Reaction of soil water repellency to artificially induced changes in soil pH

Geoderma ◽  
2010 ◽  
Vol 158 (3-4) ◽  
pp. 375-384 ◽  
Author(s):  
D. Diehl ◽  
J.V. Bayer ◽  
S.K. Woche ◽  
R. Bryant ◽  
S.H. Doerr ◽  
...  
Keyword(s):  
Soil Water ◽  
Soil Ph ◽  
Water Repellency ◽  
Soil Water Repellency ◽  
Induced Changes

scholarly journals Flexible conformation in organic matter coatings: An hypothesis about soil water repellency

2000 ◽  
Vol 80 (1) ◽  
pp. 143-152 ◽  
Author(s):  
J. L. Roy ◽  
W. B. McGill
Keyword(s):  
Soil Water ◽  
Conformational Changes ◽  
Contaminated Soils ◽  
Water Repellency ◽  
Supporting Evidence ◽  
Soil Water Repellency ◽  
Nonpolar Solvents ◽  
Causative Agents ◽  
Subsequent Exposure ◽  
Induced Changes

Some soils develop severe water repellency several years or decades following oil contamination. We previously reported that soil water repellency is completely eliminated by extraction with amphiphilic solvents, but barely reduced by extraction with nonpolar solvents. We report here on solvent-induced reversible soil water repellency. Our results indicate that: (i) water repellency is completely eliminated following extraction with amphiphilic solvent, but partially restored following subsequent exposure to nonpolar, non-H-bonding solvent; (ii) extraction with nonpolar, non-H-bonding solvent generates water repellency in readily wettable control wettable soils, but not in pristine wettable soils, and (iii) repeated sequential extractions alternating between amphiphilic and nonpolar, non-H-bonding solvent increase extractable material and reduce the magnitude of solvent-induced soil water repellency with time.We attribute reversible soil water repellency to solvent-induced changes in the conformation of causative agents of soil water repellency. Recent literature reports on the structural flexibility of "insoluble" organic macromolecules are discussed for supporting evidence. We propose that exposure to nonpolar, non-H-bonding solvents induces stretching of surface-exposed, nonpolar moieties (i.e. alkyl chains), whereas exposure to polar, H-bonding solvents induces their coiling. These solvent-induced conformational changes are retained upon solvent removal. Our results indicate that the wettability of oil-contaminated soils depends on both the interfacial conformation and the fractional coverage of their surface-exposed nonpolar moieties. Key words: Soil water repellency, crude oil, hydrophobic soil, conformational flexibility, swelling, solvents

Fire-induced changes in soil water repellency increased fingered flow and runoff rates following the 2004 Huelva wildfire

2010 ◽  
Vol 25 (10) ◽  
pp. 1614-1629 ◽  
Author(s):  
Arturo J. P. Granged ◽  
Antonio Jordán ◽  
Lorena M. Zavala ◽  
Gema Bárcenas
Keyword(s):  
Soil Water ◽  
Water Repellency ◽  
Soil Water Repellency ◽  
Induced Changes

scholarly journals Post-Fire Impacts of Vegetation Burning on Soil Properties and Water Repellency in a Pine Forest, South Korea

Forests ◽  
2021 ◽  
Vol 12 (6) ◽  
pp. 708
Author(s):  
Qiwen Li ◽  
Sujung Ahn ◽  
Taehyun Kim ◽  
Sangjun Im
Keyword(s):  
Organic Carbon ◽  
Soil Properties ◽  
Total Organic Carbon ◽  
Soil Water ◽  
Soil Ph ◽  
Forest Fires ◽  
Soil Surface ◽  
Water Repellency ◽  
Burn Severity ◽  
Soil Water Repellency

Forest fires can have a direct and immediate impact on soil properties, particularly soil water repellency. This study investigated the direct impacts of the Gangneung forest fire of 2019 on soil properties and the spatial variability of soil water repellency with vegetation burn severity in the Korean red pine (Pinus densiflora Siebold and Zucc) forest of South Korea. A total of 36 soil samples were collected at depth intervals of 0–5 cm, 10–15 cm, and 20–25 cm from three burned sites, representing surface-fuel consumption (SC), foliage necrosis (FN), and crown-fuel consumption (CC), respectively. An unburned site was also used as a control. Soil properties such as soil texture, pH, bulk density, electrical conductivity (EC), total organic carbon (TOC), and cation exchange capacity (CEC) were analyzed in the laboratory. The increase in the sand fraction near the soil surface after a fire was associated with changes in silt and clay fractions. Moderate to high vegetation burn severity at the FN and CC sites caused a decrease in soil pH due to the thermal destruction of kaolinite mineral structure, but organic matter combustion on the soil surface increased soil pH at the SC site. Forest fires led to increases in total organic carbon at the FN and SC sites, owing to the external input of heat damaged foliage and burnt materials. Molarity of an ethanol droplet (MED) tests were also conducted to measure the presence and intensity of soil water repellency from different locations and soil depths. MED tests showed that vegetation burn severity was important for determining the strength of water repellency, because severely burned sites tended to have stronger water repellency of soil than slightly burned sites. Unburned soils had very hydrophilic characteristics across soil depths, but a considerably thick hydrophobic layer was found in severely burned sites. The soil water repellency tended to be stronger on steep (>30°) slopes than on gentle (<15°) slopes.

