Solid/liquid partition coefficients to model trace element critical loads for agricultural soils in Canada

2007 ◽  
Vol 87 (Special Issue) ◽  
pp. 189-201 ◽  
Author(s):  
M I Sheppard ◽  
S C Sheppard ◽  
C A Grant
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Best Management Practices ◽  
Management Practices ◽  
Agricultural Land ◽  
National Level ◽  
Trace Element Content ◽  
Crop Productivity ◽  
Multiple Sources ◽  
Solid Liquid

Canadian consumers are demanding a sustainable agricultural industry as well as products delivered under Best Management Practices (BMPs). Trace element accumulation in soils may influence crop productivity, food quality and ecosystem and human health. Canada’s feed and foodstuff export industry has already faced cases of penalties for high trace element content [cadmium (Cd) in durum wheat]. Thus, it is imperative to be able to estimate the accumulation and potential short- and long-term impacts of trace elements in soil. A national-level Trace Element Indicator (TEI) based on present loadings of trace elements to agricultural land is in progress. An Expert Panel including Canadian, American and Australian experts guided the assembly of a proposed methodology for this TEI. The proposed TEI, described briefly here, is a critical load approach with a single expression of the risk of impact from single or multiple trace elements from multiple sources (manures, biosolids, effluents and fertilizers and natural processes), invoked in a stochastic manner. Two key data requirements are the current background levels of trace elements in soil, and the leachability of these trace elements. A survey of total and soluble concentrations of 54 elements in up to 112 soils was completed. Although preliminary in scope, these represent key soil series in Canada. From this, a database of the solid/liquid partition coefficient, Kd, was computed. These Kd values will be used to characterize the leachability of the trace elements. Key words: Cadmium, copper, zinc, lead, nickel, uranium, metals, Kd, distribution coefficient

scholarly journals Vitamin Analysis, Trace Elements Content, and Their Extractabilities in Tetrapleura tetraptera

2020 ◽  
Vol 2020 ◽  
pp. 1-8
Author(s):  
Prince Oteng ◽  
John K. Otchere ◽  
Stephen Adusei ◽  
Richard Q. Mensah ◽  
Emmanuel Tei-Mensah
Keyword(s):  
Trace Elements ◽  
Vitamin A ◽  
Vitamin C ◽  
Trace Element ◽  
Trace Element Content ◽  
Beta Carotene ◽  
Flame Atomic Absorption ◽  
Significant Difference ◽  
Tetrapleura Tetraptera ◽  
Vitamin Analysis

Tetrapleura tetraptera is widely cherished in African traditional homes because of its alleged therapeutic and nutritional properties. This present study aimed at determining the levels of vitamin A, C, E, and beta-carotene and trace element (Fe, Cu, Mn, Co, Se, and Zn) concentrations and their extractabilities in the pulp, seeds, and whole fruit (mixture of pulp and seeds) of T. tetraptera. The total trace element concentration of Fe, Cu, Co, Mn, and Zn and their extractabilities (%) were determined using flame atomic absorption spectrometer (FAAS), whereas UV-VIS spectrophotometer was used to determine selenium concentration. The trace element content (mg/kg) based on dry weight in the pulp, seeds, and whole fruit was Fe (162.00 ± 7.14, 115.00 ± 12.00, and 154.00 ± 25.20, respectively), Zn (31.60 ± 4.77, 43.40 ± 5.29, and 41.50 ± 8.97, respectively), Cu (16.10 ± 4.98, 11.90 ± 8.40, and 17.20 ± 14.50, respectively), Mn (55.30 ± 2.41, 156.00 ± 10.20, and 122.00 ± 5.29, respectively), Co (38.10 ± 6.40, 21.10 ± 7.15, and 44.00 ± 14.90, respectively), and Se (1.49 ± 0.17, 2.43 ± 0.28, and 2.97 ± 0.27 μg/g, respectively). The mineral extractabilities (%) in the pulp, seeds, and whole fruit of T. tetraptera were established to be in the order Co > Zn > Fe > Cu > Se > Mn. Also, the chromatographic method (HPLC) was used to evaluate vitamin E concentration, and vitamin C and concentration of beta-carotene were calculated from the obtained concentration of vitamin A using a conversion factor by the titrimetric method. From the results of vitamin analysis, a significant difference (p<0.05) was observed among the pulp, seeds, and whole fruit for vitamin C and E. However, no significant difference (p>0.05) was perceived among these plant parts for vitamin A and beta-carotene. This study has therefore revealed that the pulp, seeds, and whole fruit of T. tetraptera contain varying concentrations of vitamins and trace elements and has given many vital insights on which part of T. tetraptera to consume, as concentrations of these nutrients differ in the discrete parts of the fruit.

