scholarly journals Fluoroindate Glass Co-Doped with Yb3+/Ho3+ as a 2.85 μm Luminescent Source for MID-IR Sensing

Sensors ◽  
2021 ◽  
Vol 21 (6) ◽  
pp. 2155
Author(s):  
Marcin Kochanowicz ◽  
Jacek Zmojda ◽  
Agata Baranowska ◽  
Marta Kuwik ◽  
Bartłomiej Starzyk ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Near Infrared ◽  
Luminescence Spectra ◽  
Infrared Source ◽  
Mid Infrared ◽  
Infrared Luminescence ◽  
Infrared Spectral Range ◽  
Infrared Spectral ◽  
Sensing Application ◽  
Co Doped

This work reports on the fabrication and analysis of near-infrared and mid-infrared luminescence spectra and their decays in fluoroindate glasses co-doped with Yb3+/Ho3+. The attention has been paid to the analysis of the Yb3+→ Ho3+ energy transfer processed ions in fluoroindate glasses pumped by 976 nm laser diode. The most effective sensitization for 2 μm luminescence has been obtained in glass co-doped with 0.8YbF3/1.6HoF3. Further study in the mid-infrared spectral range (2.85 μm) showed that the maximum emission intensity has been obtained in fluoroindate glass co-doped with 0.1YbF3/1.4HoF3. The obtained efficiency of Yb3+→ Ho3+ energy transfer was calculated to be up to 61% (0.8YbF3/1.6HoF3), which confirms the possibility of obtaining an efficient glass or glass fiber infrared source for a MID-infrared (MID-IR) sensing application.

Mid-Infrared Luminescence and Energy Transfer Mechanism of Tm3+/Ho3+Co-Doped Tellurite Glasses

2012 ◽  
Vol 39 (10) ◽  
pp. 1006002 ◽  
Author(s):  
徐星辰 Xu Xingchen ◽  
周亚训 Zhou Yaxun ◽  
戴世勋 Dai Shixun ◽  
王训四 Wang Xunsi ◽  
郑世超 Zheng Shichao ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Transfer Mechanism ◽  
Energy Transfer Mechanism ◽  
Tellurite Glasses ◽  
Mid Infrared ◽  
Infrared Luminescence ◽  
Co Doped

scholarly journals Fluoroindate glasses co-doped with Pr3+/Er3+ for near-infrared luminescence applications

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Wojciech A. Pisarski ◽  
Joanna Pisarska ◽  
Marta Kuwik ◽  
Marcin Kochanowicz ◽  
Jacek Żmojda ◽  
...  
Keyword(s):  
Rare Earth ◽  
Near Infrared ◽  
Rare Earth Ions ◽  
Luminescence Spectra ◽  
Nonradiative Relaxation ◽  
Transfer Processes ◽  
Direct Excitation ◽  
Infrared Luminescence ◽  
Doped Glass ◽  
Co Doped

AbstractFluoroindate glasses co-doped with Pr3+/Er3+ ions were synthesized and their near-infrared luminescence properties have been examined under selective excitation wavelengths. For the Pr3+/Er3+ co-doped glass samples several radiative and nonradiative relaxation channels and their mechanisms are proposed under direct excitation of Pr3+ and/or Er3+. The energy transfer processes between Pr3+ and Er3+ ions in fluoroindate glasses were identified. In particular, broadband near-infrared luminescence (FWHM = 278 nm) associated to the 1G4 → 3H5 (Pr3+), 1D2 → 1G4 (Pr3+) and 4I13/2 → 4I15/2 (Er3+) transitions of rare earth ions in fluoroindate glass is successfully observed under direct excitation at 483 nm. Near-infrared luminescence spectra and their decays for glass samples co-doped with Pr3+/Er3+ are compared to the experimental results obtained for fluoroindate glasses singly doped with rare earth ions.

