Voltammetric Behavior of Mediator-Modified Electrode by Electrochemical Copolymerization of Nitroxyl Radical Precursor Containing Pyrrole Side Chain and Thiophenes

Heterocycles ◽  
2011 ◽  
Vol 83 (11) ◽  
pp. 2517 ◽  
Author(s):  
Yoshitomo Kashiwagi ◽  
Makiko Tsunoda ◽  
Tetsuya Ono
Heterocycles ◽  
2010 ◽  
Vol 81 (12) ◽  
pp. 2771 ◽  
Author(s):  
Yoshitomo Kashiwagi ◽  
Tetsuya Ono ◽  
Makiko Tsunoda ◽  
Shigehiro Takahashi ◽  
Toshio Obata ◽  
...  

2010 ◽  
Vol 8 (1) ◽  
pp. 155-162 ◽  
Author(s):  
Karim Asadpour-Zeynali ◽  
Mir Majidi ◽  
Mitra Zarifi

AbstractA new chemically modified electrode is constructed based on carbon ceramic electrode incorporated with zeolite ZSM-5. Voltammetric behavior of piroxicam at the carbon ceramic zeolite modified electrode (CCZME) was investigated. The modified electrode exhibited catalytic activity toward the electrooxidation of piroxicam. Experimental parameters such as solution pH, scan rate, concentration of piroxicam and zeolite amount were studied. It has been shown that using the CCZME, piroxicam can be determined by differential pulse voltammetry (DPV) and hydrodynamic amperometry (HA). Under the optimized conditions the calibration plots are linear in the concentration ranges of 0.20–25.00 and 0.20–50.10 μM with limit of detections of 0.65 and 0.29 μM for DPV and HA, respectively. The modified electrode with DPV and HA methods was successfully applied for analysis of piroxicam in pharmaceutical formulations. The results were favorably compared to those obtained by the spiked method. The results of the analysis suggest that the proposed method has promise for the routine determination of piroxicam in the products examined.


1998 ◽  
Vol 31 (2) ◽  
pp. 237-249 ◽  
Author(s):  
Zhao Min ◽  
Hu Jingbo ◽  
Lai Yongchun ◽  
Li Qilong ◽  
Wu Zhongda

2016 ◽  
Vol 8 (1) ◽  
pp. 171-176 ◽  
Author(s):  
Xiaolin Zhu ◽  
Hongwei Qin ◽  
Guanlan Wu ◽  
Jinlian Li ◽  
Xing Yuan ◽  
...  

Two voltammetric signals based on the purine metabolism of human cervical carcinoma (HeLa) cells on a sensitive p-MWCNT/IL/GCE was discovered. The cytotoxicity of three chlorophenols was tested with this double-signal electrochemical method.


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