CARBONATE MINERALOGY OF LAKE SEDIMENTS AND SURROUNDING SOILS. 2. THE QU’APPELLE LAKES

1983 ◽  
Vol 63 (2) ◽  
pp. 259-269 ◽  
Author(s):  
K. GHEBRE-EGZIABHIER ◽  
R. J. ST. ARNAUD

The nature and distribution of carbonate minerals in the upper Qu’Appelle basin in south-central Saskatchewan were investigated. The equivalent carbonate content and calcite:dolomite ratios of the deposits reflect the mechanisms of glacial deposition and some differences in the sources of the original parent material. The particle size analysis shows that the Qu’Appelle Lake sediments are more clayey than the surrounding soils and till deposits. Mg-bearing calcites occur only in the fine-sized fraction of the carbonate accumulation horizons. However, most of the upper Qu’Appelle Lake sediments contain appreciable amounts of sand-sized Mg-bearing calcites. The marked increase in carbonate content of the sediments relative to the adjacent soils and deposits is partially due to direct precipitation of calcite from the supersaturated lake waters. In this respect, a good correlation exists between the lake water ionic activity products for CaCO3 and the relative equivalent carbonatic mineral contents of the sediments. Key words: Mg-bearing calcite, dolomite, IAP, erosion

2021 ◽  
Author(s):  
Maame Croffie ◽  
Paul N. Williams ◽  
Owen Fenton ◽  
Anna Fenelon ◽  
Karen Daly

<p>Soil texture is an essential factor for effective land management in agricultural production. Knowledge of soil texture and particle size at field scale can aid with on-going soil management decisions. Standard soil physical and gravimetric methods for particle size analysis are time-consuming and X-ray fluorescence spectrometry (XRF) provides a rapid and cost-effective alternative. The objective of this study was to explore the use of XRF as a predictor for particle size. An extensive archive of Irish soils with particle size and soil texture data was used to select samples for XRF analysis. Regression and correlation analyses on XRF determined results showed that the relationship between Rb and % clay varied with soil type and was dependent on the parent material. There was a strong relationship (R > 0.62, R<sup>2</sup>>0.30, p<0.05) between Rb and clay for soils originating from bedrock such as limestones and slate. Contrastingly, no significant relationship (R<0.03, R<sup>2</sup>=0.00, p>0.05) exists between Rb and % clay for soils originating from granite and gneiss. Furthermore, there was a significant negative correlation (p<0.05) between Rb and % sand. The XRF is a useful technique for rough screening of particle size distribution in soils originating from certain parent materials. Thus, this may contribute to the rapid prediction of soil texture based on knowledge of the particle size distribution.</p><p> </p>


Polar Science ◽  
2015 ◽  
Vol 9 (4) ◽  
pp. 359-367 ◽  
Author(s):  
Badanal Siddaiah Mahesh ◽  
Anish Kumar Warrier ◽  
Rahul Mohan ◽  
Manish Tiwari ◽  
Anila Babu ◽  
...  

2007 ◽  
Vol 39 (3) ◽  
pp. 307-314 ◽  
Author(s):  
William C. Mahaney

ABSTRACT Halton Till and Glacial Lake Iroquois lacustrine sand and gravel deposits are the major surficial materials exposed at the surface of Scarborough Bluffs in South-Central Ontario. Luvisols formed in these deposits have different morphologies, including depth of weathering, complexity of horizonation, and strength of structural grades which result from parent material differences and pedogenesis. Particle size variations between the two paleosols result, in part, from different modes of deposition, and show that variable amounts of clay were produced pedogenically in the two systems. Clay mineral genesis, involving the transformation of illite and illitesmectite to vermiculite, appears to be restricted to the Iroquois sand paleosol, while some chloritization of illite occurs in both profiles. Changes in the primary mineral contents in the two paleosols suggest a similar magnitude of weathering in both systems. Distributions of vermiculite and dithionite-extractable Fe suggest some preweathering effects in the Halton Till paleosol. Morphological, mineralogical and some soil chemical properties are closely related to the physical attributes of the two different parent materials (till vs lacustrine sand and gravel).


