scholarly journals Organic chemistry on surfaces: Direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)

2014 ◽  
Vol 10 ◽  
pp. 2897-2902 ◽  
Author(s):  
Malgorzata Adamkiewicz ◽  
David O’Hagan ◽  
Georg Hähner
Keyword(s):  
Organic Chemistry ◽  
Surface Coverage ◽  
Self Assembled Monolayers ◽  
Bond Forming ◽  
Silica Surfaces ◽  
Bond Forming Reactions ◽  
Assembled Monolayers ◽  
Self Assembled

C11-Vinyl-terminated self-assembled monolayers (SAMs) on silica surfaces are successfully modified in C–C bond forming reactions with dihalocarbenes to generate SAMs, terminated with dihalo- (fluoro, chloro, bromo) cyclopropane motifs with about 30% surface coverage.

scholarly journals Absorption Spectroelectrochemistry on Mixed Perylenediimide-Based Self-Assembled Monolayers: Non-Linear Dependence of Absorbance versus Surface Coverage

2017 ◽  
Vol 4 (3) ◽  
pp. 601-606 ◽  
Author(s):  
Sihame Bkhach ◽  
Olivier Alévêque ◽  
Yohann Morille ◽  
Tony Breton ◽  
Piétrick Hudhomme ◽  
...  
Keyword(s):  
Linear Dependence ◽  
Surface Coverage ◽  
Self Assembled Monolayers ◽  
Non Linear ◽  
Assembled Monolayers ◽  
Self Assembled

A Molecular Architectural Approach to Self-Assembled Monolayers as NLO Materials

1995 ◽  
Vol 413 ◽  
Author(s):  
Xiaoguang Yang ◽  
Laura Smilowitz ◽  
C. Thomas Buscher ◽  
Duncan McBranch ◽  
Jeanne Robinson ◽  
...  
Keyword(s):  
Molecular Orientation ◽  
Surface Coverage ◽  
Second Harmonic ◽  
Fused Silica ◽  
Nonlinear Susceptibility ◽  
Self Assembled Monolayers ◽  
Fundamental Wavelength ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Derivatives Of

ABSTRACTSelf-assembled molecular architechtures of nonlinear optical (NLO) chromophores and their super-chromophores are discussed. The chromophores are derivatives of azobenzene sulfonates and the super chromophores are derivatives of calix[4]stilbazole and calix[4]stilbazolium. The studies of azobenzene sulfonates are aimed at understanding the surface coverage and molecular orientation in polar self-assembled monolayers (SAMs). The optimized molecular orientation was found to be 32±3 degree and the maximum surface coverage is approximately 2–4 molecules per nm2 depending on the molecular cross-section. The calixarene chromophores are macrocyclic compounds consisting of four simple D-π-A units bridged by methylene groups. These molecules were synthesized such that four D-π-A units of the calix[4]arene were aligned along the same direction with the calixarene in a cone conformation. Both simple and super-chromophores were subsequently fabricated into covalently bound selfassembled monolayers on the surfaces of fused silica and silicon. Spectroscopic second harmonic generation (SHG) measurements were carried out to determine the absolute value of the dominant element of the second-order nonlinear susceptibility, d33 = 60 pm/V at a fundamental wavelength of 890 nm. Furthermore, SHG imaging was employed to investigate the pattemed SAMs of NLO super chromophores.

Ultralow surface energy self-assembled monolayers of iodo-perfluorinated alkanes on silica driven by halogen bonding

Nanoscale ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 2401-2411 ◽  
Author(s):  
Keyun Shou ◽  
Jun Ki Hong ◽  
Elliot S. Wood ◽  
James M. Hook ◽  
Andrew Nelson ◽  
...  
Keyword(s):  
Surface Energy ◽  
Halogen Bonding ◽  
Self Assembled Monolayers ◽  
Silica Surfaces ◽  
Assembled Monolayers ◽  
Self Assembled

Self-assembled monolayers of iodo-perfluoro alkanes are shown to form on silica surfaces, guided by halogen bonding.

Atom Probe Study of 1-Octadecanethiol Self-Assembled Monolayers on Platinum (111) and (200) Surfaces

2021 ◽  
pp. 1-10
Author(s):  
Helena Solodenko ◽  
Patrick Stender ◽  
Guido Schmitz
Keyword(s):  
Laser Power ◽  
Surface Coverage ◽  
Atom Probe ◽  
Self Assembled Monolayers ◽  
Fragmentation Behavior ◽  
Carbon Backbone ◽  
Oriented Samples ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Carbon Molecules

Atom probe tomography measurements of self-assembled monolayers of 1-octadecanethiol on platinum tips were performed and their fragmentation behavior under the influence of different laser powers was investigated. The carbon backbone evaporates in the form of small hydrocarbon fragments consisting of one to four carbon atoms, while sulfur evaporates exclusively as single ions. The carbon molecules evaporate at very low fields of 5.9 V/nm, while S requires a considerably higher evaporation field of 23.4 V/nm. With increasing laser power, a weak, but noticeable trend toward larger fragment sizes is observed. No hydrocarbon fragments containing S are detected, indicating that a strong S–Pt bond has formed. The observed surface coverage of S fits well with literature values and is higher for (111)-oriented samples than for (200).

Formation of Self-Assembled Monolayers of Semifluorinated and Hydrocarbon Chlorosilane Precursors on Silica Surfaces from Liquid Carbon Dioxide

Langmuir ◽  
2002 ◽  
Vol 18 (16) ◽  
pp. 6170-6179 ◽  
Author(s):  
Kirill Efimenko ◽  
Brian Novick ◽  
Ruben G. Carbonell ◽  
Joseph M. DeSimone ◽  
Jan Genzer
Keyword(s):  
Carbon Dioxide ◽  
Self Assembled Monolayers ◽  
Liquid Carbon ◽  
Liquid Carbon Dioxide ◽  
Silica Surfaces ◽  
Assembled Monolayers ◽  
Self Assembled
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