Washable Coatings for Packaging Practices

2016 ◽  
Vol 2016 (DPC) ◽  
pp. 001413-001454
Author(s):  
John Moore ◽  
Alex Brewer

Many packaging processes require the protection of components while another application is conducted. This may include a planarizing coat over large topography while a deposition, bonding, or curing step is completed. Washable coatings are materials that protect the substrate during thermal or mechanical activities and are simply washed away using readily available and green products, such as water or detergent. Washable products are not new, an example includes laser washable coatings that remove debris from the heat activation zone (HAZ) during scribe and break processes. In such cases, thermal resistance is of coatings is preferred as high as possible. While many products used for such applications include polyvinyl alcohol (PVA) or polyvinylpyrrolidone (PVP), such materials are not good choices for thermal resistance as they cross-link when exposed to temperature or to metals, leaving residue that is difficult or impossible to remove. While these are water soluble, they were designed for industrial and consumer packaging applications such as laundry packets, vitamins, or other non-thermal processes. Using thermal sensitive materials as PVA and PVP for laser processes creates a narrow process window that requires special washing tools that use high-pressure nozzels or heat. Alternatively, thermal resistant washable products are available that provide protection to 300°C or more, and upon being exposed to such conditions and metal contact, will simply rinse away without the aid of mechanical tooling.[1] Planarizing coatings commonly require thermal resistance, as they can be thick (>300um) and perform in encapsulating solder bumps while a dielectric or another die is solder attached and temperatures in excess of 250°C are needed. This has been proven in the case of protecting C4 bumps while bonding micro-bumped die onto FPGA interposers.[2] Bonding and curing is conducted with water or detergent washable UV-cured adhesive coatings. Similar coatings have been proven for EMI/RFI shielding where coatings are applied to porous substrates followed by temporarily affixing die to be processed in a PVD tool. When completed, the die are removed while the coating is washed away in a cleaner.[3] The success in these and related temporary applications depend upon the use of the proper washable coating. Our experience in creating solutions for these and other industry needs will be discussed as well as the criteria for using temporary washable coatings.

2016 ◽  
Vol 2016 (1) ◽  
pp. 000094-000099
Author(s):  
Alex Brewer ◽  
Alex Laymon ◽  
John Moore

Abstract Many packaging processes require the protection of components while another application is conducted. This may include a planarizing coat over large topography while a deposition, bonding, or curing step is completed. Washable coatings are materials that protect the substrate during thermal or mechanical activities and are simply washed away using readily available and green products, such as water or detergent. Washable products are not new, an example includes laser washable coatings that remove debris from the heat activation zone (HAZ) during scribe and break processes. In such cases, thermal resistance is desired as high as possible. The chemistry of washable products includes polyvinyl alcohol (PVA) and polyvinylpyrrolidone (PVP) [1]. While these are excellent choices for consumer packaging (e.g. laundry packets, vitamins), they are best used in electronics for room temperature processing due to their cross-linking upon exposure to heat and metals. Alternatively, thermal resistant and washable products (e.g. DaeCoat™ 515) are available that provide protection to ≥300°C without the aid of mechanical tooling [2]. Planarizing coatings over metals can be thick (>300μm) as in cases where solder bump encapsulation is needed during dielectric coating and cure or when another die is thermal compression bonded. This approach has been demonstrated with washable temporary bonding adhesives in protecting C4 bumps while bonding micro-bumped die onto FPGA interposers [3]. Washable adhesives have been created for thermal and vacuum driven processing as EMI/RFI shielding in a PVD tool. Such coatings are applied to porous substrates, affixing die, processing, and removal by water washing [4]. Success in these and related temporary applications depend upon matching the chemistry of the washable coating with the process. Our experience in creating solutions for these and other industry needs will be discussed as well as the criteria for using temporary washable coatings.


1996 ◽  
Vol 59 (4) ◽  
pp. 350-355 ◽  
Author(s):  
KRISTEL J. A. HAUBEN ◽  
ELKE Y. WUYTACK ◽  
CARINE C. F. SOONTJENS ◽  
CHRIS W. MICHIELS

Escherichia coli MG1655 suspensions in 10 mM phosphate buffer (pH 7.0) were subjected to high pressures in the range of 180 to 320 MPa for 15 min. Cell death was evident at 220 MPa and increased exponentially with pressure. Surviving populations were sublethally injured, as demonstrated by their reduced ability to form colonies on violet red bile glucose agar, a selective growth medium containing crystal violet and bile salts. During exposure to high pressure (> 180 MPa), cells were sensitive to lysozyme, nisin, and ethylenediaminetetraacetic acid (EDTA), as was apparent from an increased lethality of pressure in the presence of these agents. Sublethal injury in the surviving population was lower in the presence of nisin and lysozyme, but higher in the presence of EDTA. Combinations of EDTA with nisin or lysozyme present during pressure treatment increased lethality in an additive manner. However, the addition of lysozyme, nisin and/or EDTA to pressurized cell suspensions immediately after pressure treatment did not cause any viable count reduction. Finally, we observed leakage of the periplasmic enzyme β-lactamase from an ampicillin-resistant recombinant E. coli MG1655 under high pressure. These results suggest that high pressure transiently disrupts the permeability of the E. coli outer membrane for water-soluble proteins.


2018 ◽  
Vol 45 (3) ◽  
pp. 79-86 ◽  
Author(s):  
V.A. Zhorin ◽  
M.R. Kiselev

Mixtures of polyethylene and 80% germanium dioxide, magnesium, magnesium oxide, and sodium chloride were subjected to plastic deformation under a pressure of 0.5–4.0 GPa, and were then investigated by differential scanning calorimetry. The enthalpy of melting of the polymer in certain mixtures reached 300 J/g. On thermograms of deformed mixtures, exothermic processes were observed. The observed thermal effects are possibly due to interphase interaction at the phase boundary.


2017 ◽  
Vol 79 (5) ◽  
pp. 630-636 ◽  
Author(s):  
V. A. Zhorin ◽  
M. R. Kiselev ◽  
V. I. Roldughin

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