scholarly journals Quantitative Retrieval of Organic Soil Properties from Visible Near-Infrared Shortwave Infrared (Vis-NIR-SWIR) Spectroscopy Using Fractal-Based Feature Extraction

2016 ◽  
Vol 8 (12) ◽  
pp. 1035 ◽  
Author(s):  
Lanfa Liu ◽  
Min Ji ◽  
Yunyun Dong ◽  
Rongchung Zhang ◽  
Manfred Buchroithner
Keyword(s):  
Feature Extraction ◽  
Soil Properties ◽  
Near Infrared ◽  
Organic Soil ◽  
Shortwave Infrared

Two-Dimensional Near-Infrared and Shortwave Infrared Molecular Aggregates: Taking Kasha’s Model to the Next Dimension

2019 ◽  
Author(s):  
Arundhati Deshmukh ◽  
Danielle Koppel ◽  
Chern Chuang ◽  
Danielle Cadena ◽  
Jianshu Cao ◽  
...  
Keyword(s):  
Near Infrared ◽  
Photophysical Properties ◽  
Satellite Telemetry ◽  
Transition Dipole Moment ◽  
Short Wave ◽  
Tissue Imaging ◽  
Transition Dipole ◽  
Deep Tissue Imaging ◽  
Excitonic States ◽  
Shortwave Infrared

Technologies which utilize near-infrared (700 – 1000 nm) and short-wave infrared (1000 – 2000 nm) electromagnetic radiation have applications in deep-tissue imaging, telecommunications and satellite telemetry due to low scattering and decreased background signal in this spectral region. However, there are few molecular species, which absorb efficiently beyond 1000 nm. Transition dipole moment coupling (e.g. J-aggregation) allows for redshifted excitonic states and provides a pathway to highly absorptive electronic states in the infrared. We present aggregates of two cyanine dyes whose absorption peaks redshift dramatically upon aggregation in water from ~ 800 nm to 1000 nm and 1050 nm with sheet-like morphologies and high molar absorptivities (e ~ 10<sup>5 </sup>M<sup>-1</sup>cm<sup>-1</sup>). To describe this phenomenology, we extend Kasha’s model for J- and H-aggregation to describe the excitonic states of <i> 2-dimensional aggregates</i> whose slip is controlled by steric hindrance in the assembled structure. A consequence of the increased dimensionality is the phenomenon of an <i>intermediate </i>“I-aggregate”, one which redshifts yet displays spectral signatures of band-edge dark states akin to an H-aggregate. We distinguish between H-, I- and J-aggregates by showing the relative position of the bright (absorptive) state within the density of states using temperature dependent spectroscopy. Our results can be used to better design chromophores with predictable and tunable aggregation with new photophysical properties.

scholarly journals Identification of peat type and humification by laboratory VNIR/SWIR hyperspectral imaging of peat profiles with focus on fen-bog transition in aapa mires

2020 ◽  
Author(s):  
L. Granlund ◽  
M. Keinänen ◽  
T. Tahvanainen
Keyword(s):  
Hyperspectral Imaging ◽  
Near Infrared ◽  
Support Vector ◽  
High Resolution Imaging ◽  
Factors Affecting ◽  
Vector Machines ◽  
Resolution Imaging ◽  
Shortwave Infrared ◽  
Type Classification ◽  
Wide Potential

Abstract Aims Hyperspectral imaging (HSI) has high potential for analysing peat cores, but methodologies are deficient. We aimed for robust peat type classification and humification estimation. We also explored other factors affecting peat spectral properties. Methods We used two laboratory setups: VNIR (visible to near-infrared) and SWIR (shortwave infrared) for high resolution imaging of intact peat profiles with fen-bog transitions. Peat types were classified with support vector machines, indices were developed for von Post estimation, and K-means clustering was used to analyse stratigraphic patterns in peat quality. With separate experiments, we studied spectral effects of drying and oxidation. Results Despite major effects, oxidation and water content did not impede robust HSI classification. The accuracy between Carex peat and Sphagnum peat in validation was 80% with VNIR and 81% with SWIR data. The spectral humification indices had accuracies of 82% with VNIR and 56%. Stratigraphic HSI patterns revealed that 36% of peat layer shifts were inclined by over 20 degrees. Spectral indices were used to extrapolate visualisations of element concentrations. Conclusions HSI provided reliable information of basic peat quality and was useful in visual mapping, that can guide sampling for other analyses. HSI can manage large amounts of samples to widen the scope of detailed analysis beyond single profiles and it has wide potential in peat research beyond the exploratory scope of this paper. We were able to confirm the capacity of HSI to reveal shifts of peat quality, connected to ecosystem-scale change.

