scholarly journals The Influence of a Network’s Spatial Symmetry, Topological Dimension, and Density on Its Percolation Threshold

Symmetry ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 920 ◽  
Author(s):  
Dmitry O. Zhukov ◽  
Elena G. Andrianova ◽  
Sergey A. Lesko

Analyses of the processes of information transfer within network structures shows that the conductivity and percolation threshold of the network depend not only on its density (average number of links per node), but also on its spatial symmetry groups and topological dimension. The results presented in this paper regarding conductivity simulation in network structures show that, for regular and random 2D and 3D networks, an increase in the number of links (density) per node reduces their percolation threshold value. At the same network density, the percolation threshold value is less for 3D than for 2D networks, whatever their structure and symmetry may be. Regardless of the type of networks and their symmetry, transition from 2D to 3D structures engenders a change of percolation threshold by a value exp{−(d − 1)} that is invariant for transition between structures, for any kind of network (d being topological dimension). It is observed that in 2D or 3D networks, which can be mutually transformed by deformation without breaking and forming new links, symmetry of similarity is observed, and the networks have the same percolation threshold. The presence of symmetry axes and corresponding number of symmetry planes in which they lie affects the percolation threshold value. For transition between orders of symmetry axes, in the presence of the corresponding planes of symmetry, an invariant exists which contributes to the percolation threshold value. Inversion centers also influence the value of the percolation threshold. Moreover, the greater the number of pairs of elements of the structure which have inversion, the more they contribute to the fraction of the percolation threshold in the presence of such a center of symmetry. However, if the center of symmetry lies in the plane of mirror symmetry separating the layers of the 3D structure, the mutual presence of this group of symmetry elements do not affect the percolation threshold value. The scientific novelty of the obtained results is that for different network structures, it was shown that the percolation threshold for the blocking of nodes problem could be represented as an additive set of invariant values, that is, as an algebraic sum, the value of the members of which is stored in the transition from one structure to another. The invariant values are network density, topological dimension, and some of the elements of symmetry (axes of symmetry and the corresponding number of symmetry planes in which they lie, centers of inversion).

2021 ◽  
Author(s):  
Ohjin Kwon ◽  
Xiaoqian Cai ◽  
Azhar Saeed ◽  
Feng Liu ◽  
Silvio Poppe ◽  
...  

Achiral multi-chain (polycatenar) compounds based on the 2,7-diphenyl substituted [1]benzothieno[3,2-b]benzothiophene (BTBT) unit and a 2,6-dibromo-3,4,5-trialkoxybenzoate end group lead to materials forming bicontinuous cubic liquid crystaline phases with helical network structures...


2020 ◽  
Vol 76 (6) ◽  
pp. 605-615
Author(s):  
Yong-Jin Zhao ◽  
Jian-Ping Ma ◽  
Jianzhong Fan ◽  
Yan Geng ◽  
Yu-Bin Dong

The tridentate organic ligand 4,4′,4′′-(4,4,8,8,12,12-hexamethyl-8,12-dihydro-4H-benzo[9,1]quinolizino[3,4,5,6,7-defg]acridine-2,6,10-triyl)tribenzoic acid (H3L) has been synthesized (as the methanol 1.25-solvate, C48H39NO6·1.25CH3OH). As a donor–acceptor motif molecule, H3L possess strong intramolecular charge transfer (ICT) fluorescence. Through hydrogen bonds, H3L molecules construct a two-dimensional (2D) network, which pack together into three-dimensional (3D) networks with an ABC stacking pattern in the crystalline state. Based on H3L and M(NO3)2 salts (M = Cd and Zn) under solvothermal conditions, two metal–organic frameworks (MOFs), namely, catena-poly[[triaquacadmium(II)]-μ-10-(4-carboxyphenyl)-4,4′-(4,4,8,8,12,12-hexamethyl-8,12-dihydro-4H-benzo[9,1]quinolizino[3,4,5,6,7-defg]acridine-2,6-diyl)dibenzoato], [Cd(C48H37NO6)(H2O)3] n , I, and poly[[μ3-4,4′,4′′-(4,4,8,8,12,12-hexamethyl-8,12-dihydro-4H-benzo[9,1]quinolizino[3,4,5,6,7-defg]acridine-2,6,10-triyl)tribenzoato](μ3-hydroxido)zinc(II)], [Zn2(C48H36NO6)(OH)] n , II, were synthesized. Single-crystal analysis revealed that both MOFs adopt a 3D structure. In I, partly deprotonated HL 2− behaves as a bidentate ligand to link a CdII ion to form a one-dimensional chain. In the solid state of I, the existence of weak interactions, such as O—H...O hydrogen bonds and π–π interactions, plays an essential role in aligning 2D nets and 3D networks with AB packing patterns for I. The deprotonated ligand L 3− in II is utilized as a tridentate building block to bind ZnII ions to construct 3D networks, where unusual Zn4O14 clusters act as connection nodes. As a donor–acceptor molecule, H3L exhibits fluorescence with a photoluminescence quantum yield (PLQY) of 70% in the solid state. In comparison, the PL of both MOFs is red-shifted with even higher PLQYs of 79 and 85% for I and II, respectively.


