EFFECT OF TOTAL CATION CONCENTRATION AND SODIUM ADSORPTION RATIO ON EXCHANGEABLE SODIUM RATIO

1982 ◽  
Vol 62 (1) ◽  
pp. 177-185 ◽  
Author(s):  
E. J. DOERING ◽  
S. D. MERRILL ◽  
W. O. WILLIS
Keyword(s):  
Soil Solution ◽  
Regression Line ◽  
Sodium Adsorption Ratio ◽  
High Salt ◽  
Exchangeable Sodium ◽  
Salt Solutions ◽  
Sodic Soils ◽  
Laboratory Staff ◽  
Cation Concentration ◽  
The U.S

Replicated analyses for each of five levels of total cation concentration showed that exchangeable sodium ratio (ESR) and sodium adsorption ratio (SAR) were linearly related by equations of the form ESR = a + b (SAR). The coefficient, b, decreased from 0.0163 to 0.0085 as total cation concentration increased from 39 to 1057 meq/L, showing that the equilibrium of exchange, as measured by ESR and SAR, is strongly affected by total cation concentration of the soil solution. A regression line, previously published by the U.S. Salinity Laboratory Staff, lies between the regression lines for 39 and 110 meq/L. Exchangeable sodium ratio can be inferred from SAR alone as long as SAR is not larger than about 20. However, the error of estimate for ESR is shown to increase with increasing SAR and total cation concentration unless the effect of total cation concentration is taken into account. This is an important factor to be considered when high-salt solutions are used to reclaim sodic soils.

scholarly journals Reclamation of Saline–Sodic Soils with Combined Amendments: Impact on Quinoa Performance and Biological Soil Quality

2018 ◽  
Vol 10 (9) ◽  
pp. 3083 ◽  
Author(s):  
María Alcívar ◽  
Andrés Zurita-Silva ◽  
Marco Sandoval ◽  
Cristina Muñoz ◽  
Mauricio Schoebitz
Keyword(s):  
Root Biomass ◽  
Soil Microbial Biomass ◽  
Seed Quality ◽  
Combined Treatment ◽  
Sodium Adsorption Ratio ◽  
Arid Zones ◽  
Exchangeable Sodium ◽  
Sodic Soils ◽  
Soil Microbial ◽  
The Individual

The objective of this study was to evaluate the individual and synergic effects of the application of Biochar (B), Humic Substances (HS), and Gypsum (G) on the soil properties of a saline–sodic soil, and plant growth and seed quality (polyphenols, protein and yield) of quinoa. Treatments included (B) 22 t ha−1, (HS) 5 kg ha−1, and (G) 47.7 t ha−1. Two quinoa genotypes from Arid Zones (AZ-51 and AZ-103) were selected and established in eight treatments. The B + HS + G combined treatment resulted in increases in root biomass of 206% and 176% in AZ-51 and AZ-103, respectively. Furthermore, electrical conductivity (ECe), sodium adsorption ratio (SAR), and exchangeable sodium percentage (ESP) decreased significantly in all treated soils. When compared to the control, ESP decreased 11-fold in the G treatment, and 9–13-fold in the B + G; B + HS; and B + HS + G treatments. Similarly, soil microbial biomass increased 112% and 322% in the B + HS + G treatment in AZ-51 and AZ-103 genotypes, respectively. Therefore, it can be concluded that the application of combined amendments (B + HS + G) represents an alternative for reclaiming degraded soils, including saline–sodic soils.

AN INVESTIGATION ON THE DEPENDENCE OF THE GAPON COEFFICIENT ON EXCHANGEABLE SODIUM BY THREE LINEAR TRANSFORMATIONS

1988 ◽  
Vol 68 (4) ◽  
pp. 813-820
Author(s):  
V. P. EVANGELOU ◽  
F. J. COALE
Keyword(s):  
Clay Minerals ◽  
Limited Range ◽  
Selectivity Coefficient ◽  
Sodium Adsorption Ratio ◽  
Exchangeable Sodium ◽  
Linear Transformations ◽  
Laboratory Staff ◽  
Soil Systems ◽  
Exchange Adsorption ◽  
Exchange Selectivity

