scholarly journals Flexible conformation in organic matter coatings: An hypothesis about soil water repellency

2000 ◽  
Vol 80 (1) ◽  
pp. 143-152 ◽  
Author(s):  
J. L. Roy ◽  
W. B. McGill
Keyword(s):  
Soil Water ◽  
Conformational Changes ◽  
Contaminated Soils ◽  
Water Repellency ◽  
Supporting Evidence ◽  
Soil Water Repellency ◽  
Nonpolar Solvents ◽  
Causative Agents ◽  
Subsequent Exposure ◽  
Induced Changes

Some soils develop severe water repellency several years or decades following oil contamination. We previously reported that soil water repellency is completely eliminated by extraction with amphiphilic solvents, but barely reduced by extraction with nonpolar solvents. We report here on solvent-induced reversible soil water repellency. Our results indicate that: (i) water repellency is completely eliminated following extraction with amphiphilic solvent, but partially restored following subsequent exposure to nonpolar, non-H-bonding solvent; (ii) extraction with nonpolar, non-H-bonding solvent generates water repellency in readily wettable control wettable soils, but not in pristine wettable soils, and (iii) repeated sequential extractions alternating between amphiphilic and nonpolar, non-H-bonding solvent increase extractable material and reduce the magnitude of solvent-induced soil water repellency with time.We attribute reversible soil water repellency to solvent-induced changes in the conformation of causative agents of soil water repellency. Recent literature reports on the structural flexibility of "insoluble" organic macromolecules are discussed for supporting evidence. We propose that exposure to nonpolar, non-H-bonding solvents induces stretching of surface-exposed, nonpolar moieties (i.e. alkyl chains), whereas exposure to polar, H-bonding solvents induces their coiling. These solvent-induced conformational changes are retained upon solvent removal. Our results indicate that the wettability of oil-contaminated soils depends on both the interfacial conformation and the fractional coverage of their surface-exposed nonpolar moieties. Key words: Soil water repellency, crude oil, hydrophobic soil, conformational flexibility, swelling, solvents

Petroleum residues as water-repellent substances in weathered nonwettable oil-contaminated soils

1999 ◽  
Vol 79 (2) ◽  
pp. 367-380 ◽  
Author(s):  
Julie L. Roy ◽  
William B. McGill ◽  
Marvin D. Rawluk
Keyword(s):  
Soil Water ◽  
Contaminated Soils ◽  
Impact Ionization ◽  
Water Repellency ◽  
Solvent Mixture ◽  
Water Repellent ◽  
Soil Water Repellency ◽  
Petroleum Origin ◽  
Soil Hydrophobicity ◽  
Gas Chromatography Mass Spectroscopy

Some soils develop severe water repellency several years or decades following oil contamination. We previously reported on the characteristics of three such soils. Here we report on the characteristics of putative water-repellent substances in them. We examined the effectiveness of various polar, nonpolar and amphiphilic solvents for removal of water-repellent substances in three nonwettable soils. Only the amphiphilic solvent mixture isopropanol/14.8 M ammonia (7:3, vol/vol) (IPA/NH4OH) completely eliminated soil water repellency in all three soils. We thus define putative water-repellent substances as those substances whose removal from soil by IPA/NH4OH removes water repellency. High-resolution CPMAS 13C-NMR spectroscopy and thermal desorption followed by conventional gas chromatography/mass spectroscopy with electron impact ionization (GC/EI/MS) and GC/MS with chemical ionization (GC/CI/MS) were used to characterize extracted putative water-repellent substances. We conclude that: (i) the identified representatives of these substances consist mostly of homologous series of long-chain and polycyclic aliphatic organic compounds; namely, n-fatty acids, n-alkanes, and cycloalkanes, and that (ii) they are of petroleum origin rather than plant or microbial origin. Key words: Soil hydrophobicity, petroleum hydrocarbons, soil water repellency, amphiphilic solvents, crude oil, nonwettable soil

Investigation into mechanisms leading to the development, spread and persistence of soil water repellency following contamination by crude oil

