scholarly journals Removal of Carbamazepine onto Modified Zeolitic Tuff in Different Water Matrices: Batch and Continuous Flow Experiments

Water ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1084
Author(s):  
Othman A. Al-Mashaqbeh ◽  
Diya A. Alsafadi ◽  
Layal Z. Alsalhi ◽  
Shannon L. Bartelt-Hunt ◽  
Daniel D. Snow
Keyword(s):  
Wastewater Treatment ◽  
Sorption Capacity ◽  
Pure Water ◽  
Treatment Plant ◽  
Hexadecyltrimethylammonium Bromide ◽  
Ultrapure Water ◽  
Zeolitic Tuff ◽  
X Ray ◽  
Wwtp Effluent ◽  
Surfactant Modification

Carbamazepine (CBZ) is the most frequently detected pharmaceutical residues in aquatic environments effluent by wastewater treatment plants. Batch and column experiments were conducted to evaluate the removal of CBZ from ultra-pure water and wastewater treatment plant (WWTP) effluent using raw zeolitic tuff (RZT) and surfactant modified zeolite (SMZ). Point zero net charge (pHpzc), X-ray diffraction (XRD), X-ray fluorescence (XRF), and Fourier Transform Infrared (FTIR) were investigated for adsorbents to evaluate the physiochemical changes resulted from the modification process using Hexadecyltrimethylammonium bromide (HDTMA-Br). XRD and FTIR showed that the surfactant modification of RZT has created an amorphous surface with new alkyl groups on the surface. The pHpzc was determined to be approximately 7.9 for RZT and SMZ. The results indicated that the CBZ uptake by SMZ is higher than RZT in all sorption tests (>8 fold). Batch results showed that the sorption capacity of RZT and SMZ in WWTP effluent (0.029 and 0.25 mg/g) is higher than RZT and SMZ (0.018 and 0.14 mg/g) in ultrapure water (1.6–1.8 fold). Batch tests showed that the equilibrium time of CBZ removal in the WWTP matrix (47 h) is much longer than CBZ removal in ultrapure water. The sorption capacity of RZT & SMZ in WWTP effluent (0.03, 0.33 mg/g) is higher than RZT and SMZ (0.02 and 0.17 mg/g) in ultrapure water (1.5–2 fold) using column test. This study has clearly demonstrated that the performance of RZT and SMZ is more efficient for the removal of CBZ from realistic wastewater than ultrapure water. It is evident that the surfactant modification of RZT has enhanced the CBZ removal in both matrices.

scholarly journals Solar Light-Induced Methylene Blue Removal over TiO2/AC Composites and Photocatalytic Regeneration

Nanomaterials ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 3016
Author(s):  
Fernanda Dalto ◽  
Iwona Kuźniarska-Biernacka ◽  
Clara Pereira ◽  
Elsa Mesquita ◽  
Olívia Salomé G. P. Soares ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Wastewater Treatment ◽  
Photoelectron Spectroscopy ◽  
Treatment Plant ◽  
Bulk Water ◽  
Solar Irradiation ◽  
Secondary Effluent ◽  
Ultrapure Water ◽  
X Ray ◽  
Reflectance Ftir

TiO2-containing photocatalysts, which combine TiO2 with carbon-based materials, are promising materials for wastewater treatment due to synergistic photodegradation and adsorption phenomena. In this work, TiO2/AC composites were produced by the in situ immobilization of TiO2 nanoparticles over activated carbon (AC) derived from spent coffee grains, using different TiO2/AC proportions. The TiO2/AC composites were tested as adsorbents (dark) and as photocatalysts in a combined adsorption+photocatalytic process (solar irradiation) for methylene blue (MB) removal from ultrapure water, and from a secondary effluent (SecEf) of an urban wastewater treatment plant. All the materials were characterized by XRD (X-ray powder diffraction), N2 adsorption–desorption isotherms at −196 °C, SEM (scanning electron microscopy), UV-Vis diffuse reflectance, FTIR (Fourier-transform infrared spectroscopy), TPD (temperature programmed desorption), XPS (X-ray photoelectron spectroscopy) and TGA (thermogravimetric analysis). The TiAC60 (60% C) composite presented the lowest band gap (1.84 eV), while, for TiAC29 (29% C), the value was close to that of bare TiO2 (3.18 vs. 3.17 eV). Regardless of the material, the solar irradiation improved the percentage of MB discolouration when compared to adsorption in dark conditions. In the case of simultaneous adsorption+photocatalytic assays performed in ultrapure water, TiAC29 presented the fastest MB removal. Nevertheless, both TiAC29 and TiAC60 led to excellent MB removal percentages (96.1–98.1%). UV-induced photoregeneration was a promising strategy to recover the adsorption capacity of the materials, especially for TiAC60 and AC (>95%). When the assays were performed in SecEf, all the materials promoted discolouration percentages close to those obtained in ultrapure water. The bulk water parameters revealed that TiAC60 allowed the removal of a higher amount of MB, associated with the overall improvement of the SecEf quality.