Based on theorical considerations of ideal exchangers, the traditional Gapon exchange selectivity coefficient (KG) is generally not expected to remain constant for exchangeable sodium ratio (ESR) greater than 0.20. Therefore, the ESR-SAR (SAR=sodium adsorption ratio) relationship is only expected to be linear and predictable for this limited range of exchange sites. The purpose of this study is to demonstrate that for some soils and/or clay minerals, which are considered nonideal exchangers, the KG may remain constant for ESR values greater than 0.20. This information is important for the reclamation of sodic soil systems with ESR > 0.2 to near Na+ saturation. Experimental data in the literature is most often limited in the ESR range of 0 – 1. Experimental Na+-Ca2+ exchange data for each of a number of soils and clay minerals were plotted according to three linear transformations of the Gapon expression in order to determine if a particular soil or clay mineral exhibits a constant Gapon exchange selectivity coefficient (KG) for ESR values significantly greater than 0.20. The three linear transformations are represented by plots of (1) 1/ExNa vs. 1/SAR, (2) ExNa vs. ExNa/SAR and (3) SAR/ExNa vs. SAR (ExNa = exchangeable Na). From the three plots employed, the ExNa vs. ExNa/SAR and the SAR/ExNa vs. SAR were shown to be the most applicable in predicting a constant KG for ESR values greater than 0.20. It is also shown that some generally low CEC materials may exhibit a constant KG for ESR values significantly greater than 0.20. These data also infer that for a particular soil the linearity of the widely used ESR-SAR relationship introduced by the U.S. Salinity Laboratory Staff may not be limited to an ESR value of 0.20. Key words: Exchangeable sodium percentage, sodium adsorption ratio, thermodynamics of cation exchange, adsorption maxima, ion affinity constants.

RELATIONSHIP BETWEEN EXCHANGEABLE SODIUM AND SODIUM ADSORPTION RATIO IN A SOLONETZIC SOIL ASSOCIATION

1983 ◽  
Vol 63 (3) ◽  
pp. 461-467 ◽  
Author(s):  
W. R. A. HARRON ◽  
G. R. WEBSTER ◽  
R. R. CAIRNS
Keyword(s):  
Regression Line ◽  
Organic Matter Content ◽  
Black Soil ◽  
Sodium Adsorption Ratio ◽  
Matter Content ◽  
Exchangeable Cation ◽  
Regression Equations ◽  
Exchangeable Sodium ◽  
Soil Association ◽  
Solonetzic Soil

The relationship between the sodium adsorption ratio (SAR) and exchangeable sodium ratio (ESR) in a Solonetzic soil association of the Black soil zone of East-Central Alberta was examined. Highly significant correlations between ESR and SAR were determined for the A and B horizons of this soil association, although the regression equations were different for each horizon. The slope of the regression line indicated that Na was adsorbed three times more strongly, relative to Ca, in the B horizon than in the A horizon. The difference in adsorption was attributed to differences in soil properties, particularly clay and organic matter content, between the two horizons. Equations to calculate exchangeable sodium percentage (ESP) from SAR were also determined for the two horizons studied. To relate the soluble Na levels to exchangeable Na in the Duagh-Malmo soil association, appropriate equations should be used for each horizon. Also, data showed that an SAR of 3 in the B horizon corresponds to an exchangeable Ca:Na ratio of 10 that is used to differentiate Solonetzic from Chernozemic soils in the Canadian Classification System. Key words: Solonetzic soil association, soluble-exchangeable cation ratios

Amelioration of sodic soils with blue-green algae

Soil Research ◽  
1981 ◽  
Vol 19 (3) ◽  
pp. 361 ◽  
Author(s):  
D Subhashini ◽  
BD Kaushik
Keyword(s):  
Electrical Conductivity ◽  
Hydraulic Conductivity ◽  
Nitrogen Content ◽  
Total Nitrogen ◽  
Algal Growth ◽  
Algal Flora ◽  
Exchangeable Sodium ◽  
Sodic Soils ◽  
Blue Green Algae ◽  
Biological Input

Algal growth resulted in significant reductions in pH, electrical conductivity, exchangeable sodium and in hydraulic conductivity and aggregation status of the soil. There was a significant increase in the total nitrogen content of the soil due to algal growth. Two out of the three inoculated species of algae could establish in the pots along with the indigenous algal flora. Combination of gypsum and algal application were found to have appreciable reclamative properties, and the possibility of using algae as a biological input for the reclamation of sodic soils has been indicated.

