canada), between November 2000 and March 2002, by the company H2O Innovation (2000) inc., for the municipalities of Lac Bouchette, Latulipe-et-Gaboury and Charlesbourg (now part of Quebec City). Results indicated that nanofiltration permeate quality has an advance on present drinking water regulation standard in Quebec, but important membrane fouling occurred. Fouling can be controlled by pretreatment and optimization of the operating conditions.


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