Alkali-activated portland cement-based blended cements

2019 ◽  
Vol 138 (2) ◽  
pp. 879-887
Author(s):  
Pavel Krivenko ◽  
Danutė Vaičiukynienė ◽  
Aras Kantautas ◽  
Vitoldas Vaitkevičius ◽  
Evaldas Šerelis

2021 ◽  
Vol 19 (4) ◽  
pp. 315-328
Author(s):  
N.M. Khalil ◽  
Yousif Algamal

This work aims at maximum exploitation of petroleum waste sludge as additive to portland cement to prepare blended cements and hence increasing its production capacity without further firing. This will decrease the main cement industry problems involving environmental pollution such as releasing gases and high-energy consumption during industry and hence maximizes the production economics. Six batches of ordinary portland cement (OPC) mixed with different proportions of petroleum waste sludge (PWS) donated as C1 (control batch contains no PWS), C2 (contains 90 wt.% of OPC+10 wt.% of PWS), C3 (contains 80 wt.% of OPC+20 wt.% of PWS), C4 (contains 70 wt.% of OPC+30 wt.% of PWS), C4 (contains 60 wt.% of OPC+40 wt.% of PWS) and C6 (contains 50 wt.% of OPC+50 wt.% of PWS), were prepared and mixed individually with the suitable amount of mixing water. Cement mixes C2, C3 and C4 showed improved cementing and physicomechanical properties compared with pure cement (C1) with special concern of mix C4. Such improvement is due to the relatively higher surface area as well as the high content of kaolinite and quartz in the added PWS (high pozzalanity) favoring the hydration process evidenced by the increase in the cement hydration product (portlandite mineral (Ca (OH) 2).


Materials ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 3467
Author(s):  
Ankit Kothari ◽  
Karin Habermehl-Cwirzen ◽  
Hans Hedlund ◽  
Andrzej Cwirzen

Most of the currently used concretes are based on ordinary Portland cement (OPC) which results in a high carbon dioxide footprint and thus has a negative environmental impact. Replacing OPCs, partially or fully by ecological binders, i.e., supplementary cementitious materials (SCMs) or alternative binders, aims to decrease the carbon dioxide footprint. Both solutions introduced a number of technological problems, including their performance, when exposed to low, subfreezing temperatures during casting operations and the hardening stage. This review indicates that the present knowledge enables the production of OPC-based concretes at temperatures as low as −10 °C, without the need of any additional measures such as, e.g., heating. Conversely, composite cements containing SCMs or alkali-activated binders (AACs) showed mixed performances, ranging from inferior to superior in comparison with OPC. Most concretes based on composite cements require pre/post heat curing or only a short exposure to sub-zero temperatures. At the same time, certain alkali-activated systems performed very well even at −20 °C without the need for additional curing. Chemical admixtures developed for OPC do not always perform well in other binder systems. This review showed that there is only a limited knowledge on how chemical admixtures work in ecological concretes at low temperatures and how to accelerate the hydration rate of composite cements containing high amounts of SCMs or AACs, when these are cured at subfreezing temperatures.


Author(s):  
P V Krivenko ◽  
O M Petropavlovskyi ◽  
I I Rudenko ◽  
O P Konstantynovskyi ◽  
A V Kovalchuk

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1302
Author(s):  
Andrés Játiva ◽  
Evelyn Ruales ◽  
Miren Etxeberria

The construction industry is affected by the constant growth in the populations of urban areas. The demand for cement production has an increasing environmental impact, and there are urgent demands for alternative sustainable solutions. Volcanic ash (VA) is an abundant low-cost material that, because of its chemical composition and amorphous atomic structure, has been considered as a suitable material to replace Portland cement clinker for use as a binder in cement production. In the last decade, there has been interest in using alkali-activated VA material as an alternative material to replace ordinary Portland cement. In this way, a valuable product may be derived from a currently under-utilized material. Additionally, alkali-activated VA-based materials may be suitable for building applications because of their good densification behaviour, mechanical properties and low porosity. This article describes the most relevant findings from researchers around the world on the role of the chemical composition and mineral contents of VA on reactivity during the alkali-activation reaction; the effect of synthesis factors, which include the concentration of the alkaline activator, the solution-to-binder ratio and the curing conditions, on the properties of alkali-activated VA-based materials; and the mechanical performance and durability properties of these materials.


2021 ◽  
Vol 11 (23) ◽  
pp. 11286
Author(s):  
Marina Paula Secco ◽  
Débora Thaís Mesavilla ◽  
Márcio Felipe Floss ◽  
Nilo Cesar Consoli ◽  
Tiago Miranda ◽  
...  

The increasingly strong search for alternative materials to Portland cement has resulted in the development of alkali-activated cements (AAC) that are very effective at using industrial by-products as raw materials, which also contributes to the volume reduction in landfilled waste. Several studies targeting the development of AAC—based on wastes containing silicon and calcium—for chemical stabilization of soils have demonstrated their excellent performance in terms of durability and mechanical performance. However, most of these studies are confined to a laboratory characterization, ignoring the influence and viability of the in situ construction process and, also important, of the in situ curing conditions. The present work investigated the field application of an AAC based on carbide lime and glass wastes to stabilize fine sand acting as a superficial foundation. The assessment was supported on the unconfined compressive strength (UCS) and initial shear modulus (G0) of the developed material, and the field results were compared with those prepared in the laboratory, up to 120 days curing. In situ tests were also developed on the field layers (with diameters of 450 and 900 mm and thickness of 300 mm) after different curing times. To establish a reference, the mentioned precursors were either activated with a sodium hydroxide solution or hydrated with water (given the reactivity of the lime). The results showed that the AAC-based mixtures developed greater strength and stiffness at a faster rate than the water-based mixtures. Specimens cured under controlled laboratory conditions showed better results than the samples collected in the field. The inclusion of the stabilized layers clearly increased the load-bearing capacity of the natural soil, while the different diameters produced different failure mechanisms, similar to those found in Portland cement stabilization.


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