scholarly journals Advances in Nanocatalysts Mediated Biodiesel Production: A Critical Appraisal

Symmetry ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 256 ◽  
Author(s):  
Avinash P. Ingle ◽  
Anuj K. Chandel ◽  
Rafael Philippini ◽  
Sabrina Evelin Martiniano ◽  
Silvio Silvério da Silva
Keyword(s):  
Biodiesel Production ◽  
Low Carbon ◽  
Carbon Footprints ◽  
Animal Fats ◽  
Nano Catalyst ◽  
Petroleum Resources ◽  
Excessive Consumption ◽  
Price Instability ◽  
Selective Reactivity ◽  
Catalytic Chemistry

The excessive consumption of petroleum resources leads to global warming, fast depletion of petroleum reserves, as well as price instability of gasoline. Thus, there is a strong need for alternative renewable fuels to replace petroleum-derived fuels. The striking features of an alternative fuel include the low carbon footprints, renewability and affordability at manageable prices. Biodiesel, made from waste oils, animal fats, vegetal oils, is a totally renewable and non-toxic liquid fuel which has gained significant attraction in the world. Due to technological advancements in catalytic chemistry, biodiesel can be produced from a variety of feedstock employing a variety of catalysts and recovery technologies. Recently, several ground-breaking advancements have been made in nano-catalyst technology which showed the symmetrical correlation with cost competitive biodiesel production. Nanocatalysts have unique properties such as their selective reactivity, high activation energy and controlled rate of reaction, easy recovery and recyclability. Here, we present an overview of various feedstock used for biodiesel production, their composition and characteristics. The major focus of this review is to appraise the characterization of nanocatalysts, their effect on biodiesel production and methodologies of biodiesel production.

Biodiesel production from non-edible oils: A review

2020 ◽  
pp. 149-159
Author(s):  
Jatinder Kataria ◽  
Saroj Kumar Mohapatra ◽  
Amit Pal
Keyword(s):  
Environmental Impact ◽  
Energy Demand ◽  
Fossil Fuels ◽  
World Wide ◽  
Edible Oils ◽  
Control Measure ◽  
Biodiesel Production ◽  
Pollution Level ◽  
Animal Fats ◽  
The World

The limited fossil reserves, spiraling price and environmental impact due to usage of fossil fuels leads the world wide researchers’ interest in using alternative renewable and environment safe fuels that can meet the energy demand. Biodiesel is an emerging renewable alternative fuel to conventional diesel which can be produced from both edible and non-edible oils, animal fats, algae etc. The society is in dire need of using renewable fuels as an immediate control measure to mitigate the pollution level. In this work an attempt is made to review the requisite and access the capability of the biodiesel in improving the environmental degradation.

EXPRESS: Sustainable by Design: Choice Architecture and the Carbon Footprint of Grocery Shopping

2021 ◽  
pp. 074391562110088
Author(s):  
Luca Panzone ◽  
Alistair Ulph ◽  
Denis Hilton ◽  
Ilse Gortemaker ◽  
Ibrahim Tajudeen
Keyword(s):  
Carbon Footprint ◽  
Carbon Tax ◽  
Food Products ◽  
Grocery Shopping ◽  
Choice Architecture ◽  
Low Carbon ◽  
Policy Objective ◽  
Carbon Footprints ◽  
Design Choice ◽  
Goal Priming

The increase in global temperatures requires substantial reductions in the greenhouse emissions from consumer choices. We use an experimental incentive-compatible online supermarket to analyse the effect of a carbon-based choice architecture, which presents commodities to customers in high, medium and low carbon footprint groups, in reducing the carbon footprints of grocery baskets. We relate this choice architecture to two other policy interventions: a bonus-malus carbon tax on all grocery products; and moral goal priming, using an online banner noting the moral importance of reducing one’s carbon footprint. Participants shopped from their home in an online store containing 612 existing food products and 39 existing non-food products for which we had data on carbon footprint, over three successive weeks, with the interventions occurring in the second and third weeks. Choice architecture reduced carbon footprint significantly in the third week by reducing the proportion of choices made in the high-carbon aisle. The carbon tax reduced carbon footprint in both weeks, primarily by reducing overall spend. The goal priming banner led to a small reduction in carbon footprint in the second week only. Thus, the design of the marketplace plays an important role in achieving the policy objective of reducing greenhouse gas emissions.

scholarly journals Biodiesel Production from Melia azedarach and Ricinus communis Oil by Transesterification Process

Catalysts ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 427 ◽  
Author(s):  
Muhammad Awais ◽  
Sa’ed A Musmar ◽  
Faryal Kabir ◽  
Iram Batool ◽  
Muhammad Asif Rasheed ◽  
...  
Keyword(s):  
Ricinus Communis ◽  
Cost Effective ◽  
Biodiesel Production ◽  
Molar Ratio ◽  
Melia Azedarach ◽  
Renewable Fuel ◽  
Animal Fats ◽  
Edible Crops ◽  
American Society