Soil Research ◽  
1966 ◽  
Vol 4 (2) ◽  
pp. 181 ◽  
Author(s):  
P Green

The development of a red-brown earth has been studied by means of mineral and fabric analyses. Data from particle-size analysis and zircon distribution indicate relative uniformity of the parent material throughout the profile, with a possible minor disconformity near the bottom of the B horizon. Calculations of gains and losses of major minerals during soil formation, based on the zircon content of each soil horizon and of the rock, show a break in the progressive increase in weathering towards the surface, suggesting that the soil is in fact a two-storied profile; micromorphological evidence supports this postulate. The constancy of the qualitative mineral assemblage, however, shows that both sola were formed entirely from the underlying weathered granodiorite. The top four horizons are interpreted as being a separate soil, probably developed from a surface movement layer composed of some material from the upper horizons of the older profile with accessions from weathering granodiorite boulders. Both soils are considered to have been formed dominantly by in situ weathering of primary minerals and removal of the weathering products by leaching; clay illuviation does not appear to have been more than a very minor soil-forming process.


Author(s):  
Maame E. T. Croffie ◽  
Paul N. Williams ◽  
Owen Fenton ◽  
Anna Fenelon ◽  
Karen Daly

Abstract Purpose Information about particle size distribution (PSD) and soil texture is essential for understanding soil drainage, porosity, nutrient availability, and trafficability. The sieve-pipette/gravimetric method traditionally used for particle size analysis is labour-intensive and resource-intensive. X-ray fluorescence (XRF) spectrometry may provide a rapid alternative. The study’s aim was to examine the use of XRF for rapid determination of PSD in Irish soils. Methods Soils (n = 355) from existing archives in Ireland were analysed with a benchtop energy-dispersive XRF (EDXRF). Correlation and regression analyses were determined to compare Rb, Fe, Al, and Si concentrations to % clay, % silt, and % sand. Also, linear regression models were developed to compare % clay, % sand, and % silt measured by the gravimetric method to values predicted by EDXRF. Results The relationship between element concentration and PSD was dependent on parent material. Rb, Al, and Fe showed a significant (p < 0.05) correlation (r > 0.50) with % clay and % sand in soils derived from limestone and siliceous stone parent materials. Rb was the best predictor for % clay (R2 = 0.49, RMSE = 10.20) in soils derived from limestone and siliceous stone-derived soils. Conclusion Geochemistry and clay mineralogy of the soils’ parent material strongly influenced the EDXRF’s ability to predict particle size. The EDXRF could predict % clay in soils from parent materials which weather easily, but the opposite was true for soils with parent material recalcitrant to weathering. In conclusion, this study has shown that the EDXRF can screen % clay in soils derived from limestone and siliceous stone parent materials.


Author(s):  
EL- Assal I. A. ◽  
Retnowati .

Objective of the present investigation was enthused by the possibility to develop solid lipid nanoparticles (SLNs) of hydrophilic drug acyclovir. Also study vitro and vivo drug delivery. Methods: Drug loaded SLNs (ACV-SLNs) were prepared by high pressure homogenization of aqueous surfactant solutions containing the drug-loaded lipids in the melted or in the solid state with formula optimization study (Different lipid concentration, drug loaded, homogenization / stirring speed and compritol 888ATO: drug ratio). ACV - SLN incorporated in cream base. The pH was evaluated and rheological study. Drug release was evaluated and compared with simple cream- drug, ACV – SLN with compritol 888ATO and marketed cream. The potential of SLN as the carrier for dermal delivery was studied. Results: Particle size analysis of SLNs prove small, smooth, spherical shape particle ranged from 150 to 200 nm for unloaded and from 330 to 444 nm for ACV loaded particles. The EE% for optimal formula is 72% with suitable pH for skin application. Rheological behavior is shear thinning and thixotropic. Release study proved controlled drug release for SLNs especially in formula containing compritol88 ATO. Stability study emphasized an insignificant change in SLNs properties over 6 month. In-vivo study showed significantly higher accumulation of ACV in stratum corneum, dermal layer, and receptor compartment compared with blank skin. Conclusion: AVC-loaded SLNs might be beneficial in controlling drug release, stable and improving dermal delivery of antiviral agent(s).


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