scholarly journals Recharge of River Water to Karst Aquifer Determined by Hydrogeochemistry and Stable Isotopes

Water ◽  
2019 ◽  
Vol 11 (3) ◽  
pp. 479 ◽  
Author(s):  
Yi Guo ◽  
Dajun Qin ◽  
Jie Sun ◽  
Lu Li ◽  
Fulin Li ◽  
...  
Keyword(s):  
River Water ◽  
Preferential Flow ◽  
Karst Aquifer ◽  
Water Type ◽  
Karst Groundwater ◽  
River Bank ◽  
Field Investigations ◽  
Groundwater Samples ◽  
Spring System ◽  
Preferential Flow Path

The Jinan Karst Spring System in Shandong province, China, has suffered to maintain groundwater level and spring flowing for decades. Recharge of river water to karst aquifer in Jinan is important for the outflowing of four large karst springs in the city center. Field investigations were conducted for two times in May and October, 2015, respectively and water samples were collected for hydrogeochemical and isotopic measurements. Results showed that (a) the water type was predominantly Ca-HCO3-SO4 for karst groundwater, and Ca-Mg-SO4 for river water; (b) the concentration of HCO3− and NO3− in karst groundwater were higher than that in river water, in contrast, the concentration of SO42− and K+ in karst groundwater were lower than that in river water; (c) the δ2H and δ18O values with average of −51.2‰ and −6.6‰ for river water is more enriched than the values in groundwater samples (−59.1‰ and −8.3‰), in that river experienced evaporation in the upstream reservoir; (d) Based on the distribution pattern of δ18O, groundwater near river bank was found to be recharged from river water and found a preferential flow path in karst aquifer situated from Dongkema to Manzizhuang near the river bank. This study provides useful information for understanding of the hydraulic connection between river water and karst aquifer, and benefit the protection and management of water resources.

scholarly journals Identifying Groundwater and River Water Interconnections Using Hydrochemistry, Stable Isotopes, and Statistical Methods in Hanumante River, Kathmandu Valley, Central Nepal

Water ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1524
Author(s):  
Ramita Bajracharya ◽  
Takashi Nakamura ◽  
Subesh Ghimire ◽  
Bijay Man Shakya ◽  
Naresh Kazi Tamrakar
Keyword(s):  
River Water ◽  
Statistical Methods ◽  
Shallow Groundwater ◽  
Dry Season ◽  
Kathmandu Valley ◽  
Water Type ◽  
Wet Season ◽  
Groundwater Samples ◽  
Dry Seasons ◽  
Wet And Dry Seasons

Interconnection between river water and groundwater plays an important role in maintaining water quantity and quality in hydrological systems. Furthermore, the exact interconnection is often difficult to observe and measure. This study attempts to explain river and shallow groundwater interconnection in urbanized areas of the Kathmandu Valley, Nepal. Isotopic (δD and δ18O) and chemical analyses were performed on river and groundwater samples, and the results were analyzed using statistical methods to identify areas of interconnection between river water and groundwater. Higher concentrations and positive strong correlations of Na+ with K+, NH4+-N, Cl−, HCO3−, and PO4−-P, and a change of water type from Ca-HCO3 during the wet season to Na-K-HCO3 during the dry season indicate higher contamination in river water during the dry season. Hierarchical cluster analysis was used in grouping water samples into clusters on the basis of isotopic and chemical (Na+ and Cl−) composition. Grouping of river and groundwater samples in one–one clusters from wet and dry seasons shows the presence of interconnection, indicating the contribution of river water in recharging shallow groundwater. These results imply that shallow groundwater found near rivers is chemically contaminated by polluted river water through bank infiltration, in both wet and dry seasons.

