scholarly journals Development and application of a new low cost electronic nose for the ripeness monitoring of banana using computational techniques (PCA, LDA, SIMCA and SVM)

2014 ◽  
Vol 32 (No. 6) ◽  
pp. 538-548 ◽  
Author(s):  
A. Sanaeifar ◽  
S.S. Mohtasebi ◽  
M. Ghasemi-Varnamkhasti ◽  
H. Ahmadi ◽  
J. Lozano
Keyword(s):  
Electronic Nose ◽  
Low Cost ◽  
Principal Component ◽  
Oxide Semiconductor ◽  
Support Vector ◽  
Computational Techniques ◽  
Laboratory Equipment ◽  
Linear Discriminant ◽  
Ripening Stages ◽  
Non Destructive

Potential application of a metal oxide semiconductor based electronic nose (e-nose) as a non-destructive instrument for monitoring the change in volatile production of banana during the ripening process was studied. The proposed e-nose does not need any advanced or expensive laboratory equipment and proved to be reliable in recording meaningful differences between ripening stages. Principal Component Analysis (PCA), Linear Discriminant Analysis (LDA), Soft Independent Modelling of Class Analogy (SIMCA) and Support Vector Machines (SVM) techniques were used for this purpose. Results showed that the proposed e-nose can distinguish between different ripening stages. The e-nose was able to detect a clear difference in the aroma fingerprint of banana when using SVM analysis compared with PCA and LDA, SIMCA analysis. Using SVM analysis, it was possible to differentiate and to classify the different banana ripening stages, and this method was able to classify 98.66% of the total samples in each respective group. Sensor array capabilities in the classification of ripening stages using loading analysis and SVM and SIMCA were also investigated, which leads to develop the application of a specific e-nose system by applying the most effective sensors or ignoring the redundant sensors.  

scholarly journals Fast and noninvasive electronic nose for sniffing out COVID-19 based on exhaled breath-print recognition

2021 ◽  
Author(s):  
Dian Kesumapramudya Nurputra ◽  
Ahmad Kusumaatmadja ◽  
Mohamad Saifudin Hakim ◽  
Shidiq Nur Hidayat ◽  
Trisna Julian ◽  
...  
Keyword(s):  
Machine Learning ◽  
Electronic Nose ◽  
Quantitative Polymerase Chain Reaction ◽  
Machine Learning Algorithms ◽  
Oxide Semiconductor ◽  
Support Vector ◽  
Detection Accuracy ◽  
Exhaled Breath ◽  
Laboratory Equipment ◽  
Linear Discriminant

Abstract Despite its high accuracy to detect the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2), the reverse transcription-quantitative polymerase chain reaction (RT-qPCR) approach possesses several limitations (e.g., the lengthy invasive procedure, the reagent availability, and the requirement of specialized laboratory, equipment, and trained staffs). We developed and employed a low-cost, noninvasive method to rapidly sniff out the coronavirus disease 2019 (COVID-19) based on a portable electronic nose (GeNose C19) integrating metal oxide semiconductor gas sensor array, optimized feature extraction, and machine learning models. This approach was evaluated in profiling tests involving a total number of 615 breath samples (i.e., 333 positive and 282 negative COVID-19 confirmed by RT-qPCR) obtained from 83 patients in two hospitals located in the Special Region of Yogyakarta, Indonesia. Four different machine learning algorithms (i.e., linear discriminant analysis (LDA), support vector machine (SVM), stacked multilayer perceptron (MLP), and deep neural network (DNN)) were utilized to identify the top-performing pattern recognition methods and to obtain high system detection accuracy (88–95%), sensitivity (86–94%), specificity (88–95%) levels from the testing datasets. Our results suggest that GeNose C19 can be considered a highly potential breathalyzer for fast COVID-19 screening.

scholarly journals Discrimination between Alternative Herbal Medicines from Different Categories with the Electronic Nose

