scholarly journals A New Polyvinylidene Fluoride Membrane Synthesized by Integrating of Powdered Activated Carbon for Treatment of Stabilized Leachate

Water ◽  
2021 ◽  
Vol 13 (16) ◽  
pp. 2282
Author(s):  
Salahaldin M. A. Abuabdou ◽  
Zeeshan Haider Jaffari ◽  
Choon-Aun Ng ◽  
Yeek-Chia Ho ◽  
Mohammed J. K. Bashir
Keyword(s):  
Activated Carbon ◽  
Polyvinylidene Fluoride ◽  
Membrane Filtration ◽  
Pure Water ◽  
Powdered Activated Carbon ◽  
Polymeric Membrane ◽  
Inversion Method ◽  
Transmembrane Pressure ◽  
Leachate Treatment ◽  
Water Permeation

Stabilized landfill leachate contains a wide variety of highly concentrated non-biodegradable organics, which are extremely toxic to the environment. Though numerous techniques have been developed for leachate treatment, advanced membrane filtration is one of the most environmentally friendly methods to purify wastewater effectively. In the current study, a novel polymeric membrane was produced by integrating powdered activated carbon (PAC) on polyvinylidene fluoride (PVDF) to synthesize a thin membrane using the phase inversion method. The membrane design was optimized using response surface methodology (RSM). The fabricated membrane was effectively applied for the filtration of stabilized leachate using a cross-flow ring (CFR) test. The findings suggested that the filtration properties of fabricated membrane were effectively enhanced through the incorporation of PAC. The optimum removal efficiencies by the fabricated membrane (14.9 wt.% PVDF, 1.0 wt.% PAC) were 35.34, 48.71, and 22.00% for COD, colour and NH3-N, respectively. Water flux and transmembrane pressure were also enhanced by the incorporated PAC and recorded 61.0 L/m2·h and 0.67 bar, respectively, under the conditions of the optimum removal efficiency. Moreover, the performance of fabricated membranes in terms of pollutant removal, pure water permeation, and different morphological characteristics were systematically analyzed. Despite the limited achievement, which might be improved by the addition of a hydrophilic additive, the study offers an efficient way to fabricate PVDF-PAC membrane and to optimize its treatability through the RSM tool.

Removal of geosmin and algae by ceramic membrane filtration with super-powdered activated carbon adsorption pretreatment

2007 ◽  
Vol 7 (5-6) ◽  
pp. 43-51 ◽  
Author(s):  
Y. Matsui ◽  
T. Aizawa ◽  
M. Suzuki ◽  
Y. Kawase
Keyword(s):  
Activated Carbon ◽  
Membrane Filtration ◽  
Ceramic Membrane ◽  
Tap Water ◽  
Powdered Activated Carbon ◽  
Transmembrane Pressure ◽  
Activated Carbon Adsorption ◽  
Consumer Complaints ◽  
Carbon Adsorption ◽  
Water Treatment Plants

The musty-earthy taste and odour caused by the presence of geosmin and other compounds in tap water are major causes of consumer complaints. Although ozonation and granular activated carbon (GAC) adsorption have been practiced in water-treatment plants to remove these compounds effectively, two major problems associated with the application of these processes – formation of stringently regulated bromate ions by ozonation and unhygienic invertebrate colonisation of GAC filters – are still to be resolved. This research advanced the process of adsorption by powdered activated carbon (PAC) by reducing its particle size to the submicrometre range for microfiltration pretreatment. Adsorption pretreatment by using this super (S)-PAC removed the geosmin with vastly greater efficiency than by normal PAC. Removal was attained in a much shorter contact time and at a much lower dosage. The S-PAC was also beneficial in attenuating the transmembrane pressure rises that occurred between both physical backwashings and chemical cleanings.