An Investigation of the Quantity, Quality and Sources of Groundwater Seepage into the St. Clair River near Sarnia, Ontario, Canada

1986 ◽  
Vol 21 (3) ◽  
pp. 351-367 ◽  
Author(s):  
Michael Sklash ◽  
Sharon Mason ◽  
Suzanne Scott ◽  
Chris Pugsley
Keyword(s):  
Electrical Conductivity ◽  
River Water ◽  
Organic Contaminants ◽  
Shallow Groundwater ◽  
Seepage Rate ◽  
Groundwater Seepage ◽  
Seepage Meters ◽  
Groundwater Samples ◽  
Hydraulic Gradients ◽  
Unidentified Source

Abstract We used seepage meters and minipiezometers to survey a 100 m by 7 km band of streambed of the St. Clair River near Sarnia, Ontario, Canada, to determine the quantity, quality, and sources of groundwater seepage into the river. The average observed seepage rate, 1.4 x 10−8 m3/s/m2, suggests higher than expected hydraulic conductivities and/or hydraulic gradients in the streambed. We found detectable levels of some organic contaminants in streambed groundwater samples from 1.0 and 1.5 m depths, however , concentrations did not exceed drinking water guidelines. Our isotopic and electrical conductivity data indicate that: (l) the streambed groundwater is not just river water, (2) groundwater from the “freshwater aquifer” at the base of the overburden Is not a significant component of the streambed groundwater, (3) some of the streambed groundwater is partially derived from a shallow groundwater flow system, and (4) an unidentified source of water with low tritium, river water-like δ18O, and very high electrical conductivity, contributes to the streambed groundwater.

scholarly journals Response in Growth, Scute Development, and Whole-Body Ion Composition of Acipenser fulvescens Reared in Water of Differing Chemistries

Animals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1419
Author(s):  
Janet Genz ◽  
Rachael Hicks
Keyword(s):  
River Water ◽  
Growth And Development ◽  
Lake Sturgeon ◽  
Whole Body ◽  
Acipenser Fulvescens ◽  
Water Type ◽  
Ion Composition ◽  
Ion Concentrations ◽  
Before And After ◽  
Yolk Absorption

In fishes, environmental ion availability can have substantial effects on growth and development. This study examined the development of Lake Sturgeon in response to the varying environmental ion availability that they experience as part of a conservation stocking program. We reared sturgeon in natural water from the Coosa River, which had higher concentrations of Mg2+, Na+, and Zn2+ than standard hatchery conditions, while [Ca2+] at the Warm Springs National Fish Hatchery was 2× higher than in the Coosa River. Eggs were hatched in each water type and the larvae were sampled at time points before and after yolk absorption during the first 8 weeks of development. Total length and weight in WSNFH larvae were significantly higher than larvae in Coosa River water starting at 8 dph, indicating that growth was dependent on the different environmental ion levels. Concentrations of the ions of interest were also determined for whole-body acid digests of the exposed Lake Sturgeon. We found that Lake Sturgeon reared in Coosa River water had significantly higher magnesium and zinc than Lake Sturgeon reared in WSNFH water (p < 0.05), while calcium was significantly higher in WSNFH than Coosa River water. This difference shows that different environmental ion concentrations also impact the overall development of larval Lake Sturgeon.

scholarly journals Urban Groundwater Contamination by Non-Steroidal Anti-Inflammatory Drugs

Water ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 720
Author(s):  
Anna Jurado ◽  
Enric Vázquez-Suñé ◽  
Estanislao Pujades
Keyword(s):  
Salicylic Acid ◽  
Human Health ◽  
River Water ◽  
Human Health Risk ◽  
Urban Groundwater ◽  
Pollution Source ◽  
Groundwater Samples ◽  
Water Recharge ◽  
Inflammatory Drugs ◽  
Anti Inflammatory

Pharmaceuticals, such as non-steroidal anti-inflammatory drugs (NSAIDs) and their metabolites, have become a major concern due to their increasing consumption and their widespread occurrence in the environment. In this paper, we investigate the occurrence of NSAIDs and their metabolites in an urban aquifer, which may serve as a potential resource for drinking water, and propose a methodology to assess the removal of these substances in the river–groundwater interface. Then, risk quotients (RQs) are computed, in order to determine the risk posed by the single NSAIDs and their mixture to human health. To this end, six NSAIDs and two metabolites were collected from an urban aquifer located in the metropolitan area of Barcelona (NE, Spain), in which the major pollution source is a contaminated river. All of the target NSAIDs were detected in groundwater samples, where the concentrations in the aquifer were higher than those found in the river water (except for ibuprofen). Diclofenac, ketoprofen, propyphenazone and salicylic acid were detected at high mean concentrations (ranging from 91.8 ng/L to 225.2 ng/L) in the aquifer. In contrast, phenazone and mefenamic acid were found at low mean concentrations (i.e., lower than 25 ng/L) in the aquifer. According to the proposed approach, the mixing of river water recharge into the aquifer seemed to some extent to promote the removal of the NSAIDs under the sub-oxic to denitrifying conditions found in the groundwater. The NSAIDs that presented higher mean removal values were 4OH diclofenac (0.8), ibuprofen (0.78), salicylic acid (0.35) and diclofenac (0.28), which are likely to be naturally attenuated under the aforementioned redox conditions. Concerning human health risk assessment, the NSAIDs detected in groundwater and their mixture do not pose any risk for all age intervals considered, as the associated RQs were all less than 0.05. Nevertheless, this value must be taken with caution, as many pharmaceuticals might occur simultaneously in the groundwater.

