Room-Temperature Fabrication for Functional Oxide Nanofilms Using Oxide Nanosheets

2012 ◽  
Vol 2012 (CICMT) ◽  
pp. 000228-000233
Author(s):  
Minoru Osada ◽  
Takayoshi Sasaki
Keyword(s):  
Chemical Composition ◽  
Building Block ◽  
Room Temperature ◽  
Research Interest ◽  
Bottom Up ◽  
Precise Control ◽  
Molecular Scale ◽  
Fundamental Research ◽  
Infinite Planar ◽  
Selection Of

Oxide nanosheets, which possess atomic or molecular thickness and infinite planar lengths, have increasingly attracted fundamental research interest because of their potential to be used as conductors, semiconductors, insulators, and even ferromagnets, depending on their chemical composition and how their atoms are arranged. An attractive aspect of oxide nanosheets is that nanosheets can be organized into various nanoarchitectures by applying solution-based synthetic techniques. It is even possible to tailor superlattice assemblies by tuning the number of nanosheets and their stacking sequences. Sophisticated functionalities or nanodevices can be designed through the selection of nanosheets and combining materials, and precise control over their arrangement at the molecular scale. We utilized oxide nanosheets as a building block in the bottom-up assembly, and successfully developed various functional nanofilms.

Room-Temperature Ceramic Nanocoating Using Nanosheet Deposition Technique

2013 ◽  
Vol 2013 (CICMT) ◽  
pp. 000014-000018 ◽  
Author(s):  
M. Osada ◽  
T. Sasaki
Keyword(s):  
Room Temperature ◽  
Organic Molecules ◽  
Structural Diversity ◽  
Layer By Layer ◽  
Precise Control ◽  
Langmuir Blodgett ◽  
Wide Range ◽  
Potential Applications ◽  
Layer Assembly ◽  
Selection Of

We present a novel procedure for ceramic nanocoating using oxide nanosheet as a building block. A variety of oxide nanosheets (such as Ti1−δO2, MnO2 and perovsites) were synthesized by delaminating appropriate layered precursors into their molecular single sheets. These nanosheets are exceptionally rich in both structural diversity and electronic properties, with potential applications including conductors, semiconductors, insulators, and ferromagnets. Another attractive aspect is that nanosheets can be organized into various nanoarchitectures by applying solution-based synthetic techniques involving electrostatic layer-by-layer assembly and Langmuir-Blodgett deposition. It is even possible to tailor superlattice assemblies, incorporating into the nanosheet galleries with a wide range of materials such as organic molecules, polymers, and inorganic/metal nanoparticles. Sophisticated functionalities or paper-like devices can be designed through the selection of nanosheets and combining materials, and precise control over their arrangement at the molecular scale.

Thermomechanical Treatment of a 4340 Ni-Cr-Mo Alloy Steel

1981 ◽  
Vol 39 ◽  
pp. 314-315 ◽  
Author(s):  
M.T. Jahn ◽  
J.C. Yang ◽  
C.M. Wan
Keyword(s):  
Mechanical Property ◽  
Chemical Composition ◽  
Alloy Steel ◽  
Thermomechanical Treatment ◽  
Room Temperature ◽  
Good Combination ◽  
Thermal Treatments ◽  
Low Carbon ◽  
4340 Steel ◽  
Good Improvement

4340 Ni-Cr-Mo alloy steel is widely used due to its good combination of strength and toughness. The mechanical property of 4340 steel can be improved by various thermal treatments. The influence of thermomechanical treatment (TMT) has been studied in a low carbon Ni-Cr-Mo steel having chemical composition closed to 4340 steel. TMT of 4340 steel is rarely examined up to now. In this study we obtain good improvement on the mechanical property of 4340 steel by TMT. The mechanism is explained in terms of TEM microstructures4340 (0.39C-1.81Ni-0.93Cr-0.26Mo) steel was austenitized at 950°C for 30 minutes. The TMTed specimen (T) was obtained by forging the specimen continuously as the temperature of the specimen was decreasing from 950°C to 600°C followed by oil quenching to room temperature. The thickness reduction ratio by forging is 40%. The conventional specimen (C) was obtained by quenching the specimen directly into room temperature oil after austenitized at 950°C for 30 minutes. All quenched specimens (T and C) were then tempered at 450, 500, 550, 600 or 650°C for four hours respectively.

