scholarly journals Enantiomeric Ratio of Amino Acids as a Tool for Determination of Aging and Disease Diagnostics by Chromatographic Measurement

Separations ◽  
2016 ◽  
Vol 3 (4) ◽  
pp. 30 ◽  
Author(s):  
Květa Kalíková ◽  
Tereza Šlechtová ◽  
Eva Tesařová
1999 ◽  
Vol 54 (11) ◽  
pp. 1360-1362 ◽  
Author(s):  
Andreas Böhm ◽  
Thomas Hauck ◽  
Wolfgang Beck

The chiral orthometallated palladium complex (S)-[Pd{C6H4 (CH(CH3)N(CH3)2 )-C,N}Cl]2 (1) can be used as a reagent for the determination of the enantiomeric ratio of α-amino acids. By reaction of 1 with mixtures of several D- and L-α-amino carboxylates diastereoisomers of the α-amino acidato complexes 2a - g are obtained. 1NMR determination of the ratio of the diastereoisomers provides the D/L-ratio of the used D- and L-α-amino carboxylates and is therefore a simple method for the determination of the enantiomeric ratio of α-amino acids.


2021 ◽  
Author(s):  
Eryn Nelson ◽  
Jeffrey S. S. K. Formen ◽  
Christian Wolf

The widespread occurrence and significance of chiral compounds does not only require new methods for their enantioselective synthesis but also efficient tools that allow rapid determination of the absolute configuration,...


1939 ◽  
Vol 129 (1) ◽  
pp. 263-271
Author(s):  
Lloyd E. Thomas ◽  
Janet K. Ingalls ◽  
James Murray Luck
Keyword(s):  

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