scholarly journals Deciphering the Diversities of Astroviruses and Noroviruses in Wastewater Treatment Plant Effluents by a High-Throughput Sequencing Method

2015 ◽  
Vol 81 (20) ◽  
pp. 7215-7222 ◽  
Author(s):  
B. Prevost ◽  
F. S. Lucas ◽  
K. Ambert-Balay ◽  
P. Pothier ◽  
L. Moulin ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Clinical Data ◽  
High Throughput ◽  
Human Population ◽  
High Throughput Sequencing ◽  
Treatment Plant ◽  
Enteric Viruses ◽  
Viral Diversity ◽  
Wwtp Effluent ◽  
Human Astroviruses

ABSTRACTAlthough clinical epidemiology lists human enteric viruses to be among the primary causes of acute gastroenteritis in the human population, their circulation in the environment remains poorly investigated. These viruses are excreted by the human population into sewers and may be released into rivers through the effluents of wastewater treatment plants (WWTPs). In order to evaluate the viral diversity and loads in WWTP effluents of the Paris, France, urban area, which includes about 9 million inhabitants (approximately 15% of the French population), the seasonal occurrence of astroviruses and noroviruses in 100 WWTP effluent samples was investigated over 1 year. The coupling of these measurements with a high-throughput sequencing approach allowed the specific estimation of the diversity of human astroviruses (human astrovirus genotype 1 [HAstV-1], HAstV-2, HAstV-5, and HAstV-6), 7 genotypes of noroviruses (NoVs) of genogroup I (NoV GI.1 to NoV GI.6 and NoV GI.8), and 16 genotypes of NoVs of genogroup II (NoV GII.1 to NoV GII.7, NoV GII.9, NoV GII.12 to NoV GII.17, NoV GII.20, and NoV GII.21) in effluent samples. Comparison of the viral diversity in WWTP effluents to the viral diversity found by analysis of clinical data obtained throughout France underlined the consistency between the identified genotypes. However, some genotypes were locally present in effluents and were not found in the analysis of the clinical data. These findings could highlight an underestimation of the diversity of enteric viruses circulating in the human population. Consequently, analysis of WWTP effluents could allow the exploration of viral diversity not only in environmental waters but also in a human population linked to a sewerage network in order to better comprehend viral epidemiology and to forecast seasonal outbreaks.

scholarly journals Chemometric Assessment of Bulgarian Wastewater Treatment Plants’ Effluents

Molecules ◽  
2020 ◽  
Vol 25 (19) ◽  
pp. 4408
Author(s):  
Galina Yotova ◽  
Tony Venelinov ◽  
Stefan Tsakovski
Keyword(s):  
Water Quality ◽  
Wastewater Treatment ◽  
Surface Water ◽  
Suspended Solids ◽  
Treatment Plant ◽  
Surface Water Quality ◽  
Anthropogenic Sources ◽  
Multivariate Curve Resolution ◽  
Anthropogenic Activity ◽  
Wwtp Effluent

