scholarly journals Combined effect of nano-SiO2 and nano-Fe2O3 on compressive strength, flexural strength, porosity and electrical resistivity in cement mortars

2018 ◽  
Vol 68 (329) ◽  
pp. 150 ◽  
Author(s):  
M. A. Sanjuán ◽  
C. Argiz ◽  
J. C. Gálvez ◽  
E. Reyes

The compressive strength, flexural strength, porosity and electrical resistivity properties of cement mortars with nano-Fe2O3 and nano-SiO2 are studied. Amorphous silica is the main component of pozzolanic materials due to its reaction with calcium hydroxide formed from calcium silicate (C3S and C2S) hydration. The pozzolanic reaction rate is not only proportional to the amount of amorphous silica but also to the surface area available for reaction. Subsequently, fine nano-Fe2O3 and nano-SiO2 particles in mortars are expected to improve mortar performance. The experimental results showed that the compressive strength of mortars with nano-Fe2O3 and nano-SiO2 particles were lower than those obtained with the reference mortar at seven and 28 days. It was shown that the nano-particles were not able to enhance mechanical strength on every occasion. The continuous microstructural progress monitored by mercury intrusion porosimetry (MIP) measurements, pore-size distribution (PSD), total porosity and critical pore diameter also confirmed such results.

2010 ◽  
Vol 168-170 ◽  
pp. 1886-1890 ◽  
Author(s):  
Zheng Mao Ye ◽  
Wen Chen ◽  
Xin Cheng

The impermeability and other performance of sulphoaluminate cement were studied, which mixed with redispersible polymer powders. With the help of SEM and mercury intrusion apparatus, the morphology of the hydrates and the pore structure of the cement mortars were observed. The impermeability mechanism of redispersible polymer powders in sulphoaluminate cement mortar was analyzed. The results show that sulphoaluminate cement mortar could be modified by adding redispersible polymer powders. The flexural strength of sulphoaluminate cement mortar could be increased by adding redispersible polymer powders, and compressive strength of sulphoaluminate cement mortar could also be increased to a certain extent. When the mass fraction of redispersible polymer powders was 0.9%, the flexural strength and compressive strength reached 9.2 MPa and 52.5 MPa. When small amount of redispersible polymer powders was added, the impermeability of modified sulphoaluminate cement mortar was improved significantly. When the mass fraction of redispersible polymer powders exceeded 0.9%, impermeability of Sulphoaluminate cement mortar would not be improved significantly. Due to redispersible powders gap filling and film forming, the interface of cement and aggregate is more closed, total porosity decreased and unharmful porosity increased when redispersible polymer powders is added.


Molecules ◽  
2021 ◽  
Vol 26 (8) ◽  
pp. 2136
Author(s):  
Shaokang Zhang ◽  
Ru Wang ◽  
Linglin Xu ◽  
Andreas Hecker ◽  
Horst-Michael Ludwig ◽  
...  

This paper studies the influence of hydroxyethyl methyl cellulose (HEMC) on the properties of calcium sulfoaluminate (CSA) cement mortar. In order to explore the applicability of different HEMCs in CSA cement mortars, HEMCs with higher and lower molar substitution (MS)/degree of substitution (DS) and polyacrylamide (PAAm) modification were used. At the same time, two kinds of CSA cements with different contents of ye’elimite were selected. Properties of cement mortar in fresh and hardened states were investigated, including the fluidity, consistency and water-retention rate of fresh mortar and the compressive strength, flexural strength, tensile bond strength and dry shrinkage rate of hardened mortar. The porosity and pore size distribution were also analyzed by mercury intrusion porosimetry (MIP). Results show that HEMCs improve the fresh state properties and tensile bond strength of both types of CSA cement mortars. However, the compressive strength of CSA cement mortars is greatly decreased by the addition of HEMCs, and the flexural strength is decreased slightly. The MIP measurement shows that HEMCs increase the amount of micron-level pores and the porosity. The HEMCs with different MS/DS have different effects on the improvement of tensile bond strength in different CSA cement mortars. PAAm modification can improve the tensile bond strength of HEMC-modified CSA cement mortar.


Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-10
Author(s):  
Ping Xu ◽  
Rui Shi ◽  
Chao Wang ◽  
Yuhao Cui ◽  
Minxia Zhang

In order to develop textile reinforced concrete (TRC) with good flowability and strength, colloidal nano-SiO2 (CNS) is adopted to improve the performance of TRC. The flowability, compressive strength, flexural strength, and four-point bending tests of TRC matrix with CNS are carried out, and the changes of internal micromorphological characteristics of TRC matrix are analyzed by combining with scanning electron microscopy. The results show that the CNS has an inhibitory effect on the flowability of TRC matrix, and the greater the amount of admixture is, the smaller the slump expansion of TRC matrix is. The compressive strength and flexural strength of TRC matrix show a trend of increasing and then decreasing as the amount of CNS increases, and the compressive strength reaches the maximum at each age (7 d, 14 d, 28 d) when CNS and silica fume replace 5% cement by 1 : 4 equal mass. The flexural strength reaches the maximum at each age (7 d, 14 d, 28 d) when 5% cement is replaced by CNS and silica fume with 3 : 7 equal mass. The flexural strength increases with the increase of CNS admixture. It is found by electron microscope scanning that the incorporation of CNS consumes more Ca(OH)2, refines the Ca(OH)2 crystal size, and generates more C-S-H gels. These C-S-H gels are distributed in a net-like pattern inside the concrete, filling the internal pores, effectively densifying the interfacial transition zone between the cementitious material and the aggregates, and optimizing the internal structure.


