scholarly journals Ripeness Prediction of Postharvest Kiwifruit Using a MOS E-Nose Combined with Chemometrics

Sensors ◽  
2019 ◽  
Vol 19 (2) ◽  
pp. 419 ◽  
Author(s):  
Dongdong Du ◽  
Jun Wang ◽  
Bo Wang ◽  
Luyi Zhu ◽  
Xuezhen Hong

Postharvest kiwifruit continues to ripen for a period until it reaches the optimal “eating ripe” stage. Without damaging the fruit, it is very difficult to identify the ripeness of postharvest kiwifruit by conventional means. In this study, an electronic nose (E-nose) with 10 metal oxide semiconductor (MOS) gas sensors was used to predict the ripeness of postharvest kiwifruit. Three different feature extraction methods (the max/min values, the difference values and the 70th s values) were employed to discriminate kiwifruit at different ripening times by linear discriminant analysis (LDA), and results showed that the 70th s values method had the best performance in discriminating kiwifruit at different ripening stages, obtaining a 100% original accuracy rate and a 99.4% cross-validation accuracy rate. Partial least squares regression (PLSR), support vector machine (SVM) and random forest (RF) were employed to build prediction models for overall ripeness, soluble solids content (SSC) and firmness. The regression results showed that the RF algorithm had the best performance in predicting the ripeness indexes of postharvest kiwifruit compared with PLSR and SVM, which illustrated that the E-nose data had high correlations with overall ripeness (training: R2 = 0.9928; testing: R2 = 0.9928), SSC (training: R2 = 0.9749; testing: R2 = 0.9143) and firmness (training: R2 = 0.9814; testing: R2 = 0.9290). This study demonstrated that E-nose could be a comprehensive approach to predict the ripeness of postharvest kiwifruit through aroma volatiles.

2013 ◽  
pp. 1516-1534
Author(s):  
Lochi Yu ◽  
Cristian Ureña

Since the first recordings of brain electrical activity more than 100 years ago remarkable contributions have been done to understand the brain functionality and its interaction with environment. Regardless of the nature of the brain-computer interface BCI, a world of opportunities and possibilities has been opened not only for people with severe disabilities but also for those who are pursuing innovative human interfaces. Deeper understanding of the EEG signals along with refined technologies for its recording is helping to improve the performance of EEG based BCIs. Better processing and features extraction methods, like Independent Component Analysis (ICA) and Wavelet Transform (WT) respectively, are giving promising results that need to be explored. Different types of classifiers and combination of them have been used on EEG BCIs. Linear, neural and nonlinear Bayesian have been the most used classifiers providing accuracies ranges between 60% and 90%. Some demand more computational resources like Support Vector Machines (SVM) classifiers but give good generality. Linear Discriminant Analysis (LDA) classifiers provide poor generality but low computational resources, making them optimal for some real time BCIs. Better classifiers must be developed to tackle the large patterns variability across different subjects by using every available resource, method or technology.


2021 ◽  
Author(s):  
Dian Kesumapramudya Nurputra ◽  
Ahmad Kusumaatmadja ◽  
Mohamad Saifudin Hakim ◽  
Shidiq Nur Hidayat ◽  
Trisna Julian ◽  
...  

Abstract Despite its high accuracy to detect the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2), the reverse transcription-quantitative polymerase chain reaction (RT-qPCR) approach possesses several limitations (e.g., the lengthy invasive procedure, the reagent availability, and the requirement of specialized laboratory, equipment, and trained staffs). We developed and employed a low-cost, noninvasive method to rapidly sniff out the coronavirus disease 2019 (COVID-19) based on a portable electronic nose (GeNose C19) integrating metal oxide semiconductor gas sensor array, optimized feature extraction, and machine learning models. This approach was evaluated in profiling tests involving a total number of 615 breath samples (i.e., 333 positive and 282 negative COVID-19 confirmed by RT-qPCR) obtained from 83 patients in two hospitals located in the Special Region of Yogyakarta, Indonesia. Four different machine learning algorithms (i.e., linear discriminant analysis (LDA), support vector machine (SVM), stacked multilayer perceptron (MLP), and deep neural network (DNN)) were utilized to identify the top-performing pattern recognition methods and to obtain high system detection accuracy (88–95%), sensitivity (86–94%), specificity (88–95%) levels from the testing datasets. Our results suggest that GeNose C19 can be considered a highly potential breathalyzer for fast COVID-19 screening.


Molecules ◽  
2021 ◽  
Vol 26 (16) ◽  
pp. 4916
Author(s):  
Shunsuke Tamura ◽  
Swarit Jasial ◽  
Tomoyuki Miyao ◽  
Kimito Funatsu

Activity cliffs (ACs) are formed by two structurally similar compounds with a large difference in potency. Accurate AC prediction is expected to help researchers’ decisions in the early stages of drug discovery. Previously, predictive models based on matched molecular pair (MMP) cliffs have been proposed. However, the proposed methods face a challenge of interpretability due to the black-box character of the predictive models. In this study, we developed interpretable MMP fingerprints and modified a model-specific interpretation approach for models based on a support vector machine (SVM) and MMP kernel. We compared important features highlighted by this SVM-based interpretation approach and the SHapley Additive exPlanations (SHAP) as a major model-independent approach. The model-specific approach could capture the difference between AC and non-AC, while SHAP assigned high weights to the features not present in the test instances. For specific MMPs, the feature weights mapped by the SVM-based interpretation method were in agreement with the previously confirmed binding knowledge from X-ray co-crystal structures, indicating that this method is able to interpret the AC prediction model in a chemically intuitive manner.


