scholarly journals Synthesis of titanium dioxide precursor by the hydrolysis of titanium oxychloride solution

2018 ◽  
Author(s):  
Pascal Le Bideau ◽  
Mireille Richard-Plouet ◽  
Patrick Glouannec ◽  
Anthony Magueresse ◽  
D. Iya-Sou ◽  
...  
Keyword(s):  
Mass Transfer ◽  
Titanium Dioxide ◽  
Numerical Model ◽  
Tio2 Particles ◽  
Modelling Experiment ◽  
Set Up ◽  
Mass Transfers ◽  
Titanium Oxychloride ◽  
Hydrolysis Of ◽  
Good Agreement

This communication focuses on the development of an approach to improve the synthesis of [Ti8O12(H2O)24]Cl8.HCl.7H2O crystals which is one of the precursor for titanium dioxide TiO2 particles. This study provides a significant improvement in crystallization kinetics with a production rate increased by a factor nineteen by intensifying heat and mass transfers compared to the process in a close vessel. This enhancement was made possible by the development of a new reactor to control the heat and mass transfers involved. In parallel with the experimental set-up, a numerical model representative of the transfer phenomena was initiated. The first numerical results are encouraging and present a good agreement with the measurements. Keywords: Heat and mass transfer; Co-desorption, Modelling, Experiment

Simultaneous Convective and Diffusive Mass Transfers in a Hemodialyser

1990 ◽  
Vol 112 (2) ◽  
pp. 212-219 ◽  
Author(s):  
Michel Y. Jaffrin ◽  
Luhui Ding ◽  
Jean Marc Laurent
Keyword(s):  
Mass Transfer ◽  
Blood Flow ◽  
Boundary Layers ◽  
Flow Rate ◽  
Local Blood Flow ◽  
Mass Fluxes ◽  
In Vitro Measurements ◽  
Mass Transfers ◽  
Good Agreement

The mass transfer in a hemodialyser in the presence of combined dialysis and ultrafiltration has been calculated by integration of mass fluxes across the boundary layers in blood and dialysate phase taking into account the partial rejection of solute as well as changes in local blood flow and ultrafiltration flux along the membrane. Clearances of creatinin, vitamin B12, and myoglobin have been calculated as a function of blood and ultrafiltrate flow rate and were found to be in good agreement with in vitro measurements. The data suggest the following empirical correlation for the hemodiafiltration clearance CL=CLD+0.46QF where QF is the ultrafiltration flow rate and CLD is the clearance at QF=0.

scholarly journals Pullout simulation of post installed chemically bonded anchors in UHPFRC

2018 ◽  
Vol 199 ◽  
pp. 11007
Author(s):  
Fabien Delhomme ◽  
Michael Brun
Keyword(s):  
Numerical Model ◽  
High Performance ◽  
Failure Modes ◽  
Numerical Study ◽  
Design Stage ◽  
Embedment Depth ◽  
Concrete Damage ◽  
Pullout Failure ◽  
Set Up ◽  
Good Agreement

An experimental and numerical study was completed in order to examine the mechanical behaviour of post-installed bonded anchors in ultra-high performance fibre reinforced concrete with a compressive strength higher than 130 MPa. The aim was to analyse the failure mechanisms in static pullout tests and to suggest a simple numerical model, which can be employed in a design stage, to reproduce the global behaviour of the anchor. The experimental observations show that a combined pullout and concrete cone failure occurred for an embedment depth of 40 mm and a steel rod failure for an embedment depth of 100 mm. The numerical model was set up using Abaqus software, by adopting the concrete damage plastic model and a surface-based cohesive behaviour for the interface concrete-anchor. The obtained failure modes and ultimate loads are in good agreement with experimental results. A minimum embedment depth of 50 mm was assessed to prevent a pullout failure of the anchor.

NUMERICAL MODEL TO SIMULATE THE EROSION ON THE SLOPE DUE TO OVERTOPPING

2010 ◽  
Vol 13 (3) ◽  
pp. 78-87
Author(s):  
Hoai Cong Huynh
Keyword(s):  
Numerical Model ◽  
Flow Model ◽  
Bed Load ◽  
Experiment Data ◽  
Step Method ◽  
Morphological Model ◽  
Load Transport ◽  
Bed Load Transport ◽  
The Finite Difference Method ◽  
Good Agreement

The numerical model is developed consisting of a 1D flow model and the morphological model to simulate the erosion due to the water overtopping. The step method is applied to solve the water surface on the slope and the finite difference method of the modified Lax Scheme is applied for bed change equation. The Meyer-Peter and Muller formulae is used to determine the bed load transport rate. The model is calibrated and verified based on the data in experiment. It is found that the computed results and experiment data are good agreement.