Capillary nanofiltration coupled with powdered activated carbon adsorption for high quality water reuse

2009 ◽  
Vol 60 (1) ◽  
pp. 251-259 ◽  
Author(s):  
C. Kazner ◽  
J. Meier ◽  
T. Wintgens ◽  
T. Melin
Keyword(s):  
Activated Carbon ◽  
Water Reuse ◽  
Membrane Filtration ◽  
Municipal Wastewater ◽  
Treatment Plant ◽  
Powdered Activated Carbon ◽  
Transmembrane Pressure ◽  
Municipal Wastewater Treatment ◽  
High Quality ◽  
Quality Water

Direct capillary nanofiltration was tested for reclamation of tertiary effluent from a municipal wastewater treatment plant. This process can be regarded as a promising treatment alternative for high quality water reuse applications when combined with powdered activated carbon for enhanced removal of organic compounds. The nanofiltration was operated at flux levels between 20 and 25 L/(m2 h) at a transmembrane pressure difference of 2–3 bar for approximately 4,000 operating hours. The study was conducted with PAC doses in the range from 0 to 50 mg/L. The plant removal for DOC ranged from 88–98%. The sulfate retention of the membrane filtration process was between 87 and 96%. The process provided a consistently high permeate quality with respect to organic and inorganic key parameters.

scholarly journals Optimization of Spiral-wound Microfiltration Process for Production of Micellar Casein Concentrate

2021 ◽  
Author(s):  
Chenchaiah Marella ◽  
Venkateswarlu Sunkesula ◽  
Ahmed R. A. Hammam ◽  
Anil Kommineni ◽  
and Lloyd E. Metzger
Keyword(s):  
Polyvinylidene Fluoride ◽  
Membrane Filtration ◽  
Skim Milk ◽  
Polymeric Membrane ◽  
Transmembrane Pressure ◽  
Protein Ratio ◽  
Micellar Casein ◽  
True Protein ◽  
The Impact ◽  
Spiral Wound

Micellar Casein Concentrate (MCC) is manufactured from microfiltration (MF) of skim milk utilizing ceramic or polymeric membrane filtration. While ceramic filtration has higher efficiency, use of polymeric is cost effective and the process is familiar to several US dairy processors. The aim of the present study was to develop an optimized membrane filtration process to produce MCC using spiral wound polymeric membrane filtration (SW MF) system by systematic selection of transmembrane pressure (TMP) and level of diafiltration (DF). Using skim milk as feed material, preliminary lab-scale MF experiments were conducted using 0.5 µm polyvinylidene fluoride (PVDF) membrane. Three TMP (34.5, 62.1, and 103.4 kPa) and three levels of DF (70, 100, and 150%) along with a process without DF as control were used in the study. Effect of TMP and effectiveness of DF on flux rates, SP removal, casein to total protein (CN/TKN) ratio, casein to true protein (CN/TP) ratio, rejection of casein (rej CN) and SP (rej SP) were evaluated. At all TMP values used in the study, the overall flux (O Flux) increased with the level of DF. Highest O Flux of 30.77 liter per meter square per hour (LMH) was obtained with 34.5 kPa pressure and 150% DF. The impact of DF was more pronounced at lower pressures than at the higher pressures used in the study. With controlled DF, instantaneous flux was maintained within 80% of initial flux for the entire process run. For all the experiments, casein has a rejection of 0.97 to 1.0, while serum protein has the lowest rejection of 0.10 at 34.5 kPa pressure and 150% DF level. Use of 34.5 kPa and DF level of 150 % contributed to 81.45% SP removal, and casein to true protein ratio of 0.96. SP removal data from the lab-scale experiments were fitted into a mathematical model using DF and square of TMP as factors. The model predicts SP removal within 90-95% of actual SP removal got from the pilot plant experiments.