2020 ◽  
Vol 15 (3) ◽  
pp. 409-413
Author(s):  
Cheng Zhu

Abstract Cement-based materials have been widely used in bridge construction. In order to further improve their performance, this study analyzed the modification and optimization functions of nano-SiO2 materials, designed test specimens with different content of nano-SiO2 and conducted experiments on their flow performance, compression resistance, bending resistance and impermeability. The results showed that the flow performance of the materials decreased and the impermeability decreased with the increase of nano-SiO2 content. The compressive strength and flexural strength are the best when the content of nano-SiO2 is 1%. On the whole, the best content of nano-SiO2 is 1%; when the content of nano-SiO2 is 1%, all the properties of the specimens are good, which is more conducive to the construction of bridges in various complex environments. The research in this paper has made some contributions to the further application of nano-SiO2 in the optimization of building materials, which is conducive to the better development of building materials.


Materials ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 3849 ◽  
Author(s):  
Manuel J. Chinchillas-Chinchillas ◽  
Manuel J. Pellegrini-Cervantes ◽  
Andrés Castro-Beltrán ◽  
Margarita Rodríguez-Rodríguez ◽  
Víctor M. Orozco-Carmona ◽  
...  

Currently it is necessary to find alternatives towards a sustainable construction, in order to optimize the management of natural resources. Thus, using recycled fine aggregate (RFA) is a viable recycling option for the production of new cementitious materials. In addition, the use of polymeric microfibers would cause an increase in the properties of these materials. In this work, mortars were studied with 25% of RFA and an addition of polyacrylonitrile PAN microfibers of 0.05% in cement weight. The microfibers were obtained by the electrospinning method, which had an average diameter of 1.024 µm and were separated by means of a homogenizer to be added to the mortar. Cementing materials under study were evaluated for compressive strength, flexural strength, total porosity, effective porosity and capillary absorption, resistance to water penetration, sorptivity and carbonation. The results showed that using 25% of RFA causes decreases mechanical properties and durability, but adding PAN microfibers in 0.05% caused an increase of 2.9% and 30.8% of compressive strength and flexural strength respectively (with respect to the reference sample); a decrease in total porosity of 5.8% and effective porosity of 7.4%; and significant decreases in capillary absorption (approximately 23.3%), resistance to water penetration (25%) and carbonation (14.3% after 28 days of exposure). The results showed that the use of PAN microfibers in recycled mortars allowed it to increase the mechanical properties (because they increase the tensile strength), helped to fill pores or cavities and this causes them to be mortars with greater durability. Therefore, the use of PAN microfibers as a reinforcement in recycled cementitious materials would be a viable option to increase their applications.


Nanomaterials ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 113 ◽  
Author(s):  
Hongfang Sun ◽  
Li Ling ◽  
Zhili Ren ◽  
Shazim Ali Memon ◽  
Feng Xing

This paper evaluated the effect of graphene oxide/graphene (GO/GR) hybrid on mechanical properties of cement mortar. The underlying mechanism was also investigated. In the GO/GR hybrid, GO was expected to act as a dispersant for GR while GR was used as reinforcement in mortar due to its excellent mechanical properties. For the mortar specimen, flexural and compressive strength were measured at varied GO to GR ratios of 1:0, 3:1, 1:1, 1:3, and 0:1 by keeping the total amount of GO and GR constant. The underlying mechanism was investigated through the dispersibility of GR, heat releasing characteristics during hydration, and porosity of mortar. The results showed that GO/GR hybrid significantly enhanced the flexural and compressive strength of cement mortars. The flexural strength reached maximum at GO:GR = 1:1, where the enhancement level was up to 23.04% (28 days) when compared to mortar prepared with only GO, and up to 15.63% (7 days) when compared to mortar prepared with only GR. In terms of compressive strength, the enhancement level for GO:GR = 3:1 was up to 21.10% (3 days) when compared with that of mortar incorporating GO only. The enhancement in compressive strength with mortar at GO:GR = 1:1 was up to 14.69% (7-day) when compared with mortar incorporating GR only. In addition to dispersibility, the compressive strength was also influenced by other factors, such as the degree of hydration, porosity, and pore size distribution of mortar, which made the mortars perform best at different ages.


