scholarly journals Detection of Glyphosate in Drinking Water: A Fast and Direct Detection Method without Sample Pretreatment

Sensors ◽  
2018 ◽  
Vol 18 (9) ◽  
pp. 2961 ◽  
Author(s):  
Jafar Noori ◽  
Maria Dimaki ◽  
John Mortensen ◽  
Winnie Svendsen

Glyphosate (Gly) is one of the most problematic pesticides that repeatedly appears in drinking water. Continuous on-site detection of Gly in water supplies can provide an early warning in incidents of contamination, before the pesticide reaches the drinking water. Here, we report the first direct detection of Gly in tap water with electrochemical sensing. Gold working electrodes were used to detect the pesticide in spiked tap water without any supporting electrolyte, sample pretreatment or electrode modifications. Amperometric measurements were used to quantify Gly to a limit of detection of 2 μM, which is below the regulation limit of permitted contamination of drinking water in the United States. The quantification of Gly was linearly proportional with the measured signal. The selectivity of this method was evaluated by applying the same technique on a Gly Metabolite, AMPA, and on another pesticide, omethoate, with a chemical structure similar to Gly. The testing revealed no interfering electrochemical activity at the potential range used for Gly detection. The simple detection of Gly presented in this work may lead to direct on-site monitoring of Gly contamination at drinking water sources.

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Pattan-Siddappa Ganesh ◽  
Ganesh Shimoga ◽  
Seok-Han Lee ◽  
Sang-Youn Kim ◽  
Eno E. Ebenso

Abstract Background A simple and simultaneous electrochemical sensing platform was fabricated by electropolymerization of allura red on glassy carbon electrode (GCE) for the interference-free detection of dihydroxy benzene isomers. Methods The modified working electrode was characterized by electrochemical and field emission scanning electron microscopy methods. The modified electrode showed excellent electrocatalytic activity for the electrooxidation of catechol (CC) and hydroquinone (HQ) at physiological pH of 7.4 by cyclic voltammetric (CV) and differential pulse voltammetric (DPV) techniques. Results The effective split in the overlapped oxidation signal of CC and HQ was achieved in a binary mixture with peak to peak separation of 0.102 V and 0.103 V by CV and DPV techniques. The electrode kinetics was found to be adsorption-controlled. The oxidation potential directly depends on the pH of the buffer solution, and it witnessed the transfer of equal number of protons and electrons in the redox phenomenon. Conclusions The limit of detection (LOD) for CC and HQ was calculated to be 0.126 μM and 0.132 μM in the linear range of 0 to 80.0 μM and 0 to 110.0 μM, respectively, by ultra-sensitive DPV technique. The practical applicability of the proposed sensor was evaluated for tap water sample analysis, and good recovery rates were observed. Graphical abstract Electrocatalytic interaction of ALR/GCE with dihydroxy benzene isomers.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
K. Chetankumar ◽  
B. E. Kumara Swamy ◽  
S. C. Sharma ◽  
S. A. Hariprasad

AbstractIn this proposed work, direct green 6 (DG6) decorated carbon paste electrode (CPE) was fabricated for the efficient simultaneous and individual sensing of catechol (CA) and hydroquinone (HY). Electrochemical deeds of the CA and HY were carried out by cyclic voltammetry (CV) and differential pulse voltammetry (DPV) at poly-DG6-modfied carbon paste electrode (Po-DG6-MCPE). Using scanning electron microscopy (SEM) studied the surface property of unmodified CPE (UCPE) and Po-DG6-MCPE. The decorated sensor displayed admirable electrocatalytic performance with fine stability, reproducibility, selectivity, low limit of detection (LLOD) for HY (0.11 μM) and CC (0.09 μM) and sensor process was originated to be adsorption-controlled phenomena. The Po-DG6-MCPE sensor exhibits well separated two peaks for HY and CA in CV and DPV analysis with potential difference of 0.098 V. Subsequently, the sensor was practically applied for the analysis in tap water and it consistent in-between for CA 93.25–100.16% and for HY 97.25–99.87% respectively.