Sensors ◽  
2018 ◽  
Vol 18 (9) ◽  
pp. 2936 ◽  
Author(s):  
Xianghao Zhan ◽  
Xiaoqing Guan ◽  
Rumeng Wu ◽  
Zhan Wang ◽  
You Wang ◽  
...  
Keyword(s):  
Herbal Medicine ◽  
Electronic Nose ◽  
Nearest Neighbor ◽  
Herbal Medicines ◽  
Principal Component ◽  
Support Vector ◽  
Linear Discriminant ◽  
Convenient Means ◽  
Electronic Nose System ◽  
Insight Into

As alternative herbal medicine gains soar in popularity around the world, it is necessary to apply a fast and convenient means for classifying and evaluating herbal medicines. In this work, an electronic nose system with seven classification algorithms is used to discriminate between 12 categories of herbal medicines. The results show that these herbal medicines can be successfully classified, with support vector machine (SVM) and linear discriminant analysis (LDA) outperforming other algorithms in terms of accuracy. When principal component analysis (PCA) is used to lower the number of dimensions, the time cost for classification can be reduced while the data is visualized. Afterwards, conformal predictions based on 1NN (1-Nearest Neighbor) and 3NN (3-Nearest Neighbor) (CP-1NN and CP-3NN) are introduced. CP-1NN and CP-3NN provide additional, yet significant and reliable, information by giving the confidence and credibility associated with each prediction without sacrificing of accuracy. This research provides insight into the construction of a herbal medicine flavor library and gives methods and reference for future works.

Freshness Classification of Horse Mackerels with E-Nose System Using Hybrid Binary Decision Tree Structure

2019 ◽  
Vol 34 (03) ◽  
pp. 2050003
Author(s):  
Selda Güney ◽  
Ayten Atasoy
Keyword(s):  
Decision Tree ◽  
Electronic Nose ◽  
Low Cost ◽  
Storage Conditions ◽  
Tree Structure ◽  
Training Dataset ◽  
Support Vector ◽  
Binary Decision ◽  
Linear Discriminant ◽  
Binary Decision Tree

The aim of this study is to test the freshness of horse mackerels by using a low cost electronic nose system composed of eight different metal oxide sensors. The process of freshness evaluation covers a scala of seven different classes corresponding to 1, 3, 5, 7, 9, 11, and 13 storage days. These seven classes are categorized according to six different classifiers in the proposed binary decision tree structure. Classifiers at each particular node of the tree are individually trained with the training dataset. To increase success in determining the level of fish freshness, one of the k-Nearest Neighbors (k-NN), Support Vector Machines (SVM), Linear Discriminant Analysis (LDA) and Bayes methods is selected for every classifier and the feature spaces change in every node. The significance of this study among the others in the literature is that this proposed decision tree structure has never been applied to determine fish freshness before. Because the freshness of fish is observed under actual market storage conditions, the classification is more difficult. The results show that the electronic nose designed with the proposed decision tree structure is able to determine the freshness of horse mackerels with 85.71% accuracy for the test data obtained one year after the training process. Also, the performances of the proposed methods are compared against conventional methods such as Bayes, k-NN, and LDA.

scholarly journals Rapid Non-Destructive Quantification of Eugenol in Curdlan Biofilms by Electronic Nose Combined with Gas Chromatography-Mass Spectrometry

Sensors ◽  
2020 ◽  
Vol 20 (16) ◽  
pp. 4441
Author(s):  
Lu Han ◽  
Jingyi Zhu ◽  
Xia Fan ◽  
Chong Zhang ◽  
Kang Tu ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Prediction Model ◽  
Electronic Nose ◽  
Quantitative Method ◽  
Gas Chromatography Mass Spectrometry ◽  
Support Vector ◽  
Linear Discriminant ◽  
Chromatography Mass Spectrometry ◽  
Non Destructive