Modeling of mass transfer in biofilms in oscillatory flow conditions using k-ɛ turbulence model

2003 ◽  
Vol 3 (1-2) ◽  
pp. 201-207
Author(s):  
H. Nagaoka ◽  
T. Nakano ◽  
D. Akimoto
Keyword(s):  
Numerical Simulation ◽  
Mass Transfer ◽  
Turbulence Model ◽  
Uptake Rate ◽  
Oscillatory Flow ◽  
Substrate Uptake ◽  
Flow Conditions ◽  
Mass Transfer Mechanism ◽  
Substrate Uptake Rate ◽  
Good Agreement

The objective of this research is to investigate mass transfer mechanism in biofilms under oscillatory flow conditions. Numerical simulation of turbulence near a biofilm was conducted using the low Reynold’s number k-ɛ turbulence model. Substrate transfer in biofilms under oscillatory flow conditions was assumed to be carried out by turbulent diffusion caused by fluid movement and substrate concentration profile in biofilm was calculated. An experiment was carried out to measure velocity profile near a biofilm under oscillatory flow conditions and the influence of the turbulence on substrate uptake rate by the biofilm was also measured. Measured turbulence was in good agreement with the calculated one and the influence of the turbulence on the substrate uptake rate was well explained by the simulation.

The effect of two-phase flow regime on hydrodynamics and mass transfer in a horizontal-tube gas-liquid reactor

1985 ◽  
Vol 50 (3) ◽  
pp. 745-757 ◽  
Author(s):  
Andreas Zahn ◽  
Lothar Ebner ◽  
Kurt Winkler ◽  
Jan Kratochvíl ◽  
Jindřich Zahradník
Keyword(s):  
Mass Transfer ◽  
Pressure Drop ◽  
Flow Regime ◽  
Liquid Flow ◽  
Horizontal Tube ◽  
Liquid Holdup ◽  
Two Phase ◽  
Flow Rates ◽  
Type Relation ◽  
Good Agreement

The effect of two-phase flow regime on decisive hydrodynamic and mass transfer characteristics of horizontal-tube gas-liquid reactors (pressure drop, liquid holdup, kLaL) was determined in a cocurrent-flow experimental unit of the length 4.15 m and diameter 0.05 m with air-water system. An adjustable-height weir was installed in the separation chamber at the reactor outlet to simulate the effect of internal baffles on reactor hydrodynamics. Flow regime maps were developed in the whole range of experimental gas and liquid flow rates both for the weirless arrangement and for the weir height 0.05 m, the former being in good agreement with flow-pattern boundaries presented by Mandhane. In the whole range of experi-mental conditions pressure drop data could be well correlated as a function of gas and liquid flow rates by an empirical exponential-type relation with specific sets of coefficients obtained for individual flow regimes from experimental data. Good agreement was observed between values of pressure drop obtained for weirless arrangement and data calculated from the Lockhart-Martinelli correlation while the contribution of weir to the overall pressure drop was well described by a relation proposed for the pressure loss in closed-end tubes. In the region of negligible weir influence values of liquid holdup were again succesfully correlated by the Lockhart-Martinelli relation while the dependence of liquid holdup data on gas and liquid flow rates obtained under conditions of significant weir effect (i.e. at low flow rates of both phases) could be well described by an empirical exponential-type relation. Results of preliminary kLaL measurements confirmed the decisive effect of the rate of energy dissipation on the intensity of interfacial mass transfer in gas-liquid dispersions.

scholarly journals Laboratory Measurements of Light Scattering by Dust Particles

1996 ◽  
Vol 150 ◽  
pp. 409-413
Author(s):  
Patrick P. Combet ◽  
Philippe L. Lamy
Keyword(s):  
Light Scattering ◽  
Laser Beam ◽  
Mie Theory ◽  
Spherical Particles ◽  
Dust Particles ◽  
Laboratory Measurements ◽  
Scattering Function ◽  
Hene Laser ◽  
Set Up ◽  
Good Agreement

AbstractWe have set up an experimental device to optically study the scattering properties of dust particles. Measurements over the 8 — 174° interval of scattering angles are performed on a continuously flowing dust loaded jet illuminated by a polarized red HeNe laser beam. The scattering is averaged over the population of the dust particles in the jet, which can be determined independently, and give the “volume scattering function” for the two directions of polarization directly. While results for spherical particles are in good agreement with Mie theory, those for arbitrary particles show conspicuous deviations.

scholarly journals Numerical Aspects of Particle-in-Cell Simulations for Plasma-Motion Modeling of Electric Thrusters

Aerospace ◽  
2021 ◽  
Vol 8 (5) ◽  
pp. 138
Author(s):  
Giuseppe Gallo ◽  
Adriano Isoldi ◽  
Dario Del Gatto ◽  
Raffaele Savino ◽  
Amedeo Capozzoli ◽  
...  
Keyword(s):  
Numerical Model ◽  
Computing Time ◽  
Computational Time ◽  
Electric Motors ◽  
Motion Modeling ◽  
Particle In Cell ◽  
Computing Platform ◽  
Hall Effect Thruster ◽  
Set Up ◽  
Pic Code

