scholarly journals Development of Kinetically Controlled New Functional Supramolecular　Complexes

2021 ◽  
Vol 77 (0) ◽  
pp. 26-36
Author(s):  
Yoko Sakata
Keyword(s):  
Supramolecular Complexes ◽  
Kinetically Controlled

Quantum Mechanical Calculations Suggest That Lignin Polymerization Is Kinetically Controlled

2019 ◽  
Author(s):  
Terry Gani ◽  
Michael Orella ◽  
Eric Anderson ◽  
Michael Stone ◽  
Fikile Brushett ◽  
...  
Keyword(s):  
Plant Cell ◽  
First Principles ◽  
Plant Cell Wall ◽  
Biological Processes ◽  
Plant Cell Walls ◽  
Biomass Valorization ◽  
Effective Strategies ◽  
Radical Coupling ◽  
Kinetically Controlled ◽  
Atomistic Models

Lignin is an abundant biopolymer important for plant function while holding promise as a renewable source of valuable chemicals. Although the lignification process in plant cell walls has been long-studied, a comprehensive, mechanistic understanding on the molecular scale remains elusive. A better understanding of lignification will lead to improved atomistic models of the plant cell wall that could, in turn, inform effective strategies for biomass valorization. Here, using first-principles quantum chemical calculations, we show that a simple model of kinetically-controlled radical coupling broadly rationalizes qualitative experimental observations of lignin structure across a wide variety of biomass types, thus paving the way for predictive, first-principles models of lignification while highlighting the ability of computational chemistry to help illuminate complex biological processes.

Growth of PbS Crystals under a BSA Monolayer in the Presence of Kinetically Controlled Ammonia Diffusion

2009 ◽  
Vol 25 (1) ◽  
pp. 63-67
Author(s):  
Hao-Yang XIONG ◽  
Bin-Bin HU ◽  
Zhong-Hui XUE ◽  
Li CAI ◽  
Shu-Xi DAI ◽  
...  
Keyword(s):  
Kinetically Controlled

Hydrogenation of nitrogen oxide on platinum-carbon catalysts in acidic medium

1981 ◽  
Vol 46 (11) ◽  
pp. 2669-2675 ◽  
Author(s):  
Ivo Paseka
Keyword(s):  
Nitrogen Oxide ◽  
Acidic Medium ◽  
Diffusion Region ◽  
Acid Solutions ◽  
Experimental Conditions ◽  
Platinum Content ◽  
Kinetically Controlled ◽  
Partial Pressures ◽  
Carbon Catalysts

Hydrogenation of nitrogen oxide in acid solutions on Pt-C catalysts proceeds in dependence on experimental conditions either in purely diffusion region or in the diffusion and kinetically controlled region. The boundary between these two processes shifts to the higher ratio of NO to H2 partial pressures with increasing platinum content and decreasing intensity of agitation.

scholarly journals Kinetically Controlled Formation of Semi-crystalline Conjugated Polymer Nanostructures

2021 ◽  
Author(s):  
Peter Kei ◽  
Mitchell T. Howell ◽  
Carlos A. Chavez ◽  
Joseph C. Mai ◽  
Changwoo Do ◽  
...  
Keyword(s):  
Conjugated Polymer ◽  
Polymer Nanostructures ◽  
Kinetically Controlled

Thermodynamic parameters and mitochondrial effects of supramolecular complexes of quercetin with β-cyclodextrins

2021 ◽  
Vol 325 ◽  
pp. 115184
Author(s):  
T.V. Ilyich ◽  
T.A. Kovalenia ◽  
E.A. Lapshina ◽  
A. Stępniak ◽  
B. Palecz ◽  
...  
Keyword(s):  
Thermodynamic Parameters ◽  
Supramolecular Complexes

Rule, Not Exclusion: Formation of Dichlorine-Containing Supramolecular Complexes with Chlorometalates(IV)

2021 ◽  
Author(s):  
Andrey N. Usoltsev ◽  
Nikita A. Korobeynikov ◽  
Boris A. Kolesov ◽  
Alexander S. Novikov ◽  
Denis G. Samsonenko ◽  
...  
Keyword(s):  
Supramolecular Complexes
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