Biodiesel is a renewable fuel usually produced from vegetable oils and animal fats. This study investigates the extraction of oil and its conversion into biodiesel by base-catalyzed transesterification. Firstly, the effect of various solvents (methanol, n-hexane, chloroform, di-ethyl ether) on extraction of oil from non-edible crops, such as R. communis and M. azedarach, were examined. It was observed that a higher concentration of oil was obtained from R. communis (43.6%) as compared to M. azedarach (35.6%) by using methanol and n-hexane, respectively. The extracted oils were subjected to NaOH (1%) catalyzed transesterification by analyzing the effect of oil/methanol molar ratio (1:4, 1:6, 1:8 and 1:10) and varying temperature (20, 40, 60 and 80 °C) for 2.5 h of reaction time. M. azedarach yielded 88% and R. communis yielded 93% biodiesel in 1:6 and 1:8 molar concentrations at ambient temperature whereas, 60 °C was selected as an optimum temperature, giving 90% (M. azedarach) and 94% (R. communis) biodiesel. The extracted oil and biodiesel were characterized for various parameters and most of the properties fulfilled the American Society for Testing and Materials (ASTM) standard biodiesel. The further characterization of fatty acids was done by Gas Chromatography/Mass Spectrometer (GC/MS) and oleic acid was found to be dominant in M. azedarach (61.5%) and R. communis contained ricinoleic acid (75.53%). Furthermore, the functional groups were analyzed by Fourier Transform Infrared Spectroscopy. The results suggested that both of the oils are easily available and can be used for commercial biodiesel production at a cost-effective scale.

Optimized Preparation of Moringa Oleifera Methyl Esters Using Sulfated Tin Oxide as Heterogenous Catalyst

2010 ◽  
Author(s):  
Gerald Kafuku ◽  
Makme Mbarawa ◽  
Man Kee Lam ◽  
Keat Teong Lee
Keyword(s):  
Tin Oxide ◽  
Heterogeneous Catalysts ◽  
Moringa Oleifera ◽  
Methyl Esters ◽  
Biodiesel Production ◽  
Solid Catalyst ◽  
Separation And Purification ◽  
Animal Fats ◽  
Super Acid ◽  
Moringa Oleifera Oil

Fatty acid methyl esters (biodiesel), prepared from transesterification of vegetable oils or animal fats, have gained great importance in substituting petroleum based diesel for combating environmental problems and higher diesel prices. Moringa oleifera fatty acids are among the newly investigated potentials for biodiesel production in recent years. In getting rid of soap formation and thus large waste washing water from biodiesel produced from homogenous catalysts, the use of heterogeneous catalysts is currently preferred due to easily separation and purification of the final products. In this study, biodiesel was produced from moringa oleifera oil using sulfated tin oxide enhanced with SiO2 (SO42−/SnO2−SiO2) as super acid solid catalyst. The experimental design was done using design of experiment (DoE), specifically, response surface methodology based on three-variable central composite design (CCD) with alpha (α) = 2. The reaction parameters in the optimization process were reaction temperature (60°C to 180°C), reaction period (1 to 3 hrs) and methanol to oil ratio (1:6 to 1:24 mol/mol). It was observed that the yield up to 84wt% of moringa oleifera methyl esters can be obtained with reaction conditions of 150°C temperature, 150 minutes reaction time and 1:19.5 methanol to oil ratio, while catalyst concentration and agitation speed are kept at 3wt% and 350 rpm respectively.

scholarly journals Product carbon footprints as tool for a low-carbon economy

2008 ◽  
Vol 23 (3) ◽  
Author(s):  
Fritz Reusswig
Keyword(s):  
Global Warming ◽  
Greenhouse Gas Emissions ◽  
Greenhouse Gas ◽  
Low Carbon ◽  
Emission Reductions ◽  
Carbon Footprints ◽  
Low Carbon Economy ◽  
Formidable Challenge ◽  
Social Innovations ◽  
Carbon Economy

Stabilizing greenhouse gas emissions at a level that prevents a global warming beyond plus two degree celsius is a formidable challenge. The required emission reductions can only be achieved by a series of technological, organizational and social innovations.

scholarly journals Sunflower Genotype Selection for Oil Production in the Pre-Amazon Region of Brazil