Eugenol is hepatotoxic and potentially hazardous to human health. This paper reports on a rapid non-destructive quantitative method for the determination of eugenol concentration in curdlan (CD) biofilms by electronic nose (E-nose) combined with gas chromatography-mass spectrometry (GC-MS). Different concentrations of eugenol were added to the film-forming solution to form a series of biofilms by casting method, and the actual eugenol concentration in the biofilm was determined. Analysis of the odor collected on the biofilms was carried out by GC-MS and an E-nose. The E-nose data was subjected to principal component analysis (PCA) and linear discriminant analysis (LDA) in order to establish a discriminant model for determining eugenol concentrations in the biofilms. Further analyses involving the application of all sensors and featured sensors, the prediction model-based partial least squares (PLS) and support vector machines (SVM) were carried out to determine eugenol concentration in the CD biofilms. The results showed that the optimal prediction model for eugenol concentration was obtained by PLS at R2p of 0.952 using 10 sensors. The study described a rapid, non-destructive detection and quantitative method for determining eugenol concentration in bio-based packaging materials.

Application of Visible-Near Infrared Spectra Technique Based on to the Non-Destructive Measurement of the Salmon Quality

2014 ◽  
Vol 926-930 ◽  
pp. 961-964
Author(s):  
Jiao Jiao Yin
Keyword(s):  
Infrared Spectra ◽  
Near Infrared ◽  
Principal Component ◽  
Support Vector ◽  
Analysis Method ◽  
Linear Discriminant ◽  
Near Infrared Spectra ◽  
Destructive Measurement ◽  
Non Destructive

Because the reflectivity of astaxanthin vary in different bands (mainly 400nm-600nm), so we use the visible-near infrared spectra technique to irradiate the salmon. Because in daily life, people grade the salmon flesh with a color card. In this paper, we first use principal component analysis to reduce the dimensionality of the spectral data of salmon, then use linear discriminant analysis method, least squares support vector machine classification method to distinguish the flesh quality. The correct classification rates are 60%and73.3%. The results show that we can use visible – near infrared spectra to distinguish the quality of the salmon which doesn’t be dissected.

scholarly journals Meat and Fish Freshness Assessment by a Portable and Simplified Electronic Nose System (Mastersense)

Sensors ◽  
2019 ◽  
Vol 19 (14) ◽  
pp. 3225 ◽  
Author(s):  
Grassi ◽  
Benedetti ◽  
Opizzio ◽  
Nardo ◽  
Buratti
Keyword(s):  
Electronic Nose ◽  
Ad Hoc ◽  
Low Cost ◽  
Principal Component ◽  
Partial Least Square ◽  
Least Square ◽  
Oxide Semiconductor ◽  
Prediction Ability ◽  
Nearest Neighbours ◽  
Electronic Nose System

The evaluation of meat and fish quality is crucial to ensure that products are safe and meet the consumers’ expectation. The present work aims at developing a new low-cost, portable, and simplified electronic nose system, named Mastersense, to assess meat and fish freshness. Four metal oxide semiconductor sensors were selected by principal component analysis and were inserted in an “ad hoc” designed measuring chamber. The Mastersense system was used to test beef and poultry slices, and plaice and salmon fillets during their shelf life at 4 °C, from the day of packaging and beyond the expiration date. The same samples were tested for Total Viable Count, and the microbial results were used to define freshness classes to develop classification models by the K-Nearest Neighbours’ algorithm and Partial Least Square–Discriminant Analysis. All the obtained models gave global sensitivity and specificity with prediction higher than 83.3% and 84.0%, respectively. Moreover, a McNemar’s test was performed to compare the prediction ability of the two classification algorithms, which resulted in comparable values (p > 0.05). Thus, the Mastersense prototype implemented with the K-Nearest Neighbours’ model is considered the most convenient strategy to assess meat and fish freshness.

scholarly journals ELECTRONIC NOSE FOR ANCHOVY FRESHNESS MONITORING BASED ON SENSOR ARRAY AND PATTERN RECOGNITION METHODS: PRINCIPAL COMPONENTS ANALYSIS, LINEAR DISCRIMINANT ANALYSIS AND SUPPORT VECTOR MACHINE

