Influence of crystallization rate on the microstruсture and properties of Ti–TiB alloy

2020 ◽  
Vol 2020 (1) ◽  
pp. 46-51
Author(s):  
D.O. Remisov ◽  
◽  
Yu.I. Bogomol ◽  
P.I. Loboda ◽  
◽  
...  
Keyword(s):  
Crystallization Rate ◽  
Influence Of Crystallization

scholarly journals A Review: Research Progress in Modification of Poly (Lactic Acid) by Lignin and Cellulose

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 776
Author(s):  
Sixiang Zhai ◽  
Qingying Liu ◽  
Yuelong Zhao ◽  
Hui Sun ◽  
Biao Yang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Lactic Acid ◽  
Composite Materials ◽  
Crystallization Rate ◽  
Research Progress ◽  
Poly Lactic Acid ◽  
Green Composite ◽  
Materials Development ◽  
Research Attention ◽  
Biomass Components

With the depletion of petroleum energy, the possibility of prices of petroleum-based materials increasing, and increased environmental awareness, biodegradable materials as a kind of green alternative have attracted more and more research attention. In this context, poly (lactic acid) has shown a unique combination of properties such as nontoxicity, biodegradability, biocompatibility, and good workability. However, examples of its known drawbacks include poor tensile strength, low elongation at break, poor thermal properties, and low crystallization rate. Lignocellulosic materials such as lignin and cellulose have excellent biodegradability and mechanical properties. Compounding such biomass components with poly (lactic acid) is expected to prepare green composite materials with improved properties of poly (lactic acid). This paper is aimed at summarizing the research progress of modification of poly (lactic acid) with lignin and cellulose made in in recent years, with emphasis on effects of lignin and cellulose on mechanical properties, thermal stability and crystallinity on poly (lactic acid) composite materials. Development of poly (lactic acid) composite materials in this respect is forecasted.

scholarly journals Isothermal Crystallization Kinetics of Poly(ethylene oxide)/Poly(ethylene glycol)-g-silica Nanocomposites

Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 648
Author(s):  
Xiangning Wen ◽  
Yunlan Su ◽  
Shaofan Li ◽  
Weilong Ju ◽  
Dujin Wang
Keyword(s):  
Molecular Weight ◽  
Ethylene Oxide ◽  
Crystallization Kinetics ◽  
Isothermal Crystallization ◽  
Crystallization Rate ◽  
Poly Ethylene Glycol ◽  
Isothermal Crystallization Kinetics ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene ◽  
Kinetics Of

In this work, the crystallization kinetics of poly(ethylene oxide) (PEO) matrix included with poly(ethylene glycol) (PEG) grafted silica (PEG-g-SiO2) nanoparticles and bare SiO2 were systematically investigated by differential scanning calorimetry (DSC) and polarized light optical microscopy (PLOM) method. PEG-g-SiO2 can significantly increase the crystallinity and crystallization temperature of PEO matrix under the non-isothermal crystallization process. Pronounced effects of PEG-g-SiO2 on the crystalline morphology and crystallization rate of PEO were further characterized by employing spherulitic morphological observation and isothermal crystallization kinetics analysis. In contrast to the bare SiO2, PEG-g-SiO2 can be well dispersed in PEO matrix at low P/N (P: Molecular weight of matrix chains, N: Molecular weight of grafted chains), which is a key factor to enhance the primary nucleation rate. In particular, we found that the addition of PEG-g-SiO2 slows the spherulitic growth fronts compared to the neat PEO. It is speculated that the interfacial structure of the grafted PEG plays a key role in the formation of nuclei sites, thus ultimately determines the crystallization behavior of PEO PNCs and enhances the overall crystallization rate of the PEO nanocomposites.

scholarly journals Manufacturing PLA/PCL Blends by Ultrasonic Molding Technology

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2412
Author(s):  
Inés Ferrer ◽  
Ariadna Manresa ◽  
José Alberto Méndez ◽  
Marc Delgado-Aguilar ◽  
Maria Luisa Garcia-Romeu
Keyword(s):  
Molecular Weight ◽  
Crystallization Rate ◽  
Raw Material ◽  
Small Particle Size ◽  
Polymer Mixtures ◽  
Crystallinity Degree ◽  
Correct Determination ◽  
Production Stages ◽  
Process Speed