Identification of Natal Locales of Peregrine Falcons (Falco peregrinus) by Trace-Element Analysis of Feathers

The Auk ◽  
1983 ◽  
Vol 100 (3) ◽  
pp. 560-567 ◽  
Author(s):  
Jimmie R. Parrish ◽  
David T. Rogers ◽  
F. Prescott Ward
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Trace Element Analysis ◽  
Trace Element Content ◽  
Falco Peregrinus ◽  
Element Analysis ◽  
Peregrine Falcons ◽  
Geographic Origins ◽  
Multivariate Discriminant ◽  
Discriminant Function Analyses

Abstract Samples of secondary remiges collected from nestling Peregrine Falcons (Falco peregrinus) in Alaska and western Greenland were analyzed for trace-element content using instrumental neutron-activation analysis. Concentrations of 14 trace elements were subjected to a series of multivariate discriminant function analyses to ascertain whether or not these concentrations could be used to identify the geographic origins of the birds sampled. Individual falcons from the three areas studied can be placed in their proper natal locale with 100% predictability. Mercury (Hg) was the best individual discriminator for separating sample groupings. Aluminum (A1) and Vanadium (V), in conjunction with Hg, provided the most discriminant trio of elements when various groupings of element concentrations were considered as predictors.

scholarly journals Monitoring of trace element content in tap water from Karachuny Reservoir, Kryvyi Rih city

2020 ◽  
Vol 166 ◽  
pp. 01005
Author(s):  
Viktoriia Stoliarenko ◽  
Marina Chernova ◽  
Olga Yakovchuk
Keyword(s):  
Trace Elements ◽  
Drinking Water ◽  
Trace Element ◽  
Tap Water ◽  
Trace Element Content ◽  
Element Content ◽  
Monthly Basis ◽  
Industrial Regions ◽  
The City ◽  
Inversion Voltammetry

Control of the trace element content in tap water is particularly important for large industrial regions. The estimation of Cd, Pb, Cu, As, Ni, Zn, Mn, Hg, Se and Co concentration in the tap water of Kryvyi Rih city (Karachuny Reservoir) was accomplished using electrochemical methods, the most popular methods for determining the content of trace elements in natural objects and tap water. A simple and rapid method to determine trace elements in the tap water (Kryvyi Rih city) by inversion-voltammetry has been used. The concentration of trace elements was measured by voltammetricanalyzer AVA-2 device that implements the method of inversion voltammetry on a solid rotating electrode made of carbon material. The monitoring of the trace element content in the water of the Karachuny reservoir was carried out on a monthly basis between September 2018 and August 2019. The article presents the obtained voltamperograms of some trace elements, describes content of the trace element in tap water during the year (12 data for each trace element) and analyzes the compliance of drinking water in the city of Kryvyi Rih to the standards and normative indicators of drinking water quality.

The valuation of malnutrition in the mono-digestion of maize silage by anaerobic batch tests

2008 ◽  
Vol 58 (7) ◽  
pp. 1453-1459 ◽  
Author(s):  
L. Hinken ◽  
I. Urban ◽  
E. Haun ◽  
I. Urban ◽  
D. Weichgrebe ◽  
...  
Keyword(s):  
Trace Elements ◽  
Anaerobic Digestion ◽  
Trace Element ◽  
Biogas Production ◽  
Renewable Energy Sources ◽  
Anaerobic Bacteria ◽  
Trace Element Content ◽  
Energy Crops ◽  
Maize Silage ◽  
Batch Tests

