scholarly journals Generalized Spectral Characterization of Graphs Revisited

10.37236/3748 ◽  
2013 ◽  
Vol 20 (4) ◽  
Author(s):  
Wei Wang

A graph $G$ is said to be determined by its generalized spectrum (DGS for short) if for any graph $H$, $H$ and $G$ are cospectral with cospectral complements implies that $H$ is isomorphic to $G$. Wang and Xu (2006) gave some methods for determining whether a family of graphs are DGS. In this paper, we shall review some of the old results and present some new ones along this line of research.More precisely, let $A$ be the adjacency matrix of a graph $G$, and let $W=[e,Ae,\cdots,A^{n-1}e]$ ($e$ is the all-one vector) be its walk-matrix. Denote by $\mathcal{G}_n$ the set of all graphs on $n$ vertices with $\det(W)\neq 0$. We define a large family of graphs $$\mathcal{F}_n=\{G\in{\mathcal{G}_n}|\frac{\det(W)}{2^{\lfloorn/2\rfloor}}\mbox{is square-free and }2^{\lfloorn/2\rfloor+1}\not|\det(W)\}$$ (which may have positive density among all graphs, as suggested by some numerical experiments). The main result of the paper shows that for any graph $G\in {\mathcal{F}_n}$, if there is a rational orthogonal matrix $Q$ with $Qe=e$ such that $Q^TAQ$ is a (0,1)-matrix, then $2Q$ must be an integral matrix (and hence, $Q$ has well-known structures). As a consequence, we get the conclusion that almost all graphs in $\mathcal{F}_n$ are DGS.

2011 ◽  
Vol 89 (4) ◽  
pp. 481-487 ◽  
Author(s):  
Yan Li ◽  
David Dolphin

A series of novel 1,9-diazodipyrrins (4) were readily synthesized by reacting aryldiazonium salts with 5-aryldipyrromethanes under both acidic and basic conditions. The zinc complex of 1,9-diphenylazodipyrrin (5aZn) was confirmed by X-ray crystallographic analysis, and 1,9-diazodipyrrins and their zinc and nickel complexes (5M) were characterized by 1H and 13C NMR, IR, UV–vis, and MS. All of the metal complexes absorb almost all colours of the rainbow; the absorption maximums are >650 nm and the half-band widths are over 100 nm. The fluorescence of the zinc complexes of 1,9-diphenylazodipyrrin (5aZn) and 1,9-di(2-iodophenylazo)dipyrrin (5cZn) were also explored.


10.37236/2383 ◽  
2012 ◽  
Vol 19 (3) ◽  
Author(s):  
Aida Abiad ◽  
Willem H Haemers

For a graph $\Gamma$ with adjacency matrix $A$, we consider a switching operation that takes $\Gamma$ into a graph $\Gamma'$ with adjacency matrix $A'$, defined by $A'=Q^\top A Q$, where $Q$ is a regular orthogonal matrix of level $2$ (that is, $Q^\top Q=I$, $Q$1 $=$ 1, $2Q$ is integral, and $Q$ is not a permutation matrix). If such an operation exists, and $\Gamma$ is nonisomorphic with $\Gamma'$, then we say that $\Gamma'$ is semi-isomorphic with $\Gamma$. Semi-isomorphic graphs are $\mathbb {R}$-cospectral, which means that they are cospectral and so are their complements. Wang and Xu [On the asymptotic behavior of graphs determined by their generalized spectra, Discrete Math. 310 (2010)] expect that almost all pairs of nonisomorphic $\mathbb {R}$-cospectral graphs are semi-isomorphic.Regular orthogonal matrices of level $2$ have been classified. By use of this classification we work out the requirements for this switching operation to work in case $Q$ has one nontrivial indecomposable block of size $4$, $6$, $7$ or $8$. Size $4$ corresponds to Godsil-McKay switching. The other cases provide new methods for constructions of $\mathbb {R}$-cospectral graphs. For graphs with eight vertices all these constructions are carried out. As a result we find that, out of the 1166 graphs on eight vertices which are $\mathbb {R}$-cospectral to another graph, only 44 are not semi-isomorphic to another graph.


2014 ◽  
Vol 59 (3) ◽  
pp. 313-318
Author(s):  
C. Cheptea ◽  
◽  
L.M. Ivan ◽  
D.O. Dorohoi ◽  
V. Sunel ◽  
...  