2019 ◽  
Vol 15 (3) ◽  
pp. 14-27
Author(s):  
Wang Tao ◽  
Wu Linyan ◽  
Li Yanping ◽  
Gao Nuo ◽  
Zhang Weiran

Feature extraction is an important step in electroencephalogram (EEG) processing of motor imagery, and the feature extraction of EEG directly affects the final classification results. Through the analysis of various feature extraction methods, this article finally selects Common Spatial Patterns (CSP) and wavelet packet analysis (WPA) to extract the feature and uses Support Vector Machine (SVM) to classify and compare these extracted features. For the EEG data provided by GRAZ University, the accuracy rate of feature extraction using CSP algorithm is 85.5%, and the accuracy rate of feature extraction using wavelet packet analysis is 92%. Then this paper analyzes the EEG data collected by Emotiv epoc+ system. The classification accuracy of wavelet packet extracted features can still be maintained at more than 80%, while the classification accuracy of CSP extracted feature is decreased obviously. Experimental results show that the method of wavelet packet analysis towards competition data and Emotiv epoc+ system data can both get a desirable outcome.


Author(s):  
Lochi Yu ◽  
Cristian Ureña

Since the first recordings of brain electrical activity more than 100 years ago remarkable contributions have been done to understand the brain functionality and its interaction with environment. Regardless of the nature of the brain-computer interface BCI, a world of opportunities and possibilities has been opened not only for people with severe disabilities but also for those who are pursuing innovative human interfaces. Deeper understanding of the EEG signals along with refined technologies for its recording is helping to improve the performance of EEG based BCIs. Better processing and features extraction methods, like Independent Component Analysis (ICA) and Wavelet Transform (WT) respectively, are giving promising results that need to be explored. Different types of classifiers and combination of them have been used on EEG BCIs. Linear, neural and nonlinear Bayesian have been the most used classifiers providing accuracies ranges between 60% and 90%. Some demand more computational resources like Support Vector Machines (SVM) classifiers but give good generality. Linear Discriminant Analysis (LDA) classifiers provide poor generality but low computational resources, making them optimal for some real time BCIs. Better classifiers must be developed to tackle the large patterns variability across different subjects by using every available resource, method or technology.


2019 ◽  
Vol 2019 ◽  
pp. 1-9 ◽  
Author(s):  
Charles L. Y. Amuah ◽  
Ernest Teye ◽  
Francis Padi Lamptey ◽  
Kwasi Nyandey ◽  
Jerry Opoku-Ansah ◽  
...  

The potential of predicting maturity using total soluble solids (TSS) and identifying organic from inorganic pineapple fruits based on near-infrared (NIR) spectra fingerprints would be beneficial to farmers and consumers alike. In this study, a portable NIR spectrometer and chemometric techniques were combined to simultaneously identify organically produced pineapple fruits from conventionally produced ones (thus organic and inorganic) and also predict total soluble solids. A total of 90 intact pineapple fruits were scanned with the NIR spectrometer while a digital refractometer was used to measure TSS from extracted pineapple juice. After attempting several preprocessing techniques, multivariate calibration models were built using principal component analysis (PCA), K-nearest neighbor (KNN), and linear discriminant analysis (LDA) to identify the classes (organic and conventional pineapple fruits) while partial least squares regression (PLSR) method was used to determine TSS of the fruits. Among the identification techniques, the MSC-PCA-LDA model accurately identified organic from conventionally produced fruits at 100% identification rate. For quantification of TSS, the MSC-PLSR model gave Rp = 0.851 and RMSEC = 0.950 °Brix, and Rc = 0.854 and RMSEP = 0.842 °Brix at 5 principal components in the calibration set and prediction set, respectively. The results generally indicated that portable NIR spectrometer coupled with the appropriate chemometric tools could be employed for rapid nondestructive examination of pineapple quality and also to detect pineapple fraud due to mislabeling of conventionally produced fruits as organic ones. This would be helpful to farmers, consumers, and quality control officers.