The Effect of Sodium Chloride (NaCl) Coagulant Medium of Polysulfone Ultrafiltration Membrane

2013 ◽  
Vol 372 ◽  
pp. 3-7 ◽  
Author(s):  
Muhamad Fikri Shohur ◽  
Zawati Harun ◽  
Muhamad Zaini Yunos ◽  
Sulaiman Hassan ◽  
Mohd Riduan Jamalludin
Keyword(s):  
Sodium Chloride ◽  
Humic Acid ◽  
Pure Water ◽  
Inversion Method ◽  
Asymmetric Membrane ◽  
Water Permeation ◽  
Membrane Performance ◽  
Immersion Medium ◽  
Base Polymer ◽  
Phase Inversion Method

This study investigates the effect of Sodium Chloride (NaCl) coagulant medium with different concentration to produce Polysulfone (PSf) ultrafiltration (UF) asymmetric membrane. The polymer membrane prepared by a phase inversion method using Polysulfone (PSf) as a base polymer, Polyethylene glycol (PEG) 400MW as copolymer additive, N-methyl-2-pyrrolidone (NMP) as solvent and NaCl coagulant medium with different concentration as nonsolvent. In this work, the concentration of immersion medium for membrane phase immersion process prepared based on different coagulation concentration medium NaCl was modified repeatedly in the range of 1-5%. These membrane performance were analyzed via pure water permeation and solute rejection of humic acid. Based on these results, the membrane immersed in 4% concentration of NaCl coagulant medium showed the highest pure water permeation (235.69 l.m-2. h-1) and solute rejection of humic acid which is up to 98%.

Study of antifouling modified ultrafiltration membrane based on the secondary treated water of urban sewage

2012 ◽  
Vol 66 (10) ◽  
pp. 2074-2082 ◽  
Author(s):  
Xiao-rong Meng ◽  
Liang Zhao ◽  
Lei Wang ◽  
Xu-dong Wang ◽  
Dan-xi Huang ◽  
...  
Keyword(s):  
Polyvinylidene Fluoride ◽  
Layer Structure ◽  
Pure Water ◽  
Water Flux ◽  
Inversion Method ◽  
Treated Water ◽  
Urban Sewage ◽  
Cake Layer ◽  
Modified Membrane ◽  
Section Structure

Mixtures of polyvinylidene fluoride (PVDF) and polyvinyl alcohol (PVA) containing hydrophilic ultrafiltration membranes were prepared by adding PVA (5 to 30%) to PVDF by the phase inversion method. The hydrophilic contact angle (CA), equilibrium water content, pure water flux and bovine serum albumin retention were studied to assess the membrane performance. The anti-fouling performance of modified membrane to the secondary treated water was evaluated by flux decline, washing recovery rate and fouling resistance analysis. Scanning electron microscopy showed that the cross-section structure of the membranes had finger-like pores, which were well developed and uniformly distributed, and the sub-layer structure was looser and more porous with the increasing content of PVA. The CA gradually decreased. The steady flux was 800 L/m2 h from P15 to P30, and the BSA retention sharply declined. The ultrafiltration tests for secondary treated water indicated that the main fouling source of the modified membrane was the concentration polarization and cake layer resistance. After physical flushing, the flux recovery ratio of the membrane could reach 100% when the PVA content was 5–15%, which shows excellent anti-pollution performance and good prospects for use in processing wastewater from urban sewage.

Adsorption isotherms in landfill leachate treatment using powdered activated carbon augmented sequencing batch reactor technique: Statistical analysis by response surface methodology

2012 ◽  
Vol 10 (1) ◽  
Author(s):  
Shuokr Qarani Aziz ◽  
Dr. Hamidi Abdul Aziz ◽  
Mohd Suffian Yusoff ◽  
Amin Mojiri ◽  
Salem S. Abu Amr
Keyword(s):  
Activated Carbon ◽  
Adsorption Isotherms ◽  
Landfill Leachate ◽  
Sequencing Batch Reactor ◽  
Batch Reactor ◽  
Great Part ◽  
Ammonia Nitrogen ◽  
Aeration Rate ◽  
Powdered Activated Carbon ◽  
Leachate Treatment