scholarly journals ANALISIS KUALITAS AIR TANAH AKIBAT PENGARUH SUNGAI KLAMPOK YANG TERCEMAR LIMBAH INDUSTRI DI KECAMATAN BERGAS SEMARANG JAWA TENGAH (Analysis of Groundwater Quality Due to Effect Klampok River that was Contaminated Industrial Waste in Bergas Semarang Central Java)

2020 ◽  
Vol 26 (1) ◽  
pp. 36
Author(s):  
Sepridawati Siregar ◽  
Desi Kiswiranti
Keyword(s):  
Water Quality ◽  
Groundwater Quality ◽  
River Water ◽  
Industrial Wastewater ◽  
The Body ◽  
Water Sampling ◽  
Central Java ◽  
Groundwater Samples ◽  
Quality Testing

AbstrakSungai Klampok mengalir melalui Kecamatan Bergas dan sekelilingnya terdapat beberapa industri sehingga mengakibatkan sungai tersebut tercemar karena menjadi badan penerima air limbah. Akibat penurunan kualitas air Sungai Klampok akan berimbas pada penurunan kualitas air tanah yang digunakan oleh penduduk sekitar sungai tersebut. Penelitian ini bertujuan untuk mengetahui kualitas air tanah yang berada di sekitar Sungai Klampok sebagai akibat adanya pengaruh beban pencemaran oleh air limbah industri berdasarkan Permenkes No. 416/MENKES/PER/IX/1990 tentang persyaratan kualitas air bersih. Lokasi pengambilan sampel air sungai dibagi menjadi 3 stasiun (LK1, LK2 dan LK3) sedangkan untuk sampel airtanah dari rumah-rumah penduduk dilakukan pada 6 titik yaitu 3 titik di daerah utara dari Sungai Klampok (U1,U2, U3) dan 3 titik di daerah selatan dari Sungai Klampok (S1,S2, S3). Pengambilan sampel dilakukan pada musim kemarau. Dari hasil uji kualitas air sungai, pencemaran yang terjadi pada air sungai Klampok masuk dalam kategori tercemar ringan-sedang. Sedangkan hasil uji kualitas air tanah masih berada di bawah baku mutu yang disyaratkan oleh Permenkes No. 416/MENKES/PER/IX/1990, sehingga penurunan kualitas air sungai Klampok tidak mempengaruhi kualitas air tanah di sekitar sungai tersebut. AbstractThe Klampok River flows through the Bergas Subdistrict and there are a number of industries around it, causing the river to become polluted because it becomes the body of the recipient of wastewater. As a result of the decline in the quality of the water in the Klampok River, it will impact on the quality of groundwater used by residents around the river. This study aims to determine the quality of groundwater around the Klampok River as a result of the influence of pollution load by industrial wastewater based on Permenkes No. 416 / MENKES / PER / IX / 1990 concerning requirements for clean water quality. The location of river water sampling is divided into 3 stations (LK1, LK2, and LK3) while for groundwater samples from residential houses is carried out at 6 points, namely 3 points in the northern area of Klampok River (U1, U2, U3) and 3 points in the area south of the Klampok River (S1, S2, S3). Sampling is done in the dry season. From the results of the test of river water quality, pollution that occurs in Klampok river water is categorized as mild-moderate polluted. While the results of groundwater quality testing are still below the quality standards required by Permenkes No. 416 / MENKES / PER / IX / 1990 so that the decline in the water quality of the Klampok river does not affect the quality of groundwater around the river.

scholarly journals Environmental Isotope of Radon-222 for Ciliwung River and Shallow Deep Water Interaction Study

