scholarly journals Minerály skupiny columbitu a mikrolitu v granitovom pegmatite pri Liešťanoch: prvý výskyt vzácnoprvkovej Nb-Ta mineralizácie v Strážovských vrchoch (Slovenská republika)

2020 ◽  
Vol 28 (2) ◽  
pp. 347-352
Author(s):  
Pavel Uher ◽  
Martin Števko ◽  
Sergii Kurylo
Keyword(s):  
Crystalline Basement ◽  
Western Carpathians ◽  
Granitic Pegmatite ◽  
Chemical Compositions ◽  
Accessory Minerals ◽  
Magmatic Origin ◽  
Euhedral Crystal ◽  
Compositional Variations ◽  
Central Western Carpathians

Accessory minerals of columbite and microlite groups were identified in granitic pegmatite dike intruded into parental Carboniferous (~350 Ma) leucogranites of the crystalline basement of the Tatric Unit, Central Western Carpathians. The pegmatite is situated on E slope of Bystrý Hill near Liešťany village, the Strážovské vrchy Mts., Slovakia. Primary columbite-(Fe) forms euhedral crystal (~3 mm across) with diffuse internal zoning reflecting a relatively small compositional variations: Mn/(Mn + Fe) = 0.40 - 0.45 and Ta/(Ta + Nb) = 0.21 - 0.24. Secondary anhedral domains of Ta-rich columbite-(Fe) to tantalite-(Fe) (≤200 μm) with Mn/(Mn + Fe) = 0.45 - 0.47 and Ta/(Ta + Nb) = 0.45 - 0.62 partly replace primary columbite-(Fe) along crystal rims. Moreover, secondary subhedral crystals of microlite-group minerals (≤25 μm) form fracture fillings in columbite-(Fe). The microlites show uniform high Ta/(Ta + Nb) ratio (0.77 - 0.80) and U content (7.7 - 10.2 wt.% UO2; 0.18 - 0.21 U apfu) but different contents of F, Ca, Na and Pb: central parts locally show fluorcalciomicrolite composition (~2 wt.% F, ~9.5 wt.% CaO, 2.2 - 2.7 wt.% Na2O), whereas main microlite mass forms zero-valent-dominant microlite with inclusions (≤8 μm) of Pb-rich zero-valent-dominant microlite (16.8 - 19.7 wt.% PbO; 0.46 - 0.56 Pb apfu). Textural relationships and chemical compositions of Nb-Ta minerals indicate primary magmatic origin of columbite-(Fe) and post-magmatic (early subsolidus to late hydrothermal) formation of secondary Ta-rich columbite-(Fe) to tantalite-(Fe) and microlite-group minerals.

scholarly journals Cretaceous—Quaternary tectonic evolution of the Tatra Mts (Western Carpathians): constraints from structural, sedimentary, geomorphological, and fission track data

2014 ◽  
Vol 65 (4) ◽  
pp. 307-326 ◽  
Author(s):  
Silvia Králiková ◽  
Rastislav Vojtko ◽  
Ubomír Sliva ◽  
Jozef Minár ◽  
Bernhard Fügenschuh ◽  
...  
Keyword(s):  
Tectonic Evolution ◽  
Elevated Temperatures ◽  
Fission Track ◽  
Crystalline Basement ◽  
Western Carpathians ◽  
Tectonic Activity ◽  
Zircon Fission Track ◽  
Tatra Mts ◽  
Fission Track Ages ◽  
Central Western Carpathians