scholarly journals Mineral Detection Using Sharpened VNIR and SWIR Bands of Worldview-3 Satellite Imagery

2021 ◽  
Vol 13 (10) ◽  
pp. 5518
Author(s):  
Honglyun Park ◽  
Jaewan Choi
Keyword(s):  
Spatial Resolution ◽  
Satellite Imagery ◽  
Near Infrared ◽  
False Negative ◽  
Similarity Score ◽  
Majority Voting ◽  
Similarity Analysis ◽  
Spectral Angle Mapper ◽  
Mineral Detection ◽  
Shortwave Infrared

Worldview-3 satellite imagery provides panchromatic images with a high spatial resolution and visible near infrared (VNIR) and shortwave infrared (SWIR) bands with a low spatial resolution. These images can be used for various applications such as environmental analysis, urban monitoring and surveying for sustainability. In this study, mineral detection was performed using Worldview-3 satellite imagery. A pansharpening technique was applied to the spatial resolution of the panchromatic image to effectively utilize the VNIR and SWIR bands of Worldview-3 satellite imagery. The following representative similarity analysis techniques were implemented for the mineral detection: the spectral angle mapper (SAM), spectral information divergence (SID) and the normalized spectral similarity score (NS3). In addition, pixels that could be estimated to indicate minerals were calculated by applying an empirical threshold to each similarity analysis result. A majority voting technique was applied to the results of each similarity analysis and pixels estimated to indicate minerals were finally selected. The results of each similarity analysis were compared to evaluate the accuracy of the proposed methods. From that comparison, it could be confirmed that false negative and false positive rates decreased when the methods proposed in the present study were applied.

scholarly journals Spectral Complexity of Hyperspectral Images: A New Approach for Mangrove Classification

2021 ◽  
Vol 13 (13) ◽  
pp. 2604
Author(s):  
Patrick Osei Darko ◽  
Margaret Kalacska ◽  
J. Pablo Arroyo-Mora ◽  
Matthew E. Fagan
Keyword(s):  
Statistical Physics ◽  
Near Infrared ◽  
Information Gain ◽  
Hyperspectral Imagery ◽  
Full Range ◽  
Surface Reflectance ◽  
Mangrove Species ◽  
New Approach ◽  
Spatio Temporal ◽  
Shortwave Infrared

Hyperspectral remote sensing across multiple spatio-temporal scales allows for mapping and monitoring mangrove habitats to support urgent conservation efforts. The use of hyperspectral imagery for assessing mangroves is less common than for terrestrial forest ecosystems. In this study, two well-known measures in statistical physics, Mean Information Gain (MIG) and Marginal Entropy (ME), have been adapted to high spatial resolution (2.5 m) full range (Visible-Shortwave-Infrared) airborne hyperspectral imagery. These two spectral complexity metrics describe the spatial heterogeneity and the aspatial heterogeneity of the reflectance. In this study, we compare MIG and ME with surface reflectance for mapping mangrove extent and species composition in the Sierpe mangroves in Costa Rica. The highest accuracy for separating mangroves from forest was achieved with visible-near infrared (VNIR) reflectance (98.8% overall accuracy), following by shortwave infrared (SWIR) MIG and ME (98%). Our results also show that MIG and ME can discriminate dominant mangrove species with higher accuracy than surface reflectance alone (e.g., MIG–VNIR = 93.6% vs. VNIR Reflectance = 89.7%).

scholarly journals Hazardous Noxious Substance Detection Based on Ground Experiment and Hyperspectral Remote Sensing

2021 ◽  
Vol 13 (2) ◽  
pp. 318
Author(s):  
Jae-Jin Park ◽  
Kyung-Ae Park ◽  
Pierre-Yves Foucher ◽  
Philippe Deliot ◽  
Stephane Le Floch ◽  
...  
Keyword(s):  
Near Infrared ◽  
Spectral Characteristics ◽  
Chemical Properties ◽  
Principal Component ◽  
Component Analysis ◽  
Noise Removal ◽  
Vertex Component Analysis ◽  
Shortwave Infrared ◽  
Spectral Mixture ◽  
Physical And Chemical

