Multimodal cellular redox nanosensors based on self-doped polyaniline nanocomposites

2020 ◽  
Vol 8 (47) ◽  
pp. 10739-10743
Author(s):  
Hwunjae Lee ◽  
Hyun Soo Kim ◽  
Hyun-Wook Rho ◽  
Yong-Min Huh ◽  
Yoochan Hong

We have successfully fabricated a nanocomposite, which is composed of polyaniline (PAni) and pyrene butyric acid (Pyba) via a solvent shift method, which was self-doped at a neutral pH value.

2020 ◽  
Vol 47 (2) ◽  
pp. 109-118
Author(s):  
Milan Adamović ◽  
Mirjana Stojanović ◽  
Muhamed Harbinja ◽  
Marijana Maslovarić ◽  
Aleksandra Bočarov-Stančić ◽  
...  

The paper presents the results of testing the effect of pyrophyllite shale (pyrophyllite) on the quality of maize plant silage, primarily on the production of organic acids, pH value, quality assessment and microbiological safety. The ensiling was done in plastic containers which allowed the storage of 10 kg of chopped green mass. Tested pyrophyllite doses were: 0% in the control treatment (I), 0.5 and 1.0% in experimental treatments (II and III, respectively). Granulated pyrophyllite (100 µm), originating from Parsovići, Konjic site, AD Harbi Ltd., Sarajevo, Bosnia and Herzegovina, was manually incorporated. The chopped green mass of the maize plant came from FAO 600 hybrids. The green mass containing 37.17% of dry matter (final waxy ripening phase) was compressed in the same manner in all three treatments during the filling of the vessels. The containers were then covered with nylon foil (0.2 mm) above which a layer of fine sand (approx. 5 cm) was placed in toward the silage protection from air passage. The silages were opened after 7 weeks and organoleptic, chemical and microbiological analyses were performed. The organoleptic properties of silages (colour and odour) were better in silages containing 0.5 and 1.0% pyrophyllite. The silage temperature at the moment of opening of the containers was lower in the treatments with 0.5 and 1.0% added pyrophyllite (13.7 and 13.2 °C, respectively) while in the control treatment it was 14.6 °C. The addition of pyrophyllite to silage affected the production of volatile fatty acids (p ≤ 0.05). The highest amount of lactic acid was found in the silage sample without the addition of pyrophyllite, and acetic acid in the silage treated with 0.5 and 1.0% of pyrophyllite. The lowest amount of butyric acid was determined in the silage with the addition of 1% pyrophyllite. Based on the content and interrelationship of lactic, acetic and butyric acid, as well as the pH values, all three silages were rated as the highest (I) class. The number of aerobic mesophilic bacteria, as well as the number of yeasts, was lower in the silages with the addition of 0.5 and 1.0% pyrophyllite. In future, particular attention should be paid on the possibility of pyrophyllite enrichment (e.g. with nitrogen) and more appropriate physical formulation (e.g. granules) that would allow more efficient practical application.


2021 ◽  
Author(s):  
Sarka Klementova ◽  
Martina Poncarová ◽  
Helena Langhansová ◽  
Jaroslava Lieskovská ◽  
David Kahoun ◽  
...  

Abstract Photochemical degradation of fluoroquinolones ciprofloxacin, enrofloxacin and norfloxacin in aqueous solution under light conditions relevant to surface waters at neutral and alkaline pH was found to proceed readily with half-lives between 0.9 and 2.7 min. The products of photochemical degradation identified by HPLC-MS included defluorinated, hydroxylated, and decarboxylated structures as well as structures with opened cyclic structures. For all of the studied substances, the reaction pathways were influenced significantly by the pH of the reaction system, with more products formed at alkaline pH than at neutral pH: the ratios of products in neutral and alkaline pH were 16/26, 9/19, 15/23 for ciprofloxacin, enrofloxacin, and norfloxacin, respectively. The structures of photoproducts and pathways of photochemical degradation are proposed. The antibacterial activities of photoproduct mixtures tested on E. coli and S. epidermidis were significantly higher in comparison to parental antibiotics in the case of both ciprofloxacin and enrofloxacin with p-values less than 0.0001 in most cases. The effect of the photoproducts was shown to be dependent on the pH value of the original antibiotic solutions before photodegradation: for ciprofloxacin, antibacterial activity against E. coli was more notably pronounced with regard to neutral pH photoproducts, while a less significant, or in one case not significant, effect of pH was observed against S. epidermidis ; for norfloxacin, antibacterial activity against both E. coli and S. epidermidis were especially high with regard to alkaline pH photoproducts


2020 ◽  
Vol 4 (9) ◽  
pp. 4464-4468
Author(s):  
Swetanshu Tandon ◽  
Joaquín Soriano-López ◽  
Amal C. Kathalikkattil ◽  
Guanghua Jin ◽  
Paul Wix ◽  
...  

