Using magnetic powder to enhance coagulation membrane filtration for treating micro-polluted surface water

2015 ◽  
Vol 16 (1) ◽  
pp. 104-114 ◽  
Author(s):  
Jie Wang ◽  
Lulu Liu ◽  
Jun Yang ◽  
Sasa Yang ◽  
Hongwei Zhang ◽  
...  
Keyword(s):  
Fractal Dimension ◽  
Surface Water ◽  
Membrane Fouling ◽  
Membrane Filtration ◽  
Layer Structure ◽  
Three Dimensional ◽  
Magnetic Powder ◽  
Enhanced Coagulation ◽  
Cake Layer ◽  
High Fractal Dimension

The magnetic enhanced coagulation membrane filtration (MECMF) process was introduced into micro-polluted surface water treatment. The process was conducted by adding magnetic powder (MP) for enhancing coagulation. By contrasting the water quality parameters including dissolved organic carbon (DOC), UV254 and turbidity of permeates of MECMF and coagulation/flocculation membrane filtration (CFMF), results showed that the removal efficiency in the MECMF process was higher than those in the CFMF process. According to normalized flux and resistance analysis, membrane flux declined relatively slow and irreversible fouling resistance was lesser in the MECMF process. By analyzing the three-dimensional fluorescence of permeates and raw water, it was clearly shown that the permeate quality of the MECMF process was superior to that of the CFMF process apparently, which highlighted the removal of protein-like substances was more effectively in MECMF. Furthermore, the addition of MP could provide Lorentz and magnetic dipole forces between colloidal matters during coagulation, leading to the increase of collision frequency and efficiency and the formation of large size flocs with high fractal dimension. Large and high fractal dimension flocs could form a porous cake layer, which could increase water permeability. On the basic of the above findings, it was suggested that magnetic-enhanced coagulation that promoted flocs to develop could regulate cake layer structure and mitigate membrane fouling to some extent.

Treatment of highly-colored surface water by a hybrid microfiltration membrane system incorporating ion-exchange

2018 ◽  
Vol 19 (3) ◽  
pp. 855-863 ◽  
Author(s):  
T. Miyoshi ◽  
Y. Takahashi ◽  
T. Suzuki ◽  
R. Nitisoravut ◽  
C. Polprasert
Keyword(s):  
Surface Water ◽  
Hybrid System ◽  
Membrane Fouling ◽  
Membrane Filtration ◽  
Membrane System ◽  
Pilot Scale ◽  
Manganese Concentration ◽  
Moderate Increase ◽  
Coagulant Dosage ◽  
Filtration System

Abstract This study investigated the performance of a hybrid membrane filtration system to produce industrial water from highly-colored surface water. The system consists of a membrane filtration process with appropriate pretreatments, including coagulation, pre-chlorination, and anion exchange (IE) process. The results of the pilot-scale experiments revealed that the hybrid system can produce treated water with color of around 5 Pt-Co, dissolved manganese concentration of no more than 0.05 mg/L, and a silt density index (SDI) of no more than 5 when sufficient coagulant and sodium hypochlorite were dosed. Although the IE process effectively reduced the color of the water, a moderate increase in the color of the IE effluent was observed when there was a significant increase in the color of the raw water. This resulted in a severe membrane fouling, which was likely to be attributed to the excess production of inorganic sludge associated with the increased coagulant dosage required to achieve sufficient reduction of color. Such severe membrane fouling can be controlled by optimising the backwashing and relaxation frequencies during the membrane filtration. These results indicate that the hybrid system proposed is a suitable technology for treating highly-colored surface water.

scholarly journals Optimization of In Situ Backwashing Frequency for Stable Operation of Anaerobic Ceramic Membrane Bioreactor

Processes ◽  
2020 ◽  
Vol 8 (5) ◽  
pp. 545 ◽  
Author(s):  
Rathmalgodage Thejani Nilusha ◽  
Tuo Wang ◽  
Hongyan Wang ◽  
Dawei Yu ◽  
Junya Zhang ◽  
...  
Keyword(s):  
Membrane Fouling ◽  
Membrane Filtration ◽  
Membrane Bioreactor ◽  
Ceramic Membrane ◽  
Pure Water ◽  
Ex Situ ◽  
Stable Operation ◽  
Chemical Cleaning ◽  
Cake Layer