2020 ◽  
Vol 4 (Supplement_2) ◽  
pp. 557-557
Author(s):  
Colin Rehm ◽  
Matthieu Maillot ◽  
Florent Vieux ◽  
Pamela Barrios ◽  
Adam Drewnowski

Abstract Objectives In the United States, replacing sugar-sweetened beverages (SSB) with plain drinking water is recommended via by numerous public health agencies and non-governmental organizations. While declines in SSB consumption in the US are well-documented, it is not clear if consumers are replacing SSBs with other beverages, namely plain drinking water. Methods Beverage consumption data for 7453 children (4–18y) and 15,263 adults (≥19y) came from two 24 h dietary recalls in three most recent cycles of the National Health and Nutrition Examination Survey (NHANES 2011–2016). Consumption trends for water intakes (in mL/d) from SSBs and from drinking water were analyzed by gender, age group, family income, and race/ethnicity. Results Mean water intakes from SSBs declined from 322 mL/d to 262 mL/d (p-trend = 0.002) on average, whereas plain drinking water increased from 1011 mL/d to 1144 mL/d (p-trend = 0.0108). Statistically significant reductions in SSBs were observed only among men (-18%), younger participants (-26% in 4–8, -22% in 9–13, -33% in 14–19 and -30% in 20–30), those with lower incomes (family income-to-poverty ratio < 2.0), non-Hispanic whites and non-Hispanic black participants (p-trend < 0.05 for each). Within these population sub-groups, only non-Hispanic white participants, those with a family income to poverty ratio of 1–1.99, but not < 1.0, and children aged < 14y had a corresponding increase in plain water consumption. When examining types of water, non-Hispanic white participants replaced SSBs with tap water as opposed to bottled water, and the lower income group replaced SSBs with bottled water, as opposed to tap water. Conclusions The expected replacement of SSBs with plain drinking water was not uniformly observed across socio-demographic group. Only non-Hispanic Whites and lower income groups replaced SSB with water, whereas teenagers (14–19y) and non-Hispanic black participants did not. Understanding how and if specific population sub-groups are replacing a declining food/beverage category with another category has important population health implications. Funding Sources Analyses of publicly available federal NHANES databases were sponsored by PepsiCo Inc. and conducted by MS-Nutrition. The views expressed in this abstract are those of the authors and do not necessarily reflect the position or policy of PepsiCo, Inc.


Water ◽  
2020 ◽  
Vol 12 (3) ◽  
pp. 888 ◽  
Author(s):  
Hannah Patton ◽  
Leigh-Anne Krometis ◽  
Emily Sarver

Issues surrounding water infrastructure, access, and quality are well documented in the Central Appalachian region of the United States. Even in cases where residents have in-home piped point-of-use (POU) water, some rely on alternative drinking water sources for daily needs—including water collection from roadside springs. This effort aims to better understand and document spring usage in this region by identifying the factors that influence drinking water source selection and comparing household and spring water quality to Safe Drinking Water Act (SDWA) health-based and aesthetic contaminant recommendations. Households were recruited from communities surrounding known springs in three states (Kentucky, Virginia, and West Virginia). First- and second-draw, in-home POU tap water samples were collected from participating households and compared to samples collected from local springs on the same day. Samples were analyzed for fecal indicator bacteria and inorganic ions. Study participants completed surveys to document perceptions of household drinking water and typical usage. The majority of survey participants (82.6%) did not trust their home tap water due to aesthetic issues. Water quality results suggested that fecal indicator bacteria were more common in spring water, while several metallic ions were recovered in higher concentrations from household samples. These observations highlight that health risks and perceptions may be different between sources.


2020 ◽  
Vol 23 (5) ◽  
pp. 167-176
Author(s):  
Abdul Haris Watoni ◽  
Indra Noviandri ◽  
Muhammad Nurdin ◽  
La Ode Ahmad Nur Ramadhan

