A Review of Wafer Coating Methods for 3D Packaging

2010 ◽  
Vol 2010 (DPC) ◽  
pp. 002153-002188
Author(s):  
Steven J. Adamson ◽  
James Klocke ◽  
Gareth De Sanctis
Keyword(s):  
Spin Coating ◽  
Spray Coating ◽  
High Viscosity ◽  
Filler Loading ◽  
Back Side ◽  
Stencil Printing ◽  
Low Viscosity ◽  
3D Packaging ◽  
Spinning Process ◽  
Coating Methods

For many years, Front End of Line (FEOL) wafer fabrication, has used spin coating as the method of choice for photoresist application. Today, 3D packaging requires coatings applied to the non-active side of the wafer. Popular applications for back side coatings are, temporary adhesives to hold wafers to carriers during Through Silicon Via (TSV) fabrication, applying die / wafer bonding materials, and dielectric layers. Spin coating of wafers can be used to apply a number of materials for backside coatings. Although this application method is quite fast, it has a number of drawbacks which include high material waste and its limitation to low viscosity materials. Wafer Backside Coating (WBC) adhesives applied prior to dicing poses some unique challenges due to their filler loadings, and therefore the formulations can be limited by the spinning process. Today, most companies using spin coating to apply WBC materials have to lower the viscosity of the fluid with solvents, which creates other problems. Screen or stencil printing to apply WBC adhesives is a proven method and is currently in production at manufacturing sites. Screen printing gives good print uniformity, but requires a formulation that self-levels after printing. Stencil printing can be used with almost any formulation or filler loading, but is highly dependent on the tooling accuracy to maintain the coating thickness uniformity. Both methods are limited to coating thicknesses in the 25–100 micron range. There exists a need for a wafer coating methodology that can overcome the aforementioned restrictions. The ability to apply materials of varying rheologies, with low material waste and yet provide high quality, uniform coatings is required. This paper will review the current methods of applying WBC coatings. The authors will also present results from a newly developed spray coating process developed to process high viscosity fluids such as WBC coatings.

scholarly journals A Low-Viscosity BisGMA Derivative for Resin Composites: Synthesis, Characterization, and Evaluation of Its Rheological Properties

Materials ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 338
Author(s):  
Ali Alrahlah ◽  
Abdel-Basit Al-Odayni ◽  
Haifa Fahad Al-Mutairi ◽  
Bashaer Mousa Almousa ◽  
Faisal S. Alsubaie ◽  
...  
Keyword(s):  
Substantial Reduction ◽  
Triethylene Glycol ◽  
High Viscosity ◽  
Resin Matrix ◽  
Resonance Spectroscopy ◽  
Dental Resin ◽  
Triethylene Glycol Dimethacrylate ◽  
Oh Groups ◽  
Low Viscosity ◽  
13C Nuclear Magnetic Resonance

This study aimed to synthesize new bisphenol A-glycidyl methacrylate (BisGMA) derivatives, targeting a reduction in its viscosity by substituting one of its OH groups, the leading cause of its high viscosity, with a chlorine atom. Hence, this monochloro-BisGMA (mCl-BisGMA) monomer was synthesized by Appel reaction procedure, and its structure was confirmed using Fourier transform infrared spectroscopy, 1H and 13C-nuclear magnetic resonance spectroscopy, and mass spectroscopy. The viscosity of mCl-BisGMA (8.3 Pa·s) was measured under rheometry conditions, and it was found to be more than 65-fold lower than that of BisGMA (566.1 Pa·s) at 25 °C. For the assessment of the viscosity changes of model resins in the presence of mCl-BisGMA, a series of resin matrices, in which, besides BisGMA, 50 wt % was triethylene glycol dimethacrylate, were prepared and evaluated at 20, 25, and 35 °C. Thus, BisGMA was incrementally replaced by 25% mCl-BisGMA to obtain TBC0, TBC25, TBC50, TBC75, and TBC100 blends. The viscosity decreased with temperature, and the mCl-BisGMA content in the resin mixture increased. The substantial reduction in the viscosity value of mCl-BisGMA compared with that of BisGMA may imply its potential use as a dental resin matrix, either alone or in combination with traditional monomers. However, the various properties of mCl-BisGMA-containing matrices should be evaluated.