The cost-effective and stable operation of an anaerobic ceramic membrane bioreactor (AnCMBR) depends on operational strategies to minimize membrane fouling. A novel strategy for backwashing, filtration and relaxation was optimized for stable operation of a side stream tubular AnCMBR treating domestic wastewater at the ambient temperature. Two in situ backwashing schemes (once a day at 60 s/day, and twice a day at 60 s × 2/day) maintaining 55 min filtration and 5 min relaxation as a constant were compared. A flux level over 70% of the initial membrane flux was stabilized by in situ permeate backwashing irrespective of its frequency. The in situ backwashing by permeate once a day was better for energy saving, stable membrane filtration and less permeate consumption. Ex situ chemical cleaning after 60 days’ operation was carried out using pure water, sodium hypochlorite (NaOCl), and citric acid as the order. The dominant cake layer was effectively reduced by in situ backwashing, and the major organic foulants were fulvic acid-like substances and humic acid-like substances. Proteobacteria, Firmucutes, Epsilonbacteria and Bacteroides were the major microbes attached to the ceramic membrane fouling layer which were effectively removed by NaOCl.

scholarly journals Fouling Mechanisms Analysis via Combined Fouling Models for Surface Water Ultrafiltration Process

Membranes ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 149 ◽  
Author(s):  
Bin Huang ◽  
Hangkun Gu ◽  
Kang Xiao ◽  
Fangshu Qu ◽  
Huarong Yu ◽  
...  
Keyword(s):  
Water Treatment ◽  
Surface Water ◽  
Membrane Fouling ◽  
Mechanism Analysis ◽  
Surface Water Treatment ◽  
Dead End ◽  
Cake Layer ◽  
Significant Difference ◽  
Combined Models ◽  
And Control

Membrane fouling is still the bottleneck affecting the technical and economic performance of the ultrafiltration (UF) process for the surface water treatment. It is very important to accurately understand fouling mechanisms to effectively prevent and control UF fouling. The rejection performance and fouling mechanisms of the UF membrane for raw and coagulated surface water treatment were investigated under the cycle operation of constant-pressure dead-end filtration and backwash. There was no significant difference in the UF permeate quality of raw and coagulated surface water. Coagulation mainly removed substances causing turbidity in raw surface water (including most suspended particles and a few organic colloids) and thus mitigated UF fouling effectively. Backwash showed limited fouling removal. For the UF process of both raw and coagulated surface water, the fittings using single models showed good linearity for multiple models mainly due to statistical illusions, while the fittings using combined models showed that only the combined complete blocking and cake layer model fitted well. The quantitative calculations showed that complete blocking was the main reason causing flux decline. Membrane fouling mechanism analysis based on combined models could provide theoretical supports to prevent and control UF fouling for surface water treatment.

scholarly journals Ozone Chemically Enhanced Backwash for Ceramic Membrane Fouling Control in Cyanobacteria-Laden Water

Membranes ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 213
Author(s):  
Stéphane Venne ◽  
Onita D. Basu ◽  
Benoit Barbeau
Keyword(s):  
Surface Water ◽  
Surface Waters ◽  
Membrane Fouling ◽  
Ceramic Membrane ◽  
Membrane Surface ◽  
Operating Costs ◽  
Fouling Control ◽  
Dead End ◽  
Cake Layer ◽  
Flow Experiments

Membrane fouling in surface waters impacted by cyanobacteria is currently poorly controlled and results in high operating costs. A chemically enhanced backwash (CEB) is one possible strategy to mitigate cyanobacteria fouling. This research investigates the potential of using an ozone CEB to control the fouling caused by Microcystis aeruginosa in filtered surface water on a ceramic ultrafiltration membrane. Batch ozonation tests and dead-end, continuous flow experiments were conducted with ozone doses between 0 and 19 mg O3/mg carbon. In all tests, the ozone was shown to react more rapidly with the filtered surface water foulants than with cyanobacteria. In addition, the ozone CEB demonstrated an improved mitigation of irreversible fouling over 2 cycles versus a single CEB cycle; indicating that the ozone CEB functioned better as the cake layer developed. Ozone likely weakens the compressible cake layer formed by cyanobacteria on the membrane surface during filtration, which then becomes more hydraulically reversible. In fact, the ozone CEB reduced the fouling resistance by 35% more than the hydraulic backwash when the cake was more compressed.