Anaerobic digestion is a technology which is used to produce methane from organic solids and energy crops. Especially in recent years, the fermentation of energy crops has become more and more important because of increasing costs for energy and special benefits for renewable energy sources in Germany. Anaerobic bacteria require macro and micro nutrients to grow. Absence of these elements can inhibit the anaerobic process significantly. In particular mono-substrates like maize or certain industrial wastewater often cannot provide all required nutrients. For this reason this research investigates the influence of substrate and trace elements on anaerobic digestion in detail. Different agricultural anaerobic biomasses are analysed with special regard to their trace element content. Based on these results, the influence of three trace elements (iron, cobalt, and nickel) on anaerobic digestion was studied in anaerobic batch tests at different sludge loading rates and for different substrates (maize and acetate). Biogas production was found to be 35% for maize silage and up to 70% higher for acetate with trace element dosage than in the reference reactor.

scholarly journals The Presence of Denitrifiers In Bacterial Communities of Urban Stormwater Best Management Practices (BMPs)

2021 ◽  
Author(s):  
Natalie C. Hall ◽  
Masoumeh Sikaroodi ◽  
Dianna Hogan ◽  
R. Christian Jones ◽  
Patrick M. Gillevet
Keyword(s):  
Best Management Practices ◽  
Bacterial Communities ◽  
Management Practices ◽  
Agricultural Land ◽  
Bacterial Community Composition ◽  
Rrna Gene ◽  
Sand Filters ◽  
Best Management ◽  
Nitrogen Inputs ◽  
Surface Sand

AbstractStormwater best management practices (BMPs) are engineered structures that attempt to mitigate the impacts of stormwater, which can include nitrogen inputs from the surrounding drainage area. The goal of this study was to assess bacterial community composition in different types of stormwater BMP soils to establish whether a particular BMP type harbors more denitrification potential. Soil sampling took place over the summer of 2015 following precipitation events. Soils were sampled from four bioretention facilities, four dry ponds, four surface sand filters, and one dry swale. 16S rRNA gene analysis of extracted DNA and RNA amplicons indicated high bacterial diversity in the soils of all BMP types sampled. An abundance of denitrifiers was also indicated in the extracted DNA using presence/absence of nirS, nirK, and nosZ denitrification genes. BMP soil bacterial communities were impacted by the surrounding soil physiochemistry. Based on the identification of a metabolically-active community of denitrifiers, this study has indicated that denitrification could potentially occur under appropriate conditions in all types of BMP sampled, including surface sand filters that are often viewed as providing low potential for denitrification. The carbon content of incoming stormwater could be providing bacterial communities with denitrification conditions. The findings of this study are especially relevant for land managers in watersheds with legacy nitrogen from former agricultural land use.

Agricultural land use and N losses to water: the case study of a fluvial park in Northern Italy

2003 ◽  
Vol 47 (7-8) ◽  
pp. 275-282 ◽  
Author(s):  
F. Morari ◽  
E. Lugato ◽  
M. Borin
Keyword(s):  
Water Quality ◽  
Best Management Practices ◽  
Water Resource Management ◽  
Management Practices ◽  
Agricultural Land ◽  
Subsurface Water ◽  
Agricultural Systems ◽  
N Losses ◽  
Positive Effects ◽  
The Impact

An integrated water resource management programme has been under way since 1999 to reduce agricultural water pollution in the River Mincio fluvial park. The experimental part of the programme consisted of: a) a monitoring phase to evaluate the impact of conventional and environmentally sound techniques (Best Management Practices, BMPs) on water quality; this was done on four representative landscape units, where twelve fields were instrumented to monitor the soil, surface and subsurface water quality; b) a modelling phase to extend the results obtained at field scale to the whole territory of the Mincio watershed. For this purpose a GIS developed in the Arc/Info environment was integrated into the CropSyst model. The model had previously been calibrated to test its ability to describe the complexity of the agricultural systems. The first results showed a variable efficiency of the BMPs depending on the interaction between management and pedo-climatic conditions. In general though, the BMPs had positive effects in improving the surface and subsurface water quality. The CropSyst model was able to describe the agricultural systems monitored and its linking with the GIS represented a valuable tool for identifying the vulnerable areas within the watershed.