Entropy ◽  
2019 ◽  
Vol 21 (5) ◽  
pp. 517
Author(s):  
Edgar Baeza-Blancas ◽  
Bibiana Obregón-Quintana ◽  
Candelario Hernández-Gómez ◽  
Domingo Gómez-Meléndez ◽  
Daniel Aguilar-Velázquez ◽  
...  

We present a study of natural language using the recurrence network method. In our approach, the repetition of patterns of characters is evaluated without considering the word structure in written texts from different natural languages. Our dataset comprises 85 ebookseBooks written in 17 different European languages. The similarity between patterns of length m is determined by the Hamming distance and a value r is considered to define a matching between two patterns, i.e., a repetition is defined if the Hamming distance is equal or less than the given threshold value r. In this way, we calculate the adjacency matrix, where a connection between two nodes exists when a matching occurs. Next, the recurrence network is constructed for the texts and some representative network metrics are calculated. Our results show that average values of network density, clustering, and assortativity are larger than their corresponding shuffled versions, while for metrics like such as closeness, both original and random sequences exhibit similar values. Moreover, our calculations show similar average values for density among languages which that belong to the same linguistic family. In addition, the application of a linear discriminant analysis leads to well-separated clusters of family languages based on based on the network-density properties. Finally, we discuss our results in the context of the general characteristics of written texts.


2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Byung-Gak Son ◽  
Sangho Chae ◽  
Canan Kocabasoglu-Hillmer

PurposeCatastrophic supply chain disruptions can significantly damage the operational and financial performance of firms. While a growing body of literature on supply network structures has studied what influences supply networks' vulnerability to supply chain disruptions and capability to recover from them, it remains unclear how supply network structures change after major supply chain disruptions. We aim to provide an understanding of how these changes occur.Design/methodology/approachUsing a natural experiment approach and supply network data from Factset, this study investigates how firms' supply network structures change after experiencing the catastrophic supply chain disruptions caused by the 2011 Tohoku earthquake and tsunami in Japan. We capture post-earthquake supply network changes using the measures of degree centrality and ego network density.FindingsThe results of the analysis suggest that compared to unaffected firms, the affected firms experience changes in their supply network structures tending toward lower complexity measured by in-degree centrality, out-degree centrality and ego network density.Originality/valueThis study contributes to social network theory and the complex adaptive supply network literature by providing empirical evidence of structural changes in supply networks after catastrophic supply chain disruptions. A managerial contribution is made by providing a reflection on why these changes might be occurring and alert firms to the challenges of managing complexity in their supply networks.


2021 ◽  
Vol 118 (46) ◽  
pp. e2109921118
Author(s):  
Daeho Sung ◽  
Chan Lim ◽  
Masatoshi Takagi ◽  
Chulho Jung ◽  
Heemin Lee ◽  
...  

DNA molecules are atomic-scale information storage molecules that promote reliable information transfer via fault-free repetitions of replications and transcriptions. Remarkable accuracy of compacting a few-meters-long DNA into a micrometer-scale object, and the reverse, makes the chromosome one of the most intriguing structures from both physical and biological viewpoints. However, its three-dimensional (3D) structure remains elusive with challenges in observing native structures of specimens at tens-of-nanometers resolution. Here, using cryogenic coherent X-ray diffraction imaging, we succeeded in obtaining nanoscale 3D structures of metaphase chromosomes that exhibited a random distribution of electron density without characteristics of high-order folding structures. Scaling analysis of the chromosomes, compared with a model structure having the same density profile as the experimental results, has discovered the fractal nature of density distributions. Quantitative 3D density maps, corroborated by molecular dynamics simulations, reveal that internal structures of chromosomes conform to diffusion-limited aggregation behavior, which indicates that 3D chromatin packing occurs via stochastic processes.