With an increase in the overseas maritime transport of hazardous and noxious substances (HNSs), HNS-related spill accidents are on the rise. Thus, there is a need to completely understand the physical and chemical properties of HNSs. This can be achieved through establishing a library of spectral characteristics with respect to wavelengths from visible and near-infrared (VNIR) bands to shortwave infrared (SWIR) wavelengths. In this study, a ground HNS measurement experiment was conducted for artificially spilled HNS by using two hyperspectral cameras at VNIR and SWIR wavelengths. Representative HNSs such as styrene and toluene were spilled into an outdoor pool and their spectral characteristics were obtained. The relative ratio of HNS to seawater decreased and increased at 550 nm and showed different constant ratios at the SWIR wavelength. Noise removal and dimensional compression procedures were conducted by applying principal component analysis on HNS hyperspectral images. Pure HNS and seawater endmember spectra were extracted using four spectral mixture techniques—N-FINDR, pixel purity index (PPI), independent component analysis (ICA), and vertex component analysis (VCA). The accuracy of detection values of styrene and toluene through the comparison of the abundance fraction were 99.42% and 99.56%, respectively. The results of this study are useful for spectrum-based HNS detection in marine HNS accidents.

scholarly journals Algorithm theoretical baseline for formaldehyde retrievals from S5P TROPOMI and from the QA4ECV project

2018 ◽  
Vol 11 (4) ◽  
pp. 2395-2426 ◽  
Author(s):  
Isabelle De Smedt ◽  
Nicolas Theys ◽  
Huan Yu ◽  
Thomas Danckaert ◽  
Christophe Lerot ◽  
...  
Keyword(s):  
Near Infrared ◽  
Horizontal Resolution ◽  
Retrieval Algorithm ◽  
User Requirements ◽  
Vertical Column ◽  
Ultraviolet Range ◽  
Order Of Magnitude ◽  
Shortwave Infrared ◽  
Double Channel ◽  
The Eu

Abstract. On board the Copernicus Sentinel-5 Precursor (S5P) platform, the TROPOspheric Monitoring Instrument (TROPOMI) is a double-channel, nadir-viewing grating spectrometer measuring solar back-scattered earthshine radiances in the ultraviolet, visible, near-infrared, and shortwave infrared with global daily coverage. In the ultraviolet range, its spectral resolution and radiometric performance are equivalent to those of its predecessor OMI, but its horizontal resolution at true nadir is improved by an order of magnitude. This paper introduces the formaldehyde (HCHO) tropospheric vertical column retrieval algorithm implemented in the S5P operational processor and comprehensively describes its various retrieval steps. Furthermore, algorithmic improvements developed in the framework of the EU FP7-project QA4ECV are described for future updates of the processor. Detailed error estimates are discussed in the light of Copernicus user requirements and needs for validation are highlighted. Finally, verification results based on the application of the algorithm to OMI measurements are presented, demonstrating the performances expected for TROPOMI.

scholarly journals Shortwave Infrared Imaging with J-Aggregates Stabilized in Hollow Mesoporous Silica Nanoparticles

2018 ◽  
Author(s):  
Wei Chen ◽  
ChiAn Cheng ◽  
Emily Cosco ◽  
Shyam Ramakrishnan ◽  
Jakob Lingg ◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Contrast Agents ◽  
Silica Nanoparticles ◽  
Near Infrared ◽  
Infrared Imaging ◽  
Mesoporous Silica Nanoparticles ◽  
J Aggregates ◽  
Hollow Mesoporous Silica ◽  
Shortwave Infrared

Tissue is translucent to shortwave infrared (SWIR) light, rendering optical imaging superior in this region. However, the widespread use of optical SWIR imaging has been limited, in part, by the lack of bright, biocompatible contrast agents that absorb and emit light above 1000 nm. J-aggregation offers a means to transform stable, near-infrared (NIR) fluorophores into red-shifted SWIR contrast agents. Here we demonstrate that hollow mesoporous silica nanoparticles (HMSNs) can template the J-aggregation of NIR fluorophore IR-140 to result in nanomaterials that absorb and emit SWIR light. The J-aggregates inside PEGylated HMSNs are stable for multiple weeks in buffer and enable high resolution imaging <i>in vivo</i>with 980 nm excitation.

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