Implementation of best management practices in agriculture: modelling and monitoring of impacts on nitrogen leaching

2002 ◽  
Vol 45 (9) ◽  
pp. 43-50 ◽  
Author(s):  
A. Joelsson ◽  
K. Kyllmar
Keyword(s):  
Best Management Practices ◽  
Management Practices ◽  
Time Perspective ◽  
Agricultural Land ◽  
Root Zone ◽  
Agricultural Practices ◽  
Nitrogen Leaching ◽  
Best Management ◽  
Indexing Technique ◽  
The Impact

In Kattegat and the coastal water of the Baltic Sea, high nitrogen input from agricultural land is considered to be the main reason for eutrophication. International agreements and governmental programs have set a target to reduce the anthropogenic nitrogen load by 50 percent. Improved nitrogen removal in treatment plants and efforts in agriculture have so far not decreased nitrogen transport to a sufficient extent. In this project the impact of agricultural practices on nitrogen leaching was investigated in two small agricultural catchments in Southwest Sweden. The root-zone leaching was estimated by an indexing technique. Simultaneously the transports in the stream outlets were monitored. During 1995 and 1999 the agricultural practices in the catchments were surveyed. Field data from the first survey indicated that fertilisation did not always match crop requirements, the area of undersown catch crop can be increased and autumn cultivation can be reduced. The second survey was preceded by an advisory campaign where each farmer was visited and presented with an environmental plan including fertilisation, cultivation, and crop rotation for the farm. The plan summarised the best management practices that could be realised under actual conditions. Results from the second survey showed that some changes in the agricultural practices were carried out after the advisory campaign. The nitrogen leaching from the root-zone was then estimated by the indexing technique, both for the time before and after the advisory program. The results showed that the estimated nitrogen leaching, as a mean value for 330 fields, decreased from 53 to 50 kgN ha−1, due to adjustments of the agricultural practices. Monitoring of stream transports showed values of the same magnitude after correction for retention and other sources. In this short time perspective, decreases in transport due to changes in agricultural practices could not be separated from influence of weather conditions. In comparison to results from the Swedish monitoring programme for agriculture, the measured transports were normal for the region, where annual variation in precipitation and runoff is large. Theoretically, nitrogen leaching could be reduced by one third without any major economic constraints for the farmers. In general, the farmers were positive to advice and willing to try new farming techniques even if some measurements were not fully implemented during the investigation period.

Geochemistry of Framboids

2021 ◽  
pp. 169-190
Author(s):  
David Rickard
Keyword(s):  
Trace Elements ◽  
Isotopic Composition ◽  
Trace Element ◽  
Trace Element Content ◽  
Spatial Variations ◽  
Element Content ◽  
Pyrite Framboids ◽  
Geologic Time ◽  
Dissolved Sulfide ◽  
Late Diagenesis

The stoichiometry of pyrite in framboids is unknown. The trace element content of framboids has been reported since framboids usually constitute the earliest pyrite phase in a sediment and therefore are more likely to pick up trace element variations in contemporary seawater. The trace element ratios in sedimentary framboids are similar to those in the host shales. Analyses of hydrothermal framboids are fewer, and As, Sb, and Tl appear to be enriched in hydrothermal framboids, with As, Sb, Ni, and Co also being enriched in framboids formed during metamorphism. In contrast with trace element distributions, no spatial variations in sulfur isotopic compositions have been reported within individual framboids. Framboids pick up a more accurate measure of the sulfur isotopic composition of the prevailing dissolved sulfide and are likely to retain this over geologic time. Although it is probable that pyrite framboids collect the local environmental trace element variations, interpretations of the results in terms of paleoenvironmental reconstructions are currently complex. The original sequestration of trace elements is likely to be in part determined by the pyrite crystal chemistry, and there may be a limit to how much of any given trace element can be sequestered by pyrite. This is likely to be enhanced during late diagenesis and early metamorphism and it is not altogether clear how individual trace elements behave over geologic time.

Influence of biochar application to soil on the availability of As, Cd, Cu, Pb, and Zn to maize (Zea mays L.)

