scholarly journals Using Biofilter Packed with Different Wood Waste Charges for Purification of Air Contaminated with Benzene

Author(s):  
Rasa Vaiškūnaitė

The main aim of this work was the analysis and assessment of benzene removal from air using bio-filter packed with a mixture of wood waste. The results of this work show that the small scale bio-filter with various coniferous and deciduous wood waste charges is capable of efficiently removing benzene from polluted air stream. The analysis of different mixtures of wood waste charge, while pH value was kept at neutral (pH = 7), determined, that the best wood waste mixture is consisted of 70% coniferous wood (45% pine trees, 25% fir trees), 30% deciduous wood (20% maple, 10% hazel) which was consisted of 10–20 mm fraction particles and had porosity value of 46%. This bio-media was best used for benzene removal from contaminated air stream (E = 93.86–74.78%).

A numerical study on the transition from laminar to turbulent of two-dimensional fuel jet flames developed in a co-flowing air stream was made by adopting the flame surface model of infinite chemical reaction rate and unit Lewis number. The time dependent compressible Navier–Stokes equation was solved numerically with the equation for coupling function by using a finite difference method. The temperature-dependence of viscosity and diffusion coefficient were taken into account so as to study effects of increases of these coefficients on the transition. The numerical calculation was done for the case when methane is injected into a co-flowing air stream with variable injection Reynolds number up to 2500. When the Reynolds number was smaller than 1000 the flame, as well as the flow, remained laminar in the calculated domain. As the Reynolds number was increased above this value, a transition point appeared along the flame, downstream of which the flame and flow began to fluctuate. Two kinds of fluctuations were observed, a small scale fluctuation near the jet axis and a large scale fluctuation outside the flame surface, both of the same origin, due to the Kelvin–Helmholtz instability. The radial distributions of density and transport coefficients were found to play dominant roles in this instability, and hence in the transition mechanism. The decreased density in the flame accelerated the instability, while the increase in viscosity had a stabilizing effect. However, the most important effect was the increase in diffusion coefficient. The increase shifted the flame surface, where the large density decrease occurs, outside the shear layer of the jet and produced a thick viscous layer surrounding the jet which effectively suppressed the instability.


1949 ◽  
Vol 2 (4) ◽  
pp. 451 ◽  
Author(s):  
AA Townsend

Extending previous work on turbulent diffusion in the wake of a circular-cylinder, a series of measurements have been made of the turbulent transport of mean stream momentum, turbulent energy, and heat in the wake of a cylinder of 0.169 cm. diameter, placed in an air-stream of velocity 1280 cm. sec.-1. It has been possible to extend the measurements to 960 diameters down-stream from the cylinder, and it 1s found that, at distances in excess of 600 diameters, the requirements of dynamical similarity are very nearly satisfied. To account for the observed rates of transport of turbulent energy and heat, it is necessary that only part of this transport be due to bulk convection by the slow large-scale motion of the jets of turbulent fluid emitted by the central, fully turbulent core of the wake, which had been supposed previously to perform most of the transport. The remainder of the transport is carried out by the small-scale diffusive motion of the turbulent eddies within the jets, and may be described by assigning diffusion coefficients to the turbulent fluid. It is found that the diffusion coefficients for momentum and heat are approximately equal, but that for turbulent energy is considerably smaller. On the basis of these hypotheses, it is possible to calculate $he form of the mean velocity distribution in good agreement with experiment, and to give a qualitative explanation of the apparently more rapid diffusion of heat.


2021 ◽  
Author(s):  
Sarka Klementova ◽  
Martina Poncarová ◽  
Helena Langhansová ◽  
Jaroslava Lieskovská ◽  
David Kahoun ◽  
...  

Abstract Photochemical degradation of fluoroquinolones ciprofloxacin, enrofloxacin and norfloxacin in aqueous solution under light conditions relevant to surface waters at neutral and alkaline pH was found to proceed readily with half-lives between 0.9 and 2.7 min. The products of photochemical degradation identified by HPLC-MS included defluorinated, hydroxylated, and decarboxylated structures as well as structures with opened cyclic structures. For all of the studied substances, the reaction pathways were influenced significantly by the pH of the reaction system, with more products formed at alkaline pH than at neutral pH: the ratios of products in neutral and alkaline pH were 16/26, 9/19, 15/23 for ciprofloxacin, enrofloxacin, and norfloxacin, respectively. The structures of photoproducts and pathways of photochemical degradation are proposed. The antibacterial activities of photoproduct mixtures tested on E. coli and S. epidermidis were significantly higher in comparison to parental antibiotics in the case of both ciprofloxacin and enrofloxacin with p-values less than 0.0001 in most cases. The effect of the photoproducts was shown to be dependent on the pH value of the original antibiotic solutions before photodegradation: for ciprofloxacin, antibacterial activity against E. coli was more notably pronounced with regard to neutral pH photoproducts, while a less significant, or in one case not significant, effect of pH was observed against S. epidermidis ; for norfloxacin, antibacterial activity against both E. coli and S. epidermidis were especially high with regard to alkaline pH photoproducts


2020 ◽  
Vol 8 (47) ◽  
pp. 10739-10743
Author(s):  
Hwunjae Lee ◽  
Hyun Soo Kim ◽  
Hyun-Wook Rho ◽  
Yong-Min Huh ◽  
Yoochan Hong

We have successfully fabricated a nanocomposite, which is composed of polyaniline (PAni) and pyrene butyric acid (Pyba) via a solvent shift method, which was self-doped at a neutral pH value.


