scholarly journals Investigation on the Printed CNT-Film-Based Electrochemical Sensor for Detection of Liquid Chemicals

Sensors ◽  
2021 ◽  
Vol 21 (15) ◽  
pp. 5179
Author(s):  
Jaeha Noh ◽  
Sangsu An ◽  
Changhan Lee ◽  
Jiho Chang ◽  
Snagtae Lee ◽  
...  
Keyword(s):  
Electrochemical Sensor ◽  
Electrochemical Sensors ◽  
Mechanical Stability ◽  
Limit Of Detection ◽  
Superior Performance ◽  
Detection Mechanism ◽  
Time Sensitivity ◽  
Sensor Structure ◽  
Optimum Sensor ◽  
Pet Substrate

We studied electrochemical sensors using printed carbon nanotubes (CNT) film on a polyethylene telephtalate (PET) substrate. The mechanical stability of the printed CNT film (PCF) was confirmed by using bending and Scotch tape tests. In order to determine the optimum sensor structure, a resistance-type PCF sensor (R-type PCF sensor) and a comb-type PCF sensor (C-type PCF sensor) were fabricated and compared using a diluted NH3 droplet with various concentrations. The magnitude of response, response time, sensitivity, linearity, and limit of detection (LOD) were compared, and it was concluded that C-type PCF sensor has superior performance. In addition, the feasibility of PCF electrochemical sensor was investigated using 12 kinds of hazardous and noxious substances (HNS). The detection mechanism and selectivity of the PCF sensor are discussed.

scholarly journals Enhanced Performance of GCE/N-Reduced Graphene Oxide-Au Nanocomposite in Dopamine Sensing

Proceedings ◽  
2019 ◽  
Vol 15 (1) ◽  
pp. 41 ◽  
Author(s):  
Minta ◽  
Wiench ◽  
Gryglewicz
Keyword(s):  
Gold Nanoparticles ◽  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Electrochemical Sensors ◽  
Limit Of Detection ◽  
Superior Performance ◽  
Homogeneous Distribution ◽  
Hydrothermal Conditions ◽  
Reduced Graphene ◽  
Working Parameters

The reduced graphene oxide (rGO) and nitrogen-reduced graphene oxide (N-rGO) were electrochemically coated with gold nanoparticles and compared as the modifier of a glassy carbon electrode (GCE) for dopamine (DA) electrochemical sensors. The rGO and N-rGO were prepared by reduction of graphene oxide (GO) under hydrothermal conditions. Urea was applied as a nitrogen dopant. The modified GCEs were tested as working electrodes in the electrochemical DA detection in the presence of ascorbic and uric acids. Initially, the working parameters of sensors in a pure dopamine solution were determined. The GCE/N-rGO-Au electrode exhibited a lower limit of detection compared with the GCE/rGO-Au (385 vs. 700 nM). Both sensors had a wide linear range of 1-100 µM and high sensitivity of 0.78 µA/µM for GCE/N-rGO-Au and 1.78 µA/µM for GCE/rGO-Au. The presence of ascorbic and uric acids in the solution resulted in a decrease in the intensity of DA oxidation peak, maintaining acceptable limit of detection. This study showed that the surface modification of the graphene materials with gold nanoparticles allows to obtain satisfactory working parameters of DA sensors. The GCE/N-rGO-Au demonstrated the superior performance in DA sensing due to a homogeneous distribution of gold nanoparticles on the surface of the N-doped graphene material.

scholarly journals A Facile Electrochemical Sensor Labeled by Ferrocenoyl Cysteine Conjugate for the Detection of Nitrite in Pickle Juice

Sensors ◽  
2019 ◽  
Vol 19 (2) ◽  
pp. 268 ◽  
Author(s):  
Xiao-Zhen Feng ◽  
Annaleizle Ferranco ◽  
Xiaorui Su ◽  
Zhencheng Chen ◽  
Zhiliang Jiang ◽  
...  
Keyword(s):  
Electrochemical Sensor ◽  
Electrochemical Sensors ◽  
Limit Of Detection ◽  
Differential Pulse ◽  
Operating Conditions ◽  
Current Response ◽  
Optimal Operating ◽  
Nitrite Detection ◽  
Pulse Voltammetry ◽  
Lower Overpotential