scholarly journals CORREÇÃO DA SODICIDADE DE DOIS SOLOS IRRIGADOS EM RESPOSTA À APLICAÇÃO DE GESSO AGRÍCOLA

Irriga ◽  
2007 ◽  
Vol 12 (2) ◽  
pp. 168-176 ◽  
Author(s):  
Egeiza Moreira Leite ◽  
Lourival Ferreira Cavalcante ◽  
Adriana Araújo Diniz ◽  
Rivaldo Vital dos Santos ◽  
Gibran Da Silva Alves ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Magnesium Content ◽  
Soil Reclamation ◽  
Exchangeable Sodium Percentage ◽  
Exchangeable Sodium ◽  
Sodic Soils ◽  
Positive Effects ◽  
Sodium Percentage ◽  
Irrigated Perimeter ◽  
Physical Degradation

CORREÇÃO DA SODICIDADE DE DOIS SOLOS IRRIGADOS EM RESPOSTA À APLICAÇÃO DE GESSO AGRÍCOLA  Egeiza Moreira Leite1; Lourival Ferreira Cavalcante1; Adriana Araujo Diniz1; Rivaldo Vital dos Santos2; Gibran da Silva Alves3; Italo Herbert Lucena Cavalcante41Departamento de Solos e Engenharia Rural, Universidade Federal da Paraíba, Areia, PB, [email protected] de Engenharia Florestal, Universidade Federal de Campina Grande, Patos, PB3Departamento de Fitotecnia, Universidade Federal da Paraíba, Areia, PB4Departamento de Produção Vegetal, Universidade Estadual Paulista, Jaboticabal, SP  1 RESUMO             Uma das limitações das áreas irrigadas, nas regiões áridas e semi-áridas, ao sistema produtivo é a degradação química e física dos solos pela salinidade e sodicidade. Com o objetivo de avaliar o efeito do gesso sobre a condutividade elétrica, pH, percentagem de sódio trocável, teores de cálcio, magnésio, sódio do extrato de saturação e de sódio trocável de dois solos salino-sódicos: um do Perímetro Irrigado Engenheiro Arco Verde no município de Condado-PB e o outro do Perímetro Irrigado de São Gonçalo em Sousa-PB, conduziu-se um experimento em abrigo protegido do Departamento de Solos e Engenharia Rural do CCA/UFPB, Areia, PB. O delineamento foi inteiramente casualizado em esquema fatorial 2x5 referente a dois solos e cinco doses de gesso equivalentes a 0; 3,2; 6,3; 9,4 e 12,5 g kg-1 de cada solo. Pelos resultados a incorporação do gesso exerceu efeito positivo sobre a redução da salinidade e da sodicidade dos solos. Os valores da condutividade elétrica, percentagem de sódio trocável, pH e os teores de sódio solúvel e trocável em relação aos que os solos possuíam antes da aplicação dos tratamentos, foram sensivelmente reduzidos e os de cálcio e magnésio incrementados com a incorporação do gesso em ambos os solos. UNITERMOS: salinidade, sódio trocável, recuperação de solo.  LEITE, E. M.; CAVALCANTE, L. F.; DINIZ, A. A.; SANTOS, R. V.; ALVES, G. S.; CAVALCANTE, I. H. L. SODICITY CORRECTION OF TWO IRRIGATED SOILS IN RESPONSE TO APPLICATION OF AGRICULTURAL GYPSUM  2 ABSTRACT             The chemical and physical degradation of the soils by salinity and sodicity problems constitutes a serious obstacle in productive irrigated areas in arid and semi-arid regions. An experiment was carried out in green house at the Soil and Rural Engeneering Department in the Centro de Ciências Agrárias of the Universidade Federal da Paraíba, Areia, Brazil, in order to evaluate the effect of gypsum on electrical conductivity, pH, exchangeable sodium percentage, sodium, calcium and magnesium content in saturation extract and exchangeable sodium of two saline-sodic soils: one from irrigated Perimeter Engenheiro Arco Verde in the municipality of Condado and another from irrigated Perimeter of São Gonçalo, in the municipality of Sousa,  both in Paraiba State,  Brazil.  The experiment factorial design 2 x 5 referred to two soils and five gypsum levels equivalent to 0; 3.2; 6.3; 9.4 and 12.5 gkg-1 for each soil. The gypsum application had positive effects on salinity and sodicity reduction. The valued for electrical conductivity, exchangeable sodium percentage, pH and contents of soluble and exchangeable sodium in relation to soil data before the application of gypsum treatments in both soils  decreased. KEYWORDS: salinity, exchangeable sodium, soil reclamation

scholarly journals Saline-sodic soil treated with gypsum, organic sources and leaching for successive cultivation of sunflower and rice