2019 ◽  
Vol 11 (8) ◽  
pp. 248
Author(s):  
Francirose Shigaki ◽  
Ludhanna Marinho Veras ◽  
Elane Tyara de Jesus Siqueira ◽  
José Roberto Brito Freitas ◽  
Mayanna Karlla Lima Costa ◽  
...  
Keyword(s):  
Experimental Period ◽  
Climatic Conditions ◽  
Amazon Region ◽  
Biodiesel Production ◽  
Alternative Source ◽  
Animal Fats ◽  
Oil Crops ◽  
Energy Needs ◽  
High Production ◽  
Alternative Sources

Part of the energy consumed in the world comes from limited sources, which eventually are expected to be depleted. The search for alternative sources to meet energy needs is crucial. Biodiesel derived from vegetable oils and animal fats stands out as a biodegradable and renewable alternative source of energy. Sunflower is among the top four oil crops produced worldwide, and Brazil has a high production potential for this crop. This study aimed to identify the sunflower genotypes with the highest potential for biodiesel production in the Pre-amazon region of Brazil, where the advance of agricultural frontier represents an important role on biodiesel production. This study was conducted over 2 years of observations. The following genotypes were used: M734 (T), Helio358, EMBRAPA 122, and BRS G 35. The following parameters were assessed: initial flowering date (IFD), physiological maturity date (PMD), plant height (PH), grain yield (YIELD), thousand achene weight (TAW), and oil content (%OC). The climatic conditions of each experimental period were distinctive and directly affected the results obtained. The genotype Embrapa 122 showed the best performance regarding yield and was recommended for the pre-Amazon region of Brazil as the best adapted genotype to the local environmental conditions.

scholarly journals Pre-Treatment of Waste Frying Oils for Biodiesel Production

2015 ◽  
Vol 9 (7) ◽  
pp. 99 ◽  
Author(s):  
Nyoman Puspa Asri ◽  
Diah Agustina Puspita Sari
Keyword(s):  
Raw Materials ◽  
Batch Reactor ◽  
Biodiesel Production ◽  
Molar Ratio ◽  
High Price ◽  
Composite Catalyst ◽  
Frying Oils ◽  
Animal Fats ◽  
Waste Frying Oils ◽  
Pre Treatment

Synthesis of biodiesel is a strategic step in overcoming energy scarcity and the environmental degradationcaused by the continuous use of the petroleum based energy. Biodiesel as an alternative fuel for diesel engine isproduced from renewable resources such as vegetable oils and animal fats. The main obstacle in the biodieselproduction is the high price of the raw materials, resulting in the price of biodiesel is not competitive comparedto the petroleum diesel. Therefore, the use of waste frying oils (WFO) is one way to reduce the cost of biodieselproduction, because of its availability and low price. In the present work, WFO from California Fried chicken(CFC) restaurants in Surabaya were used as feed stock for the biodiesel production. The experiments wereconducted using three steps of processes: pre-treatment of WFO, preparation of alumina based compositecatalyst CaO/KI/γ-Al2O3 and transesterification of treated WFO. WFO was treated by several types and variousamounts of activated adsobents. The treated WFO was transesterified in three neck glass batch reactor withrefluxed methanol using CaO/KI/γ-Al2O3. The results reveal that the best method for treating WFO is using 7.5%(wt. % to WFO) of coconut coir. Alumina based composite catalyst CaO/KI/γ-Al2O3 was very promising fortransesterification of WFO into biodiesel. The yield of biodiesel was 83% and obtained at 65ºC, 5 h of reactiontime, 1:18 of molar ratio WFO to methanol and 6% amount of catalyst.

Synthesis of Biodiesel from Neem Oil Using Mg-Al Nano Hydrotalcite

2013 ◽  
Vol 678 ◽  
pp. 268-272 ◽  
Author(s):  
R. Manivannan ◽  
C. Karthikeyan
Keyword(s):  
Methyl Esters ◽  
Biodiesel Production ◽  
Molar Ratio ◽  
Solid Base ◽  
Neem Oil ◽  
Solid Base Catalysts ◽  
Animal Fats ◽  
Base Catalysts ◽  
Benign Process ◽  
Nano Catalysts

Abstract Methyl ester of fatty acids, derived from vegetable oils or animal fats are known as biodiesel. The most common method of biodiesel production is transesterification (alcoholysis) of oil (triglycerides) with methanol in the presence of a catalyst which gives biodiesel (fatty acid methyl esters, FAME) and glycerol (by product). In this work, an environmentally benign process for the methanolysis of neem oil to methyl esters using Mg–Al nano hydrotalcites as solid base catalysts in a heterogeneous manner was developed. The effect of the reaction temperature, reaction time, catalyst amount, and methanol /oil molar ratio on the Mg-Al nano hydrotalcite was analyzed. The nano catalysts were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM). Biodiesel produced from the neem oil by using Mg-Al nano hydrotalcite catalyst was analyzed by gas chromatography.

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