Simple and facile electrochemical sensors for nitrite detection were fabricated by directly depositing ferrocenoyl cysteine conjugates Fc[CO-Cys(Trt)-OMe]2 [Fc(Cys)2] or Fc[CO-Glu-Cys-Gly-OH] [Fc-ECG] on screen-printed electrodes (SPEs). The modified carbon electrodes were characterized by scanning electron microscopy (SEM), cyclic voltammetry (CV) and differential pulse voltammetry (DPV). Results indicated that Fc-ECG/SPE sensor showed enhanced current response and a lower overpotential than Fc(Cys)2/SPE sensor for nitrite detection. Optimal operating conditions were estimated for nitrite detection by DPV. The concentration of nitrite showed a good linear relationship with the current response in the range of 1.0–50 μmol·L−1 and with 0.3 μmol·L−1 as the concentration for limit of detection. There were no interferences from most common ions. The development of this electrochemical sensor was used for nitrite detection in pickled juice with a R.S.D. lower than 2.1% and average recovery lower than 101.5%, which indicated that disposable electrochemical sensor system can be applied for rapid and precise nitrite detection in foods.

scholarly journals An Electrochemical Sensor Based on Gold-Nanocluster-Modified Graphene Screen-Printed Electrodes for the Detection of β-Lactoglobulin in Milk

Sensors ◽  
2020 ◽  
Vol 20 (14) ◽  
pp. 3956
Author(s):  
Jingyi Hong ◽  
Yuxian Wang ◽  
Liying Zhu ◽  
Ling Jiang
Keyword(s):  
Electrochemical Sensor ◽  
Electrochemical Sensors ◽  
Limit Of Detection ◽  
Gold Nanoclusters ◽  
Enzyme Linked Immunosorbent Assay ◽  
Gold Nanocluster ◽  
Detection Range ◽  
Screen Printed Electrodes ◽  
Β Lactoglobulin ◽  
Screen Printed

A simple and low-cost electrochemical sensor based on multimodified screen-printed electrodes (SPEs) was successfully synthesized for the sensitive detection of β-lactoglobulin (β-Lg). The surface treatment of SPEs was accomplished by a simple drip coating method using polyethyleneimine (PEI), reduced graphene oxide (rGO), and gold nanoclusters (AuNCs), and the treated SPEs showed excellent electrical conductivity. The modified SPEs were then characterized with UV-Vis, SEM, TEM, and FTIR to analyze the morphology and composition of the AuNCs and the rGO. An anti-β-Lg antibody was then immobilized on the composite material obtained by modifying rGO with PEI and AuNCs (PEI-rGO-AuNCs), leading to the remarkable reduction in conductivity of the SPEs due to the reaction between antigen and antibody. The sensor obtained using this novel approach enabled a limit of detection (LOD) of 0.08 ng/mL and a detection range from 0.01 to 100 ng/mL for β-Lg. Furthermore, pure milk samples from four milk brands were measured using electrochemical sensors, and the results were in excellent agreement with those from commercial enzyme-linked immunosorbent assay (ELISA) methods.

scholarly journals A Gravure Printed Flexible Electrochemical Sensor for the Detection of Heavy Metal Compounds

Proceedings ◽  
2018 ◽  
Vol 2 (13) ◽  
pp. 950
Author(s):  
Dinesh Maddipatla ◽  
Binu Narakathu ◽  
Vikram Turkani ◽  
Bradley Bazuin ◽  
Massood Atashbar
Keyword(s):  
Heavy Metal ◽  
Electrochemical Sensor ◽  
Electrical Impedance ◽  
Electrochemical Sensors ◽  
Reference Electrode ◽  
Electrical Impedance Spectroscopy ◽  
Impedance Change ◽  
Metal Compounds ◽  
Heavy Metal Detection ◽  
Pet Substrate

An electrochemical sensor was fabricated on a flexible polyethylene terephthalate (PET) substrate for the detection of cadmium sulfide (CdS), a heavy metal compound. The sensor consists of a working and reference electrode that were gravure printed using silver (Ag) ink on the PET substrate. The performance of the sensor was investigated by measuring electrical impedance spectroscopy (EIS) for varying concentrations of the CdS. From the EIS based response, an impedance change of 11 ± 1%, 23 ± 1%, 34 ± 2% and 50 ± 3% was observed for the 1 pM, 1 nM, 1 µM and 1 mM concentrations of CdS, respectively when compared to de-ionized (DI) water, thus demonstrating the potential of employing gravure printed electrochemical sensors for heavy metal detection applications.