Ultrabroadband near-infrared luminescence and efficient energy transfer in Bi and Bi/Ho co-doped thin films

2014 ◽  
Vol 2 (14) ◽  
pp. 2482 ◽  
Author(s):  
Beibei Xu ◽  
Jianhua Hao ◽  
Qiangbing Guo ◽  
Juechen Wang ◽  
Gongxun Bai ◽  
...  
Keyword(s):  
Thin Films ◽  
Energy Transfer ◽  
Near Infrared ◽  
Efficient Energy Transfer ◽  
Efficient Energy ◽  
Infrared Luminescence ◽  
Co Doped

scholarly journals Indirect Red and Near-Infrared Z-to-E Photoisomerization of ortho-Functionalized Azobenzenes via Triplet Energy Transfer

2021 ◽  
Author(s):  
Jussi Isokuortti ◽  
Kim Kuntze ◽  
Matti Virkki ◽  
Zafar Ahmed ◽  
Elina Vuorimaa-Laukkanen ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Spectral Range ◽  
Near Infrared ◽  
Triplet Energy ◽  
Long Wavelength ◽  
Whole Process ◽  
Infrared Spectral Range ◽  
Porphyrin Photosensitizers ◽  
Infrared Spectral ◽  
Triplet Energy Transfer

Designing azobenzene photoswitches capable of selective and efficient photoisomerization by long wavelength excitation is a long-standing challenge. Indirect excitation can expand the properties of the photoswitching system beyond the intrinsic limits of azobenzenes. Herein, a rapid Z-to-E isomerization of two ortho-functionalized azobenzenes with near-unity photoconversion was facilitated via triplet energy transfer upon red and near-infrared (up to 770 nm) excitation of porphyrin photosensitizers in catalytic micromolar concentrations. Our results indicate that the whole process of triplet-sensitized isomerization is strongly entropy-driven. This ensures efficient Z-to-E photoswitching even when the azobenzene triplet energy is considerably higher (>200 meV) than for the sensitizer, which is the key for the expansion of excitation wavelengths into the near-infrared spectral range.<br>

Quantum Cutting Downconversion in Tb3+,Yb3+ Codoped Sr3AlO4F Phosphor

2013 ◽  
Vol 683 ◽  
pp. 172-175 ◽  
Author(s):  
Jia Yue Sun ◽  
Yi Ning Sun ◽  
Jun Hui Zeng ◽  
Ji Cheng Zhu ◽  
Hai Yan Du
Keyword(s):  
Energy Transfer ◽  
High Temperature ◽  
Solid State ◽  
Quantum Efficiency ◽  
Solid State Reaction ◽  
Near Infrared ◽  
Luminescence Spectra ◽  
Promising Candidate ◽  
Quantum Cutting ◽  
Co Doped

A near Infrared (NIR) quantum cutting (QC) Sr3AlO4F:Tb3+,Yb3+phosphor was synthesized by the conventional high temperature solid-state reaction. The luminescence spectra both in visible (VIS) and NIR regions and decay lifetime curves of Tb3+have been measured to prove energy transfer (ET) from Tb3+to Yb3+. Quantum efficiency (QE) related to Yb3+concentration was calculated and the highest QE was found to be 135% hen Yb3+doped concentration at 20%. The present Tb3+and Yb3+co-doped Sr3AlO4F phosphor may be a promising candidate to modify the spectral of the solar light.

Near-Infrared Luminescence and Energy Transfer Characteristics of Dy3+-Tm3+ Co-Doped Selenide Glasses

2007 ◽  
Vol 336-338 ◽  
pp. 647-650
Author(s):  
Zhi Yong Yang ◽  
Lan Luo ◽  
Wei Chen
Keyword(s):  
Energy Transfer ◽  
Near Infrared ◽  
Direct Interaction ◽  
Infrared Emission ◽  
Emission Properties ◽  
Diffusion Limited ◽  
Infrared Luminescence ◽  
Near Infrared Emission ◽  
Energy Acceptor ◽  
Co Doped

Near-infrared emission properties of Dy3+-Tm3+ co-doped Ge-Ga-Sb-Se glasses were investigated. Possible energy transfer routes and the regime of donor decay were discussed. Tm3+ is found to be an efficient sensitizer on the Dy3+:1.34μm luminescence. Probable energy transfer schemes include Tm3+:3H4 → Dy3+: 6F5/2 and Tm3+:3H5 → Dy3+:6F11/2· 6H9/2. The donor (Tm3+) excitation is transferred to an acceptor (Dy3+) by direct interaction or migrates among donors by diffusion-limited regime until it comes into the vicinity of an energy acceptor where direct interaction and transfer occur.

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