scholarly journals Performance of a novel recycling magnetic flocculation membrane filtration process for tetracycline-polluted surface water treatment

2017 ◽  
Vol 76 (2) ◽  
pp. 490-500 ◽  
Author(s):  
Yufei Wang ◽  
Hui Jia ◽  
Hongwei Zhang ◽  
Jie Wang ◽  
Wenjin Liu
Keyword(s):  
Surface Water ◽  
Membrane Fouling ◽  
Membrane Filtration ◽  
Average Particle Size ◽  
Quality Parameters ◽  
Average Particle ◽  
Permeate Flux ◽  
Personal Care Product ◽  
Surface Water Treatment ◽  
Scale Experiment

A recycling magnetic flocculation membrane filtration (RMFMF) process integrating circulating coagulation, magnetic enhanced flocculation and membrane filtration was investigated for the treatment of surface water micro-polluted by tetracycline, a typical pharmaceutical and personal care product. A bench-scale experiment was conducted and several water quality parameters including turbidity, ultraviolet absorbance at 254 nm (UV254), total organic carbon and tetracycline concentration were evaluated, taking coagulation membrane filtration and magnetic flocculation membrane filtration processes as reference treatments. The experimental results showed that at the optimum doses of 20 mg·L−1 ferric chloride (FeCl3), 4 mg·L−1 magnetite (Fe3O4) and 6 mg·L−1 reclaimed magnetic flocs in RMFMF processes, removal efficiencies of above evaluated parameters ranged from 55.8% to 92.9%, which performed best. Simultaneously, the largest average particle size of 484.71 μm and the highest fractal dimension of 1.37 of flocs were achieved, which did not only present the best coagulation effect helpful in enhancing the performance of removing multiple contaminants, but also lead to the generation of loose and porous cake layers favouring reduced permeate flux decline and membrane fouling.

scholarly journals Application of Coagulation–Membrane Rotation to Improve Ultrafiltration Performance in Drinking Water Treatment

Membranes ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 643
Author(s):  
Hongjian Yu ◽  
Weipeng Huang ◽  
Huachen Liu ◽  
Tian Li ◽  
Nianping Chi ◽  
...  
Keyword(s):  
Shear Stress ◽  
Drinking Water ◽  
Water Treatment ◽  
Membrane Fouling ◽  
Membrane Filtration ◽  
Drinking Water Treatment ◽  
Permeate Flux ◽  
Organic Removal ◽  
Cake Layer ◽  
The Impact

The combination of conventional and advanced water treatment is now widely used in drinking water treatment. However, membrane fouling is still the main obstacle to extend its application. In this study, the impact of the combination of coagulation and ultrafiltration (UF) membrane rotation on both fouling control and organic removal of macro (sodium alginate, SA) and micro organic matters (tannic acid, TA) was studied comprehensively to evaluate its applicability in drinking water treatment. The results indicated that membrane rotation could generate shear stress and vortex, thus effectively reducing membrane fouling of both SA and TA solutions, especially for macro SA organics. With additional coagulation, the membrane fouling could be further reduced through the aggregation of mediate and macro organic substances into flocs and elimination by membrane retention. For example, with the membrane rotation speed of 60 r/min, the permeate flux increased by 90% and the organic removal by 35% in SA solution, with 40 mg/L coagulant dosage, with an additional 70% increase of flux and 5% increment of organic removal to 80% obtained. However, too much shear stress could intensify the potential of fiber breakage at the potting, destroying the flocs and resulting in the reduction of permeate flux and deterioration of effluent quality. Finally, the combination of coagulation and membrane rotation would lead to the shaking of the cake layer, which is beneficial for fouling mitigation and prolongation of membrane filtration lifetime. This study provides useful information on applying the combined process of conventional coagulation and the hydrodynamic shear force for drinking water treatment, which can be further explored in the future.

scholarly journals The Effect of Ca and Mg Ions on the Filtration Profile of Sodium Alginate Solution in a Polyethersulfone-2-(methacryloyloxy) Ethyl Phosphorylchloline Membrane