2014 ◽  
pp. 61-67
Author(s):  
A. Amari ◽  
N. El Bari ◽  
B. Bouchikhi
Keyword(s):  
Support Vector Machine ◽  
Discriminant Analysis ◽  
Linear Discriminant Analysis ◽  
Electronic Nose ◽  
Tin Dioxide ◽  
Principal Component ◽  
Support Vector ◽  
Current Pattern ◽  
Linear Discriminant ◽  
Pattern Recognition Methods

An electronic nose based system, which employs an array of six inexpensive commercial gas sensors based on tin dioxide (Figaro Engineering Inc., Japan), has been used to analyse the freshness states of anchovies. Fresh anchovies were stored in a refrigerator at 4 ± 1°C over a period of 15 days. Electronic nose measurements need no sample preparation and the results indicated that the spoilage process of anchovies could be followed by using this technique. Conductance responses of volatile compounds produced during storage of anchovy were monitored and the result were analysed by multivariate analysis methods. In this paper principal component analysis (PCA) and linear discriminant analysis (LDA) were used to investigate whether the electronic nose was able to distinguishing among different freshness states (fresh, moderated and non-fresh samples). The loadings analysis was used to identify the sensors responsible for discrimination in the current pattern file. Therefore, the support vector machines (SVM) method was applied to the new subset, with only the selected sensors, to confirm that a subset of a few sensors can be chosen to explain all the variance. The results obtained prove that the electronic nose can discriminate successfully different freshness state using LDA analysis. Some sensors have the highest influence in the current pattern file for electronic nose. Support vector machine (SVM) model, applied to the new subset of sensors show the good performance.

scholarly journals Detection of Water Stress in Khasi Mandarin Orange Plants from Volatile Organic Compound Emission Profile Implementing Electronic Nose

2019 ◽  
Vol 9 (1) ◽  
pp. 133-137 ◽  
Keyword(s):  
Water Stress ◽  
Electronic Nose ◽  
Principal Component ◽  
Kernel Principal Component Analysis ◽  
Support Vector ◽  
Gene Expressions ◽  
Volatile Organic Compound Emission ◽  
Linear Discriminant ◽  
Volatile Organic ◽  
Mandarin Orange

Plants in the absence of an innate immune system like animals and being immobile are regularly exposed to a host of stresses, ranging from biotic to abiotic stresses. In response to these, plants have developed a complicated response system like reprogramming gene expressions and emission of secondary metabolites as volatile organic compounds (VOCs) by its various tissues like roots, stems, leaves etc. These VOCs can be used as biomarkers for inspecting plants’ in situ health status. This paper address the usefulness of electronic nose (e-nose) system to sense the VOCs emitted by plants’ leaves to detect the stresses in it. Standard commercial electronic nose (e-nose) system Alfa Mos Fox 3000 has been used here to identify the stressed and non-stressed plants. Fifteen Mandarin orange plants were considered for the study and were subdivided into three categories. Each one was subjected to a different level of water stress. Leaf samples were collected for e-nose analyses from each plant of all three categories on the 15th day and 30th day of induction of water stresses. Dimensionality reduction techniques like kernel Principal Component Analysis (kPCA), Linear Discriminant Analysis (LDA) and classification algorithms like Support Vector Machines (SVC) and Multi-Layer Perceptron Classifier (MLPC) have been used to classify the three categories of plants. The scores obtained from these analyses reveals the feasibility of using an e nose system in discriminating plants based on the status of water stress in them. This paper analyses the applicability of e nose system in stress diagnosis of agricultural and horticultural crops, which would significantly help in controlling the irrigation regime.

scholarly journals The Electronic Nose Coupled with Chemometric Tools for Discriminating the Quality of Black Tea Samples In Situ

Chemosensors ◽  
2019 ◽  
Vol 7 (3) ◽  
pp. 29 ◽  
Author(s):  
Shidiq Nur Hidayat ◽  
Kuwat Triyana ◽  
Inggrit Fauzan ◽  
Trisna Julian ◽  
Danang Lelono ◽  
...  
Keyword(s):  
Electronic Nose ◽  
External Validation ◽  
Principal Component ◽  
Black Tea ◽  
Oxide Semiconductor ◽  
Support Vector ◽  
Quality Level ◽  
Validation Data ◽  
Signal Preprocessing