Abstract The Tatra Mts area, located in the northernmost part of Central Western Carpathians on the border between Slovakia and Poland, underwent a complex Alpine tectonic evolution. This study integrates structural, sedimentary, and geomorphological data combined with fission track data from the Variscan granite rocks to discuss the Cretaceous to Quaternary tectonic and landscape evolution of the Tatra Mts. The presented data can be correlated with five principal tectonic stages (TS), including neotectonics. TS-1 (~95-80 Ma) is related to mid-Cretaceous nappe stacking when the Tatric Unit was overlain by Mesozoic sequences of the Fatric and Hronic Nappes. After nappe stacking the Tatric crystalline basement was exhumed (and cooled) in response to the Late Cretaceous/Paleogene orogenic collapse followed by orogen-parallel extension. This is supported by 70 to 60 Ma old zircon fission track ages. Extensional tectonics were replaced by transpression to transtension during the Late Paleocene to Eocene (TS-2; ~80-45 Ma). TS-3 (~45-20 Ma) is documented by thick Oligocene-lowermost Miocene sediments of the Central Carpathian Paleogene Basin which kept the underlying Tatric crystalline basement at elevated temperatures (ca. > 120 °C and < 200 °C). The TS-4 (~20-7 Ma) is linked to slow Miocene exhumation rate of the Tatric crystalline basement, as it is indicated by apatite fission track data of 9-12 Ma. The final shaping of the Tatra Mts has been linked to accelerated tectonic activity since the Pliocene (TS-5; ~7-0 Ma).

scholarly journals Komplexní magmaticko-hydrotermální vývoj columbitu, mikrolitu a fersmitu z beryl-columbitového pegmatitu D6e u Maršíkova, Česká republika

2020 ◽  
Vol 28 (1) ◽  
pp. 23-34 ◽  
Author(s):  
Štěpán Chládek ◽  
Pavel Uher
Keyword(s):  
Czech Republic ◽  
Granitic Pegmatite ◽  
Accessory Minerals ◽  
Partial Dissolution ◽  
Pegmatite Body ◽  
Magmatic Fluids ◽  
Compositional Variations ◽  
Homogeneous Pattern ◽  
Oscillatory Zonation

The recently rediscovered small D6e granitic pegmatite body, enclosed in amphibole gneiss of the Sobotín amfibolite massif (Jeseníky Mountains, Czech Republic), is characterized by numerous accessory minerals, including common columbite group minerals (CGM) and minor microlite and fersmite related to blocky K-feldspar unit. The CGM show complex internal zoning. Primary magmatic columbite-(Mn) occurs as corroded domains of prevailing homogeneous pattern, followed by less evolved oscillatory zonation. Primary CGM were overprinted by extensive recrystallization controlled by late-magmatic to post-magmatic fluids and leading to a formation of complex patchy and convolute oscillatory domains of secondary (hydrothermal) CGM. Primary columbite-(Mn) shows significantly limited Ta/(Ta+Nb) and Mn/(Mn+Fe) ratios, whereas secondary columbite-(Fe) to -(Mn) show slightly wider Fe-Mn and Nb-Ta compositional variations. Complex textures and the element fluctuations indicate a partial dissolution-reprecipitation of primary CGM caused by late- to post-magmatic fluids. Moreover, late calciomicrolite I, II and fersmite precipitated on the cracks of columbite crystals. Rare U-rich calciomicrolite I was extensively replaced by fersmite and oscillatorily zoned U-poor calciomicrolite II, slightly enriched in F. Their formation sequestrated part of hydrotermally released Na, Ca, U and represents the final subsolidus fluid-driven stage of the pegmatite evolution. Textural and compositional variations of Nb-Ta mineralization point to a complex magmatic to hydrothermal evolution of the D6e beryl-columbite pegmatite similar to other pegmatites in this region.

Exemples de mélange de magmas en contexte plutonique: les enclaves des tonalites–granodiorites du massif de Bono (Sardaigne septentrionale)

1989 ◽  
Vol 26 (6) ◽  
pp. 1264-1281 ◽  
Author(s):  
C. Cocirta ◽  
J. B. Orsini ◽  
C. Coulon
Keyword(s):  
Geochemical Data ◽  
Mixing Process ◽  
Calc Alkaline ◽  
Specific Group ◽  
Mineralogical Analysis ◽  
Magmatic Origin ◽  
Interaction Mechanisms ◽  
Compositional Variations ◽  
End Members ◽  
Host Rocks