Water ◽  
2018 ◽  
Vol 10 (9) ◽  
pp. 1207 ◽  
Author(s):  
Nasrul Arahman ◽  
Suffriandy Satria ◽  
Fachrul Razi ◽  
M. Bilad
Keyword(s):  
Sodium Alginate ◽  
Relative Permeability ◽  
Hollow Fiber ◽  
Membrane Fouling ◽  
Membrane Filtration ◽  
Hollow Fiber Membrane ◽  
Pure Water ◽  
Fiber Membrane ◽  
Cake Layer ◽  
The Stability

The efforts to improve the stability of membrane filtration in applications for wastewater treatment or the purification of drinking water still dominate the research in the field of membrane technology. Various factors that cause membrane fouling have been explored to find the solution for improving the stability of the filtration and prolong membrane lifetime. The present work explains the filtration performance of a hollow fiber membrane that is fabricated from polyethersulfone-2-(methacryloyloxy) ethyl phosphorylchloline while using a sodium alginate (SA) feed solution. The filtration process is designed in a pressure driven cross-flow module using a single piece hollow fiber membrane in a flow of outside-inside We investigate the effect of Ca and Mg ions in SA solution on the relative permeability, membrane resistance, cake resistance, and cake formation on the membrane surface. Furthermore, the performance of membrane filtration is predicted while using mathematical models that were developed based on Darcy’s law. Results show that the presence of Ca ions in SA solution has the most prominent effect on the formation of a cake layer. The formed cake layer has a significant effect in lowering relative permeability. The developed models have a good fit with the experimental data for pure water filtration with R2 values between 0.9200 and 0.9999. When treating SA solutions, the developed models fit well with experimental with the best model (Model I) shows R2 of 0.9998, 0.9999, and 0.9994 for SA, SA + Ca, and SA + Mg feeds, respectively.

Modeling NOM fouling of low pressure membranes: impact of membrane properties and NOM characteristics

2008 ◽  
Vol 8 (1) ◽  
pp. 75-83
Author(s):  
NoHwa Lee ◽  
John Pellegrino ◽  
Gary Amy
Keyword(s):  
Membrane Fouling ◽  
Membrane Filtration ◽  
Principal Component ◽  
Low Pressure ◽  
Time Frame ◽  
Membrane Properties ◽  
Flux Decline ◽  
Cake Layer ◽  
Highly Correlated ◽  
Significant Flux

This research attempted to identify characteristic coordinates responsible for significant flux decline in low pressure membrane filtration, and to explain relationships among those coordinates with a modeling approach. A Pearson's correlation matrix supported that significant flux decline over a short time frame (low delivered DOC) is highly correlated with high molecular weight (MW) components of NOM. Simulations of flux decline by model equations were close to the experimental results revealing that low pressure membrane fouling is dominantly affected by NOM characteristics and membrane properties. One source water, exhibiting the highest flux decline, showed mostly cake formation as a fouling mechanism. The results indicate that significant flux decline is caused by high MW components leading to formation of a cake layer. Principal component analysis (PCA) revealed that high MW polysaccharides are the most important NOM component affecting significant membrane fouling.

Integrating activated sludge floc size information in MBR fouling modeling

2015 ◽  
Vol 71 (7) ◽  
pp. 1073-1080 ◽  
Author(s):  
T. A. Cao ◽  
G. Van De Staey ◽  
I. Y. Smets
Keyword(s):  
Activated Sludge ◽  
Membrane Fouling ◽  
Three Dimensional ◽  
Strong Impact ◽  
Layer Formation ◽  
Floc Size ◽  
Pore Blocking ◽  
Three Dimensional Modeling ◽  
Cake Layer ◽  
Floc Size Distributions

Although studied extensively, modeling fouling phenomena in membrane bioreactors (MBRs) remains challenging. It has been well established that cake layer formation and pore blocking have a strong impact on the filtration performance but how to capture that in comprehensive models is not fully defined yet. Since it has been shown that bioflocculation characteristics of activated sludge have a clear link with (the extent of) membrane fouling, this study integrates activated sludge floc size (i.e., particle size distribution) information in the model for pore blocking and cake layer formation with a focus on constant flux operated MBRs. Based on these floc size distributions, a three-dimensional modeling and visualization of the cake layer is envisaged which can then provide the required input information (e.g., the porosity of the cake layer) for the fouling model. The model is calibrated and validated on the basis of experimental data from Hwang et al. (2012) in ‘Membrane bioreactor: TMP rise and characterization of biocake structure using CLSM-image analysis’ (see J. Membr. Sci. 419–420, 33–41).

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