scholarly journals Electrochemical Sensor Based on Nanodiamonds and Manioc Starch for Detection of Tetracycline

2021 ◽  
Vol 2021 ◽  
pp. 1-10
Author(s):  
Wilson Silva Fernandes-Junior ◽  
Leticia Fernanda Zaccarin ◽  
Geiser Gabriel Oliveira ◽  
Paulo Roberto de Oliveira ◽  
Cristiane Kalinke ◽  
...  
Keyword(s):  
Electrochemical Sensor ◽  
Electrochemical Sensors ◽  
Dynamic Range ◽  
Limit Of Detection ◽  
Low Cost ◽  
Polymeric Materials ◽  
Relative Standard ◽  
Repeatability And Reproducibility ◽  
High Repeatability

The use of nanostructured materials is already well-known as a powerful tool in the development of electrochemical sensors. Among several immobilization strategies of nanomaterials in the development of electrochemical sensors, the use of low-cost and environmentally friendly polymeric materials is highlighted. In this context, a new nanostructured biocomposite electrode is proposed as an electrochemical sensor for the analysis and determination of tetracycline. The composite electrode consists of a modified glassy carbon electrode (GCE) with a nanodiamond-based (ND) and manioc starch biofilm (MS), called ND-MS/GCE. The proposed sensor showed better electrochemical performance in the presence of tetracycline in comparison to the unmodified electrode, which was attributed to the increase in the electroactive surface area due to the presence of nanodiamonds. A linear dynamic range from 5.0 × 10 − 6 to 1.8 × 10 − 4  mol L−1 and a limit of detection of 2.0 × 10 − 6  mol L−1 were obtained for the proposed sensor. ND-MS/GCE exhibited high repeatability and reproducibility for successive measurements with a relative standard deviation (RSD) of 6.3% and 1.5%, respectively. The proposed electrode was successfully applied for the detection of tetracycline in different kinds of water samples, presenting recoveries ranging from 86 to 112%.

scholarly journals MnO2@Reduced Graphene Oxide Nanocomposite-Based Electrochemical Sensor for the Simultaneous Determination of Trace Cd(II), Zn(II) and Cu(II) in Water Samples

Membranes ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 517
Author(s):  
Siyamthanda Hope Mnyipika ◽  
Tshimangadzo Saddam Munonde ◽  
Philiswa Nosizo Nomngongo
Keyword(s):  
Heavy Metals ◽  
Electrochemical Sensor ◽  
Simultaneous Determination ◽  
Rapid Detection ◽  
Electrochemical Sensors ◽  
Simultaneous Detection ◽  
Cyclic Voltammograms ◽  
Current Response ◽  
Mno2 Nanoparticles

The rapid detection of trace metals is one of the most important aspect in achieving environmental monitoring and protection. Electrochemical sensors remain a key solution for rapid detection of heavy metals in environmental water matrices. This paper reports the fabrication of an electrochemical sensor obtained by the simultaneous electrodeposition of MnO2 nanoparticles and RGO nanosheets on the surface of a glassy carbon electrode. The successful electrodeposition was confirmed by the enhanced current response on the cyclic voltammograms. The XRD, HR-SEM/EDX, TEM, FTIR, and BET characterization confirmed the successful synthesis of MnO2 nanoparticles, RGO nanosheets, and MnO2@RGO nanocomposite. The electrochemical studies results revealed that MnO2@RGO@GCE nanocomposite considerably improved the current response on the detection of Zn(II), Cd(II) and Cu(II) ions in surface water. These remarkable improvements were due to the interaction between MnO2 nanomaterials and RGO nanosheets. Moreover, the modified sensor electrode portrayed high sensitivity, reproducibility, and stability on the simultaneous determination of Zn(II), Cd(II), and Cu(II) ions. The detection limits of (S/N = 3) ranged from 0.002–0.015 μg L−1 for the simultaneous detection of Zn(II), Cd(II), and Cu(II) ions. The results show that MnO2@RGO nanocomposite can be successfully used for the early detection of heavy metals with higher sensitivity in water sample analysis.

scholarly journals Immobilization-Free Electrochemical Sensor Coupled with a Graphene-Oxide-Based Aptasensor for Glycated Albumin Detection