Ultrasonic molding (USM) is a good candidate for studying the plasticization of polymer mixtures or other composite materials due to either the little amount of material needed for processing, low waste or the needed low pressure and residence time of the mold. Thus, the novelty of this research is the capability of USM technology to process PLA/PCL blends and their corresponding neat materials, encompassing all the production stages, from raw material to the final specimen. The major findings of the work revealed that the thermal properties of the blends were not affected by the USM process, although the crystallinity degree experienced variations, decreasing for PLA and increasing for PCL, which was attributed to the crystallization rate of each polymer, the high process speed, the short cooling time and the small particle size. The employed ultrasonic energy increased the molecular weight with low variations through the specimen. However, the degradation results aligned with the expected trend of these material blends. Moreover, this study also showed the effect pellet shape and dimensions have over the process parameters, as well as the effect of the blend composition. It can be concluded that USM is a technology suitable to successfully process PLA/PCL blends with the correct determination of process parameter windows.

Influence of crystallization temperature on growth rate of epitaxial gallium arsenide layers in the system GaAs-AsCl3-H2

1982 ◽  
Vol 25 (9) ◽  
pp. 859-862 ◽  
Author(s):  
L. G. Lavrent'eva ◽  
V. G. Ivanov ◽  
I. V. Ivonin ◽  
V. A. Moskovkin ◽  
S. E. Toropov
Keyword(s):  
Growth Rate ◽  
Gallium Arsenide ◽  
Crystallization Temperature ◽  
Influence Of Crystallization

A comparison of induction time and crystallization rate for syndiotactic polystyrene

2002 ◽  
Vol 42 (4) ◽  
pp. 694-706 ◽  
Author(s):  
Richard D. Sudduth ◽  
Pavan Kyarala ◽  
Qin Sheng
Keyword(s):  
Induction Time ◽  
Crystallization Rate ◽  
Syndiotactic Polystyrene

scholarly journals The Effect of WS2 Nanosheets on the Non-Isothermal Cold- and Melt-Crystallization Kinetics of Poly(l-lactic acid) Nanocomposites

Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2214
Author(s):  
Mohammed Naffakh ◽  
Pablo Rica ◽  
Carmen Moya-Lopez ◽  
José Antonio Castro-Osma ◽  
Carlos Alonso-Moreno ◽  
...  
Keyword(s):  
Lactic Acid ◽  
Transition Metal Dichalcogenides ◽  
Crystallization Rate ◽  
Melting Behavior ◽  
Hybrid Nanocomposites ◽  
Melt Crystallization ◽  
Heating Rates ◽  
Solution Blending ◽  
New Perspective ◽  
Ws2 Nanosheets

In the present work, hybrid nanocomposite materials were obtained by a solution blending of poly(l-lactic acid) (PLLA) and layered transition-metal dichalcogenides (TMDCs) based on tungsten disulfide nanosheets (2D-WS2) as a filler, varying its content between 0 and 1 wt%. The non-isothermal cold- and melt-crystallization and melting behavior of PLLA/2D-WS2 were investigated. The overall crystallization rate, final crystallinity, and subsequent melting behavior of PLLA were controlled by both the incorporation of 2D-WS2 and variation of the cooling/heating rates. In particular, the analysis of the cold-crystallization behavior of the PLLA matrix showed that the crystallization rate of PLLA was reduced after nanosheet incorporation. Unexpectedly for polymer nanocomposites, a drastic change from retardation to promotion of crystallization was observed with increasing the nanosheet content, while the melt-crystallization mechanism of PLLA remained unchanged. On the other hand, the double-melting peaks, mainly derived from melting–recrystallization–melting processes upon heating, and their dynamic behavior were coherent with the effect of 2D-WS2 involved in the crystallization of PLLA. Therefore, the results of the present study offer a new perspective for the potential of PLLA/hybrid nanocomposites in targeted applications.

scholarly journals cPCN-Regulated SnO2 Composites Enables Perovskite Solar Cell with Efficiency Beyond 23%