In calc-alkaline orogenic plutons, the dark xenoliths and their host rocks must be considered the expression of partial mixing of magma.Three associations of this type have been investigated and are illustrated by the Bono pluton (northern Sardinia)— a composite pluton including three intrusives of different nature (tonalitic to granodioritic) and containing a very large number of basaltic xenoliths of magmatic origin. Detailed mineralogical analysis of the two end members in each association, coupled with geochemical data, has determined the major petrogenetic mechanisms intervening in the mixing process in a plutonic setting: temperature equilibration, mechanical exchanges of crystals, chemical exchanges, etc. The most important result of this article, however, is to show that each intrusion is related to a specific group of xenoliths that is characterized by constant FeOt/MgO. The latter reflects the different composition of basaltic components, and it is concluded that each intrusive event is associated with a unique mixing episode. As in volcanic settings, the mixing process may have initiated the intrusion.The extreme compositional variations in the magmatic xenoliths, recognized in several series of orogenic plutons, is explained here by different initial basaltic end members and by variation in the intensity of the interaction mechanisms. [Journal Translation]

scholarly journals A Middle Triassic pachypleurosaur (Diapsida: Eosauropterygia) from a restricted carbonate ramp in the Western Carpathians (Gutenstein Formation, Fatric Unit): paleogeographic implications

2018 ◽  
Vol 69 (1) ◽  
pp. 3-16 ◽  
Author(s):  
Andrej Čerňanský ◽  
Nicole Klein ◽  
Ján Soták ◽  
Mário Olšavský ◽  
Juraj Šurka ◽  
...  
Keyword(s):  
Middle Triassic ◽  
Carbonate Platform ◽  
Small Body ◽  
Western Carpathians ◽  
Subtidal Zone ◽  
Postcranial Skeleton ◽  
Tatra Mountains ◽  
Carbonate Ramps ◽  
Shallow Subtidal ◽  
Central Western Carpathians

AbstractAn eosauropterygian skeleton found in the Middle Triassic (upper Anisian) Gutenstein Formation of the Fatric Unit (Demänovská dolina Valley, Low Tatra Mountains, Slovakia) represents the earliest known occurrence of marine tetrapods in the Western Carpathians. The specimen represents a partly articulated portion of the postcranial skeleton (nine dorsal vertebrae, coracoid, ribs, gastral ribs, pelvic girdle, femur and one zeugopodial element). It is assigned to the Pachypleurosauria, more precisely to theSerpianosaurus–Neusticosaurusclade based on the following combination of features: (1) small body size; (2) morphology of vertebrae, ribs and femur; (3) tripartite gastral ribs; and (4) microanatomy of the femur as revealed by μCT. Members of this clade were described from the epicontinental Germanic Basin and the Alpine Triassic (now southern Germany, Switzerland, Italy), and possibly from Spain. This finding shows that pachypleurosaur reptiles attained a broader geographical distribution during the Middle Triassic, with their geographical range reaching to the Central Western Carpathians. Pachypleurosaurs are often found in sediments formed in shallow, hypersaline carbonate-platform environments. The specimen found here occurs in a succession with vermicular limestones in a shallow subtidal zone and stromatolitic limestones in a peritidal zone, indicating that pachypleurosaurs inhabited hypersaline, restricted carbonate ramps in the Western Carpathians.

Mineralogical and chemical heterogeneity of three standard clay mineral samples

Clay Minerals ◽  
1996 ◽  
Vol 31 (3) ◽  
pp. 417-422 ◽  
Author(s):  
H. M. Köster
Keyword(s):  
Particle Size ◽  
Chemical Analysis ◽  
Clay Mineral ◽  
Chemical Heterogeneity ◽  
X Ray Diffraction ◽  
Accessory Minerals ◽  
Size Fractions ◽  
X Ray ◽  
Compositional Variations

AbstractMineralogical and chemical heterogeneity within three standard clay mineral samples have been identified by X-ray diffraction and chemical analysis of various size-fractions. This heterogeneity is partly attributed to accessory minerals, but mostly to structural and compositional variations in the 2:1 layer minerals of different particle size in the same specimen.