Author(s):  
Tian Lu ◽  
Qinxue Chen ◽  
Zeyu Liu

Although cyclo[18]carbon has been theoretically and experimentally investigated since long time ago, only very recently it was prepared and directly observed by means of STM/AFM in condensed phase (Kaiser et al., <i>Science</i>, <b>365</b>, 1299 (2019)). The unique ring structure and dual 18-center π delocalization feature bring a variety of unusual characteristics and properties to the cyclo[18]carbon, which are quite worth to be explored. In this work, we present an extremely comprehensive and detailed investigation on almost all aspects of the cyclo[18]carbon, including (1) Geometric characteristics (2) Bonding nature (3) Electron delocalization and aromaticity (4) Intermolecular interaction (5) Reactivity (6) Electronic excitation and UV/Vis spectrum (7) Molecular vibration and IR/Raman spectrum (8) Molecular dynamics (9) Response to external field (10) Electron ionization, affinity and accompanied process (11) Various molecular properties. We believe that our full characterization of the cyclo[18]carbon will greatly deepen researchers' understanding of this system, and thereby help them to utilize it in practice and design its various valuable derivatives.


Author(s):  
Tian Lu ◽  
Qinxue Chen ◽  
Zeyu Liu

Although cyclo[18]carbon has been theoretically and experimentally investigated since long time ago, only very recently it was prepared and directly observed by means of STM/AFM in condensed phase (Kaiser et al., <i>Science</i>, <b>365</b>, 1299 (2019)). The unique ring structure and dual 18-center π delocalization feature bring a variety of unusual characteristics and properties to the cyclo[18]carbon, which are quite worth to be explored. In this work, we present an extremely comprehensive and detailed investigation on almost all aspects of the cyclo[18]carbon, including (1) Geometric characteristics (2) Bonding nature (3) Electron delocalization and aromaticity (4) Intermolecular interaction (5) Reactivity (6) Electronic excitation and UV/Vis spectrum (7) Molecular vibration and IR/Raman spectrum (8) Molecular dynamics (9) Response to external field (10) Electron ionization, affinity and accompanied process (11) Various molecular properties. We believe that our full characterization of the cyclo[18]carbon will greatly deepen researchers' understanding of this system, and thereby help them to utilize it in practice and design its various valuable derivatives.


2018 ◽  
Vol 8 (2) ◽  
pp. 278-287
Author(s):  
Selvarathy Grace P ◽  
Ravindran Durainayagam B ◽  
Pon Matheswari P.

2019 ◽  
Author(s):  
Chem Int

Liquid effluents discharged by hospitals may contain chemical and biological contaminants whose main source is the different substances used for the treatment of patients. This type of rejection can present a sanitary potentially dangerous risk for human health and can provoke a strong degradation of diverse environmental compartments mainly water and soils. The present study focuses on the quality of the liquid effluents of Hassani Abdelkader’s hospital of Sidi Bel-Abbes (West of Algeria). The results reveal a significant chemical pollution (COD: 879 mgO2/L, BOD5: 850 mgO2/L, NH4+ : 47.9 mg/l, NO2- : 4.2 mg/l, NO3- : 56.8 mg/l with respect to WHO standard of 90 mgO2/L, 30 mgO2/L, 0.5 mg/l, 1 mg/l and 1 mg/l respectively). However, these effluents are biodegradable since the ratio COD/BOD5 do not exceeded the value of 2 in almost all samples. The presence of pathogen germs is put into evidence such as pseudomonas, the clostridium, the staphylococcus, the fecal coliforms and fecal streptococcus. These results show that the direct discharge of these effluents constitutes a major threat to human health and the environment.


2017 ◽  
Vol 68 (10) ◽  
pp. 2436-2439
Author(s):  
Stefania Felicia Barbuceanu ◽  
Laura Ileana Socea ◽  
Constantin Draghici ◽  
Elena Mihaela Pahontu ◽  
Theodora Venera Apostol ◽  
...  

In the work we presented the behavior of 5-(4-(4-X-phenylsulfonyl)phenyl)-4-(n-propyl)-2H-1,2,4-triazole-3(4H)-thiones (X= Cl or Br) with some alkylation agents. Thus, new S-alkylated 1,2,4-triazole derivatives were synthesized by reaction of the corresponding 1,2,4-triazole-3-thione derivatives with different �-halogenated compounds (ethyl bromide, ethyl chloroacetate or phenacyl bromide), in basic medium. The structures of synthesized compounds were elucidated by spectral data (1H-NMR, 13C-NMR, mass spectrometry) and elemental analysis.


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