A Mn coordination cluster whose core shares some features with the natural oxygen evolving complex provides a bio-inspired complex that promotes catalytic H2O oxidation at neutral pH value.


1998 ◽  
Vol 13 (1_suppl) ◽  
pp. S19-S22 ◽  
Author(s):  
Lawrence Daniel Morton

Fosphenytoin, a phenytoin prodrug, can be administered in a variety of intravenous diluents and has a more neutral pH value than phenytoin. The pharmacokinetics, safety, and tolerability of fosphenytoin in children from 1 day to 16 years old have been evaluated in two multicenter studies. Data are available from 78 patients who received loading doses (62 with intravenous administration and 16 with intramuscular administration). In these studies, fosphenytoin was converted to phenytoin within 8.3 minutes (range, 2.5-18.5 minutes). In addition, no significant difference in conversion rates was noted from the youngest to the oldest patient. No deaths or serious, alarming, or unexpected adverse events occurred; most adverse events were consistent with those seen with phenytoin therapy in adults. Both intravenous and intramuscular administration were well tolerated, with mild bruising, tenderness, swelling, and/or erythema seen at infusion and injection sites in a small number of patients. (J Child Neurol 1998;13(Suppl 1):S19-S22).


2017 ◽  
Vol 500 ◽  
pp. 20-29 ◽  
Author(s):  
Jinhua Zhang ◽  
Caihua Zhang ◽  
Gaoling Wei ◽  
Ying Li ◽  
Xiaoliang Liang ◽  
...  

2011 ◽  
Vol 183-185 ◽  
pp. 552-556
Author(s):  
Zhi Qin ◽  
Dan Qin ◽  
Dan Li

Bio-hydrogen production from diluted molasses by anaerobic activated sludge was investigated in a continuous stirred-tank reactor (CSTR) under condition of continuous flow in this study. Research shows that the reactor started up under the condition of influent COD concentration 3000mg/L, HRT8h, pH6.5~7.5 and (35±1) °C. The process performed steadily and a dominant butyric acid and acetic acid type fermentation population was established, acetic acid and butyric acid accounted for about 80% in the liquid fermentation products. The effluent PH value was maintained about 5.0. The biogas yield could reach at 4.87L/d while hydrogen yield reached 41.25mL/d under the condition. When influent COD concentration rose to 5500 mg/L, the biogas yield and hydrogen yield as high as 9.45L/d and 119.98mL/d were obtained.


Author(s):  
Rasa Vaiškūnaitė

The main aim of this work was the analysis and assessment of benzene removal from air using bio-filter packed with a mixture of wood waste. The results of this work show that the small scale bio-filter with various coniferous and deciduous wood waste charges is capable of efficiently removing benzene from polluted air stream. The analysis of different mixtures of wood waste charge, while pH value was kept at neutral (pH = 7), determined, that the best wood waste mixture is consisted of 70% coniferous wood (45% pine trees, 25% fir trees), 30% deciduous wood (20% maple, 10% hazel) which was consisted of 10–20 mm fraction particles and had porosity value of 46%. This bio-media was best used for benzene removal from contaminated air stream (E = 93.86–74.78%).


1968 ◽  
Vol 106 (4) ◽  
pp. 841-845 ◽  
Author(s):  
Nils Georg Asp ◽  
Arne Dahlqvist

1. The chromatography of rat small-intestinal β-galactosidase activities on gel-filtration and ion-exchange columns has been studied. Five different substrates were used to measure β-galactosidase activity (lactose, phenyl β-galactoside, o-nitrophenyl β-galactoside, p-nitrophenyl β-galactoside and 6-bromo-2-naphthyl β-galactoside) and the activity was measured at one acid and one more neutral pH value. 2. By gel filtration one acid β-galactosidase, hydrolysing lactose and the hetero-β-galactosides at about the same rate, and one more neutral β-galactosidase, hydrolysing lactose much more rapidly than the hetero-β-galactosides, were separated. 3. By ion-exchange chromatography the acid enzyme was fractionated into two components. These may be individual enzymes or different forms of the same enzyme.


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