Preparation of polymer inclusion membrane with sodium diethyldithiocarbamate as a carrier reagent for selective transport of zinc ions

2017 ◽  
Vol 75 ◽  
pp. 348-356 ◽  
Author(s):  
Gulsin Arslan ◽  
Abdurrahman Yılmaz ◽  
Ali Tor ◽  
Mustafa Ersoz
Keyword(s):  
Sodium Diethyldithiocarbamate ◽  
Zinc Ions ◽  
Inclusion Membrane ◽  
Polymer Inclusion Membrane ◽  
Selective Transport

scholarly journals Selective recovery of cobalt(II) towards lithium(I) from chloride media by transport across polymer inclusion membrane with triisooctylamine

2014 ◽  
Vol 16 (1) ◽  
pp. 15-20 ◽  
Author(s):  
Beata Pospiech
Keyword(s):  
Cellulose Triacetate ◽  
Deionized Water ◽  
Inclusion Membrane ◽  
Chloride Solutions ◽  
Selective Recovery ◽  
Polymer Inclusion Membrane ◽  
Selective Transport ◽  
Nitrophenyl Octyl Ether ◽  
Aqueous Chloride ◽  
Source Phase

Abstract In this work the selective transport of cobalt(II) and lithium(I) ions from aqueous chloride solutions through polymer inclusion membranes (PIMs) is presented. Triisooctylamine (TIOA) has been applied as the ion carrier in membrane. The effects of various parameters on the transport of Co(II) and Li(I) were studied. The obtained results show that Co(II) ions were effectively removed from source phase through PIM containing 32 wt.% TIOA, 22 wt.% CTA (cellulose triacetate) and 46 wt.% ONPOE (o-nitrophenyl octyl ether) or ONPPE (o-nitrophenyl pentyl ether) into deionized water as the receiving phase. The results indicate that there is a possibility of polymer inclusion membranes application to recover Co(II) and Li(I) from aqueous chloride solutions

scholarly journals Calixresorcin[4]arene-Mediated Transport of Pb(II) Ions Through Polymer Inclusion Membrane

Membranes ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 285
Author(s):  
Joanna Konczyk ◽  
Wojciech Ciesielski
Keyword(s):  
Activation Energy ◽  
Transport Process ◽  
Optimal Conditions ◽  
Inclusion Membrane ◽  
Polymer Inclusion Membrane ◽  
Membrane Effect ◽  
Feed Phase ◽  
Ion Carrier ◽  
Feed Effect ◽  
Nitrate Solutions

A facilitated transport of Pb(II) through polymer inclusion membrane (PIM) containing 1,8,15,22-tetra(1-heptyl)-calixresorcin[4]arene and its tetra- and octasubstituted derivatives containing phosphoryl, thiophosphoryl or ester groups as an ion carrier was investigated. The efficiency of Pb(II) removal from aqueous nitrate solutions was considered as a function of the composition of membrane (effect of polymer, plasticizer, and carrier), feed (effect of initial metal concentration and presence of other metal ions) and stripping phases, and temperature of the process conducting. Two kinetic models were applied for the transport description. The highest Pb(II) ions removal efficiency was obtained for the membrane with tetrathiophosphorylated heptyl-calixresorcin[4]arene as an ion carrier. The activation energy value, found from Eyring plot to be equal 38.7 ± 1.3 kJ/mol, suggests that the transport process is controllable both by diffusion and chemical reaction. The competitive transport of Pb(II) over Zn(II), Cd(II), and Cr(III) ions across PIMs under the optimal conditions was also performed. It was found that the Cr(III) ions’ presence in the feed phase disturb effective re-extraction of Pb(II) ions from membrane to stripping phase. Better stability of PIM-type than SLM-type membrane was found.

Crosslinking Improved Ion transport in Polymer Inclusion Membrane‐Electrodialysis Process and the Underlying Mechanism

AIChE Journal ◽  
2021 ◽  
Author(s):  
Baoying Wang ◽  
Qiaolin Lang ◽  
Ming Tan ◽  
Heqing Jiang ◽  
Lingyun Wang ◽  
...  
Keyword(s):  
Ion Transport ◽  
Underlying Mechanism ◽  
Inclusion Membrane ◽  
Polymer Inclusion Membrane
Sign in / Sign up

Export Citation Format

Share Document