scholarly journals Durability of Fly Ash Based Geopolymer Concrete against Chloride and Sulphuric Acid Attack

2020 ◽  
Vol 5 (6) ◽  
pp. 1507-1510
Author(s):  
Kartika Ilma Pratiw ◽  
Saloma .
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Portland Cement ◽  
Sulphuric Acid ◽  
Test Object ◽  
Sulfate Solution ◽  
Geopolymer Concrete ◽  
Acid Attack

The aim of this study was to replace Portland cement with fly ash-based geopolymer as precursors, to serve as a binder after reacting with NaOH and Na2SiO3 activators. The test object existed in the form of a cube of size 50 x 50 x 50 mm. The mortar was treated for 28 days and then immersed in a sulfate solution at similar interval using the wet-dry cycle and non-cycle methods. The compressive strength of the geopolymer mortar was estimated as 45.90 MPa before immersion. Therefore, 35.79 MPa, 41.09 MPa, as well as 37.85 MPa were reported after submersion in the respective solutions of 5% H2SO4, Na2SO4, and NaCl, using wet-dry cycle. Based on the non-cycle approach, the resulting strength was 37.36 MPa, 43.05 MPa and 39.52 MPa correspondingly.

scholarly journals Study of Proportional Variation of Geopolymer Concrete which Self Compacting Concrete

2019 ◽  
Vol 2 (2) ◽  
pp. 65
Author(s):  
Purwanto P. ◽  
Himawan Indarto
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Power Plant ◽  
Portland Cement ◽  
Fine Aggregate ◽  
Geopolymer Concrete ◽  
Conventional Concrete ◽  
Basic Characteristics ◽  
Carbon Dioxide Co2 ◽  
Proportional Variation

Portland cement production process which is the conventional concrete constituent materials always has an impact on producing carbon dioxide (CO2) which will damage the environment. To maintain the continuity of development, while maintaining the environment, Portland cement substitution can be made with more environmentally friendly materials, namely fly ash. The substitution of fly ash material in concrete is known as geopolymer concrete. Fly ash is one of the industrial waste materials that can be used as geopolymer material. Fly ash is mineral residue in fine grains produced from coal combustion which is mashed at power plant power plant [15]. Many cement factories have used fly ash as mixture in cement, namely Portland Pozzolan Cement. Because fly ash contains SiO2, Al2O3, P2O3, and Fe2O3 which are quite high, so fly ash is considered capable of replacing cement completely.This study aims to obtain geopolymer concrete which has the best workability so that it is easy to work on (Workable Geopolymer Concrete / Self Compacting Geopolymer Concrete) and obtain the basic characteristics of geopolymer concrete material in the form of good workability and compressive strength. In this study, geopolymer concrete is composed of coarse aggregate, fine aggregate, fly ash type F, and activators in the form of NaOH and Na2SiO3 Be52. In making geopolymer concrete, additional ingredients such as superplastizer are added to increase the workability of geopolymer concrete. From this research, the results of concrete compressive strength above fc' 25 MPa and horizontal slump values reached 60 to 80 centimeters.

scholarly journals Effect of Elevated Temperature on Alkali Activated Slag and Fly Ash based Geopolymer Concrete

2020 ◽  
Vol 9 (4) ◽  
pp. 1241-1250
Keyword(s):  
Compressive Strength ◽  
Elevated Temperature ◽  
Fly Ash ◽  
Flexural Strength ◽  
Portland Cement ◽  
Ordinary Portland Cement ◽  
Geopolymer Concrete ◽  
Base Materials ◽  
Activated Slag ◽  
Alkali Activated

Activated Slag (AAS) and Fly Ash (FA) based geopolymer concrete a new blended alkali-activated concrete that has been progressively studied over the past years because of its environmental benefits superior engineering properties. Geopolymer has many favorable characteristics in comparison to Ordinary Portland Cement. Many base materials could be utilized to make geopolymer with the convenient concentration of activator solution. In this study, the experimental program composed of two phases; phase on divided into four groups; Group one deliberated the effect of sodium hydroxide molarity and different curing condition on compressive strength. Group two studied the effect of alkali activated solution (NaOH and Na2SiO3) content on compressive strength and workability. The effect of sand replacement with slag on compressive strength and workability was explained in group three. Group four studied the effect of slag replacement with several base materials Fly Ash (FA), Ordinary Portland Cement (OPC), pulverized Red Brick (PRB), and Meta Kaolin (MK). Phase two contains three mixtures from phase one which had the highest compressive strength. For each mixture, the fresh concrete test was air content. In addition the hardened concrete tests were the compressive strength at 3, 7, 28, 90, 180, and 365 days, the flexural strength at 28, 90, and 365 days, and the young's modulus at 28, 90, and 365 days. Moreover; the three mixtures were exposed to elevated temperature at 100oC, 300oC, and 600oC to study the effect of elevated temperature on compressive and flexural strength.