Advances in MXene Films: Synthesis, Assembly, and Applications

2021 ◽  
Author(s):  
Xiaohua Li ◽  
Feitian Ran ◽  
Fan Yang ◽  
Jun Long ◽  
Lu Shao
Keyword(s):  
Spin Coating ◽  
Reaction Mechanisms ◽  
Membrane Separation ◽  
Synthesis Methods ◽  
Metal Carbides ◽  
Max Phases ◽  
Practical Applications ◽  
Coating Methods ◽  
And Performance ◽  
Important Form

AbstractA growing family of two-dimensional (2D) transition metal carbides or nitrides, known as MXenes, have received increasing attention because of their unique properties, such as metallic conductivity and good hydrophilicity. The studies on MXenes have been widely pursued, given the composition diversity of the parent MAX phases. This review focuses on MXene films, an important form of MXene-based materials for practical applications. We summarized the synthesis methods of MXenes, focusing on emerging synthesis strategies and reaction mechanisms. The advanced assembly technologies of MXene films, including vacuum-assisted filtration, spin-coating methods, and several other approaches, were then highlighted. Finally, recent progress in the applications of MXene films in electrochemical energy storage, membrane separation, electromagnetic shielding fields, and burgeoning areas, as well as the correlation between compositions, architecture, and performance, was discussed.

scholarly journals A Conceptional Approach of Resin-Transfer-Molding to Rosin-Sourced Epoxy Matrix Green Composites

Aerospace ◽  
2020 ◽  
Vol 8 (1) ◽  
pp. 5
Author(s):  
Sicong Yu ◽  
Xufeng Zhang ◽  
Xiaoling Liu ◽  
Chris Rudd ◽  
Xiaosu Yi
Keyword(s):  
Composite Laminates ◽  
Resin Transfer Molding ◽  
High Viscosity ◽  
Ramie Fiber ◽  
Liquid Composite Molding ◽  
Curing Agent ◽  
Molding Process ◽  
Transfer Molding ◽  
Low Viscosity ◽  
Composite Molding

In this concept-proof study, a preform-based RTM (Resin Transfer Molding) process is presented that is characterized by first pre-loading the solid curing agent onto the preform, and then injecting the liquid nonreactive resin with an intrinsically low viscosity into the mold to infiltrate and wet the pre-loaded preform. The separation of resin and hardener helped to process inherently high viscosity resins in a convenient way. Rosin-sourced, anhydrite-cured epoxies that would normally be regarded as unsuited to liquid composite molding, were thus processed. Rheological tests revealed that by separating the anhydrite curing agent from a formulated RTM resin system, the remaining epoxy liquid had its flowtime extended. C-scan and glass transition temperature tests showed that the preform pre-loaded with anhydrite was fully infiltrated and wetted by the liquid epoxy, and the two components were diffused and dissolved with each other, and finally, well reacted and cured. Composite laminates made via this approach exhibited roughly comparable quality and mechanical properties with prepreg controls via autoclave or compression molding, respectively. These findings were verified for both carbon and ramie fiber composites.

Electrochemical Evaluation for Rust Preventive Properties of Rust Preventive Oils Coated on Fe-Cu-C Sintered Steel

2014 ◽  
Vol 783-786 ◽  
pp. 2537-2540 ◽  
Author(s):  
Satoshi Sunada ◽  
Norio Nunomura ◽  
Sayaka Hirata ◽  
Naoki Nagase
Keyword(s):  
Open Circuit Potential ◽  
High Viscosity ◽  
Open Circuit ◽  
Second Step ◽  
Sintered Steel ◽  
Corrosive Solution ◽  
The Third ◽  
Low Viscosity ◽  
Sintered Steels ◽  
Electrochemical Evaluation