Abstract Landfill leachate was treated using non-powdered activated carbon sequencing batch reactor (NPAC-SBR) and powdered activated carbon (PAC) augmented SBR (PAC-SBR) processesto examine Langmuir and Freundlichadsorption isothermsin the SBR technique.Response surface methodology (RSM) was used for the experimental design and statistical analysis.Based on the obtained results, the maximum adsorption capacitiesof ammonia nitrogen (NH3-N), color, and chemical oxygen demand (COD) for the Langmuir adsorption isotherm were 5.63 mg/g, 25.30 Pt.Co/g, and 13.21 mg/g,respectively, whereas for the Freundlichadsorption isotherm, thesewere 6 mg/g, 46.29Pt.Co/g, and 15.41 mg/g, respectively.Generally, Freundlich isotherm values for NH3-N, color, and COD were higher than Langmuir isotherm values.The NH3-N adsorption on PAC was lower than the color and COD adsorptions because a great part of NH3-Nwas biologically removed in the SBR process.Increasing aeration rate and contact times in the SBR processes increased the adsorption isotherms of NH3-N, color, and COD on PAC

scholarly journals Effects of Ferrihydrite-Impregnated Powdered Activated Carbon on Phosphate Removal and Biofouling of Ultrafiltration Membrane

Water ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1178
Author(s):  
Jenyuk Lohwacharin ◽  
Thitiwut Maliwan ◽  
Hideki Osawa ◽  
Satoshi Takizawa
Keyword(s):  
Activated Carbon ◽  
Membrane Fouling ◽  
Membrane Filtration ◽  
Membrane Surface ◽  
Powdered Activated Carbon ◽  
Phosphate Removal ◽  
Phosphate Adsorption ◽  
Surface Water Treatment ◽  
Filtration System ◽  
Pore Blockage

The presence of multiple contaminant species in surface waters makes surface water treatment difficult to accomplish through a single process. Herein, we evaluated the ability of an integrated adsorption/ultrafiltration (UF) membrane filtration system to simultaneously remove phosphates and dissolved organic matter (DOM). When bare powdered activated carbon (PAC) and PAC impregnated with amorphous ferrihydrite (FHPAC) adsorbents were compared, FHPAC showed a greater adsorption rate and capacity for phosphate. FHPAC had a phosphate adsorption capacity of 2.32 mg PO43−/g FHPAC, even when DOM was present as a competing adsorbate. In a lab-scale hybrid FHPAC-UF system (i.e. integrated adsorption by FHPAC with UF membrane filtration), irreversible membrane fouling was ca. three times lower than that in a PAC-UF system. When membrane fouling in the PAC-UF system was described with pore blockage models, we found that the main cause of fouling was bacterial deposition on the membrane surface. CLSM analysis determined that the chemical composition of foulants in the PAC-UF system included higher proportions of proteins, nucleic acids, and alpha-polysaccharides than that in the FHPAC-UF system. Overall, FHPAC’s ability to undergo ligand exchanges with DOM helped to reduce the nutrients and bacteria that cause biofouling to accumulate on the membrane surface.

Preparation and Characterization of BaBi2Nb2O9/PVDF Inorganic-Organic Composite Ultrafiltration Membranes

2013 ◽  
Vol 681 ◽  
pp. 309-313
Author(s):  
Dong Hua Zhang ◽  
Li Jing Pan ◽  
Da Zhi Sun
Keyword(s):  
Polyvinylidene Fluoride ◽  
Pure Water ◽  
Water Flux ◽  
Composite Membranes ◽  
Rejection Rate ◽  
Inversion Method ◽  
Ultrafiltration Membranes ◽  
Cross Sectional ◽  
Uf Membranes ◽  
Phase Inversion Method

BaBi2Nb2O9/PVDF (polyvinylidene fluoride) composite ultrafiltration (UF)membranes were prepared by alloying BaBi2Nb2O9 (BBN) particles uniformly in the PVDF solution (15% polymer weight) and used a phase-inversion method. This paper studied the effect of the concentration of BBN from 0% to 5% in 0.2Mpa on pure water flux and rejection rate to Bovine serum albumin (BSA). The cross-sectional structures of composite membranes were observed by scanning electron microscopy (SEM). Moreover, XRD results revealed the crystal structure of PVDF. The experimental results showed that the BBN/PVDF composite ultrafiltration membranes were superior in separation performances than the pure PVDF membranes due to the addition of BBN.

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