2015 ◽  
Vol 72 ◽  
pp. 57-63 ◽  
Author(s):  
Indra Muizniece ◽  
Dagnija Blumberga

2020 ◽  
Vol 4 (9) ◽  
pp. 4464-4468
Author(s):  
Swetanshu Tandon ◽  
Joaquín Soriano-López ◽  
Amal C. Kathalikkattil ◽  
Guanghua Jin ◽  
Paul Wix ◽  
...  

A Mn coordination cluster whose core shares some features with the natural oxygen evolving complex provides a bio-inspired complex that promotes catalytic H2O oxidation at neutral pH value.


1998 ◽  
Vol 13 (1_suppl) ◽  
pp. S19-S22 ◽  
Author(s):  
Lawrence Daniel Morton

Fosphenytoin, a phenytoin prodrug, can be administered in a variety of intravenous diluents and has a more neutral pH value than phenytoin. The pharmacokinetics, safety, and tolerability of fosphenytoin in children from 1 day to 16 years old have been evaluated in two multicenter studies. Data are available from 78 patients who received loading doses (62 with intravenous administration and 16 with intramuscular administration). In these studies, fosphenytoin was converted to phenytoin within 8.3 minutes (range, 2.5-18.5 minutes). In addition, no significant difference in conversion rates was noted from the youngest to the oldest patient. No deaths or serious, alarming, or unexpected adverse events occurred; most adverse events were consistent with those seen with phenytoin therapy in adults. Both intravenous and intramuscular administration were well tolerated, with mild bruising, tenderness, swelling, and/or erythema seen at infusion and injection sites in a small number of patients. (J Child Neurol 1998;13(Suppl 1):S19-S22).


Author(s):  
Weiwei Yu ◽  
Pedro M. Vargas ◽  
Jonathan Bowman

The embrittlement of steel in the presence of water and hydrogen sulfide is a well known phenomenon. For the resulting degradation in fatigue performance, the industry today applies a knock-down factor onto in-air S-N endurance curve that relates the sour-service life to the in-air performance. Several published results are available, and most of these, although rigorous in test approach, report knock-down factors that include unspecified levels of conservatism, consistent with that particular author’s engineering intuition. (For example, typically a lower bound S-N curve in sour-service testing is related to a mean S-N curve in-air). This paper summarizes all of the published small scale sour service testing results, and applies a consistent knock-down factor calculation. Analyses of the data show that sour degradation is highly correlated to H2S concentration and solution pH value. In practice frequency scanning test is highly recommended since sour fatigue test results are highly dependent on loading frequency. Although the database is small, some trends are discernable. In particular, observations indicate that sour service exposure may act as an equalizer, removing the initiation life associated with the time for initial micro-defects at the weld toes to become macro-cracks and leaving only aggravated propagation due to sour service. In this paper, we use initiation life (for welds) to describe the life for the micro-defects (∼0.1mm height) to become macro-cracks (∼1.0 mm height), and a postulation is made that associates the fatigue performance of girth welds (F2, E, D, etc.) with the size and magnitude presence of these micro-defects. The metal surface attack of the sour environment is postulated to provide pitting-like initiation sites for the macro-crack for fatigue propagation. As a base we can use the F2 level performance as the performance due to presence of macro-cracks, and any margin for the D and E level fatigue performances then is associated with more benign initial micro-defects. Once we remove the differences in initiation life; all of the sour performance converges on a single lower performance curve. In this scenario, the knockdown factor is more consistently computed from a standard performance S-N curve rather than the same girth weld’s in-air performance since the in-air data may include significant initiation life. Furthermore, if project sour condition is less severe than NACE TM0177, Solution B with pH = 3.5 and H2S partial pressure = 70mbar, a knock down factor of 45 indexed to BS7608 E design curve is supported from the current database. This provides a design recommendation which can be used for preliminary design in sour environments.


2017 ◽  
Vol 500 ◽  
pp. 20-29 ◽  
Author(s):  
Jinhua Zhang ◽  
Caihua Zhang ◽  
Gaoling Wei ◽  
Ying Li ◽  
Xiaoliang Liang ◽  
...  

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