Since Fe-Cu-C sintered steels are easily rusted, they are coated with rust preventive oils. High viscosity of those rust preventive oils decrease workability, and low viscosity deteriorates rust preventive performance. Therefore, it is necessary to develop new rust preventive oils with contradictory properties of low viscosity and superior rust prevention. However, precise methodology to evaluate rust prevention ability has not been established. In this study, we developed new technique to quantitatively evaluate rust prevention ability by measuring the open circuit potential through thin corrosive solution on Fe-Cu-C sintered steels coated with a rust preventive oils. As a result, the ability for rust prevention can be measured quantitatively, and it decreases slowly over time, with repeating destruction and restoration. Furthermore, it was found that the deteriorating processes of rust prevention ability for rust prevention oils are composed of three characteristics steps respectively. That is, in the first step the great open circuit potential changes from 0V to-0.3V with repetition were observed where the excellent rust prevention ability was kept, in the second step it decreases slowly from-0.1V to-0.4V with oscillation of the small potential changes where the gradual decrease of rust prevention ability was recognized and in the third step it decreases monotonously in the lower potential than-0.4V where the rust was observed because of the remarkable deteriorating of the rust prevention ability.

scholarly journals Improved Morphology of Poly(3,4-ethylenedioxythiophene):Poly(styrenesulfonate) Thin Films for All-Electrospray-Coated Organic Photovoltaic Cells

2016 ◽  
Vol 2016 ◽  
pp. 1-8 ◽  
Author(s):  
Yingjie Liao ◽  
Takeshi Fukuda ◽  
Norihiko Kamata
Keyword(s):  
Thin Films ◽  
High Performance ◽  
Photovoltaic Cells ◽  
Spray Coating ◽  
Organic Photovoltaic ◽  
Organic Photovoltaic Cells ◽  
Ambient Conditions ◽  
Deposition Parameters ◽  
Coating Methods ◽  
Organic Devices

Spray coating technique has been established as a promising substitute for the traditional coating methods in the fabrication of organic devices in many reports recently. Control of film morphology at the microscopic scale is critical if spray-coated devices are to achieve high performance. Here we investigate electrospray deposition protocols for the fabrication of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) thin films with a single additive system under ambient conditions at room temperature. Critical deposition parameters including solution composition, applied voltage, and relative humidity are discussed systematically. Optimized process for preparing homogenous PEDOT:PSS thin films is applied to all-electrospray-coated organic photovoltaic cells and contributes to a power conversion efficiency comparable to that of the corresponding all-spin-coated device.

Synthesis and Characterization of Polydimethylsiloxane (PDMS) with Medium Viscosity via Ring-Opening Polymerization

2021 ◽  
Vol 1028 ◽  
pp. 346-351
Author(s):  
Soni Setiadji ◽  
Zulfi Mofa Agasa ◽  
Diba G Auliya ◽  
Fitrilawati ◽  
Norman Syakir ◽  
...  
Keyword(s):  
Ring Opening ◽  
Vitreoretinal Surgery ◽  
High Viscosity ◽  
Ring Opening Polymerization ◽  
Vitreous Humour ◽  
Synthesis And Characterization ◽  
Low Viscosity ◽  
A Value ◽  
Medium Viscosity

Duration of use and injectability are external factors for Polydimethylsiloxane (PDMS) that needs to be considered when PDMS utilized as a vitreous substituted liquid in vitreoretinal surgery. In general, PDMS which has been used as a substitute for vitreous humour is PDMS with a low viscosity in the value about 1000 cSt and a high viscosity at a value of about 5000 cSt. Various deficiencies have been encountered from low and high viscosity of PDMS, causing research to be continued to obtain PDMS which has suitable properties as a substitute for vitreous humour. One of them is research to obtain medium viscosity of PDMS with a viscosity value of about 2000 cSt. Here, we reported synthesis and characterization of PDMS with medium viscosity in ranges from 1800 to 2600 mPas. PDMS was synthesized through Ring-Opening Polymerization (ROP) pathway using the monomer of Octamethylcyclotetrasiloxane (D4) and the chain terminator of Hexamethyldisiloxane (MM). Various concentrations of potassium hydroxide (KOH) of 3, 4, 6 and 8 %(w/v) were applied as initiator to form gel of PDMS. All synthesized PDMS samples were identified to have viscosity values of 1800-2600 mPas, refractive index values of 1.4042-1.4044 and surface tension values of 22-23 mN/m. Meanwhile, the results of Fourier-Transform Infrared (FTIR) measurement showed that the absorption peaks were similar to that of our previous report.