Surface water quality strongly depends on anthropogenic activity. Among the main anthropogenic sources of this activity are the wastewater treatment plant (WWTP) effluents. The discharged loads of nutrients and suspended solids could provoke serious problems for receiving water bodies and significantly alter the surface water quality. This study presents inventory analysis and chemometric assessment of WWTP effluents based on the mandatory monitoring data. The comparison between the Bulgarian WWTPs and previously reported data from other countries reveals that discharged loads from investigated WWTPs are lower. This is particularly valid for total suspended solids (TSS). The low TSS loads are the reason for the deviations of the typical calculated WWTP effluent ratios of Bulgarian WWTPs compared to the WWTPs worldwide. The performed multivariate analysis reveals the hidden factors that determine the content of WWTP effluents. The source apportioning based on multivariate curve resolution analysis provides detailed information for source contribution profiles of the investigated WWTP effluent loads and elucidate the difference between WWTPs included in this study.

scholarly journals Contamination of Surface Water and River Sediments by Antibiotic and Antiretroviral Drug Cocktails in Low and Middle-Income Countries: Occurrence, Risk and Mitigation Strategies

Water ◽  
2020 ◽  
Vol 12 (5) ◽  
pp. 1376 ◽  
Author(s):  
Pius Kairigo ◽  
Elijah Ngumba ◽  
Lotta-Riina Sundberg ◽  
Anthony Gachanja ◽  
Tuula Tuhkanen
Keyword(s):  
Wastewater Treatment ◽  
Aqueous Phase ◽  
Surface Waters ◽  
River Sediments ◽  
Treatment Plant ◽  
Antiretroviral Drugs ◽  
Mitigation Strategies ◽  
Active Pharmaceutical Ingredients ◽  
Pharmaceutical Ingredients ◽  
Wwtp Effluent

Presence of antimicrobial cocktails in the hydrological cycles is of interest because of their potential to mediate antimicrobial resistance within the natural environment. In this study, we determined the concentrations of selected antibiotics and antiretroviral drugs (ARVDs) in wastewater treatment plant (WWTP) effluent, effluent suspended particulate matter (SPM), surface waters and river sediments in Kenya in order to determine the extent of pollution within the sampled environment. Target analysis for the most common antibiotics and ARVDs was done. Sulfamethoxazole (SMX), ciprofloxacin (CIP), trimethoprim (TMP), norfloxacin (NOR), zidovidine (ZDV), lamivudine (3TC) and nevirapine (NVP) were analyzed using LC-ESI-MS/MS. Effluent aqueous phase had concentrations ranging between 1.2 µg L−1 to 956.4 µg L−1 while the effluent SPM showed higher concentrations, ranging between 2.19 mg Kg−1 and 82.26 mg Kg−1. This study shows emission of active pharmaceutical ingredients (APIs) from WWTP to the environment mainly occurs via the SPM phase, which is usually overlooked in environmental analyses. Concentrations in surface waters and river sediments ranged between 1.1 µg L−1 to 228 µg L−1 and 11 µg Kg−1 to 4125 µg Kg−1 respectively. ARVDs occurred at consistently higher concentrations than antibiotics in both the aqueous and solid samples. The wastewater treatment plants and lagoons where sludge degradation should occur, are sources of active pharmaceutical ingredients (APIs) including transformational products, nutrients and organic matter that are released back to the aqueous phase.

Fate of phthalate esters in municipal wastewater treatment plant and their environmental impact

2015 ◽  
Vol 73 (6) ◽  
pp. 1395-1400
Author(s):  
Minghao Kong ◽  
Yonghui Song ◽  
Yizhang Zhang ◽  
Ruixia Liu ◽  
Jian Wei ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Wastewater Treatment Plant ◽  
Municipal Wastewater ◽  
Water Solubility ◽  
Phthalate Esters ◽  
Treatment Plant ◽  
Municipal Wastewater Treatment ◽  
Municipal Wastewater Treatment Plant ◽  
Wwtp Effluent ◽  
Receiving River