The present work is focused on a detailed description of an in-house, particle-in-cell code developed by the authors, whose main aim is to perform highly accurate plasma simulations on an off-the-shelf computing platform in a relatively short computational time, despite the large number of macro-particles employed in the computation. A smart strategy to set up the code is proposed, and in particular, the parallel calculation in GPU is explored as a possible solution for the reduction in computing time. An application on a Hall-effect thruster is shown to validate the PIC numerical model and to highlight the strengths of introducing highly accurate schemes for the electric field interpolation and the macroparticle trajectory integration in the time. A further application on a helicon double-layer thruster is presented, in which the particle-in-cell (PIC) code is used as a fast tool to analyze the performance of these specific electric motors.

The Reduction of Bias Error in Transfer Function Estimates Using FFT-Based Analyzers

1984 ◽  
Vol 106 (1) ◽  
pp. 29-35 ◽  
Author(s):  
P. Cawley
Keyword(s):  
Transfer Function ◽  
Random Excitation ◽  
Analogue Computer ◽  
Bias Error ◽  
Testing Time ◽  
Theoretical Predictions ◽  
Set Up ◽  
Modal Mass ◽  
Time Required ◽  
Good Agreement

The susceptibility to bias error of two methods for computing transfer (frequency response) functions from spectra produced by FFT-based analyzers using random excitation has been investigated. Results from tests with an FFT analyzer on a single degree-of-freedom system set up on an analogue computer show good agreement with the theoretical predictions. It has been shown that, around resonance, the bias error in the transfer function estimate H2 (Syy/Sxy*) is considerably less than that in the more commonly used estimate, H1 (Sxy/Sxx). The record length, and hence the testing time, required for a given accuracy is reduced by over 50 percent if the H2 calculation procedure is used. The analysis has also shown that if shaker excitation is used on lightly damped structures with low modal mass, it is important to minimize the mass of the force gage and the moving element of the shaker.

Simulating the behaviour of folded cartons during complex packing operations

2006 ◽  
Vol 220 (12) ◽  
pp. 1797-1811 ◽  
Author(s):  
D M Sirkett ◽  
B J Hicks ◽  
C Berry ◽  
G Mullineux ◽  
A J Medland
Keyword(s):  
End Users ◽  
Fundamental Issue ◽  
Trial And Error ◽  
Machine Material ◽  
Packaging Machine ◽  
Set Up ◽  
Fine Tune ◽  
Responsiveness To Change ◽  
Lower Production ◽  
Good Agreement

The folding carton is a widely used packaging solution. Recent European Union packaging legislation has forced carton manufacturers to use lighter-weight grades of carton board. This typically results in a reduction in board stiffness, which can lead to decreased process efficacy or even prevent successful processing. In order to overcome this, end-users lower production rates and fine-tune packaging machine settings for each pack and material. This trial-and-error approach is necessary because the rules relating machine set-up to pack design and material properties are not generally well known. The present study addresses this fundamental issue through the creation of a finite-element computer simulation of carton processing. Mechanical testing was performed to ascertain the key mechanical properties of the carton walls and creases. The carton model was validated against the experimental results and was then subjected to the machine-material interactions that take place during complex packaging operations. The overall approach was validated and the simulation showed good agreement with the physical system. The results of the simulation can be used to determine guidelines relating machine set-up criteria to carton properties. This will improve responsiveness to change and will ultimately allow end-users to process thinner lighter-weight materials more effectively.

Effect of Dispersant on the Measurement of Particle Size Distribution of Titanium Dioxide

2012 ◽  
Vol 512-515 ◽  
pp. 261-264
Author(s):  
Li Shen ◽  
Jin Hu ◽  
Da Ping Wu
Keyword(s):  
Particle Size ◽  
Titanium Dioxide ◽  
Zeta Potential ◽  
Particle Size Distribution ◽  
Size Distribution ◽  
Anionic Surfactant ◽  
Sodium Sulfate ◽  
Aqueous Media ◽  
Rutile Tio2 ◽  
Tio2 Particles

As anionic surfactant, a commercial salt of lauryl sodium sulfate was used. The effects of different amounts of dispersant on the measurement of particle size distribution between two titanium dioxide powders (anatase and rutile) in aqueous media were discussed. Diluted aqueous suspensions were characterized in terms of particle size distribution and zeta potential. The results demonstrate that the measurement of particle size distribution strongly depends on the amounts of dispersant. The amounts of dispersant have a significant effect on the behavior of the rutile-TiO2 particles. The particle size first decreases significantly with an increase in the amounts of dispersant and then lesser increases with a further increase in the amounts of dispersant. The tendency show significant differences between two particles.

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