Development of sustainable construction material from fly ash class C

2020 ◽  
Vol 18 (6) ◽  
pp. 1615-1640
Author(s):  
Eric Asa ◽  
Monisha Shrestha ◽  
Edmund Baffoe-Twum ◽  
Bright Awuku
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Portland Cement ◽  
Alkaline Solution ◽  
Sustainable Construction ◽  
Geopolymer Concrete ◽  
Curing Time ◽  
Portland Cement Concrete ◽  
Cement Concrete ◽  
Content Type

Purpose Environmental issues caused by the production of Portland cement have led to it being replaced by waste materials such as fly ash, which is more economical and safer for the environment. Also, fly ash is a material with sustainable properties. Therefore, this paper aims to focus on the development of sustainable construction materials using 100% high-calcium fly ash and potassium hydroxide (KOH)-based alkaline solution and study the engineering properties of the resulting fly ash-based geopolymer concrete. Laboratory tests were conducted to determine the mechanical properties of the geopolymer concrete such as compressive strength, flexural strength, curing time and slump. In phase I of the study, carbon nanotubes (CNTs) were added to determine their effect on the strength of the geopolymer mortar. The results derived from the experiments indicate that mortar and concrete made with 100% fly ash C require an alkaline solution to produce similar (comparable) strength characteristics as Portland cement concrete. However, it was determined that increasing the amount of KOH generates a considerable amount of heat causing the concrete to cure too quickly; therefore, it is notable to forming a proper bond was unable to form a stronger bond. This study also determined that the addition of CNTs to the mix makes the geopolymer concrete tougher than the traditional concrete without CNT. Design/methodology/approach Tests were conducted to determine properties of the geopolymer concrete such as compressive strength, flexural strength, curing time and slump. In Phase I of the study, CNTs were studied to determine their effect on the strength of the geopolymer mortar. Findings The results derived from the experiments indicate that mortar and concrete made with 100% fly ash C require an alkaline solution to produce the same strength characteristics as Portland cement concrete. However, it was determined that increasing the amount of KOH generates too much heat causing the concrete to cure too quickly; therefore, it is notable to forming a proper bond. This study also determined that the addition of CNTs to the mix makes the concrete tougher than concrete without CNT. Originality/value This study was conducted at the construction engineering and management concrete laboratory at North Dakota State University in Fargo, North Dakota. All the experiments were conducted and analyzed by the authors.

scholarly journals Study on Setting & Strength Characteristic of GGBS based Geopolymer Concrete by Blending of Fly Ash and Metakaoline

2020 ◽  
Vol 13 (1) ◽  
pp. 117-122
Author(s):  
Addepalli Mallinadh Kashyap ◽  
Tanimki Chandra Sekhar Rao ◽  
N.V. Ramana Rao
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Portland Cement ◽  
Sodium Hydroxide ◽  
Sodium Silicate ◽  
Setting Time ◽  
Engineering Properties ◽  
Geopolymer Concrete ◽  
Conventional Concrete ◽  
New Material

Carbon dioxide is liberated in huge amounts by the manufacturing of Portland Pozzolana Cement. Normally, conventional concrete is manufactured with Portland cement, which acts as a binder. The production of cement emits CO2 into the atmosphere, which is a green house gas and causes the environmental pollution. Considering this as a serious environmental problem, there is a need to develop sustainable alternatives to Portland cement utilizing the industrial byproducts such as fly ash, ground granulated blast furnace slag and Metakaoline which are pozzolonic in nature. It has been established that fly ash can replace cement partially. In this context, a new material was developed known as ‖Geopolymer‖. In this study, the various parameters on the short term engineering properties of fresh and hardened properties of Geopolymer Mortar were studied. In the present investigation, cement is replaced by geopolymer source material and water is replaced by alkaline activator consisting of Sodium Silicate and Sodium Hydroxide of molarity (12M). The ratio of sodium silicate to sodium hydroxide adopted was 2.5. The test results showed that final setting time decreases as the GGBS content in the mix increases and also increase in compressive strength. Where as in the case of metakaoline, as the content increases, there is a decrease in compressive strength and setting times of the geopolymer concrete.