Impact of Resin Composite Viscosity and Fill-technique on Internal Gap in Class I Restorations: An OCT Evaluation

2021 ◽  
Author(s):  
KR Kantovitz ◽  
LL Cabral ◽  
NR Carlos ◽  
AZ de Freitas ◽  
DC Peruzzo ◽  
...  
Keyword(s):  
Repeated Measures ◽  
Resin Composite ◽  
Oral Care ◽  
High Viscosity ◽  
Class I ◽  
Low Viscosity ◽  
Significant Difference ◽  
Before And After ◽  
Internal Adaptation ◽  
Internal Gap

SUMMARY The aim of this in vitro study was to quantitatively evaluate the internal gap of resin composites of high-and low-viscosity used in single- and incremental-fill techniques in Class I cavities exposed to thermal cycling (TC) using optical coherence tomography (OCT). Cavities of 4-mm depth and 3-mm diameter were prepared in 36 third molars randomly distributed into four groups, according to viscosity of restorative resin-based composite (high or low viscosity, all from 3M Oral Care) and technique application (bulk or incremental fill) used (n=9): RC, high-viscosity, incremental-fill, resin-based composite (Filtek Z350 XT Universal Restorative); BF, high-viscosity, bulk-fill, resin-based composite (Filtek One Bulk Fill); LRC, low-viscosity, incremental-fill, resin-based composite (Filtek Z350 XT Flowable Universal Restorative); and LBF, low-viscosity, bulk-fill, resin-based composite (Filtek Flowable Restorative). Single Bond Universal Adhesive system (3M Oral Care) was used in all the experimental groups. The incremental-fill technique was used for RC and LRC groups (2-mm increments), and a single-layer technique was used for BF and LBF groups, as recommended by the manufacturer. The internal adaptation of the resin at all dentin walls was evaluated before and after TC (5000 cycles between 5°C and 55°C) using OCT images. Five images of each restored tooth were obtained. Images were analyzed using ImageJ software that measured the entire length of the gaps at the dentin–restoration interface. The length of gaps (μm) was analyzed using two-way repeated measures ANOVA and the Tukey tests (α=0.05). There was a significant interaction between material types and TC (p=0.006), and a significant difference among all material types (p<0.0001), before and after TC (p<0.0001). Increased internal gaps at the dentin–restoration interface were noticed after TC for all groups. RC presented the lowest value of internal gap before and after TC, while LBF showed the highest values of internal gap after TC. In conclusion, TC negatively affected the integrity of internal gap, whereas high-viscosity, incremental-fill, resin-based composite presented better performance in terms of internal adaptation than low-viscosity, bulk-fill materials in Class I cavities.

scholarly journals Research and Development of a 3D Jet Printer for High-Viscosity Molten Liquids

Micromachines ◽  
2018 ◽  
Vol 9 (11) ◽  
pp. 554
Author(s):  
Yang Yang ◽  
Shoudong Gu ◽  
Jianfang Liu ◽  
Hongyu Tian ◽  
Qingqing Lv
Keyword(s):  
Liquid Velocity ◽  
New Technology ◽  
Droplet Diameter ◽  
Average Diameter ◽  
High Viscosity ◽  
Taper Angle ◽  
Voltage Difference ◽  
Low Viscosity ◽  
Cooling Mechanism ◽  
Molten Liquid

Micro-droplet jetting manufacture is a new 3D printing technology developed in recent years. Presently, this new technology mainly aims at ejecting a low-viscosity medium. Therefore, a device for ejecting high-viscosity molten liquid is designed by analyzing the injection principle of high-viscosity molten liquid. Initially, the cooling mechanism is designed to overcome the defect that the piezoelectric stacks cannot operate in high-temperature conditions. Thereafter, the mathematical model of the liquid velocity in the nozzle is derived, and the factors influencing injection are verified by Fluent. Subsequently, a prototype of the jet printer is fabricated, and the needle velocity is tested by the laser micrometer; the relationship between voltage difference and the needle velocity is also obtained. The experimental results matched the theoretical model well, showing that the voltage difference, needle radius, nozzle diameter, and taper angle are closely related to the injection performance of the 3D jet printer. By using a needle with a radius of 0.4 mm, a nozzle with a diameter of 50 μm, a taper angle of 90°, a supply pressure of 0.05 Mpa, and a voltage difference of 98 V, a molten liquid with a viscosity of 8000 cps can be ejected with a minimum average diameter of 275 μm, and the variation of the droplet diameter is within ±3.8%.

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