2020 ◽  
Vol 21 (2) ◽  
pp. 139
Author(s):  
Evarista Ristin Pujiindiyati ◽  
Bungkus Pratikno
Keyword(s):  
River Water ◽  
Residence Time ◽  
Shallow Groundwater ◽  
Infiltration Rate ◽  
Scientific Basis ◽  
Dry Season ◽  
River Bank ◽  
222Rn Concentration ◽  
Significant Difference ◽  
Groundwater Infiltration

Aquifer in river bank area is mostly susceptive toward pollution occurring in river. One of parameters to determine the interaction process between groundwater and river is a natural isotope of 222Rn. The significant difference of radon concentration in groundwater and river water can be utilized as a scientific basis for investigating groundwater infiltration in river bank. Those studied parameters are residence time and infiltration rate. The research using 222Rn had been conducted in shallow groundwater of Ciliwung river bank - South Jakarta during rainy and dry season. The range of 222Rn concentration in shallow groundwater monitored in dry season was between 666 - 2590 Bq/m3 which was higher than that of rainy season ranging at 440 to 1546 Bq/m3. Otherwise, concentration of 222Rn in river water could not be detected (its 222Rn concentration = 0 Bq/m3) due to its much lower concentration either rainy or dry season. During dry season monitoring, equilibration between groundwater and river water was reached at the distance approximately 98 - 140 m away from river side. Estimating residence time based on 222Rn concentration at nearest site from the river and at equlibration area was 4.2 days such that the infiltration rate from river water into aquifer might be 7.8 m/day.Keywords: 222Rn, groundwater, residence time, infiltration rate.

scholarly journals Hydrochemical Evolution in Ciliwung River – Java, Indonesia: Study of Sea Water Mixture and Mineral Dissolution

2020 ◽  
Vol 20 (6) ◽  
pp. 1360
Author(s):  
Evarista Ristin Pujiindiyati ◽  
Paston Sidauruk ◽  
Tantowi Eko Prayogi ◽  
Faizal Abdillah
Keyword(s):  
River Water ◽  
Rainy Season ◽  
Sea Water ◽  
Dry Season ◽  
Mineral Dissolution ◽  
Water Type ◽  
Water Mixture ◽  
Hydrochemical Evolution ◽  
Increasing Trend ◽  
Saturation Indexes

The chemical characteristics of the Ciliwung River were analyzed to understand hydrochemical evolution. A fraction of sea water mixture and kinds of mineral controlling for chemicals were also determined. During three year investigations in 2015, 2016, and 2018, electrical conductivity increased with decreasing elevations. Two hydrochemical facies had been identified for the Ciliwung river water; those were Ca-Mg-HCO3 and Ca-Na-HCO3.  The river water mixing with seawater was recognized in the Mangga Dua site in which its water type had shifted to Na-Ca-HCO3-Cl. Based on Na-Cl contents, the fraction of sea water into the Ciliwung River reached 2% in the Mangga Dua site during the dry season and decreased to 0.7% during the rainy season in 2015. The much higher monthly rainfall during the dry season in 2016 and 2018 had washed out invading seawater from the Mangga Dua site; its fraction of sea water was less than 0.4%. Saturation indexes with respect to calcite, dolomite, and gypsum minerals showed an increasing trend related to the decreasing elevations. All water samples were undersaturated with respect to gypsum. Meanwhile, saturation indexes with respect to calcite and dolomite mostly indicated undersaturated, except in the Mangga Dua site that was saturated (during the rainy season in 2015 and dry season in 2018) and supersaturated during the dry season in 2015.

scholarly journals Hydrochemistry of Groundwater in Northeast Part of Anbar Governorate – West of Iraq

2019 ◽  
Vol 16 (1) ◽  
pp. 0088
Author(s):  
Hussein Ilaibi Zamil Al-Sudani
Keyword(s):  
Electrical Conductivity ◽  
Groundwater Quality ◽  
Total Dissolved Solids ◽  
Water Type ◽  
Hydrochemical Parameters ◽  
Dissolved Solids ◽  
Drinking Purposes ◽  
Groundwater Samples ◽  
Geological Formation ◽  
Continental Origin