The development of polypyrrole as a potential mediator membrane candidate for sodium dodecyl sulfate (SDS) sensor electrode has been investigated. The polypyrrole membrane was synthesized electrochemically from the pyrrole and coated at the surface of a 1.0 mm diameter of the gold-wire electrode. Electropolymerization of pyrrole and coating of the polypyrrole produced was performed by cyclic voltammetry technique in the electrochemical cell containing supporting electrolyte of 0.01 M NaClO4 with an optimum potential range of -0.9 V–1.0 V, the scanning rate of 100 mV/s, an electric current of 2 mA, and running of potential scanning of 10 cycles. By using the similar optimal parameters of cyclic voltammetry, electropolymerization of 0.01 M pyrrole solution containing 0.001 M SDS also produces a polypyrrole membrane coated at the gold-wire electrode surface. These coated electrodes have the potential response-ability toward DS- anions in the concentration range of 10-7 M–10-5 M with a limit of detection of 10-7 M and sensitivity of electrode of 9.9 mV/decade. This finding shows that the SDS solution’s role is as supporting electrolyte and also as a source of DS- dopant during the pyrrole electropolymerization processes. Dopants are trapped in the polymer membrane during the electrochemical formation of polypyrrole and role as ionophores for DS- anion in the analyte solution. A potential response to the electrode phenomena is excellent basic scientific information for further synthesis of conducting polymer and development of conducting polymer-coated wire electrode model, especially in the construction of ion-selective electrode (ISE) for the determination of anionic surfactants with those models.


Water ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2097
Author(s):  
Louise Feld ◽  
Vitor Hugo da Silva ◽  
Fionn Murphy ◽  
Nanna B. Hartmann ◽  
Jakob Strand

Microplastics (MPs) are omnipresent in our surroundings and in the environment, with drinking water being a potential pathway for human exposure. This study investigated the presence of MPs in Danish drinking water from 17 different households and workplaces in Denmark. Samples of tap water were collected using a closed sampling system to decrease airborne contamination, and QA/QC measurements were performed to assess background contamination. Particles >100 µm were visually analysed by stereomicroscopy in combination with spectroscopy analysis (µ-FTIR) to evaluate morphology and chemical composition. An assessment of MP particles down to 10 µm was performed on water samples from three locations using hyperspectral image analysis. The results indicate a low level of MPs in Danish drinking water, with a total of seven MP particles across all samples, comprising PET, PP, PS, and ABS. Microfibers were the most common type of MP-like particles in both drinking water and blanks, but the concentration for all samples was below the limit of detection and could not be differentiated from background contamination. Most of the particles analysed by µ-FTIR were identified as cellulose fibres and a smaller subset as protein. Based on this work, we discuss the status of MP drinking water studies and address challenges and limitations regarding the analysis of MP in drinking water.


Biosensors ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 413
Author(s):  
Jong-Won Park ◽  
Lee-Woon Jang ◽  
Erik C. Jensen ◽  
Amanda Stockton ◽  
Jungkyu Kim

Toxic organochloride molecules are widely used in industry for various purposes. With their high volatility, the direct detection of organochlorides in environmental samples is challenging. Here, a new organochloride detection mechanism using 1,5-diazabicyclo[4.3.0]non-5-ene (DBN) is introduced to simplify a sensing method with higher detection sensitivity. Three types of organochloride compounds-trichloroethylene (TCE), dichloromethane (DCM), and dichlorodiphenyltrichloroethane (DDT)—were targeted to understand DCM conjugation chemistry by using nuclear magnetic resonance (NMR) and liquid chromatography with a mass spectrometer (LC-MS). 13C-NMR spectra and LC-MS data indicated that DBN can be labeled on these organochloride compounds by chlorine–nitrogen interaction. Furthermore, to demonstrate the organochloride sensing capability, the labeling yield and limit of detection were determined by a colorimetric assay as well as micellar electrokinetic chromatography (MEKC). The interaction with DBN was most appreciable for TCE, among other organochlorides. TCE was detected at picomolar levels, which is two orders of magnitude lower than the maximum contaminant level set by the United States Environmental Protection Agency. MEKC, in conjunction with this DBN-labeling method, enables us to develop a field-deployable sensing platform for detecting toxic organochlorides with high sensitivity.


2011 ◽  
Vol 9 (1) ◽  
pp. 1-9 ◽  
Author(s):  
Pinar Omur-Ozbek ◽  
Andrea M. Dietrich

Drinking water flavour has a strong role in water quality perception, service satisfaction, willingness to pay and selection of water sources. Metallic flavours are often caused by the dissolved iron and copper, commonly found in groundwater or introduced to tap water by corroding infrastructure. Taste thresholds of iron and copper have been investigated by several studies; however, reported results and test methods vary considerably. This study determined the taste thresholds of ferrous and cuprous ions in room temperature reagent water by using the one-of-five test with multi-nation panellists in the United States. For ferrous and cuprous ions, individual thresholds ranged from 0.003 to >5 mg l−1 and 0.035 to >5 mg l−1, respectively. Population thresholds were determined by logistic regression and geometric mean methods as 0.031 and 0.05 mg l−1 for ferrous ion, and 0.61 mg l−1 for cuprous ion by both methods. The components of metallic sensation were investigated by use of nose-clips while panellists ingested iron and copper solutions. Results showed that metallic sensation has a significant odour component and should be treated as a flavour instead of a taste. Ferrous, cuprous and cupric ions also produced weak bitter and salty tastes as well as astringent mouthfeel. In comparison, ferric ion produced no sensation.