2014 ◽  
Vol 32 (No. 6) ◽  
pp. 538-548 ◽  
Author(s):  
A. Sanaeifar ◽  
S.S. Mohtasebi ◽  
M. Ghasemi-Varnamkhasti ◽  
H. Ahmadi ◽  
J. Lozano

Potential application of a metal oxide semiconductor based electronic nose (e-nose) as a non-destructive instrument for monitoring the change in volatile production of banana during the ripening process was studied. The proposed e-nose does not need any advanced or expensive laboratory equipment and proved to be reliable in recording meaningful differences between ripening stages. Principal Component Analysis (PCA), Linear Discriminant Analysis (LDA), Soft Independent Modelling of Class Analogy (SIMCA) and Support Vector Machines (SVM) techniques were used for this purpose. Results showed that the proposed e-nose can distinguish between different ripening stages. The e-nose was able to detect a clear difference in the aroma fingerprint of banana when using SVM analysis compared with PCA and LDA, SIMCA analysis. Using SVM analysis, it was possible to differentiate and to classify the different banana ripening stages, and this method was able to classify 98.66% of the total samples in each respective group. Sensor array capabilities in the classification of ripening stages using loading analysis and SVM and SIMCA were also investigated, which leads to develop the application of a specific e-nose system by applying the most effective sensors or ignoring the redundant sensors.  


Sensors ◽  
2019 ◽  
Vol 19 (15) ◽  
pp. 3417 ◽  
Author(s):  
Longtu Zhu ◽  
Honglei Jia ◽  
Yibing Chen ◽  
Qi Wang ◽  
Mingwei Li ◽  
...  

Soil organic matter (SOM) is a major indicator of soil fertility and nutrients. In this study, a soil organic matter measuring method based on an artificial olfactory system (AOS) was designed. An array composed of 10 identical gas sensors controlled at different temperatures was used to collect soil gases. From the response curve of each sensor, four features were extracted (maximum value, mean differential coefficient value, response area value, and the transient value at the 20th second). Then, soil organic matter regression prediction models were built based on back-propagation neural network (BPNN), support vector regression (SVR), and partial least squares regression (PLSR). The prediction performance of each model was evaluated using the coefficient of determination (R2), root-mean-square error (RMSE), and the ratio of performance to deviation (RPD). It was found that the R2 values between prediction (from BPNN, SVR, and PLSR) and observation were 0.880, 0.895, and 0.808. RMSEs were 14.916, 14.094, and 18.890, and RPDs were 2.837, 3.003, and 2.240, respectively. SVR had higher prediction ability than BPNN and PLSR and can be used to accurately predict organic matter contents. Thus, our findings offer brand new methods for predicting SOM.


Sensors ◽  
2021 ◽  
Vol 21 (15) ◽  
pp. 5059
Author(s):  
Paula Ciursa ◽  
Mircea Oroian

The aim of this study is to establish the usefulness of an electronic tongue based on cyclic voltammetry e-tongue using five working electrodes (gold, silver, copper, platinum and glass) in honey adulteration detection. Authentic honey samples of different botanical origin (acacia, tilia, sunflower, polyfloral and raspberry) were adulterated with agave, maple, inverted sugar, corn and rice syrups in percentages of 5%, 10%, 20% and 50%. The silver and copper electrodes provided the clearest voltammograms, the differences between authentic and adulterated honey samples being highlighted by the maximum current intensity. The electronic tongue results have been correlated with physicochemical parameters (pH, free acidity, hydroxymethylfurfural content—5 HMF and electrical conductivity—EC). Using statistical methods such as Linear discriminant analysis (LDA) and Support vector machines (SVM), an accuracy of 94.87% and 100% respectively was obtained in the calibration step and 89.65% and 100% respectively in the validation step. The PLS-R (Partial Least Squares Regression) model (constructed from the minimum and maximum current intensity obtained for all electrodes) was used in physicochemical parameters prediction; EC reached the highest regression coefficients (0.840 in the calibration step and 0.842 in the validation step, respectively), being followed by pH (0.704 in the calibration step and 0.516 in the validation step, respectively).


Author(s):  
S Kazemi ◽  
P Katibeh

Background: Migraine headache without aura is the most common type of migraine especially among pediatric patients. It has always been a great challenge of migraine diagnosis using quantitative electroencephalography measurements through feature classification. It has been proven that different feature extraction and classification methods vary in terms of performance regarding detection and diagnostic accuracy. Previous work on the subject was controversial, hence a comparison of these methods seems necessary.Objectives: The aim of this research is to compare two parametric and non-parametric feature extraction methods and also two classification methods in order to obtain optimal combinations of diagnostic accuracy.Materials and Methods: Having recorded background EEG from 24 pediatric migraineurs and 19 control subjects, data was processed by Welch’s and Yule-Walker’s methods. Features were selected using genetic algorithm, and then given to a support vector machine and the linear discriminant analysis for the classification. Accuracy was calculated for all combinations having the dominant frequency and the correlated absolute power of each EEG wave band (theta, alpha, and beta) and for all wave bands combined.Results: The highest migraine detection accuracy of 93% was obtained utilizing Welch’s method for EEG feature extraction alongside support vector machine for a classifier. Besides, Yule-Walker autoregressive method showed better performance than Welch’s, when only power bands (and not the dominant frequency) were used as classification input.Conclusion: The superiority of Welch’s method over Yule-Walker’s and the support vector machine over linear discriminant analysis can be great help for further researches on computer aided EEG-based diagnosis of migraine


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