An electronic nose (E-nose), comprising eight metal oxide semiconductor (MOS) gas sensors, was used in situ for real-time classification of black tea according to its quality level. Principal component analysis (PCA) coupled with signal preprocessing techniques (i.e., time set value preprocessing, F1; area under curve preprocessing, F2; and maximum value preprocessing, F3), allowed grouping the samples from seven brands according to the quality level. The E-nose performance was further checked using multivariate supervised statistical methods, namely, the linear and quadratic discriminant analysis, support vector machine together with linear or radial kernels (SVM-linear and SVM-radial, respectively). For this purpose, the experimental dataset was split into two subsets, one used for model training and internal validation using a repeated K-fold cross-validation procedure (containing the samples collected during the first three days of tea production); and the other, for external validation purpose (i.e., test dataset, containing the samples collected during the 4th and 5th production days). The results pointed out that the E-nose-SVM-linear model together with the F3 signal preprocessing method was the most accurate, allowing 100% of correct predictive classifications (external-validation data subset) of the samples according to their quality levels. So, the E-nose-chemometric approach could be foreseen has a practical and feasible classification tool for assessing the black tea quality level, even when applied in-situ, at the harsh industrial environment, requiring a minimum and simple sample preparation. The proposed approach is a cost-effective and fast, green procedure that could be implemented in the near future by the tea industry.

scholarly journals Classification of Lampung robusta Specialty Coffee According to Differences in Cherry Processing Methods Using UV Spectroscopy and Chemometrics

Agriculture ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 109
Author(s):  
Diding Suhandy ◽  
Meinilwita Yulia
Keyword(s):  
Discriminant Analysis ◽  
Linear Discriminant Analysis ◽  
Uv Spectroscopy ◽  
Low Cost ◽  
Principal Component ◽  
Support Vector ◽  
Processing Methods ◽  
Linear Discriminant ◽  
Specialty Coffee ◽  
Supervised Classification Methods

The postharvest processing factors including cherry processing methods highly influence the final quality of coffee beverages, especially in the composition of several coffee metabolites such as glucose, fructose, the amino acid (glutamic acid), and chlorogenic acids (CGA) as well as trigonelline contents. In this research, UV spectroscopy combined with chemometrics was used to classify a ground roasted Lampung robusta specialty coffee according to differences in the cherry processing methods. A total of 360 samples of Lampung robusta specialty coffee with 1 g of weight for each sample from three different cherry processing methods were prepared as samples: 100 samples of pure dry coffee (DRY), 100 samples of pure semi-dry coffee (SMD), 100 samples of pure wet coffee (WET) and 60 samples of adulterated coffee (ADT) (SMD coffee was adulterated with DRY and WET coffee). All samples were extracted using a standard protocol as explained by previous works. A low-cost benchtop UV-visible spectrometer (Genesys™ 10S UV-Vis, Thermo Scientific, Waltham, MA, USA) was utilized to obtain UV spectral data in the interval of 190–400 nm using the fast scanning mode. Using the first three principal components (PCs) with a total of 93% of explained variance, there was a clear separation between samples. The samples were clustered into four possible groups according to differences in cherry processing methods: dry, semi-dry, wet, and adulterated. Four supervised classification methods, partial least squares–discriminant analysis (PLS-DA), principal component analysis–linear discriminant analysis (PCA-LDA), linear discriminant analysis (LDA) and support vector machine classification (SVMC) were selected to classify the Lampung robusta specialty coffee according to differences in the cherry processing methods. PCA-LDA is the best classification method with 91.7% classification accuracy in prediction. PLS-DA, LDA and SVMC give an accuracy of 56.7%, 80.0% and 85.0%, respectively. The present research suggested that UV spectroscopy combining with chemometrics will be highly useful in Lampung robusta specialty coffee authentication.

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