The fate and distribution of six phthalate esters (PAEs) in a municipal wastewater treatment plant (WWTP) employing an anaerobic/anoxic/oxic (A2/O) process were investigated. The process achieved relatively high removal efficiencies of PAEs in the range 55–97%. It illustrated that biotransformation and sludge-adsorption were major elimination pathways by analyzing the mass balance and flux of PAEs. About 83% of ∑PAEs was entirely removed by A2/O bioreactors indicating biotransformation is the dominant removal mechanism. PAEs with shorter alkyl chain length and higher water solubility were more biodegradable. Less than 6% of ∑PAEs were removed by excess sludge adsorption. The sludge-adsorption capacity of PAE depends on its hydrophobicity. The levels and fluxes of PAEs were analyzed by monitoring different sites of the receiving river of the WWTP effluent to clarify the potential impact of discharge. Daily flux of PAEs upstream and downstream of the discharging point were 113 kg·d−1 and 205 kg·d−1, respectively, which were higher than the effluent devotion value of 6.67 kg·d−1. It suggested that the emissions from the WWTP appeared to be less than those from the other possible sources, such as potential untreated discharge and surface runoff. Improvement of wastewater collection efficiencies is necessary to eliminate the PAE load in the urban river.

scholarly journals The Effect of the Effluent from a Small-Scale Conventional Wastewater Treatment Plant Treating Municipal Wastewater on the Composition and Abundance of the Microbial Community, Antibiotic Resistome, and Pathogens in the Sediment and Water of a Receiving Stream

Water ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 865
Author(s):  
Kertu Tiirik ◽  
Hiie Nõlvak ◽  
Marika Truu ◽  
Angela Peeb ◽  
Margit Kõiv-Vainik ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Microbial Community ◽  
Municipal Wastewater ◽  
Stream Water ◽  
Treatment Plant ◽  
Small Scale ◽  
Discharge Point ◽  
Water And Sediment ◽  
Wwtp Effluent ◽  
Receiving Stream

The effluents of wastewater treatment plants (WWTPs) are major contributors of nutrients, microbes—including those carrying antibiotic resistance genes (ARGs)—and pathogens to receiving waterbodies. The effect of the effluent of a small-scale activated sludge WWTP treating municipal wastewater on the composition and abundance of the microbial community as well as the antibiotic resistome and pathogens in the sediment and water of the receiving stream and river was studied using metagenome sequencing and a quantitative approach. Elevated Bacteroidetes proportions in the prokaryotic community, heightened sulfonamide and aminoglycoside resistance determinants proportions, and an increase of up to three orders of magnitude of sul1–sul2–aadA–blaOXA2 gene cluster abundances were recorded in stream water and sediments 0.3 km downstream of a WWTP discharge point. Further downstream, a gradual recovery of affected microbial communities along a distance gradient from WWTP was recorded, culminating in the mostly comparable state of river water and sediment parameters 3.7 km downstream of WWTP and stream water and sediments upstream of the WWTP discharge point. Archaea, especially Methanosarcina, Methanothrix, and Methanoregula, formed a substantial proportion of the microbial community of WWTP effluent as well as receiving stream water and sediment, and were linked to the spread of ARGs. Opportunistic environmental-origin pathogens were predominant in WWTP effluent and receiving stream bacterial communities, with Citrobacter freundii proportion being especially elevated in the close vicinity downstream of the WWTP discharge point.

scholarly journals Inputs from wastewater treatment plant effluent influence the temporal variability of nutrient uptake in an intermittent stream

2021 ◽  
Author(s):  
Sara Castelar ◽  
Susana Bernal ◽  
Miquel Ribot ◽  
Stephanie N. Merbt ◽  
Marta Tobella ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Nutrient Uptake ◽  
Stream Water ◽  
Hot Spot ◽  
Inorganic Nitrogen ◽  
Treatment Plant ◽  
Ammonium Concentration ◽  
Stream Water Quality ◽  
Wwtp Effluent ◽  
Wide Range