BÖHLER W403 VMR

Alloy Digest ◽  
2013 ◽  
Vol 62 (9) ◽  
Keyword(s):  
Heat Treatment ◽  
Chemical Composition ◽  
Physical Properties ◽  
Tool Steel ◽  
Raw Materials ◽  
Heat Treating ◽  
Diffusion Annealing ◽  
Selection Of

Abstract Böhler (or Boehler) W403 VMR is a tool steel with outstanding properties, based not only on a modified chemical composition, but on the selection of highly clean raw materials for melting, remelting under vacuum (VMF), optimized diffusion annealing, and a special heat treatment. This datasheet provides information on composition, physical properties, and elasticity. It also includes information on forming and heat treating. Filing Code: TS-721. Producer or source: Böhler Edelstahl GmbH.

Divergent synthesis of CF3-substituted polycyclic skeletons based on control of activation site of acid catalysts

2018 ◽  
Vol 54 (50) ◽  
pp. 6927-6930 ◽  
Author(s):  
Kazuma Yokoo ◽  
Keiji Mori
Keyword(s):  
Acid Catalysts ◽  
Precise Control ◽  
Selection Of ◽  
Activation Site

We report a divergent synthesis of CF3-substituted fused skeletons based on precise control of the activation site through the selection of acid catalysts.

scholarly journals Precise Control of CsPbBr3 Perovskite Nanocrystal Growth at Room Temperature: Size Tunability and Synthetic Insights

2021 ◽  
Vol 33 (7) ◽  
pp. 2387-2397
Author(s):  
Alasdair A. M. Brown ◽  
Parth Vashishtha ◽  
Thomas J. N. Hooper ◽  
Yan Fong Ng ◽  
Gautam V. Nutan ◽  
...  
Keyword(s):  
Room Temperature ◽  
Precise Control ◽  
Nanocrystal Growth

scholarly journals Mid infrared polarization engineering via sub-wavelength biaxial hyperbolic van der Waals crystals

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Saurabh Dixit ◽  
Nihar Ranjan Sahoo ◽  
Abhishek Mall ◽  
Anshuman Kumar
Keyword(s):  
Room Temperature ◽  
Extinction Ratio ◽  
Polarization State ◽  
Van Der Waals ◽  
Photonic Devices ◽  
Mid Infrared ◽  
Precise Control ◽  
Electromagnetic Simulations ◽  
Frequency Regime ◽  
Sub Wavelength

AbstractMid-infrared (IR) spectral region is of immense importance for astronomy, medical diagnosis, security and imaging due to the existence of the vibrational modes of many important molecules in this spectral range. Therefore, there is a particular interest in miniaturization and integration of IR optical components. To this end, 2D van der Waals (vdW) crystals have shown great potential owing to their ease of integration with other optoelectronic platforms and room temperature operation. Recently, 2D vdW crystals of $$\alpha$$ α -$$\hbox {MoO}_{3}$$ MoO 3 and $$\alpha$$ α -$$\hbox {V}_2 \hbox {O}_5$$ V 2 O 5 have been shown to possess the unique phenomenon of natural in-plane biaxial hyperbolicity in the mid-infrared frequency regime at room temperature. Here, we report a unique application of this in-plane hyperbolicity for designing highly efficient, lithography free and extremely subwavelength mid-IR photonic devices for polarization engineering. In particular, we show the possibility of a significant reduction in the device footprint while maintaining an enormous extinction ratio from $$\alpha$$ α -$$\hbox {MoO}_{3}$$ MoO 3 and $$\alpha$$ α -$$\hbox {V}_2$$ V 2 $$\hbox {O}_5$$ O 5 based mid-IR polarizers. Furthermore, we investigate the application of sub-wavelength thin films of these vdW crystals towards engineering the polarization state of incident mid-IR light via precise control of polarization rotation, ellipticity and relative phase. We explain our results using natural in-plane hyperbolic anisotropy of $$\alpha$$ α -$$\hbox {MoO}_{3}$$ MoO 3 and $$\alpha$$ α -$$\hbox {V}_2$$ V 2 $$\hbox {O}_5$$ O 5 via both analytical and full-wave electromagnetic simulations. This work provides a lithography free alternative for miniaturized mid-infrared photonic devices using the hyperbolic anisotropy of $$\alpha$$ α -$$\hbox {MoO}_{3}$$ MoO 3 and $$\alpha$$ α -$$\hbox {V}_2$$ V 2 $$\hbox {O}_5$$ O 5 .