Effect of Sulphuric Acid on Compressive Strength of Fly Ash based Geopolymer Concrete

2019 ◽  
Vol 11 (10-SPECIAL ISSUE) ◽  
pp. 574-580
Author(s):  
Malluri Ashok Kumar ◽  
Dr.H. Sudarsana Rao ◽  
Dr. Vaishali G. Ghorpade
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Sulphuric Acid ◽  
Geopolymer Concrete

COMPRESSIVE STRENGTH AND THERMAL CONDUCTIVITY OF WATER AND AIR CURED PORTLAND CEMENT-FLY ASH-SILICA FUME MORTARS

2018 ◽  
Vol 17 (9) ◽  
pp. 2023-2030
Author(s):  
Arnon Chaipanich ◽  
Chalermphan Narattha ◽  
Watcharapong Wongkeo ◽  
Pailyn Thongsanitgarn
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Fly Ash ◽  
Portland Cement ◽  
Silica Fume

scholarly journals Assessment of the Rheological and Mechanical Properties of Geopolymer Concrete Comprising Fly Ash and Fluid Catalytic Cracking Residue as Aluminosilicate Precursor

2021 ◽  
Vol 11 (7) ◽  
pp. 3032
Author(s):  
Tuan Anh Le ◽  
Sinh Hoang Le ◽  
Thuy Ninh Nguyen ◽  
Khoa Tan Nguyen
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Elastic Modulus ◽  
Fly Ash ◽  
Flexural Strength ◽  
Catalytic Cracking ◽  
Fluid Catalytic Cracking ◽  
High Alumina ◽  
Geopolymer Concrete ◽  
Sem Images

The use of fluid catalytic cracking (FCC) by-products as aluminosilicate precursors in geopolymer binders has attracted significant interest from researchers in recent years owing to their high alumina and silica contents. Introduced in this study is the use of geopolymer concrete comprising FCC residue combined with fly ash as the requisite source of aluminosilicate. Fly ash was replaced with various FCC residue contents ranging from 0–100% by mass of binder. Results from standard testing methods showed that geopolymer concrete rheological properties such as yield stress and plastic viscosity as well as mechanical properties including compressive strength, flexural strength, and elastic modulus were affected significantly by the FCC residue content. With alkali liquid to geopolymer solid ratios (AL:GS) of 0.4 and 0.5, a reduction in compressive and flexural strength was observed in the case of geopolymer concrete with increasing FCC residue content. On the contrary, geopolymer concrete with increasing FCC residue content exhibited improved strength with an AL:GS ratio of 0.65. Relationships enabling estimation of geopolymer elastic modulus based on compressive strength were investigated. Scanning electron microscope (SEM) images and X-ray diffraction (XRD) patterns revealed that the final product from the geopolymerization process consisting of FCC residue was similar to fly ash-based geopolymer concrete. These observations highlight the potential of FCC residue as an aluminosilicate source for geopolymer products.

Microstructure and Mechanical Properties of Ambiently-Cured Blended Coal Ash-Based Geopolymer Concrete

2016 ◽  
Vol 857 ◽  
pp. 400-404
Author(s):  
Tian Yu Xie ◽  
Togay Ozbakkaloglu
Keyword(s):  
Mechanical Properties ◽  
Experimental Study ◽  
Compressive Strength ◽  
Fly Ash ◽  
Bottom Ash ◽  
Coal Ash ◽  
Geopolymer Concrete ◽  
Mass Ratio ◽  
Blended Coal ◽  
Microstructure And Mechanical Properties

This paper presents the results of an experimental study on the behavior of fly ash-, bottom ash-, and blended fly and bottom ash-based geopolymer concrete (GPC) cured at ambient temperature. Four bathes of GPC were manufactured to investigate the influence of the fly ash-to-bottom ash mass ratio on the microstructure, compressive strength and elastic modulus of GPC. All the results indicate that the mass ratio of fly ash-to-bottom ash significantly affects the microstructure and mechanical properties of GPCs

scholarly journals Novel Analytical Method for Mix Design and Performance Prediction of High Calcium Fly Ash Geopolymer Concrete

Polymers ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 900
Author(s):  
Chamila Gunasekara ◽  
Peter Atzarakis ◽  
Weena Lokuge ◽  
David W. Law ◽  
Sujeeva Setunge
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Gradient Algorithm ◽  
Geopolymer Concrete ◽  
Statistical Regression ◽  
Solid Ratio ◽  
Marquardt Algorithm ◽  
High Calcium ◽  
High Calcium Fly Ash ◽  
Matlab Programming

Despite extensive in-depth research into high calcium fly ash geopolymer concretes and a number of proposed methods to calculate the mix proportions, no universally applicable method to determine the mix proportions has been developed. This paper uses an artificial neural network (ANN) machine learning toolbox in a MATLAB programming environment together with a Bayesian regularization algorithm, the Levenberg-Marquardt algorithm and a scaled conjugate gradient algorithm to attain a specified target compressive strength at 28 days. The relationship between the four key parameters, namely water/solid ratio, alkaline activator/binder ratio, Na2SiO3/NaOH ratio and NaOH molarity, and the compressive strength of geopolymer concrete is determined. The geopolymer concrete mix proportions based on the ANN algorithm model and contour plots developed were experimentally validated. Thus, the proposed method can be used to determine mix designs for high calcium fly ash geopolymer concrete in the range 25–45 MPa at 28 days. In addition, the design equations developed using the statistical regression model provide an insight to predict tensile strength and elastic modulus for a given compressive strength.

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