Soil Research ◽  
2010 ◽  
Vol 48 (7) ◽  
pp. 638 ◽  
Author(s):  
Tshewang Namgay ◽  
Balwant Singh ◽  
Bhupinder Pal Singh
Keyword(s):  
Zea Mays ◽  
Trace Elements ◽  
Trace Element ◽  
Dry Matter ◽  
Zea Mays L ◽  
Crop Productivity ◽  
Dry Matter Yield ◽  
Soil Carbon Pool ◽  
Maize Plants

Biochar has gained importance due to its ability to increase the long-term soil carbon pool and improve crop productivity. However, little research has been done to evaluate the influence of biochar application to soil on the bioavailability of trace elements to plants. A pot experiment was conducted to investigate the influence of biochar on the availability of As, Cd, Cu, Pb, and Zn to maize (Zea mays L.). An activated wood biochar, pyrolysed at 550°C, was applied at 3 rates (0, 5, and 15 g/kg) in factorial combinations with 3 rates (0, 10, and 50 mg/kg) each of As, Cd, Cu, Pb, and Zn separately to a sandy soil. After 10 weeks of growth, plants were harvested, shoot dry matter yield was measured, and concentration of trace elements in shoots was analysed. The soil in pots was analysed for extractable trace elements. The results showed that the addition of wood biochar to soil did not have any significant effect on the dry matter yield of maize plants, even at the highest rate of application. However, trace element application significantly reduced the dry matter yield from 10 to 93% depending on the type of trace element. Biochar application decreased the concentration of As, Cd, and Cu in maize shoots, especially at the highest rate of trace element application, whereas the effects were inconsistent on Pb and Zn concentrations in the shoots. The concentrations of extractable As and Zn in soil increased with biochar application, whereas extractable Cu did not change, Pb decreased, and Cd showed an inconsistent trend. Sorption of trace elements on biochar with initial loadings up to 200 µmol at pH 7 occurred in the order: Pb > Cu > Cd > Zn > As. The results show that biochar application can significantly reduce the availability of trace elements to plants and suggest that biochar application may have potential for the management of soils contaminated by trace elements.

scholarly journals Comparison of RUSLE and MMF Soil Loss Models and Evaluation of Catchment Scale Best Management Practices for a Mountainous Watershed in India

2020 ◽  
Vol 13 (1) ◽  
pp. 232
Author(s):  
Susanta Das ◽  
Proloy Deb ◽  
Pradip Kumar Bora ◽  
Prafull Katre
Keyword(s):  
Soil Erosion ◽  
Best Management Practices ◽  
Soil Loss ◽  
Management Practices ◽  
Agricultural Land ◽  
Soil Layer ◽  
Catchment Scale ◽  
Suitable Alternative ◽  
Best Management ◽  
Management Plans

Soil erosion from arable lands removes the top fertile soil layer (comprised of humus/organic matter) and therefore requires fertilizer application which affects the overall sustainability. Hence, determination of soil erosion from arable lands is crucial to planning conservation measures. A modeling approach is a suitable alternative to estimate soil loss in ungauged catchments. Soil erosion primarily depends on soil texture, structure, infiltration, topography, land uses, and other erosive forces like water and wind. By analyzing these parameters, coupled with geospatial tools, models can estimate storm wise and annual average soil losses. In this study, a hilly watershed called Nongpoh was considered with the objective of prioritizing critical erosion hazard areas within the micro-catchment based on average annual soil loss and land use and land cover and making appropriate management plans for the prioritized areas. Two soil erosion models namely Revised Universal Soil Loss Equation (RUSLE) and Modified Morgan–Morgan–Finney (MMF) models were used to estimate soil loss with the input parameters extracted from satellite information and automatic weather stations. The RUSLE and MMF models showed similar results in estimating soil loss, except the MMF model estimated 7.74% less soil loss than the RUSLE model from the watershed. The results also indicated that the study area is under severe erosion class, whereas agricultural land, open forest area, and scrubland were prioritized most erosion prone areas within the watershed. Based on prioritization, best management plans were developed at catchment scale for reducing soil loss. These findings and the methodology employed can be widely used in mountainous to hilly watersheds around the world for identifying best management practices (BMP).

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