Ultralow surface energy self-assembled monolayers of iodo-perfluorinated alkanes on silica driven by halogen bonding

Nanoscale ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 2401-2411 ◽  
Author(s):  
Keyun Shou ◽  
Jun Ki Hong ◽  
Elliot S. Wood ◽  
James M. Hook ◽  
Andrew Nelson ◽  
...  
Keyword(s):  
Surface Energy ◽  
Halogen Bonding ◽  
Self Assembled Monolayers ◽  
Silica Surfaces ◽  
Assembled Monolayers ◽  
Self Assembled

Self-assembled monolayers of iodo-perfluoro alkanes are shown to form on silica surfaces, guided by halogen bonding.

Formation of Self-Assembled Monolayers of Semifluorinated and Hydrocarbon Chlorosilane Precursors on Silica Surfaces from Liquid Carbon Dioxide

Langmuir ◽  
2002 ◽  
Vol 18 (16) ◽  
pp. 6170-6179 ◽  
Author(s):  
Kirill Efimenko ◽  
Brian Novick ◽  
Ruben G. Carbonell ◽  
Joseph M. DeSimone ◽  
Jan Genzer
Keyword(s):  
Carbon Dioxide ◽  
Self Assembled Monolayers ◽  
Liquid Carbon ◽  
Liquid Carbon Dioxide ◽  
Silica Surfaces ◽  
Assembled Monolayers ◽  
Self Assembled

Halogen-bond driven self-assembly of perfluorocarbon monolayers on silicon nitride

2019 ◽  
Vol 7 (42) ◽  
pp. 24445-24453 ◽  
Author(s):  
Antonio Abate ◽  
Raphael Dehmel ◽  
Alessandro Sepe ◽  
Ngoc Linh Nguyen ◽  
Bart Roose ◽  
...  
Keyword(s):  
Silicon Nitride ◽  
Self Assembly ◽  
Halogen Bond ◽  
Halogen Bonding ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

We demonstrate that self-assembled monolayers of reproducible thickness can be formed on silicon nitride, driven by halogen bonding using iodo-perfluorinated molecules.

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