scholarly journals Performance of a Ditch-Style Phosphorus Removal Structure for Treating Agricultural Drainage Water with Aluminum-Treated Steel Slag

Water ◽  
2020 ◽  
Vol 12 (8) ◽  
pp. 2149 ◽  
Author(s):  
Vinayak S. Shedekar ◽  
Chad J. Penn ◽  
Lindsay Pease ◽  
Kevin W. King ◽  
Margaret M. Kalcic ◽  
...  

Several structural, treatment, and management approaches exist to minimize phosphorus (P) transport from agricultural landscapes (e.g., cover cropping and conservation tillage). However, many of these practices are designed to minimize particulate P transport and are not as effective in controlling dissolved P (DP) losses. Phosphorus removal structures employ a P sorption material (PSM) to trap DP from flowing water. These structures have been successful in treating surface runoff by utilizing aluminum (Al)-treated steel slag, but subsurface tile drainage has never been tested with this material. The goal of this study was to evaluate the performance and economics of a ditch-style P removal structure using Al-treated steel slag for treating agricultural subsurface drainage discharge. The structure treated subsurface drainage water from a 4.5 ha agricultural field with elevated soil test P levels. Overall, the structure removed approximately 27% and 50% of all DP and total P (TP) entering the structure, respectively (i.e., 2.4 and 9.4 kg DP and TP removal). After an initial period of strong DP removal, the discrete DP removal became highly variable. Flow-through analysis of slag samples showed that the slag used to construct the structure was coarser and less sorptive compared to the slag samples collected prior to construction that were used to design and size the structure. Results of this study highlight the importance of correctly designing the P removal structures using representative PSMs.

2016 ◽  
Vol 73 (11) ◽  
pp. 2644-2653 ◽  
Author(s):  
Yuan Ge ◽  
Xiaochang C. Wang ◽  
Mawuli Dzakpasu ◽  
Yucong Zheng ◽  
Yaqian Zhao ◽  
...  

Phosphorus (P) removal in constructed wetlands (CWs) is often low unless special substrates with high sorption capacities are used. However, the use of special substrates in vertical flow (VF) CWs has not been proved to enhance P sorption. Thus, two VF wetlands were designed to evaluate the potential for enhanced P removal from polluted urban river water, one with slag as substrate and the other as a control with gravel as substrate. Findings from batch experiments showed P sorption capacities of 3.15 gP/kg and 0.81 gP/kg, respectively, for steel slag and gravel. Different organic matter fractions played different roles in P sorption, the effects of which were significant only at high concentrations. Over a 220 days' operation, the VF-slag removed 76.0% of the influent total phosphorus (TP) at 0.159 g/m2·d and PO4-P of 70.9% at 0.063 g/m2·d, whereas the VF-gravel removed 65.0% at 0.136 g/m2·d and 48.6% at 0.040 g/m2·d, respectively. Therefore, the merit of using a steel slag substrate in VF wetlands can be significant for the removal of PO4-P.


Water ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 443 ◽  
Author(s):  
Chad Penn ◽  
Stan Livingston ◽  
Vinayak Shedekar ◽  
Kevin King ◽  
Mark Williams

Reducing dissolved phosphorus (P) losses from legacy P soils to surface waters is necessary for preventing algal blooms. Phosphorus removal structures containing steel slag have shown success in treating surface runoff for dissolved P, but little is known about treating subsurface (tile) drainage. A ditch-style and subsurface P removal structure were constructed using steel slag in a bottom-up flow design for treating tile drainage. Nearly 97% of P was delivered during precipitation-induced flow events (as opposed to baseflow) with inflow P concentrations increasing with flow rate. Structures handled flow rates approximately 12 L s−1, and the subsurface and ditch structures removed 19.2 (55%) and 0.9 kg (37%) of the cumulative dissolved P load, respectively. Both structures underperformed relative to laboratory flow-through experiments and exhibited signs of flow inhibition with time. Dissolved P removal decreased dramatically when treated water pH decreased <8.5. Although slag has proven successful for treating surface runoff, we hypothesize that underperformance in this case was due to tile drainage bicarbonate consumption of slag calcium through the precipitation of calcium carbonate, thereby filling pore space, decreasing flow and pH, and preventing calcium phosphate precipitation. We do not recommend non-treated steel slag for removing dissolved P from tile drainage unless slag is replaced every 4–6 months.