scholarly journals Influence of the Chemical Composition on Electrical Conductivity and Mechanical Properties of the Hypoeutectic Al-Si-Mg Alloys

2016 ◽  
Vol 61 (1) ◽  
pp. 353-360 ◽  
Author(s):  
B. Dybowski ◽  
J. Szymszal ◽  
Ł. Poloczek ◽  
A. Kiełbus
Keyword(s):  
Mechanical Properties ◽  
Electrical Conductivity ◽  
Chemical Composition ◽  
Aluminium Alloys ◽  
Mg Alloys ◽  
High Electrical Conductivity ◽  
Transportation Industry ◽  
Proper Selection ◽  
Ti Addition ◽  
Selection Of

Due to low density and good mechanical properties, aluminium alloys are widely applied in transportation industry. Moreover, they are characterized by the specific physical properties, such as high electrical conductivity. This led to application of the hypoeutectic Al-Si-Mg alloys in the power generation industry. Proper selection of the alloys chemical composition is an important stage in achievement of the demanded properties. The following paper presents results of the research on the influence of alloys chemical composition on their properties. It has been revealed that Si and Ti addition decreases electrical conductivity of the Al-Si-Mg alloys, while Na addition increases it. The mechanical properties of the investigated alloys are decreased by both silicon and iron presence. Sodium addition increases ductility of the Al-Si-Mg alloys.

UV-Light-Induced Dehydrogenative N-Acylation of Amines with 2-Nitrobenzaldehydes to Give 2-Aminobenzamides

Synthesis ◽  
2022 ◽  
Author(s):  
Dishu Zeng ◽  
Tianbao Yang ◽  
Niu Tang ◽  
Wei Deng ◽  
Jiannan Xiang ◽  
...  
Keyword(s):  
Amino Acid ◽  
Organic Synthesis ◽  
Efficient Method ◽  
Building Block ◽  
Room Temperature ◽  
Uv Light ◽  
Amino Acid Derivatives ◽  
One Pot ◽  
Plausible Mechanism ◽  
High Yields

A simple, mild, green and efficient method for the synthesis of 2-aminobenzamides was highly desired in organic synthesis. Herein, we developed an efficient, one-pot strategy for the synthesis of 2-aminobenzamides with high yields irradiated by UV light. 32 examples proceeded successfully by this photo-induced protocol. The yield reached up to 92%. The gram scale was also achieved easily. This building block could be applied in the preparation of quinazolinones derivatives. Amino acid derivatives could be employed smoothly at room temperature. Finally, a plausible mechanism was proposed.

Room-temperature Barbier single-atom polymerization induced emission as a versatile approach for the utilization of monofunctional carboxylic acid resources

2021 ◽  
Author(s):  
Quan-Xi Shi ◽  
Qian Li ◽  
Hang Xiao ◽  
Xiaoli Sun ◽  
Hongli Bao ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Carboxylic Acids ◽  
Building Block ◽  
Room Temperature ◽  
Single Atom ◽  
The Earth

Carboxylic acids are widely available from both biomass and fossil sources on the earth. In comparison with multifunctional carboxylic acid containing chemicals those have been comprehensively used as building block...

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