scholarly journals Expanded Application of the Passive Flux Meter: In-Situ Measurements of 1,4-Dioxane, Sulfate, Cr(VI) and RDX

Water ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1335 ◽  
Author(s):  
Alexander Haluska ◽  
Meghan Thiemann ◽  
Patrick Evans ◽  
Jaehyun Cho ◽  
Michael Annable
Keyword(s):  
Inorganic Ions ◽  
Contaminated Sites ◽  
Chromium Vi ◽  
Reducing Conditions ◽  
Uptake Rates ◽  
Consumption Rates ◽  
Flux Measurements ◽  
Passive Flux Meter ◽  
Ion Species

Passive flux meters (PFMs) have become invaluable tools for site characterization and evaluation of remediation performance at groundwater contaminated sites. To date, PFMs technology has been demonstrated in the field to measure midrange hydrophobic contaminants (e.g., chlorinated ethenes, fuel hydrocarbons, perchlorate) and inorganic ions (e.g., uranium and nitrate). However, flux measurements of low partitioning contaminants (e.g., 1,4-dioxane, hexahydro-1,3,5-trinitro-s-triazine (RDX)) and reactive ions-species (e.g., sulfate (SO42−), Chromium(VI) (Cr(VI)) are still challenging because of their low retardation during transport and quick transformation under highly reducing conditions, respectively. This study is the first application of PFMs for in-situ mass flux measurements of 1,4-dioxane, RDX, Cr(VI) and SO42− reduction rates. Laboratory experiments were performed to model kinetic uptake rates and extraction efficiency for sorbent selections. Silver impregnated granular activated carbon (GAC) was selected for the capture of 1,4-dioxane and RDX, whereas Purolite 300A (Bala Cynwyd, PA, USA) was selected for Cr(VI) and SO42−. PFM field demonstrations measured 1,4-dioxane fluxes ranging from 13.3 to 55.9 mg/m2/day, an RDX flux of 4.9 mg/m2/day, Cr(VI) fluxes ranging from 2.3 to 2.8 mg/m2/day and SO42− consumption rates ranging from 20 to 100 mg/L/day. This data suggests other low-partitioning contaminates and reactive ion-species could be monitored using the PFM.

Expanded application of the Passive Flux Meter: in-situ measurements of 1,4-dioxane, sulfate, Cr(VI), and RDX

2018 ◽  
Author(s):  
Alexander Haluska ◽  
Meghan Thiemann ◽  
Patrick Evans ◽  
Jaehyun Cho ◽  
Mike Annable
Keyword(s):  
Inorganic Ions ◽  
Contaminated Sites ◽  
Chromium Vi ◽  
Reducing Conditions ◽  
Uptake Rates ◽  
Consumption Rates ◽  
Flux Measurements ◽  
Passive Flux Meter ◽  
Ion Species

Passive flux meters (PFMs) have become invaluable tools for site characterization and evaluation of remediation performance at groundwater contaminated sites. To date, PFMs technology has been demonstrated in the field to measure low - to midrange hydrophobic contaminants (e.g., chlorinated ethenes, fuel hydrocarbons, perchlorate) and inorganic ions (e.g., uranium and nitrate). However, flux measurements of a low partitioning contaminant (e.g., 1,4-dioxane, hexahydro-1,3,5-trinitro-s-triazine (RDX)) and reactive ions-species (e.g., sulfate (SO42-), Chromium(VI) (Cr(VI)) are still challenging because of their low retardation during transport and quick transformation under highly reducing conditions, respectively. This study comprises the first application of PFMs for the in-situ mass flux measurements of 1,4-Dioxane, RDX, Cr(VI) and SO42- reduction rates. Laboratory experiments were performed to model kinetic uptake rates and extraction efficiency for sorbent selections. Silver impregnated granular activated carbon (GAC) was selected for capture of 1,4-Dioxane and RDX, whereas Purolite 300A was selected for chromium and SO42-. PFM field demonstrations measured 1,4-Dioxane fluxes ranging from 13.3 to 55.9 mg/m2/day, an RDX flux of 4.9 mg/m2/day, Cr(VI) fluxes ranging from 2.3 to 2.8 mg/m2/day, and SO42- consumption rates ranging from 20 to 100 mg/L/day. These data suggest other low-partitioning contaminates and reactive ion-species could be monitored using the PFM.

scholarly journals Phosphate Induced Arsenic Mobilization as a Potentially Effective In-Situ Remediation Technique—Preliminary Column Tests

Water ◽  
2019 ◽  
Vol 11 (11) ◽  
pp. 2364
Author(s):  
Martin V. Maier ◽  
Yvonne Wolter ◽  
Daniel Zentler ◽  
Christian Scholz ◽  
Charlotte N. Stirn ◽  
...  
Keyword(s):  
Microbial Activity ◽  
Ph Value ◽  
Surface Complexation ◽  
Contaminated Sites ◽  
Contaminated Site ◽  
Anoxic Conditions ◽  
Arsenic Mobility ◽  
Pump And Treat ◽  
Reducing Conditions