Soil water repellency in sandy soil depends on the soil drying method, incubation temperature and specific surface area

Geoderma ◽  
2021 ◽  
Vol 402 ◽  
pp. 115264
Author(s):  
Enoch V.S. Wong ◽  
Philip R. Ward ◽  
Daniel V. Murphy ◽  
Matthias Leopold ◽  
Louise Barton
Keyword(s):  
Specific Surface ◽  
Soil Water ◽  
Surface Area ◽  
Specific Surface Area ◽  
Sandy Soil ◽  
Incubation Temperature ◽  
Water Repellency ◽  
Soil Drying ◽  
Drying Method ◽  
Soil Water Repellency

The use of visible and near-infrared spectroscopy for the analysis of soil water repellency

2014 ◽  
Vol 65 (3) ◽  
pp. 360-368 ◽  
Author(s):  
I. Kim ◽  
R. R. Pullanagari ◽  
M. Deurer ◽  
R. Singh ◽  
K. Y. Huh ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Soil Water ◽  
Near Infrared Spectroscopy ◽  
Near Infrared ◽  
Water Repellency ◽  
Soil Water Repellency

Soil water repellency persistence after recurrent forest fires on Mount Carmel, Israel

2013 ◽  
Vol 22 (4) ◽  
pp. 515 ◽  
Author(s):  
Naama Tessler ◽  
Lea Wittenberg ◽  
Noam Greenbaum
Keyword(s):  
Organic Matter ◽  
Soil Water ◽  
Forest Fires ◽  
Water Drop ◽  
Chemical Properties ◽  
Water Repellency ◽  
Mediterranean Ecosystem ◽  
Long Term Effects ◽  
Soil Water Repellency ◽  
Chemical Properties Of Soils

Variations in forest fires regime affect: (1) the natural patterns of community structure and vegetation; (2) the physico-chemical properties of soils and consequently (3) runoff, erosion and sediment yield. In recent decades the Mediterranean ecosystem of Mount Carmel, north-western Israel, is subjected to an increasing number of forest fires, thus, the objectives of the study were to evaluate the long-term effects of single and recurrent fires on soil water repellency (WR) and organic matter (OM) content. Water repellency was studied by applying water drop penetration time (WDPT) tests at sites burnt by single-fire, two fires, three fires and unburnt control sites. Water repellency in the burnt sites was significantly lower than in the unburnt control sites, and the soil maintained its wettability for more than 2 decades, whereas after recurrent fires, the rehabilitation was more complicated and protracted. The OM content was significantly lower after recurrent than after a single fire, causing a clear proportional decrease in WR. The rehabilitation of WR to natural values is highly dependent on restoration of organic matter and revegetation. Recurrent fires may cause a delay in recovery and reduced productivity of the soil for a long period.

Organic Matter Fractions Controlling Soil Water Repellency in Sandy Soils From the Doñana National Park (Southwestern Spain)

2014 ◽  
Vol 27 (5) ◽  
pp. 1413-1423 ◽  
Author(s):  
Nicasio T. Jiménez‐Morillo ◽  
José A. González‐Pérez ◽  
Antonio Jordán ◽  
Lorena M. Zavala ◽  
José María Rosa ◽  
...  
Keyword(s):  
Organic Matter ◽  
Soil Water ◽  
National Park ◽  
Sandy Soils ◽  
Water Repellency ◽  
Soil Water Repellency ◽  
Doñana National Park ◽  
Organic Matter Fractions

Effect of Irrigated Crop Rotation and Phosphorus Fertilizer-Manure on Soil Water Repellency of a Clay Loam Soil in Southern Alberta

2021 ◽  
Author(s):  
Jim J. Miller ◽  
Mallory Owen ◽  
Ben Ellert ◽  
Xueming Yang ◽  
Craig F. Drury ◽  
...  
Keyword(s):  
Soil Water ◽  
Water Repellency ◽  
Fertilizer Application ◽  
Clay Loam ◽  
P Fertilization ◽  
Soil Water Repellency ◽  
Hydrophobic Coatings ◽  
Southern Alberta ◽  
P Fertilizer ◽  
Loam Soil

Soil water repellency (SWR) was measured for a 28 yr field study under irrigation on a clay loam Dark Brown soil in southern Alberta. The objectives were to study the effect of legume-cereal crop rotations, feedlot manure, and phosphorus (P) fertilizer application on soil hydrophobicity (SH) and soil water repellency index (RI) under irrigation. Mean SH and RI were similar (P > 0.05) for a legume-cereal and cereal rotation, and were unaffected by P fertilization. However, P fertilization shifted the RI classification from slight to sub-critical. In contrast, SH was significantly greater for manured than non-manured treatments, while RI was unaffected. Soil organic carbon (SOC) concentration was significantly (P ≤ 0.05) correlated with SH (r=0.74), but not with RI (r=-0.17). This suggested a closer association between the quantity of SOC and quantity of hydrophobic compounds (SH method) compared to the hydrophobic coatings inhibiting infiltration of water (RI method). No significant correlation between SH and RI (r=-0.09) suggests that SH is not a good predictor of SWR using the RI method. Overall, manure application increased SH and P fertilization shifted the RI classification from slight to sub-critical. In contrast, legume-cereal rotations had no influence on SH and SWR using RI method compared to continuous cereal.

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