2021 ◽  
Vol 19 (1) ◽  
pp. 481-491
Author(s):  
Jamil A. Buledi ◽  
Sidra Ameen ◽  
Saba A. Memon ◽  
Almas Fatima ◽  
Amber R. Solangi ◽  
...  

Abstract This study displays the facile and fluent electrochemical determination of uric acid (UA) through exceptional copper oxide nanostructures (CuO), as an effective sensing probe. The copper oxide nanostructures were fabricated via an aqueous chemical growth method using sodium hydroxide as a reducing agent, which massively hold hydroxide source. Copper oxide nanostructures showed astonishing electrocatalytic behavior in the detection of UA. Different characterization techniques such as XRD, FESEM, and EDS were exploited to determine crystalline nature, morphologies, and elemental composition of synthesized nanostructures. The cyclic voltammetry (CV) was subjected to investigate the electrochemical performance of UA using copper oxide nanostructures modified glassy carbon electrode CuO/GCE. The CV parameters were optimized at a scan rate of 50 mV/s with −0.7 to 0.9 potential range, and the UA response was investigated at 0.4 mV. PBS buffer of pH 7.4 was exploited as a supporting electrolyte. The linear dynamic range for UA was 0.001–351 mM with a very low limit of detection observed as 0.6 µM. The proposed sensor was successfully applied in urine samples for the detection of UA with improved sensitivity and selectivity.


2020 ◽  
Author(s):  
Kombo Mpindou Gilver Odilon Mendel ◽  
Chorda Ramon Estela ◽  
Garcia Ganzalez Eva

<p>In developing countries, diseases related to lack of water or inadequate water quality cause the death of approximately 5 million people annually, of whom about 1.8 million die from diarrhoeal diseases, 90% of them being children under five, which is equivalent to 4,500 children per day (WHO, 2004; Rojas, 2006). The WHO reports that improvements in water quality alone reduce morbidity from diarrhoeal diseases by a third or more (WHO, 2007), and drinking water treatment plants  are currently the focus of Protozoan studies on water supply. Giardia and Crytosporidium are two of the protozoa that are currently of greatest interest due to their resistance to conventional disinfection processes (Johnson et al., 2003), and they can exist in the presence of high concentrations of free chlorine (Corbitt, 1999). A reality that confirms this fact is that 98% of the individuals affected by epidemic outbreaks in the United States were supplied by drinking water plants using a conventional treatment system.</p><p>The DWTP of the Dam that caters 859885 people, corresponds to a series of municipalities in the northern area of the metropolitan area of Valencia (Spain), and the central-north-western districts of the city of Valencia face this problem. In a study conducted from 2006 to 2010, in the water used for human consumption in the city of Valencia, some positive concentrations of networked oocysts were detected. In conclusion, it is possible that the protozoa entered the network, as the analyses indicate, and that the pathology exists in the environment although no outbreaks have been recorded to date. Given that it is present in raw water, it is very convenient and interesting to develop a tool capable of evaluating the water treatment process, from production to the consumer, a useful tool for operators as a support for decision-making. The campaign was carried out throughout the year, taking a weekly sample, the analyses were made with the EPA1623 method. A survey was also carried out in person on volunteers who indicate their age, sex, postal code o and number of glasses of tap water ingested. The purpose of this study was to show how an artificial neural network  can be useful to predict the consumption of pathogenic microorganisms. More specifically, the aim is to develop a backpropagation type neuronal network capable of discriminating between those who consume and those who do not, based on the answers given by the subjects to a questionnaire, with the main objective of demonstrating the usefulness of the methodology based on neuronal networks for risk stratification, applying it to the calculation of the probability of the annual risk of individual contamination of the population supplied</p>


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