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Zicheng Li ◽  
Yifeng Gao ◽  
Zhihao Zhang ◽  
Qiu Xiong ◽  
Longhui Deng ◽  
...  
Keyword(s):  
Steady State ◽  
Power Conversion ◽  
Perovskite Solar Cells ◽  
Crystallization Rate ◽  
Nucleation And Growth ◽  
Perovskite Solar Cell ◽  
Perovskite Layer ◽  
Carrier Separation ◽  
Polymeric Carbon ◽  
Electron Extraction

AbstractEfficient electron transport layers (ETLs) not only play a crucial role in promoting carrier separation and electron extraction in perovskite solar cells (PSCs) but also significantly affect the process of nucleation and growth of the perovskite layer. Herein, crystalline polymeric carbon nitrides (cPCN) are introduced to regulate the electronic properties of SnO2 nanocrystals, resulting in cPCN-composited SnO2 (SnO2-cPCN) ETLs with enhanced charge transport and perovskite layers with decreased grain boundaries. Firstly, SnO2-cPCN ETLs show three times higher electron mobility than pristine SnO2 while offering better energy level alignment with the perovskite layer. The SnO2-cPCN ETLs with decreased wettability endow the perovskite films with higher crystallinity by retarding the crystallization rate. In the end, the power conversion efficiency (PCE) of planar PSCs can be boosted to 23.17% with negligible hysteresis and a steady-state efficiency output of 21.98%, which is one of the highest PCEs for PSCs with modified SnO2 ETLs. SnO2-cPCN based devices also showed higher stability than pristine SnO2, maintaining 88% of the initial PCE after 2000 h of storage in the ambient environment (with controlled RH of 30% ± 5%) without encapsulation.

Analysis of the Effect of Crystallization Additives on the Resistance of Self-Compacting Concrete Exposed to Aggressive Gases

2021 ◽  
Vol 325 ◽  
pp. 194-199
Author(s):  
Ámos Dufka ◽  
Tomáš Žlebek ◽  
Tomáš Melichar
Keyword(s):  
Pore Structure ◽  
Self Compacting Concrete ◽  
Aggressive Environment ◽  
Physico Chemical ◽  
Influence Of Crystallization ◽  
Long Life ◽  
Capillary Pore

The article deals with the influence of crystallization additives on the life of self-compacting concrete (so-called SCC concrete), which are exposed to chemically aggressive environments. The focus is not only on the effect of the crystallization additive on the characteristics of the capillary-pore structure of SCC concrete, but especially long life durability of self-compacting concrete (two years expozition). The effect of individual types of aggressive environment is assessed on the basis of a set of physico-mechanical and physico-chemical analyzes.

Non-Isothermal Crystallization Kinetics of Graphene Oxide-Carbon Nanotubes Hybrids / Polyamide 6 Composites

2019 ◽  
Vol 41 (3) ◽  
pp. 394-394
Author(s):  
Zhi Qiang Wang Zhi Qiang Wang ◽  
Yong Ke Zhao and Xiang Feng Wu Yong Ke Zhao and Xiang Feng Wu
Keyword(s):  
Carbon Nanotubes ◽  
Graphene Oxide ◽  
Cooling Rate ◽  
Crystallization Kinetics ◽  
Isothermal Crystallization ◽  
Crystallization Rate ◽  
Polyamide 6 ◽  
Degree Of Crystallinity ◽  
Isothermal Crystallization Kinetics ◽  
Kinetics Of

The hybrids combined by nano-materials with different dimensions usually possess much better enhancement effects than single one. Graphene oxide-carbon nanotubes hybrids / polyamide 6 composites has been fabricated. The non-isothermal crystallization kinetics of the as-prepared samples was discussed. Research results showed that increasing the cooling rate was in favor of increasing the crystallization rate and the degree of crystallinity for the as-prepared samples. Moreover, the crystallization rate was first decreased and then increased with increasing the hybrids loading. Furthermore, the crystallization mechanism was changed with increasing the crystallization temperature and the cooling rate. The nucleation and growth modes of the non-isothermal crystallization could be classified into three different types, according to the Ozawa’s theory. These complicated results could be attributed to the important role of crystallization rate as well as the simultaneous hindering and promoting effects of the as-prepared hybrids. This work has reference values for understanding the crystallization kinetics of the polyamide 6-based composites.

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