A groundwater quality assessment has been carried out in northeast part of Anbar governorate in western Iraq. We analyzed hydrochemical parameters such as pH, electrical conductivity, total dissolved solids presence of ions to describe groundwater quality. The study area has the only confined aquifer within the geological formation extended in area. Values of groundwater hydrochemical parameters were ranged from (7) to (7.9) for ph, (1599) to (6800) µmhos/cm for electrical conductivity (EC) and (1048) to (4446) mg/l for total dissolved solids (TDS). The origins and types of groundwater in the area were of marine origin and MgCl2 water type while only (6) samples were of continental origin and Na2SO4 water type. Groundwater utilization indicated that it can't be used for drinking purposes, while few groundwater wells can be used for agricultural and (33) groundwater samples can be used for animal purposes. However, the nature of the soil in the area and the depth of the groundwater qualified water for agricultural uses in significant and wide ranges.

scholarly journals Enhanced Characterization of the Krania–Elassona Structure and Functioning Allogenic Karst Aquifer in Central Greece

Geosciences ◽  
2018 ◽  
Vol 9 (1) ◽  
pp. 15 ◽  
Author(s):  
Antonios Manakos ◽  
Maria Ntona ◽  
Nerantzis Kazakis ◽  
Konstantinos Chalikakis
Keyword(s):  
Conceptual Model ◽  
Moving Average ◽  
Karst Aquifer ◽  
Groundwater Vulnerability ◽  
Spring Water ◽  
Geological Mapping ◽  
Spring Discharge ◽  
Water Type ◽  
Central Greece

The present study highlights the importance of geological, hydrogeological, and hydrogeochemical characterization of a karst aquifer in building a conceptual model of the system. The karst system of Krania–Elassona in central Greece was chosen for this application. Hydrogeological research included geological mapping and hydrogeological analysis. Additionally, hydrochemical analysis of water samples was performed in boreholes, rivers, and the system’s main spring. The Krania–Elassona aquifer consists of three horizons of marbles and is characterized by mature karstification. The karst aquifer is characterized by allogenic recharge mainly from the River Deskatis that accounts for up to 92% of the total flow. Groundwater and spring water are generally characterized as good quality and are suitable for irrigation and domestic use. The water type of the spring water is classified as Mg-HCO3. The application of a SARIMA (Seasonal Autoregressive Integrated Moving Average Model) model verified the conceptual model and successfully simulated spring discharge for a two-year period. The results of this study highlight the importance of basic hydrogeological research and the initial conceptualization of karst systems in reliably assessing groundwater vulnerability and modeling.

scholarly journals Hydrogeochemical Properties Providing Links to Methanogenesis in Deep Aquifer of Bhola Island, Bangladesh

2019 ◽  
Vol 45 (2) ◽  
pp. 217-228
Author(s):  
Masuma Chowdhury ◽  
Sarmin Sultana ◽  
Md Atikul Islam ◽  
Aziz Hasan ◽  
Kazi Matin Uddin Ahmed
Keyword(s):  
Geothermal Gradient ◽  
Water Type ◽  
Gas Generation ◽  
Deep Aquifer ◽  
Upward Migration ◽  
Methane Generation ◽  
Biogenic Methane ◽  
Low Concentrations ◽  
Groundwater Samples ◽  
Favourable Environment

This paper compares the hydrogeochemical signatures between naturally flowing wells with methane (FWs) and non-flowing wells (require pumping) without methane (NFWs) by analyzing a total of 59 groundwater samples to find possible links for methane gas generation. Relatively higher concentration of HCO3 ⁻ indicates oxidation of organic matter (OM) for both the cases which is corroborated by the dominance of Na-Mg-HCO3 and Na- Mg-HCO3-Cl water type. Low concentrations of redox sensitive parameters i.e., NO3 ⁻, SO4 2⁻, Fe2+ and Mn2+ are indicating prevalence of extremely reducing condition and relatively lower concentrations of SO₄²⁻ in FWs suggest microbial sulphate reduction reaching final stage of redox ladder i.e., methanogenesis. Comparatively higher temperature and subsequent higher electrical conductivity (EC) in FWs possibly attributed by the chemical reactions of methane generation or vice versa. Low geothermal gradient, presence of OM and distribution of the FWs over a paleo valley in the deep confined aquifer zone refer to the existence of favourable environment for biogenic methane production rather than the upward migration or leakage of thermogenic gas from the reservoir below. Asiat. Soc. Bangladesh, Sci. 45(2): 217-228, December 2019

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