scholarly journals Metastable level properties of the excited configuration 4p64d84f

2015 ◽  
Vol 55 (2) ◽  
Author(s):  
Rasa Karpuškienė ◽  
Pavel Bogdanovich ◽  
Romualdas Kisielius
Keyword(s):  
Ab Initio ◽  
Configuration Interaction ◽  
Transition Probabilities ◽  
Excited Configuration ◽  
Metastable Level ◽  
Radiative Lifetimes ◽  
Hartree Fock ◽  
Radiative Transitions

Metastable levels in rhodium-like ions with the ground configuration 4p64d9 and the excited configurations 4p64d84f and 4p54d10 are investigated. The ab initio calculations of the level energies, radiative multipole transition probabilities are performed in a quasirelativistic Hartree–Fock approximation employing an extensive configuration interaction based on quasirelativistic transformed radial orbitals. Systematic trends in the behavior of calculated radiative lifetimes of the metastable levels are studied for the ions from Z = 60 to Z = 92. The significance of the radiative transitions of higher multipole order (M2 and E3) for the calculated radiative lifetimes is demonstrated and discussed.

scholarly journals Recombination Spectra of Planetary Nebulae

1983 ◽  
Vol 103 ◽  
pp. 514-516
Author(s):  
P.O. Bogdanovich ◽  
Z.B. Rudzikas ◽  
T. H. Feklistova ◽  
A.F. Kholtygin ◽  
A.A. Nikitin ◽  
...  
Keyword(s):  
Transition Probabilities ◽  
Planetary Nebulae ◽  
Dielectronic Recombination ◽  
Wave Functions ◽  
Energy Spectra ◽  
Coupling Scheme ◽  
Intermediate Coupling ◽  
Hartree Fock ◽  
Radiative Transitions ◽  
Intermediate Coupling Scheme

The lines of the transitions between the subordinate levels of the CIII, NIII etc. ions are observed in the spectra of planetary nebulae (PN) (1). Their theoretical intensities may be found by solving the stationarity equations and accounting for both the recombination and cascade radiative transitions. It is possible to calculate the recombination spectra in various approaches: the single- or multi-configuration approximations (SCA and MCA) making use of both the superposition of configurations (SC) or the multiconfigurational Hartree-Fock-Jucys equations (2), taking into consideration the contribution of the dielectronic recombination to the intensities of the recombination lines. The energy spectra, the transition probabilities etc., as a rule ought to be calculated in the intermediate coupling scheme (2). Both analytical or numerical (e.g. Hartree-Fock) wave functions may be adopted.

scholarly journals Transition Parameters for Doubly Ionized Lanthanum

2012 ◽  
Vol 2012 ◽  
pp. 1-15 ◽  
Author(s):  
Betül Karaçoban ◽  
Leyla Özdemir
Keyword(s):  
Least Squares ◽  
Configuration Interaction ◽  
Electric Dipole ◽  
Transition Probabilities ◽  
Energy Levels ◽  
Relativistic Effects ◽  
Oscillator Strengths ◽  
Least Squares Fitting ◽  
Hartree Fock

The transition parameters such as the wavelengths, weighted oscillator strengths, and transition probabilities (or rates) for the nd (n=5−9)−nf (n=4−8), nd (n=5−9)−np (n=6−9), np (n=6−9)−ns (n=6−10), and ng (n=5−8)−nf (n=4−8) electric dipole (E1) transitions of doubly ionized lanthanum (La III, Z=57) have been calculated using the relativistic Hartree-Fock (HFR) method. In this method, configuration interaction and relativistic effects have been included in the computations combined with a least squares fitting of the Hamiltonian eigenvalues to the observed energy levels. We have compared the results obtained from this work with the previously available calculations and experiments in literature. We have also reported new transitions with the weighted transition probabilities greater than or equal to 105.

scholarly journals Radiative transitions for three lowest configurations of tungsten ions W38+–W43+

2017 ◽  
Vol 57 (3) ◽  
Author(s):  
Rasa Karpuškienė ◽  
Pavel Bogdanovich ◽  
Romualdas Kisielius
Keyword(s):  
Transition Probabilities ◽  
Relativistic Effects ◽  
Electric Quadrupole ◽  
Radiative Transition ◽  
Configuration Interaction Method ◽  
Hartree Fock ◽  
Radiative Transitions ◽  
Emission Transition ◽  
Magnetic Quadrupole ◽  
Electron Correlation Effects

The ab initio quasirelativistic approximation was used to derive transition data for the multicharged tungsten ions W38+–W43+ with an open 4p shell. The configuration interaction method with transformed radial orbitals was applied to include electron correlation effects. The relativistic effects were taken into account in the Breit–Pauli approximation for the quasirelativistic Hartree–Fock radial orbitals. The level energies E, radiative lifetimes τ, and Landé g-factors were calculated for the 4s24pN, 4s24pN–14d, and 4s4pN+1 configurations of six tungsten ions. The radiative transition wavelengths λ, spontaneous emission transition probabilities A and their uncertainties for the electric dipole, electric quadrupole, electric octupole, magnetic dipole and magnetic quadrupole transitions among the levels of these configurations are presented.

scholarly journals Fine-structure energy levels and radiative rates in Al-like molybdenum

2017 ◽  
Vol 95 (1) ◽  
pp. 59-64 ◽  
Author(s):  
Feng Hu ◽  
Yan Sun ◽  
Meifei Mao
Keyword(s):  
Configuration Interaction ◽  
Quantum Electrodynamics ◽  
Transition Probabilities ◽  
Energy Levels ◽  
Ground Level ◽  
Hartree Fock ◽  
Relativistic Configuration ◽  
Relativistic Configuration Interaction ◽  
Configuration Interaction Calculations ◽  
Good Agreement

Based on relativistic wavefunctions from multiconfigurational Dirac–Hartree–Fock and configuration interaction calculations, energy levels, radiative rates, and wavelengths are evaluated for all levels of 3s23p, 3s3p2, 3s23d, 3p3, 3s3p3d, 3p23d, and 3s3d2 configurations of Al-like molybdenum ion (Mo XXX). Transition probabilities are reported for E1 and M2 transitions from the ground level. The valence–valence and core–valence correlation effects are accounted for in a systematic way. Breit interactions and quantum electrodynamics effects are estimated in subsequent relativistic configuration interaction calculations. Comparisons are made with the available data in the literature and good agreement has been found, which confirms the reliability of our results.

Radiative lifetimes, branching fractions, and oscillator strengths of high-lying levels in Re I

2019 ◽  
Author(s):  
Yongfan Li ◽  
Sébastien Gamrath ◽  
Patrick Palmeri ◽  
Pascal Quinet ◽  
Qiu Li ◽  
...  
Keyword(s):  
Transition Probabilities ◽  
Branching Fractions ◽  
Laser Induced Fluorescence ◽  
Oscillator Strengths ◽  
Core Polarization ◽  
Radiative Lifetimes ◽  
Time Resolved ◽  
Hartree Fock ◽  
Semi Empirical ◽  
First Time

Abstract Radiative lifetimes of 19 levels in Re I were measured using the time-resolved laser-induced fluorescence method. As far as we know, 15 results are reported for the first time. By combining the experimental lifetimes determined from the present work with theoretical branching fractions obtained by a pseudo-relativistic Hartree–Fock model including core-polarization contributions, a new set of semi-empirical transition probabilities and oscillator strengths for 47 Re I lines from 18 newly measured levels were derived.

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