scholarly journals The Distribution of Rare Metals in the LCT Pegmatites from the Giraúl Field, Angola

Minerals ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 580
Author(s):  
Gonçalves ◽  
Melgarejo ◽  
Alfonso ◽  
Amores ◽  
Paniagua ◽  
...  
Keyword(s):  
Grain Size ◽  
Hydrothermal Fluids ◽  
Granitic Pegmatite ◽  
Rare Metals ◽  
Accessory Minerals ◽  
Critical Elements ◽  
Incompatible Elements ◽  
Pegmatite Body ◽  
Quartz Core ◽  
Oxide Minerals

The Giraúl granitic pegmatite field in Angola is composed of five pegmatite types, the most evolved belong to the beryl-columbite, beryl-columbite-phosphate and spodumene types. Pegmatites are concentrically zoned with increased grain size toward a quartz core; the most evolved pegmatites have well-developed replacement units. These pegmatites are rich in Nb-Ta oxide minerals and the field has a moderate interest for critical elements such as Ta and Hf. Tourmaline, garnet and micas occur as accessory minerals. The abundance of Zr and Nb-Ta minerals increases with the evolution of the pegmatites, as well as the proportions of beryl and Li-rich minerals. The Ta/(Ta + Nb) ratio in Nb-Ta oxide minerals and the Hf/(Hf + Zr) ratio in zircon also increase with the evolution of the pegmatites and within each pegmatite body from border to inner zones, and especially in the late veins and subsolidus replacements. Textural patterns and occurrence of late veins with Ta-rich minerals suggest that Nb and especially Ta can be enriched in late hydrothermal fluids exsolved from the magma, along with Hf and other incompatible elements as Sn, U, Pb, Sb and Bi.

scholarly journals Structural pattern and emplacement mechanisms of the Krížna cover nappe (Central Western Carpathians)

2012 ◽  
Vol 63 (1) ◽  
pp. 13-32 ◽  
Author(s):  
Roberta Prokešová ◽  
Dušan Plašienka ◽  
Rastislav Milovský
Keyword(s):  
Driving Forces ◽  
Structural Evolution ◽  
Evolutionary Model ◽  
Structural Data ◽  
Western Carpathians ◽  
Low Grade ◽  
Structural Pattern ◽  
Thrust Tectonics ◽  
Central Western Carpathians ◽  
Nappe Emplacement

Structural pattern and emplacement mechanisms of the Krížna cover nappe (Central Western Carpathians)The Central Western Carpathians are characterized by both the thick- and thin-skinned thrust tectonics that originated during the Cretaceous. The Krížna Unit (Fatric Superunit) with a thickness of only a few km is the most widespread cover nappe system that completely overthrusts the Tatric basement/cover superunit over an area of about 12 thousands square km. In searching for a reliable model of its origin and emplacement, we have collected structural data throughout the nappe body from its hinterland backstop (Veporic Superunit) to its frontal parts. Fluid inclusion (FI) data from carbonate cataclastic rocks occurring at the nappe sole provided useful information about the p-T conditions during the nappe transport. The crucial phenomena considered for formulation of our evolutionary model are: (1) the nappe was derived from a broad rifted basinal area bounded by elevated domains; (2) the nappe body is composed of alternating, rheologically very variable sedimentary rock complexes, hence creating a mechanically stratified multilayer; (3) presence of soft strata serving as décollement horizons; (4) stress and strain gradients increasing towards the backstop; (5) progressive internal deformation at very low-grade conditions partitioned into several deformation stages reflecting varying external constraints for the nappe movement; (6) a very weak nappe sole formed by cataclasites indicating fluid-assisted nappe transport during all stages; (7) injection of hot overpressured fluids from external sources (deformed basement units) facilitating frontal ramp overthrusting under supralithostatic conditions. It was found that no simple mechanical model can be applied, but that all known principal emplacement mechanisms and driving forces temporarily participated in progressive structural evolution of the nappe. The rear compression operated during the early stages, when the sedimentary succession was detached, shortened and transported over the frontal ramp. Subsequently, gravity spreading and gliding governed the final nappe emplacement over the unconstrained basinal foreland.