2017 ◽  
Vol 2017 ◽  
pp. 1-9 ◽  
Author(s):  
Basheer A. Alshammari ◽  
Arthur N. Wilkinson ◽  
Ghzzai Almutairi

Graphite nanoplatelets (GNP) were incorporated with poly(ethylene terephthalate) (PET) matrix by melt-compounding technique using minilab compounder to produce PET-GNP nanocomposites, and then the extruded nanocomposites were compressed using compression molding to obtain films of 1 mm thickness. Percolation threshold value was determined using percolation theory. The electrical conductivity, morphology, and thermal behaviors of these nanocomposites were investigated at different contents of GNP, that is, below, around, and above its percolation threshold value. The results demonstrated that the addition of GNP at loading >5 wt.% made electrically conductive nanocomposites. An excellent electrical conductivity of ~1 S/m was obtained at 15 wt.% of GNP loading. The nanocomposites showed a typical insulator-conductor transition with a percolation threshold value of 5.7 wt.% of GNP. In addition, increasing screw speed enhanced the conductivity of the nanocomposites above its threshold value by ~2.5 orders of magnitude; this behavior is attributed to improved dispersion of these nanoparticles into the PET matrix. Microscopies results exhibited no indication of aggregations at 2 wt.% of GNP; however, some rolling up at 6 wt.% of GNP contents was observed, indicating that a conductive network has been formed, whereas more agglomeration and rolling up could be seen as the GNP content is increased in the PET matrix. These agglomerations reduced their aspect ratio and then reduced their reinforcement efficiency. NP loading (>2 wt.%) increased degree of crystallinity and improved thermal stability of matrix slightly, suggesting that 2 wt.% of GNP is more than enough to nucleate the matrix.


2011 ◽  
Vol 25 (19) ◽  
pp. 2543-2556 ◽  
Author(s):  
MALTI BANSAL ◽  
RITU SRIVASTAVA ◽  
C. LAL ◽  
M. N. KAMALASANAN ◽  
L. S. TANWAR

Carbon nanotubes have been the subject of extensive research during the past decade because of their exceptional properties. These tiny nanostructures have eventually paved their way into the exciting and promising field of organic electronics, which is expected to dominate the area of low cost and flexible electronics in the near future. We have prepared multiwall carbon nanotube (MWNT) and poly(3,4-ethylenedioxythiophene):poly(styrenesulphonic acid) (PEDOT:PSS) based nanocomposites using different concentrations of MWNTs. These nanocomposites have been characterized using SEM, AFM, absorption spectroscopy, and electrical characterization methods. The SEM micrographs clearly reveal that the nanotubes are quasi uniformly dispersed in huge quantities throughout the polymer matrix. They also show the wetting of the nanotubes by the polymer. It is observed that the solution processed MWNT–PEDOT:PSS nanocomposite based films exhibit improved, higher current, and lower turn-on voltage as compared to pure PEDOT:PSS based films. On the basis of percolation theory, a low electrical percolation threshold value of 0.1 wt% was obtained for this nanocomposite system, signifying the formation of a continuous conductive network at a very low MWNT concentration. The ease of fabrication of the nanocomposite (solution processed), higher current, lower turn-on voltage and low electrical percolation threshold value, make it an excellent candidate for flexible electronics applications, which will dominate the electronics scenario in the near future.


10.37236/320 ◽  
2010 ◽  
Vol 17 (1) ◽  
Author(s):  
Klas Markström ◽  
John C. Wierman

We explicitly construct an uncountable class of infinite aperiodic plane graphs which have equal, and explicitly computable, bond percolation thresholds. Furthermore for both bond percolation and the random-cluster model all large scale properties, such as the values of the percolation threshold and the critical exponents, of the graphs are equal. This equivalence holds for all values of $p$ and all $q\in[0,\infty]$ for the random-cluster model. The graphs are constructed by placing a copy of a rotor gadget graph or its reflection in each hyperedge of a connected self-dual 3-uniform plane hypergraph lattice. The exact bond percolation threshold may be explicitly determined as the root of a polynomial by using a generalised star-triangle transformation. Related randomly oriented models share the same bond percolation threshold value.


Mathematics ◽  
2021 ◽  
Vol 9 (11) ◽  
pp. 1278
Author(s):  
Anton Aleshkin

This paper examines some approaches to modeling and managing traffic flows in modern megapolises and proposes using the methods and approaches of the percolation theory. The author sets the task of determining the properties of the transport network (percolation threshold) when designing such networks, based on the calculation of network parameters (average number of connections per crossroads, road network density). Particular attention is paid to the planarity and nonplanarity of the road transport network. Algorithms for building a planar random network (for modeling purposes) and calculating the percolation thresholds in the resulting network model are proposed. The article analyzes the resulting percolation thresholds for road networks with different relationship densities per crossroad and analyzes the effect of network density on the percolation threshold for these structures. This dependence is specified mathematically, which allows predicting the qualitative characteristics of road network structures (percolation thresholds) in their design. The conclusion shows how the change in the planar characteristics of the road network (with adding interchanges to it) can improve its quality characteristics, i.e., its overall capacity.


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