Water ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1593
Author(s):  
Javier M. Gonzalez ◽  
Chad J. Penn ◽  
Stan J. Livingston

Blind inlets are implemented to promote obstruction-free surface drainage of field depressions as an alternative to tile risers for the removal of sediment and particulate phosphorus (P) through an aggregate bed. However, conventional limestone used in blind inlets does not remove dissolved P, which is a stronger eutrophication agent than particulate P. Steel slag has been suggested as an alternative to limestone in blind inlets for removing dissolved P. The objectives of this study were to construct a blind inlet with steel slag and evaluate its ability to remove dissolved P, nitrogen (N), and herbicides. A blind inlet was constructed with steel slag in late 2015; data from only 2018 are reported due to inflow sampling issues. The blind inlet removed at least 45% of the dissolved P load and was still effective after three years. The dissolved P removal efficiency was greater with higher inflow P concentrations. More than 70% of glyphosate and its metabolite, and dicamba were removed. Total N was removed in the form of organic N and ammonium, although N cycling processes within the blind inlet appeared to produce nitrate. Higher dissolved atrazine and organic carbon loads were measured in outflow than inflow, likely due to the deposition of sediment-bound particulate forms not measured in inflow, which then solubilized with time. At a cost similar to local aggregate, steel slag in blind inlets represents a simple update for improving dissolved P removal.


1994 ◽  
Vol 29 (7) ◽  
pp. 153-156 ◽  
Author(s):  
D. Wedi ◽  
P. A. Wilderer

Most of the fundamental processes responsible for enhanced biological phosphorus removal (EBPR) were obtained through laboratory tests under defined conditions with pure or enriched cultures. Acinetobacter sp. was identified as the most important group of bacteria responsible for bio-P removal. Full scale data showed, however, that laboratory results do not match full scale results well enough. There is a lack of data on the effects of sub-optimal process conditions such as inadequate availability of volatile fatty acids (VFA), high nitrate recycle, storm water inflow or low temperatures. In this paper the results of full scale experiments on P-release are presented and compared with theoretical values. Measurements at a full scale Phoredox-system showed a surprisingly low P-release in the anaerobic reactor. Only 4 to 10% of the phosphorus in the activated sludge was released in the bulk liquid. With laboratory batch-tests, a maximum of 20% of the P in the sludge could be released. It is assumed that under the prevailing process conditions either the fraction of Acinetobacter sp. was very small, or bacteria other than Acinetobacter sp. were responsible for the P-removal, or most of the phosphorus was bound chemically but mediated by biological processes.


2003 ◽  
Vol 48 (1) ◽  
pp. 87-94 ◽  
Author(s):  
B. Lesjean ◽  
R. Gnirss ◽  
C. Adam ◽  
M. Kraume ◽  
F. Luck

The enhanced biological phosphorus removal (EBPR) process was adapted to membrane bioreactor (MBR) technology. One bench-scale plant (BSP, 200-250 L) and two pilot plants (PPs, 1,000-3,000 L each) were operated under several configurations, including pre-denitrification and post-denitrification without addition of carbon source, and two solid retention times (SRT) of 15 and 26 d. The trials showed that efficient Bio-P removal can be achieved with MBR systems, in both pre- and post-denitrification configurations. EBPR dynamics could be clearly demonstrated through batch-tests, on-line measurements, profile analyses, P-spiking trials, and mass balances. High P-removal performances were achieved even with high SRT of 26 d, as around 9 mgP/L could be reliably removed. After stabilisation, the sludge exhibited phosphorus contents of around 2.4%TS. When spiked with phosphorus (no P-limitation), P-content could increase up to 6%TS. The sludge is therefore well suited to agricultural reuse with important fertilising values. Theoretical calculations showed that increased sludge age should result in a greater P-content. This could not be clearly demonstrated by the trials. This effect should be all the more significant as the influent is low in suspended solids.


2002 ◽  
Vol 45 (5) ◽  
Author(s):  
P. S. Miller ◽  
J. K. Mitchell ◽  
R. A. Cooke ◽  
B. A. Engel

1983 ◽  
Vol 15 (3-4) ◽  
pp. 127-152 ◽  
Author(s):  
I P Siebritz ◽  
G A Ekama ◽  
G v R Marais

Biological excess phosphorus removal in nitrification-denitrification single sludge activated sludge processes is shown to be stimulated by having a concentration of rapidly biodegradable COD (Sbsa) ≧25 mg/ℓ in the anaerobic reactor; the magnitude of the P removal is determined by a P removal propensity factor (Pf) defined by the product of (Sbsa−25) and the fractional mass of sludge in the anaerobic reactor. Sbsa is rapidly depleted by nitrate entering the anaerobic reactor; in the Phoredox process treating municipal waste flows if the TKN/COD ratio of the influent is greater than about 0,08 mgN/mgCOD the process, if designed to ensure efficient nitrification, is unlikely to remove all the nitrate and nitrate is recycled to the anaerobic reactor whereupon P removal declines. A new process is proposed that protects the anaerobic reactor from the nitrate in the effluent; tests indicate that this process can give excess P removal for TKN/COD ratios up to 0,14 mgN/mgCOD.


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