Abstract Effluents from wastewater treatment plants (WWTP) affect water chemistry and in-stream nutrient uptake capacity from receiving freshwaters, thus altering the amount and fate of nutrients exported. In Mediterranean regions, the dilution capacity of receiving streams to buffer the WWTP biogeochemical fingerprint can vary seasonally due to changes in hydrologic conditions. We assessed the temporal patterns and controls on nutrient uptake in an intermittent Mediterranean stream receiving WWTP effluent inputs. We compiled data on longitudinal profiles of ambient concentrations of dissolved inorganic nitrogen and phosphorus along a 800 m reach on 47 sampling dates between 2001 and 2017 that cover a wide range of hydrological conditions. Data were used to estimate net nutrient uptake in the receiving stream. Ammonium concentration decreased along the reach in 72% of dates, and these decreases were coupled with increases of either nitrite or nitrate. This phenomenon suggests that the stream acted as a hot spot of nitrification. Conversely, concentration of phosphorus did not show any longitudinal pattern in 75% of dates, suggesting that uptake and release processes for this element were commonly counterbalanced. Finally, ammonium net uptake decreased when the stream had a low dilution capacity, suggesting that excess of available nutrients associated with WWTP inputs control de temporal variation of the bioreactive capacity of the receiving streams. Overall, this study suggests that water management should consider the biogeochemical interplay between WWTP operation and the functioning of receiving streams as a strategy to improve stream water quality in urban landscapes.

scholarly journals Crystal structure of a β-aminopeptidase from an AustralianBurkholderiasp.

2017 ◽  
Vol 73 (7) ◽  
pp. 386-392 ◽  
Author(s):  
Marietta John-White ◽  
Geoff J. Dumsday ◽  
Priscilla Johanesen ◽  
Dena Lyras ◽  
Nyssa Drinkwater ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Amino Acids ◽  
Wastewater Treatment ◽  
Mechanism Of Action ◽  
Treatment Plant ◽  
Β Subunit ◽  
Α Subunit ◽  
Gram Negative ◽  
X Ray ◽  
Tetrameric Assembly

β-Aminopeptidases are a unique group of enzymes that have the unusual capability to hydrolyze N-terminal β-amino acids from synthetic β-peptides. β-Peptides can form secondary structures mimicking α-peptide-like structures that are resistant to degradation by most known proteases and peptidases. These characteristics of β-peptides give them great potential as peptidomimetics. Here, the X-ray crystal structure of BcA5-BapA, a β-aminopeptidase from a Gram-negativeBurkholderiasp. that was isolated from activated sludge from a wastewater-treatment plant in Australia, is reported. The crystal structure of BcA5-BapA was determined to a resolution of 2.0 Å and showed a tetrameric assembly typical of the β-aminopeptidases. Each monomer consists of an α-subunit (residues 1–238) and a β-subunit (residues 239–367). Comparison of the structure of BcA5-BapA with those of other known β-aminopeptidases shows a highly conserved structure and suggests a similar proteolytic mechanism of action.

Rapid small-scale column testing of granular activated carbon for organic micro-pollutant removal in treated domestic wastewater

2014 ◽  
Vol 70 (7) ◽  
pp. 1271-1278 ◽  
Author(s):  
F. Zietzschmann ◽  
J. Müller ◽  
A. Sperlich ◽  
A. S. Ruhl ◽  
F. Meinel ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Pure Water ◽  
Treatment Plant ◽  
Domestic Wastewater ◽  
Granular Activated Carbon ◽  
Breakthrough Curves ◽  
Pollutant Removal ◽  
Small Scale ◽  
Hydrodynamic Conditions ◽  
Wwtp Effluent

This study investigates the applicability of the rapid small-scale column test (RSSCT) concept for testing of granular activated carbon (GAC) for organic micro-pollutants (OMPs) removal from wastewater treatment plant (WWTP) effluent. The chosen experimental setup was checked using pure water, WWTP effluent, different GAC products, and variable hydrodynamic conditions with different flow velocities and differently sized GAC, as well as different empty bed contact times (EBCTs). The setup results in satisfying reproducibility and robustness. RSSCTs in combination with WWTP effluent are effective when comparing the OMP removal potentials of different GAC products and are a useful tool for the estimation of larger filters. Due to the potentially high competition between OMPs and bulk organics, breakthrough curves are likely to have unfavorable shapes when treating WWTP effluent. This effect can be counteracted by extending the EBCT. With respect to the strong competition observed in GAC treatment of WWTP effluent, the small organic acid and neutral substances are retained longer in the RSSCT filters and are likely to cause the majority of the observed adsorption competition with OMPs.

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