2019 ◽  
Vol 23 (12) ◽  
pp. 891-898 ◽  
Author(s):  
Petrônio D. dos Santos ◽  
Lourival F. Cavalcante ◽  
Hans R. Gheyi ◽  
Geovani S. de Lima ◽  
Everaldo M. Gomes ◽  
...  
Keyword(s):  
Surface Layer ◽  
Rice Husk ◽  
Rice Variety ◽  
Rice Cultivation ◽  
Exchangeable Sodium ◽  
Sodic Soils ◽  
Sodic Soil ◽  
Soil Layers ◽  
Before And After ◽  
Irrigated Perimeter

ABSTRACT Correction of saline and sodic soils aims to reduce salts dissolved in the solution and exchangeable sodium, respectively, to allow the growth and production of crops. In this context, an experiment was carried out between August/2011 and September/2012, in saline-sodic soil of the Irrigated Perimeter of São Gonçalo, in the municipality of Sousa, PB, Brazil. Agricultural gypsum, organic sources and continuous leaching for reducing salinity, sodicity and alkalinity in the saline-sodic soil and their effects on the production of the sunflower cultivar Embrapa 122/V-2000 and the rice variety Diamante were evaluated. The treatments were distributed in four randomized blocks and the soil was subjected to continuous leaching for 50 days and evaluated for salinity, sodicity and alkalinity before and after leaching, as well after sunflower and rice cultivation, in the 0-0.20 and 0.20-0.40 m layers. Leaching and the application of gypsum and organic sources reduced the initial salinity in both soil layers, to a greater extent in the surface layer. Exchangeable sodium decreased in 0-0.20 m and increased in 0.20-0.40 m. After rice cultivation, the soil in the 0-0.20 m layer changed from saline-sodic to non-saline in the treatments gypsum + bovine manure and gypsum + rice husk. The reduction of salinity, sodicity and alkalinity in the soil was higher during rice cultivation than during sunflower cultivation.

Speciation of cadmium in soil solutions of saline/sodic soils and relationship with cadmium concentrations in potato tubers (Solanum tuberosum L.)

Soil Research ◽  
1997 ◽  
Vol 35 (1) ◽  
pp. 183 ◽  
Author(s):  
M. J. McLaughlin ◽  
K. G. Tiller ◽  
M. K. Smart
Keyword(s):  
Soil Solution ◽  
Soil Ph ◽  
Solanum Tuberosum L ◽  
Alkaline Soil ◽  
Sodic Soils ◽  
Chloro Complexes ◽  
Soil Solutions ◽  
High Concentrations ◽  
The Stability ◽  
Saline Solutions

Fifty commercial potato crops and associated soils were sampled. Soil solutions were extracted from rewetted soils by centrifugation, and solution composition was related to Cd concentrations in tubers. Soils were also extracted with 0·01 M Ca(NO3)2 and 0·01 M CaCl2 solutions, and Cd2+ activities in the extracts were calculated by difference using the stability constants for formation of CdCl2-nn species. The soils had saline solutions (>4 dS/m), and Cl- and SO2-4 in solution markedly affected the speciation of Cd in soil solution, with chloro-complexes, in particular, dominating. While low soil pH was associated with high (>25 nM) concentrations of Cd in soil solution, chloro-complexation also led to high concentrations of Cd in solution, even at neutral to alkaline soil pH values. Tuber Cd concentrations were not related to activities of Cd2+ in soil solution or to activities in dilute salt extracts of soil. Tuber Cd concentrations were related to the degree of chloro-complexation of Cd in solution. The relationship of tuber Cd concentrations to chloro-complexation in soil solution suggests that Cd species other than the free Cd2+ ion are involved in the transport through soil and uptake of Cd by plants.

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