Biosensors ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 85
Author(s):  
Wassa Waiwinya ◽  
Thitirat Putnin ◽  
Dechnarong Pimalai ◽  
Wireeya Chawjiraphan ◽  
Nuankanya Sathirapongsasuti ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Electrochemical Sensor ◽  
Detection Method ◽  
Limit Of Detection ◽  
Glycated Albumin ◽  
Cost Effective ◽  
Logarithmic Scale ◽  
Electrochemical Aptasensor ◽  
Alternative Approach

An immobilization-free electrochemical sensor coupled with a graphene oxide (GO)-based aptasensor was developed for glycated human serum albumin (GHSA) detection. The concentration of GHSA was monitored by measuring the electrochemical response of free GO and aptamer-bound GO in the presence of glycated albumin; their currents served as the analytical signals. The electrochemical aptasensor exhibited good performance with a base-10 logarithmic scale. The calibration curve was achieved in the range of 0.01–50 µg/mL. The limit of detection (LOD) was 8.70 ng/mL. The developed method was considered a one-drop measurement process because a fabrication step and the probe-immobilization process were not required. This simple sensor offers a cost-effective, rapid, and sensitive detection method, and could be an alternative approach for determination of GHSA levels.

Highly sensitive real-time detection of intracellular oxidative stress and application in mycotoxin toxicity evaluation based on living single-cell electrochemical sensors

The Analyst ◽  
2021 ◽  
Author(s):  
Lu Gao ◽  
Jiadi Sun ◽  
Liping Wang ◽  
Qigao Fan ◽  
Gaowen Zhu ◽  
...  
Keyword(s):  
Oxidative Stress ◽  
Electrochemical Sensor ◽  
Single Cell ◽  
Real Time ◽  
Electrochemical Sensors ◽  
Living Cells ◽  
Selective Detection ◽  
Toxicity Evaluation ◽  
Highly Sensitive ◽  
Intracellular Oxidative Stress

Single-cell electrochemical sensor is used in the local selective detection of living cells because of its high spatial–temporal resolution and sensitivity, as well as its ability to obtain comprehensive cellular physiological states and processes.

Development of Au-Pd@UiO-66-on-ZIF-L/CC as a self-supported electrochemical sensor for in situ monitoring of cellular hydrogen peroxide

2021 ◽  
Author(s):  
Jilin Zheng ◽  
Peng Zhao ◽  
Shiying Zhou ◽  
Sha Chen ◽  
Yi Liang ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Electrochemical Sensor ◽  
Noble Metals ◽  
Electrochemical Sensors ◽  
Metal Organic Frameworks ◽  
Electrochemical Sensing ◽  
In Situ Monitoring ◽  
Metal Organic

Integrating metal-organic frameworks (MOFs) of different components or structures together and exploiting them as electrochemical sensors for electrochemical sensing have aroused great interest. And the incorporation of noble metals with...

scholarly journals An Electrochemical Sensor Based On Graphite Electrode Modified With Silica Containing 1-N-Propyl-3-Methylimidazolium Species For Determination Of Ascorbic Acid

2019 ◽  
Vol Vol. 14, No.1 ◽  
pp. 5-14 ◽  
Author(s):  
Anastasiya Tkachenko ◽  
Mykyta Onizhuk ◽  
Oleg Tkachenko ◽  
Leliz T. Arenas ◽  
Edilson V. Benvenutt ◽  
...  
Keyword(s):  
Ascorbic Acid ◽  
Cyclic Voltammetry ◽  
Electrochemical Sensor ◽  
Electrochemical Impedance ◽  
Limit Of Detection ◽  
Pharmaceutical Formulations ◽  
Differential Pulse ◽  
Long Term Stability ◽  
Diffusion Limited

In the present study, an electrochemical sensor based on the electrode (SiMImCl/C) consisting of graphite and silica, grafted with 1-n-propyl-3-methylimidazolium chloride was used for ascorbic acid (AA) quantification in pharmaceuticals and food formulations. Cyclic voltammetry and electrochemical impedance spectroscopy were applied for electrochemical characterization of the SiMImCl/C electrode. The cyclic voltammetry study revealed that the oxidation of AA on this electrode is an irreversible process, realized by adsorption and diffusion limited step. The differential pulse voltammetry was applied to develop a procedure for the AA determination. The linear range was found to be 0.3–170 μmol L-1 and the limit of detection – 0.1 μmol L-1. The proposed SiMImCl/C electrode has long term stability and does not show electrochemical activity towards the analytes, which commonly coexist with AA. The sensor was successfully used for quantification of AA in food and pharmaceutical formulations.

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