2000 ◽  
Vol 80 (4) ◽  
pp. 595-606 ◽  
Author(s):  
J. L. Roy ◽  
W. B. McGill
Keyword(s):  
Crude Oil ◽  
Soil Water ◽  
Oil Spill ◽  
Water Repellency ◽  
Vapour Phase ◽  
Water Repellent ◽  
Soil Sorption ◽  
Soil Water Repellency ◽  
Causative Agents ◽  
Crude Oil Spill

We investigated mechanisms by which soil water repellency may develop, spread and persist at old crude oil spill sites. We tested if its development may be due to soil sorption of vapour-phase petroleum compounds, its spread due to mechanical dispersal and mixing, and its persistence due to association of causative agents with humin and soil mineral surfaces. Development. Readily wettable soils acquired water repellency following 60 d of storage in the presence of oil-contaminated subsoil material. Change in soil wettability was attributed to soil sorption of vapour-phase petroleum compounds emanating from the contaminated material. We cite literature reports indicating that liquid-phase petroleum compounds can also cause soil water repellency. To that effect, we report how we tested and finally rejected the hypothesis that sorption of petroleum asphaltenes might be the sole cause of soil water repellency. Spread. We describe how mixing one mass unit of water-repellent soil with two to four mass units of wettable adjacent soil is sufficient to impart severe water repellency to soil mixes from three sites. Persistence. The water-repellent condition found at old crude oil spill sites is highly resistant to natural weathering and nondestructive extraction procedures. We show here that it also resists exhaustive extraction with 0.1 M NaOH and conclude that causative agents of soil water repellency are at least not solely associated with humic and fulvic acid fractions. Key words: Soil water repellency, asphaltenes, cultivation, humic acids, sorption, crude oil

Reaction of soil water repellency to artificially induced changes in soil pH

Geoderma ◽  
2010 ◽  
Vol 158 (3-4) ◽  
pp. 375-384 ◽  
Author(s):  
D. Diehl ◽  
J.V. Bayer ◽  
S.K. Woche ◽  
R. Bryant ◽  
S.H. Doerr ◽  
...  
Keyword(s):  
Soil Water ◽  
Soil Ph ◽  
Water Repellency ◽  
Soil Water Repellency ◽  
Induced Changes

Fire-induced changes in soil water repellency increased fingered flow and runoff rates following the 2004 Huelva wildfire

2010 ◽  
Vol 25 (10) ◽  
pp. 1614-1629 ◽  
Author(s):  
Arturo J. P. Granged ◽  
Antonio Jordán ◽  
Lorena M. Zavala ◽  
Gema Bárcenas
Keyword(s):  
Soil Water ◽  
Water Repellency ◽  
Soil Water Repellency ◽  
Induced Changes

Soil water repellency in sandy soil depends on the soil drying method, incubation temperature and specific surface area

Geoderma ◽  
2021 ◽  
Vol 402 ◽  
pp. 115264
Author(s):  
Enoch V.S. Wong ◽  
Philip R. Ward ◽  
Daniel V. Murphy ◽  
Matthias Leopold ◽  
Louise Barton
Keyword(s):  
Specific Surface ◽  
Soil Water ◽  
Surface Area ◽  
Specific Surface Area ◽  
Sandy Soil ◽  
Incubation Temperature ◽  
Water Repellency ◽  
Soil Drying ◽  
Drying Method ◽  
Soil Water Repellency

The use of visible and near-infrared spectroscopy for the analysis of soil water repellency

2014 ◽  
Vol 65 (3) ◽  
pp. 360-368 ◽  
Author(s):  
I. Kim ◽  
R. R. Pullanagari ◽  
M. Deurer ◽  
R. Singh ◽  
K. Y. Huh ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Soil Water ◽  
Near Infrared Spectroscopy ◽  
Near Infrared ◽  
Water Repellency ◽  
Soil Water Repellency

Soil water repellency persistence after recurrent forest fires on Mount Carmel, Israel