Arsenic (As) contamination of groundwater is commonly remediated by pump and treat. However, this technique is difficult to apply or maintain efficiently because the mobility of arsenic varies depending on the geochemical aquifer conditions. Arsenic interacting with the sediment can cause strong retardation, which is counteracted by ions competing for sedimentary sorption sites like silica, bicarbonate and phosphate. Phosphate competes most effectively with arsenic for sorption sites due to its chemical similarity. To accelerate an ongoing but ineffective pump and treat remediation, we examined the competitive effect of increasing phosphate doses on contaminated aquifer material of different depths and thus under distinct geochemical conditions. In the columns with phosphate addition, significant amounts of arsenic were released rapidly under oxic and anoxic conditions. In all tests, the grade of leaching was higher under anoxic conditions than under oxic conditions. As(III) was the dominant species, in particular during the first release peaks and the anoxic tests. Higher amounts of phosphate did not trigger the arsenic release further and led to a shift of arsenic species. We suggest that the competitive surface complexation is the major process of arsenic release especially when higher amounts of phosphate are used. Commonly arsenic release is described at iron reducing conditions. In contrast, we observed that a change in prevailing redox potential towards manganese reducing conditions in the oxic tests and iron reducing conditions in the anoxic column took place later and thus independently of arsenic release. The reduction of As(V) to As(III) under both redox conditions is presumed to be an effect of microbial detoxification. A loss of sulphate in all columns with phosphate indicates an increased microbial activity, which might play a significant role in the process of arsenic release. Preliminary tests with sediment material from a contaminated site showed that phosphate additions did not change the pH value significantly. Therefore, a release of other metals is not likely. Our results indicate that in-situ application of phosphate amendments to arsenic-contaminated sites could accelerate and enhance arsenic mobility to improve the efficiency of pump and treat remediation without negative side effects. The novelty of this approach is the use of only small amounts of phosphate in order to stimulate microbial activity in addition to surface complexation. Therefore, this method might become an innovative and cost-effective remediation for arsenic contaminated sites.

scholarly journals Microbial N2O consumption in and above marine N2O production hotspots

2020 ◽  
Author(s):  
Xin Sun ◽  
Amal Jayakumar ◽  
John C. Tracey ◽  
Elizabeth Wallace ◽  
Colette L. Kelly ◽  
...  
Keyword(s):  
Kinetic Parameters ◽  
Substrate Affinity ◽  
N2o Production ◽  
Anoxic Waters ◽  
Production And Consumption ◽  
Consumption Rates ◽  
Anoxic Zones ◽  
First Time ◽  
Microbial N

AbstractThe ocean is a net source of N2O, a potent greenhouse gas and ozone-depleting agent. However, the removal of N2O via microbial N2O consumption is poorly constrained and rate measurements have been restricted to anoxic waters. Here we expand N2O consumption measurements from anoxic zones to the sharp oxygen gradient above them, and experimentally determine kinetic parameters in both oxic and anoxic seawater for the first time. We find that the substrate affinity, O2 tolerance, and community composition of N2O-consuming microbes in oxic waters differ from those in the underlying anoxic layers. Kinetic parameters determined here are used to model in situ N2O production and consumption rates. Estimated in situ rates differ from measured rates, confirming the necessity to consider kinetics when predicting N2O cycling. Microbes from the oxic layer consume N2O under anoxic conditions at a much faster rate than microbes from anoxic zones. These experimental results are in keeping with model results which indicate that N2O consumption likely takes place above the oxygen deficient zone (ODZ). Thus, the dynamic layer with steep O2 and N2O gradients right above the ODZ is a previously ignored potential gatekeeper of N2O and should be accounted for in the marine N2O budget.

scholarly journals A Green Microbial Fuel Cell-Based Biosensor for In Situ Chromium (VI) Measurement in Electroplating Wastewater

Sensors ◽  
2017 ◽  
Vol 17 (11) ◽  
pp. 2461 ◽  
Author(s):  
Li-Chun Wu ◽  
Teh-Hua Tsai ◽  
Man-Hai Liu ◽  
Jui-Ling Kuo ◽  
Yung-Chu Chang ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
Electroplating Wastewater ◽  
Chromium Vi

scholarly journals Effect of incubation time and substrate concentration on N-uptake rates by phytoplankton in the Bay of Bengal

2005 ◽  
Vol 2 (5) ◽  
pp. 1331-1352
Author(s):  
S. Kumar ◽  
R. Ramesh ◽  
S. Sardesai ◽  
M. S. Sheshshayee
Keyword(s):  
Incubation Time ◽  
Uptake Rate ◽  
Nitrate Uptake ◽  
N Uptake ◽  
Marine Phytoplankton ◽  
Total Production ◽  
New Production ◽  
Urea Uptake ◽  
Uptake Rates

Abstract. We report here the results of three experiments, which are slight variations of the 15N method (JGOFS protocol) for determination of new production. The first two test the effect of (i) duration of incubation time and (ii) concentration of tracer added on the uptake rates of various N-species (nitrate, ammonium and urea) by marine phytoplankton; while the third compares in situ and deck incubations from dawn to dusk. Results indicate that nitrate uptake can be underestimated by experiments where incubation times shorter than 4h or when more than 10% of the ambient concentration of nitrate is added prior to incubation. The f-ratio increases from 0.28 to 0.42 when the incubation time increases from two to four hours. This may be due to the observed increase in the uptake rate of nitrate and decrease in the urea uptake rate. Unlike ammonium [y{=}2.07x{-}0.002\\, (r2=0.55)] and urea uptakes [y{=}1.88x{+}0.004 (r2=0.88)], the nitrate uptake decreases as the concentration of the substrate (x) increases, showing a negative correlation [y{=}-0.76x+0.05 (r2=0.86)], possibly due to production of glutamine, which might suppress nitrate uptake. This leads to decline in the f-ratio from 0.47 to 0.10, when concentration of tracer varies from 0.01 to 0.04μ M. The column integrated total productions are 519 mg C m-2 d-1 and 251 mg C m-2 d-1 for in situ and deck incubations, respectively. The 14C based production at the same location is ~200 mg C m-2 d-1, which is in closer agreement to the 15N based total production measured by deck incubation.

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