2009 ◽  
Vol 405-406 ◽  
pp. 356-360 ◽  
Author(s):  
Dong Mei Liu ◽  
Kun He Fang ◽  
Hua Shan Yang

The strengthening effect of phosphorus slag powder (PSP) in cement-based materials was researched by model of strengthening effect of mineral admixes, and the mechanism of strengthening effect of PSP was also studied by SEM. The results indicate that, in early hydration period, the strengthening effect of PSP on strength of cement mortars is zero. At 90 days, strengthening effect has been exerted, and increases with the amount of PSP when that is no more than 40%, but decreases with larger content of PSP. At 180 days, the strengthening effect was further enhanced, the greater the amount of PSP, the greater its effect. For compressive strength of cement mortars, the strengthening effect of PSP is more than that of PSP on flexural strength. The results analyses of SEM show that, strengthening effect of PSP mainly come from its pozzolana reaction. With double excitation of cement hydration product hydroxide and gypsum, the low alkalinity C-S-H was produced.


Materials ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 2373 ◽  
Author(s):  
Wenxin Tian ◽  
Chao Tang ◽  
Qian Wang ◽  
Shiling Zhang ◽  
Yali Yang

Moisture has a significant effect on the internal insulation performance of transformers, and is closely related to the breakdown voltage of transformer insulating oil. In the present work, we studied the effect of nano-SiO2 particles on the diffusion of water in insulating naphthenic mineral oil using molecular dynamics simulation. Six models were established, three of which contained nano-SiO2 particles together with water concentration of 1 wt.%, 2 wt.%, or 3 wt.%. For each model variations in free volume, mean square displacement, and interaction energy were assessed. The addition of nano SiO2 particles was found to reduce the free volume fraction of the model and as well as the free motion of water molecules in the oil. These particles also increased the interaction between the oil and water molecules, indicating that insulating oil containing nano-particles has a greater binding effect on water. The diffusion coefficient of water in oil containing nano-SiO2 particles was reduced, such that water molecules were less likely to diffuse. The results also show that these particles adsorb water molecules in the oil and to reduce diffusion. Consequently, the addition nano-scale SiO2 particles could potentially improve the breakdown voltage of the insulating oil.


2020 ◽  
Vol 55 (1) ◽  
pp. 95-107
Author(s):  
Alireza Mansoori ◽  
Mohammad Mohtasham Moein ◽  
Ehsan Mohseni

This paper aims to evaluate the impact of ceramic waste powder (CWP), micro silica (MS) and steel fiber (SF) on self-compacting mortar. CWP at ratios of 10 and 20%, and MS at 1 and 5% by weight of cement were replaced the cement. Beside, SF was added at ratios of 0.5 and 1% of cement. Mini slump flow diameter and mini V-funnel flow time tests were carried out to determine the workability of fresh composites. Compressive strength, flexural strength, water absorption, electrical resistivity and drying shrinkage tests were performed on hardened mortars. Scanning electron microscope (SEM) technique was employed to assess the microstructure. The results indicated that CWP reduced the mechanical properties by about 20% and increased permeability by about 14%. However, inclusion of micro silica particles improved the properties outstandingly. Compressive strength increased about 30% by inclusion of MS. It was also observed that the addition of fibers from 0.5% to 1% increased the flexural strength. This improvement was more obvious in samples with higher contents of micro silica. It can be reported that by including the both micro silica and steel fibers, the bonding between the cement paste and fibers was developed. Replacement of micro silica led to increase of electrical resistivity by about 99% in samples containing 20% ceramic waste powder. The microstructure studies confirmed the significant increase of density and uniformity of the hydration products in the presence of micro silica particles.


2018 ◽  
Vol 174 ◽  
pp. 02006 ◽  
Author(s):  
Elżbieta Janowska-Renkas ◽  
Jolanta Kowalska ◽  
Grzegorz Janus ◽  
Agnieszka Kaliciak

The study shows results of research on the aggressive environment impact (1, 3 and 5% HCl solution) on durability of cement mortars with fraction from 30 to 45% by mass of fly ashes from the fluidized bed combustion (FBC fly ash) and conventional fly ashes used separately and in the form of a mixture. The impact of aggressive environments on durability of cement and ash mortars was tested for aperiod of 365 days, by testing the compressive strength, linear changes, mass loss and porosity. It was demonstrated that mortars with the content of FBC fly ashes, after 365 days of tests showed the higher resistance to aggressive environment impact. It is confirmed by e.g. their higher compressive strength, and thus the reduced total porosity. Reduction of total porosity content (<50 nm) was accompanied by the increased compressive strength, which in the aqueous environment was in favour of cement mortars, and in the aggressive environment in favour of cement and ash mortars. It was demonstrated that the content of pores < 200 nm was lower for mortars with FBC fly ashes and mixtures of ashes regardless of environment the mortars were stored in. A beneficial impact of FBC fly ashes was found on physical properties of mortars, i.e. reduction of the shrinkage, lower mass loss and reduced destruction of mortars in the acid corrosion environment. That effect was especially beneficial for the mortar with higher (45% by mass) content of FBC fly ashes, regardless of aggressive character of the environment.


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