2013 ◽  
Vol 22 (4) ◽  
pp. 515 ◽  
Author(s):  
Naama Tessler ◽  
Lea Wittenberg ◽  
Noam Greenbaum
Keyword(s):  
Organic Matter ◽  
Soil Water ◽  
Forest Fires ◽  
Water Drop ◽  
Chemical Properties ◽  
Water Repellency ◽  
Mediterranean Ecosystem ◽  
Long Term Effects ◽  
Soil Water Repellency ◽  
Chemical Properties Of Soils

Variations in forest fires regime affect: (1) the natural patterns of community structure and vegetation; (2) the physico-chemical properties of soils and consequently (3) runoff, erosion and sediment yield. In recent decades the Mediterranean ecosystem of Mount Carmel, north-western Israel, is subjected to an increasing number of forest fires, thus, the objectives of the study were to evaluate the long-term effects of single and recurrent fires on soil water repellency (WR) and organic matter (OM) content. Water repellency was studied by applying water drop penetration time (WDPT) tests at sites burnt by single-fire, two fires, three fires and unburnt control sites. Water repellency in the burnt sites was significantly lower than in the unburnt control sites, and the soil maintained its wettability for more than 2 decades, whereas after recurrent fires, the rehabilitation was more complicated and protracted. The OM content was significantly lower after recurrent than after a single fire, causing a clear proportional decrease in WR. The rehabilitation of WR to natural values is highly dependent on restoration of organic matter and revegetation. Recurrent fires may cause a delay in recovery and reduced productivity of the soil for a long period.

Organic Matter Fractions Controlling Soil Water Repellency in Sandy Soils From the Doñana National Park (Southwestern Spain)

2014 ◽  
Vol 27 (5) ◽  
pp. 1413-1423 ◽  
Author(s):  
Nicasio T. Jiménez‐Morillo ◽  
José A. González‐Pérez ◽  
Antonio Jordán ◽  
Lorena M. Zavala ◽  
José María Rosa ◽  
...  
Keyword(s):  
Organic Matter ◽  
Soil Water ◽  
National Park ◽  
Sandy Soils ◽  
Water Repellency ◽  
Soil Water Repellency ◽  
Doñana National Park ◽  
Organic Matter Fractions

Effect of Irrigated Crop Rotation and Phosphorus Fertilizer-Manure on Soil Water Repellency of a Clay Loam Soil in Southern Alberta

2021 ◽  
Author(s):  
Jim J. Miller ◽  
Mallory Owen ◽  
Ben Ellert ◽  
Xueming Yang ◽  
Craig F. Drury ◽  
...  
Keyword(s):  
Soil Water ◽  
Water Repellency ◽  
Fertilizer Application ◽  
Clay Loam ◽  
P Fertilization ◽  
Soil Water Repellency ◽  
Hydrophobic Coatings ◽  
Southern Alberta ◽  
P Fertilizer ◽  
Loam Soil

Soil water repellency (SWR) was measured for a 28 yr field study under irrigation on a clay loam Dark Brown soil in southern Alberta. The objectives were to study the effect of legume-cereal crop rotations, feedlot manure, and phosphorus (P) fertilizer application on soil hydrophobicity (SH) and soil water repellency index (RI) under irrigation. Mean SH and RI were similar (P > 0.05) for a legume-cereal and cereal rotation, and were unaffected by P fertilization. However, P fertilization shifted the RI classification from slight to sub-critical. In contrast, SH was significantly greater for manured than non-manured treatments, while RI was unaffected. Soil organic carbon (SOC) concentration was significantly (P ≤ 0.05) correlated with SH (r=0.74), but not with RI (r=-0.17). This suggested a closer association between the quantity of SOC and quantity of hydrophobic compounds (SH method) compared to the hydrophobic coatings inhibiting infiltration of water (RI method). No significant correlation between SH and RI (r=-0.09) suggests that SH is not a good predictor of SWR using the RI method. Overall, manure application increased SH and P fertilization shifted the RI classification from slight to sub-critical. In contrast, legume-cereal rotations had no influence on SH and SWR using RI method compared to continuous cereal.

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