Coupled substitutions in goldfieldite–tetrahedrite minerals from the Iriki mine, Japan

1991 ◽  
Vol 55 (381) ◽  
pp. 515-519 ◽  
Author(s):  
Masaaki Shimizu ◽  
Chris J. Stanley
Keyword(s):  
Solid Solution ◽  
Continuous Solid Solution ◽  
Chemical Compositions ◽  
Coupled Substitution ◽  
Compositional Variations ◽  
The Ideal

AbstractChemical compositions of goldfieldite-tetrahedrite series minerals from the Iriki mine in Japan are reported for the frst time. The compositional variations of coexisting goldfieldite [atomic proportion Te > (Sb + As + Bi)], tellurian tetrahedrite [Sb > (Te + As + Bi)], and Te-free tetrahedrite from this locality are considered alongside data from the literature. These show that the substitution of (Sb, As)3+ for Te4+ in natural goldfieldite-tetrahedrite series minerals occurs by the following two mechanisms: (i) tetrahedrite, and goldfieldite, form a continuous solid-solution according to the coupled substitution of Cu+Te4+ for (Cu,Fe,Zn)2+(Sb,As)3+, and (ii) goldfieldite, and the ideal end-member, might also form a continuous solid-solution by the coupled substitution of ☐(vacancy)Te4+ for Cu+(Sb,As)3+. According to this work, the general formulae of tellurian tetrahedrite and goldfieldite are, therefore, respectively, , with x = 0 to 2 and , with y = 0 to 2.

Origin of placer laurite from Borneo: Se and As contents, and S isotopic compositions

2004 ◽  
Vol 68 (2) ◽  
pp. 353-368 ◽  
Author(s):  
K. H. Hattori ◽  
L. J. Cabri ◽  
B. Johanson ◽  
M. L. Zientek
Keyword(s):  
Solid Solutions ◽  
Ultramafic Rocks ◽  
Compositional Variation ◽  
Chemical Compositions ◽  
Group Mineral ◽  
Isotopic Compositions ◽  
Ophiolitic Rocks ◽  
Stage Process ◽  
Compositional Variations ◽  
Spherical Grains

AbstractWe examined grains of the platinum-group mineral, laurite (RuS2), from the type locality, Pontyn River, Tanah Laut, Borneo, and from the Tambanio River, southeast Borneo. The grains show a variety of morphologies, including euhedral grains with conchoidal fractures and pits, and spherical grains with no crystal faces, probably because of abrasion. Inclusions are rare, but one grain contains Ca-Al amphibole inclusions, and another contains an inclusion of chalcopyrite+bornite+pentlandite+heazlewoodite (Ni3S2) that is considered to have formed by a two-stage process of exsolution and crystallization from a once homogeneous Fe-Cu-Ni sulphide melt.All grains examined are solid solutions of Ru and Os with Ir (2.71 –11.76 wt.%) and Pd (0.31–0.66 wt.%). Their compositions are similar to laurite from ophiolitic rocks. The compositions show broad negative correlations between Os and Ir, between As and Ir, and between As (0.4 –0.74 wt.%) and Se (140 to 240 ppm). Laurite with higher Os contains more Se and less Ir and As. The negative correlations between Se and As may be attributed to their occupancy of the S site, but the compositional variations of Os, Ir and As probably reflect the compositional variation of rocks where the crystals grew.Ratios of S/Se in laurite show a narrow spread from 1380 to 2300, which are similar to ratios for sulphides from the refractory sub-arc mantle. Sulphur isotopic compositions of laurite are independent of chemical compositions and morphologies and are similar to the chondritic value of 0%. The data suggest that S in laurite has not undergone redox changes and originated from the refractory mantle. The data support the formation of laurite in the residual mantle or in a magma generated from such a refractory mantle, followed by erosion after the obduction of the host ultramafic rocks.

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